8 Prop Coligativas

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\pard\li4773\ri0\sl-440\slmult0 \fs22\cf0\f0\charscalex100\b {PRACTICA 8 }\b0 \
par\pard\li3813\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100\b {PROPIEDADES COL
IGATIVAS }\b0 \par\pard\li1000\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100\b {
ELEVACION DEL PUNTO DE EBULLICION DE UN LIQUIDO EN PRESENCIA DE UN}\b0 \par\pard
\li4240\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100\b {SOLUTO NO VOLATIL }\b0
\par\pard\sect\sectd\sbknone\cols2\colno1\colw4906\colsr-0\colno2\colw6533\pard\
li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\p
ar\pard\li920\ri0\sl-426\slmult0 \fs22\cf0\f0\charscalex100\ul {Material}\ul0 \p
ar\pard\li920\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100 {1 probeta de 100 mL
}\par\pard\li920\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100 {2 matraces esfri
cos 50 mL }\par\pard\li920\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100 {3 tapo
nes de goma }\par\pard\li920\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100 {2 ba
ses de corcho }\par\pard\li920\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100 {2
vasos de precipitados de 100 mL }\par\pard\li920\ri0\sl-253\slmult0 \fs22\cf0\f
0\charscalex100 {Perlas de vidrio}\par\pard\li920\ri0\sl-266\slmult0 \fs22\cf0\f
0\charscalex100 {Agitador magntico }\par\pard\li920\ri0\sl-253\slmult0 \fs22\cf0\
f0\charscalex100 {Bao para refrigerar matraces }\par\pard\li920\ri0\sl-266\slmult
0 \fs22\cf0\f0\charscalex100 {Embudo para slidos}\par\column\pard\li0\ri0\sl-213\
slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl426\slmult0 \fs22\cf0\f0\charscalex100\ul {Productos}\ul0 \fs22\cf0\f0\charscale
x100\ul { }\ul0 \par\pard\li13\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100 {Ac
etona}\par\pard\li13\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100 {Acetanilida}
\par\pard\li13\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100 {Sustancia X }\par\
pard\li13\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100 {Cloruro de sodio }\par\
pard\li13\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100 {Sulfato de sodio }\par\
pard\li13\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100 {Cloruro de aluminio }\p
ar\pard\sect\sectd\sbknone\cols2\colno1\colw9866\colsr-0\colno2\colw1573\pard\li
920\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100 {Aparato de destilacin con cont
rolador Cobra}\par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\ri0\sl
-213\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li92
0\ri0\sl-426\slmult0 \fs22\cf0\f0\charscalex100\b {Objetivos}\b0 \fs22\cf0\f0\ch
arscalex100\b { }\b0 \par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920
\ri0\sl-280\slmult0 \fs22\cf0\f0\charscalex100 {El alumno/a debe ser capaz de:}\

par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-213\slmult0 \f
s18\cf0\par\pard\li920\ri0\sl-346\slmult0 \fs22\cf0\f0\charscalex100\b {A) Objet
ivos Generales}\b0 \par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\r
i0\sl-306\slmult0 \fs22\cf0\f0\charscalex100 {1. Determinar la constante ebullos
cpica de la acetona. }\par\pard\li920\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex1
00 {2. Determinar la masa molecular de un slido por ebulloscopa. }\par\pard\li920\
ri0\sl-400\slmult0 \fs22\cf0\f0\charscalex100 {3. Determinar coeficientes de }\
fs22\cf0\f0\charscalex100 {Vant Hoff para solutos inicos.}\par\pard\li920\ri0\sl-3
86\slmult0 \fs22\cf0\f0\charscalex100 {4. Plantear un esquema de la prctica, en d
onde se especifique:}\par\pard\li1320\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex
100 {i) El procedimiento experimental utili}\fs22\cf0\f0\charscalex100 {zado par
a obtener las magnitudes necesarias.}\par\pard\li1320\ri0\sl-386\slmult0 \fs22\c
f0\f0\charscalex100 {ii) El procedimiento de clculo que permite determinar dichas
magnitudes.}\par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\ri0\sl213\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920
\ri0\sl-400\slmult0 \fs22\cf0\f0\charscalex100\b {B) Objetivos Experimentales}\b
0 \fs22\cf0\f0\charscalex100\b { }\b0 \par\pard\li920\ri0\sl-213\slmult0 \fs18\c
f0\par\pard\li920\ri0\sl-306\slmult0 \fs22\cf0\f0\charscalex100 {1. Manejar adec
uadamente el material volumtrico. }\par\pard\li920\ri0\sl-386\slmult0 \fs22\cf0\f
0\charscalex100 {2. Preparar disoluciones de concentracin (molal) conocida a part
ir de reactivos slidos. }\par\pard\li920\ri0\sl-386\slmult0 \fs22\cf0\f0\charscal
ex100 {3. Pesar correctamente el matraz de fondo redondo en}\fs22\cf0\f0\charsca
lex100 { las diferentes etapas de la experiencia. }\par\pard\li920\ri0\sl-400\sl
mult0 \fs22\cf0\f0\charscalex100 {4. Aadir correctamente los diferent}\fs22\cf0\f
0\charscalex100 {es solutos (acetanilida , benzona}\fs22\cf0\f0\charscalex100 {
o la sal inica) al matraz}\par\pard\li1320\ri0\sl-386\slmult0 \fs22\cf0\f0\chars
calex100 {redondo correspondiente.}\par\pard\li920\ri0\sl-386\slmult0 \fs22\cf0\
f0\charscalex100 {5. Manejo del equipo de destilacin. }\par\pard\li920\ri0\sl-386
\slmult0 \fs22\cf0\f0\charscalex100 {6. Manejo y calibrado del multiparmetro Cobr
a. }\par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-213\slmul
t0 \fs18\cf0\par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-2
13\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\
ri0\sl-373\slmult0 \fs18\cf0\f0\charscalex100 {Laboratorio de Qumica Fsica(09-10),
Grupo Innovacin, P8 }\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\
li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\p
ard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\p
ar\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\c
f0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs
18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0
\fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slm
ult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213
\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl
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0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li
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d\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par
\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0
\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18
\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \
fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmul
t0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\s
lmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-2
13\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\
sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\
ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\
ard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-400\slmult0 \fs22\cf0\f
0\charscalex100 {1}\par\pard\sect\sectd\sbknone\pard\sect\sectd\sbkpage
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3\margtsxn666\margbsxn93\pard\li920\ri0\sl-400\slmult0 \fs22\cf0\f0\charscalex10
0\b \ul {C) Objetivos Conceptuales}\b0 \ul0 \fs22\cf0\f0\charscalex100\b \ul { }

\b0 \ul0 \par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-306\
slmult0 \*\tx1320\fs22\cf0\f0\charscalex100 {1.}\tab \fs22\cf0\f0\charscalex100
{Propiedades coligativas asociadas a una disoluci}\fs22\cf0\f0\charscalex100 {n d
e un soluto no voltil en un disolvente. }\par\pard\li920\ri0\sl-386\slmult0 \*\tx
1320\fs22\cf0\f0\charscalex100 {2.}\tab \fs22\cf0\f0\charscalex100 {Conocer el d
iagrama de fases de una sustancia pura.}\par\pard\li920\ri0\sl-386\slmult0 \*\tx
1320\fs22\cf0\f0\charscalex100 {3.}\tab \fs22\cf0\f0\charscalex100 {Conocer la i
nfluencia de la adicin de un soluto no voltil sobre la presin de vapor de un lquido}
\par\pard\li1320\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {puro.}\par\pard\
li920\ri0\sl-386\slmult0 \*\tx1320\fs22\cf0\f0\charscalex100 {4.}\tab \fs22\cf0\
f0\charscalex100 {Conocer la influencia de la adicin de un soluto no voltil sobre
la temperatura de un lquido puro. }\par\pard\li920\ri0\sl-400\slmult0 \*\tx1320\f
s22\cf0\f0\charscalex100 {5.}\tab \fs22\cf0\f0\charscalex100 {Definicin de la con
stante ebulloscpica y sus unidades.}\par\pard\li920\ri0\sl-386\slmult0 \*\tx1320\
fs22\cf0\f0\charscalex100 {6.}\tab \fs22\cf0\f0\charscalex100 {Definicin de molal
idad de una disolucin y sus unidades. }\par\pard\li920\ri0\sl-386\slmult0 \*\tx13
20\fs22\cf0\f0\charscalex100 {7.}\tab \fs22\cf0\f0\charscalex100 {Aplicacin de la
elevacin del punto de e}\fs22\cf0\f0\charscalex100 {bullicin al clculo de masas mo
leculares. }\par\pard\li920\ri0\sl-386\slmult0 \*\tx1320\fs22\cf0\f0\charscalex1
00 {8.}\tab \fs22\cf0\f0\charscalex100 {Definir electrolito.}\par\pard\li920\ri0
\sl-386\slmult0 \*\tx1320\fs22\cf0\f0\charscalex100 {9.}\tab \fs22\cf0\f0\charsc
alex100 {Definir grado de disociacin. }\par\pard\li920\ri0\sl-400\slmult0 \*\tx13
20\fs22\cf0\f0\charscalex100 {10.}\tab \fs22\cf0\f0\charscalex100 {Definir facto
r i de Van\uc1\u8217Xt Hoff. }\par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\
pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-213\slmult0 \fs18\
cf0\par\pard\li920\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100\b {D) Objetivos
ligados al desarrollo de }\b0 \fs22\cf0\f0\charscalex100\b {la prctica y obtencin
de resultados}\b0 \par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\r
i0\sl-346\slmult0 \fs22\cf0\f0\charscalex100 {1. Calcular la molalidad de cada u
na de las disoluciones de acetanilida preparadas. }\par\pard\li920\ri0\sl-386\sl
mult0 \fs22\cf0\f0\charscalex100 {2. Medir la T}\fs14\cf0\f0\charscalex100 {eb}\
fs22\cf0\f0\charscalex100 { de las disoluciones de acetanilida en acetona. }\par
\pard\li920\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {3. Obtener }\fs22\cf0
\f0\charscalex100 {la K}\fs14\cf0\f0\charscalex100 {eb}\fs22\cf0\f0\charscalex10
0 { experimental de la acetona a partir de la representacin grfica de }\fs22\cf0\f
0\charscalex100 {\uc1\u8710X}\fs22\cf0\f0\charscalex100 {T}\fs14\cf0\f0\charscal
ex100 {eb}\fs22\cf0\f0\charscalex100 { vs. molalidad }\par\pard\li1320\ri0\sl-38
6\slmult0 \fs22\cf0\f0\charscalex100 {(uso hoja Excel). }\par\pard\li920\ri0\sl400\slmult0 \fs22\cf0\f0\charscalex100 {4. Obtener las fracciones molares de las
disoluciones de acetanilida en acetona. }\par\pard\li920\ri0\sl-386\slmult0 \fs
22\cf0\f0\charscalex100 {5. Obtener la K}\fs14\cf0\f0\charscalex100 {eb}\fs22\cf
0\f0\charscalex100 { experimental de la acetona a partir de la representacin grfic
a de }\fs22\cf0\f0\charscalex100 {\uc1\u8710X}\fs22\cf0\f0\charscalex100 {T}\fs1
4\cf0\f0\charscalex100 {eb}\fs22\cf0\f0\charscalex100 { vs. fraccin }\par\pard\li
1320\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {molar (uso hoja Excel).}\par
\pard\li920\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {6. Comparar los dos v
alores experimentales de K}\fs14\cf0\f0\charscalex100 {eb}\fs22\cf0\f0\charscale
x100 { (a partir de molalidad y de fraccin molar).}\par\pard\li920\ri0\sl-400\slm
ult0 \fs22\cf0\f0\charscalex100 {7. Obtener la K}{\sub \fs14\cf0\f0\charscalex10
0 {eb}}\fs22\cf0\f0\charscalex100 { terica utilizando el valor de }\fs22\cf0\f0\c
harscalex100 {\uc1\u8710X}\fs22\cf0\f0\charscalex100 {H}{\sub \fs14\cf0\f0\chars
calex100 {vap}}\fs22\cf0\f0\charscalex100 { y T}{\sub \fs14\cf0\f0\charscalex100
{vap}}\fs22\cf0\f0\charscalex100 { de la acetona que puedes encontrar en una}\p
ar\pard\li1320\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {base de datos (p.e
. http://chemnetbase.com/).}\par\pard\li920\ri0\sl-386\slmult0 \fs22\cf0\f0\char
scalex100 {8. Comparar el valor terico de K}\fs14\cf0\f0\charscalex100 {eb}\fs22\
cf0\f0\charscalex100 { con los experimentales anterior}\fs22\cf0\f0\charscalex10
0 {es, analizando las aproximaciones}\par\pard\li1320\ri0\sl-386\slmult0 \fs22\c
f0\f0\charscalex100 {realizadas en la deduccin de la ecuacin terica. }\par\pard\li9
20\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {9. Obtener la expresin que perm

ite determinar la ma}\fs22\cf0\f0\charscalex100 {sa molecular de un soluto }\fs2
2\cf0\f0\charscalex100 {desconocido a partir de}\par\pard\li1320\ri0\sl-386\slmu
lt0 \fs22\cf0\f0\charscalex100 {la tcnica ebulloscpica. }\par\pard\li920\ri0\sl-40
0\slmult0 \fs22\cf0\f0\charscalex100 {10. Determinar la masa molecular de un sol
uto desc}\fs22\cf0\f0\charscalex100 {onocido por ebulloscopa: a partir de la temp
eratura}\par\pard\li1320\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {de ebull
icin de la disolucin soluto/acetona correspondiente.}\par\pard\li920\ri0\sl-386\sl
mult0 \fs22\cf0\f0\charscalex100 {11. Obtener la expresin del factor i de VantHoff
en funcin de la T}\fs14\cf0\f0\charscalex100 {eb}\fs22\cf0\f0\charscalex100 { y
de la concentracin molar de}\par\pard\li1320\ri0\sl-386\slmult0 \fs22\cf0\f0\char
scalex100 {una disolucin inica. }\par\pard\li920\ri0\sl-400\slmult0 \fs22\cf0\f0\c
harscalex100 {12. Calcular los factores i de VantHoff de dife}\fs22\cf0\f0\charsc
alex100 {rentes disoluciones acuosas de solutos inicos. }\par\pard\li920\ri0\sl-3
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0\b \ul {Fundamentos}\b0 \ul0 \fs22\cf0\f0\charscalex100\b \ul { }\b0 \ul0 \par\
cf0\f0\charscalex100 {Se denominan propiedades coligativas a las propied}\fs22\c
f0\f0\charscalex100 {ades fsicas de las disoluciones que dependen }\par\pard\li92
0\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100 {del nmero y no de la naturaleza
de las partculas }\fs22\cf0\f0\charscalex100 {de soluto no voltil, disuelto en una
cantidad de}\par\pard\li920\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100 {diso
lvente. }\par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-306\
slmult0 \fs22\cf0\f0\charscalex100 {Las propiedades coligativas son cuatro: }\pa
r\pard\li1266\ri0\sl-280\slmult0 \*\tx1600\fs22\cf0\f0\charscalex100 {\uc1\u8226
X}\tab \fs22\cf0\f0\charscalex100 {Descenso de la presin de vapor.}\par\pard\li12
66\ri0\sl-280\slmult0 \*\tx1600\fs22\cf0\f0\charscalex100 {\uc1\u8226X}\tab \fs2

2\cf0\f0\charscalex100 {Elevacin de la temperatura de ebullicin. }\par\pard\li1266
\ri0\sl-280\slmult0 \*\tx1600\fs22\cf0\f0\charscalex100 {\uc1\u8226X}\tab \fs22\
cf0\f0\charscalex100 {Descenso de la temperatura de fusin. }\par\pard\li1266\ri0\
sl-280\slmult0 \*\tx1600\fs22\cf0\f0\charscalex100 {\uc1\u8226X}\tab \fs22\cf0\f
0\charscalex100 {Generacin de una presin osmtica. }\par\pard\li920\ri0\sl-213\slmul
t0 \fs18\cf0\par\pard\li920\ri0\sl-293\slmult0 \fs22\cf0\f0\charscalex100 {En es
ta prctica vamos a estudiar el efecto de un soluto no voltil sobre la temperatura
de ebullicin }\par\pard\li920\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100 {de u
n disolvente. }\par\pard\li920\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100 {Su
pondremos: a) que el soluto es no voltil, de form}\fs22\cf0\f0\charscalex100 {a q
ue no contribuye al vapor, b) que el soluto }\par\pard\li920\ri0\sl-253\slmult0
\fs22\cf0\f0\charscalex100 {no se disuelve en el disolvente slido y c) la disolu
cin es ideal. }\par\pard\li920\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100 {Una
caracterstica comn de las propiedades coligativas es la disminucin del potencia
l qumico }\par\pard\li920\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100 {del diso
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24\cf0\f0\charscalex100 {<}{ }\fs26\cf0\f0\charscalex100 {\uc1\u956X}{\sub \fs14
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d\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-266\slmult0 \fs22\cf0
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arscalex100 {slida permanecen inalterados por la presencia del }\par\pard\li920\r
i0\sl-253\slmult0 \fs22\cf0\f0\charscalex100 {soluto no voltil. Fig.1. }\par\pard
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6\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li4026\ri0\sl-213\slmult0 \fs18\cf0\par\
pard\li4026\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li4026\ri0\sl-320\slmult0 \fs2
2\cf0\f0\charscalex100 {El equilibrio implicado en el clculo del ascenso del pto
de }\par\pard\li4026\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {ebullicin es
entre A en el vapor puro y A en la mezcla, siendo A}\par\pard\li4026\ri0\sl-386\
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i0\sl-453\slmult0 \fs22\cf0\f0\charscalex100 {El equilibrio a una T, viene dado
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pard\li160\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100 {\uc1\u9116X}\par\pard\
li0\ri0\sl-266\slmult0 \fs20\cf0\f0\charscalex100 {1}{ }\fs20\cf0\f0\charscalex1
00 {\uc1\u9116X}\par\column\pard\li0\ri0\sl-440\slmult0 \fs22\cf0\f0\charscalex1
00 {\uc1\u9116X}\fs22\cf0\f0\charscalex100 {\uc1\u9117X}\par\column\pard\li0\ri0
\sl-240\slmult0 \fs22\cf0\f0\charscalex100\i {T}\i0 \par\column\pard\li0\ri0\sl480\slmult0 \fs22\cf0\f0\charscalex100 {\uc1\u9119X}\fs22\cf0\f0\charscalex100 {
\uc1\u9120X}{ }\fs22\cf0\f0\charscalex100 {\uc1\u9119X}\fs22\cf0\f0\charscalex10
0 {\uc1\u9115X}{ }\fs22\cf0\f0\charscalex100 {\uc1\u916X}\fs22\cf0\f0\charscalex
100\i {G}\i0 \fs22\cf0\f0\charscalex100 {\uc1\u9118X}{ }\fs22\cf0\f0\charscalex1
00 {\uc1\u9131X}\par\pard\sect\sectd\sbknone\pgwsxn12240\pghsxn15840\marglsxn666
\margrsxn133\cols6\colno1\colw2573\colsr-0\colno2\colw1440\colsr-0\colno3\colw26
6\colsr-0\colno4\colw3866\colsr-0\colno5\colw280\colsr-0\colno6\colw3013\pard\li
1826\ri0\sl-506\slmult0 \fs16\cf0\f0\charscalex100 {\uc1\u9120X}\fs16\cf0\f0\cha
rscalex100 {\uc1\u9119X}{\sub \fs18\cf0\f0\charscalex100\i {p}\i0 }\fs22\cf0\f0\
charscalex100 {=}\par\column\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f0\charscalex
100 {\uc1\u9116X}\par\column\pard\li0\ri0\sl-266\slmult0 \fs20\cf0\f0\charscalex
100 {\uc1\u9119X}\par\column\pard\li0\ri0\sl-413\slmult0 \*\tx3120\fs22\cf0\f0\c
harscalex100\i {
ec. Gibbs}\i0 { }\fs22\cf0\f0\charscalex100 {\uc1
\u8722X}{ }\fs22\cf0\f0\charscalex100\i {Helmholtz
}\i0 \tab \fs22\cf0\f0\cha
rscalex100 {\uc1\u8706X}\par\column\pard\li0\ri0\sl-266\slmult0 \fs22\cf0\f0\cha
rscalex100 {\uc1\u9132X}\par\column\pard\li0\ri0\sl-373\slmult0 \fs22\cf0\f0\cha
rscalex100 {= \uc1\u8722X}{ }\fs22\cf0\f0\charscalex100 {\uc1\u916X}\fs22\cf0\f0
\charscalex100\i {H}\i0 \par\pard\sect\sectd\sbknone\pgwsxn12240\pghsxn15840\mar
glsxn666\margrsxn133\cols10\colno1\colw1173\colsr-0\colno2\colw1240\colsr-0\coln
o3\colw160\colsr-0\colno4\colw200\colsr-0\colno5\colw293\colsr-0\colno6\colw946\
colsr-0\colno7\colw133\colsr-0\colno8\colw3000\colsr-0\colno9\colw1653\colsr-0\c
olno10\colw2640\pard\li946\ri0\sl-266\slmult0 \fs16\cf0\f0\charscalex100 {\uc1\u
9117X}\fs16\cf0\f0\charscalex100 {\uc1\u9116X}\par\column\pard\li146\ri0\sl-240\
slmult0 \fs22\cf0\f0\charscalex100\i {dT}\i0 \par\pard\li0\ri0\sl-213\slmult0 \f
s18\cf0\par\pard\li0\ri0\sl-493\slmult0 \fs22\cf0\f0\charscalex100 {\uc1\u9115X}
{ }\fs22\cf0\f0\charscalex100\i {d(ln x}\i0 { }\fs18\cf0\f0\charscalex100\i \ul
{A}\i0 \ul0 { }\fs22\cf0\f0\charscalex100\i {)}\i0 \fs22\cf0\f0\charscalex100 {\
uc1\u9118X}\par\column\pard\li0\ri0\sl-240\slmult0 \fs22\cf0\f0\charscalex100\i
{R}\i0 \par\column\pard\li0\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100 {\uc1\
u9116X}\par\pard\li0\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100 {\uc1\u9116X}
\par\pard\li0\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100 {\uc1\u9117X}\par\co
lumn\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18
\cf0\par\pard\li0\ri0\sl-520\slmult0 \fs22\cf0\f0\charscalex100 {\uc1\u916X}{\su
b \fs22\cf0\f0\charscalex100\i \ul {H}\i0 \ul0 }\fs18\cf0\f0\charscalex100\i {A}
\i0 \par\column\pard\li160\ri0\sl-240\slmult0 \fs22\cf0\f0\charscalex100\i {dT}\
i0 \par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-453\slmult0 \f
s18\cf0\f0\charscalex100\i {*}\i0 { }\fs22\cf0\f0\charscalex100\i {( vap )}\i0 \

par\column\pard\li0\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100 {\uc1\u9119X}\
par\pard\li0\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100 {\uc1\u9119X}\par\par
d\li0\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100 {\uc1\u9120X}\par\column\par
d\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-240\slmult0 \fs18\cf0\f0\
charscalex100\i {p}\i0 \par\column\pard\li0\ri0\sl-386\slmult0 \*\tx666\*\tx893\
fs22\cf0\f0\charscalex100 {\uc1\u9129X}{ }\fs22\cf0\f0\charscalex100\ul {\uc1\u8
706X}\ul0 \fs22\cf0\f0\charscalex100\i {T}\i0 { }\fs16\cf0\f0\charscalex100 {\uc
1\u9117X}\fs16\cf0\f0\charscalex100 {\uc1\u9116X}\tab \fs22\cf0\f0\charscalex100
\i {T}\i0 \tab \fs16\cf0\f0\charscalex100 {\uc1\u9120X}\fs16\cf0\f0\charscalex10
0 {\uc1\u9119X}{ }\fs22\cf0\f0\charscalex100 {\uc1\u9133X}{\sub \fs18\cf0\f0\cha
rscalex100\i {p}\i0 }\par\column\pard\li0\ri0\sl-306\slmult0 \fs22\cf0\f0\charsc
alex100\i {T}\i0 {\super \fs18\up3\cf0\f0\charscalex100 {2}}\par\pard\sect\sectd
\sbknone\pgwsxn12240\pghsxn15840\marglsxn666\margrsxn133\cols3\colno1\colw2053\c
olsr-0\colno2\colw1013\colsr-0\colno3\colw8373\pard\li1173\ri0\sl-266\slmult0 \*
\tx1546\fs16\cf0\f0\charscalex100 {\uc1\u9117X}\fs16\cf0\f0\charscalex100 {\uc1\
u9116X}\tab \fs22\cf0\f0\charscalex100\i {dT}\i0 \par\column\pard\li0\ri0\sl-506
\slmult0 \*\tx533\fs16\cf0\f0\charscalex100 {\uc1\u9120X}\fs16\cf0\f0\charscalex
100 {\uc1\u9119X}{\sub \fs18\cf0\f0\charscalex100\i {p}\i0 }\fs22\cf0\f0\charsca
lex100 {=}\tab \fs22\cf0\f0\charscalex100 {\uc1\u8722X}\par\column\pard\li0\ri0\
sl-306\slmult0 \fs22\cf0\f0\charscalex100\i {RT}\i0 \fs18\cf0\f0\charscalex100 {
2}\par\pard\sect\sectd\sbknone\pgwsxn12240\pghsxn15840\marglsxn666\margrsxn133\p
ard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-413\slmult0 \fs22\c
f0\f0\charscalex100 {Si ahora integramos esta ecuacin entre (x}\fs14\cf0\f0\chars
calex100 {A}\fs22\cf0\f0\charscalex100 { = 1, Te}{\super \fs14\up4\cf0\f0\charsc
alex100 {*}}\fs22\cf0\f0\charscalex100 {, disolvente puro) y una fraccin molar}\p
ar\pard\li920\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {cualquiera en la di
solucin, (x}\fs14\cf0\f0\charscalex100 {A}\fs22\cf0\f0\charscalex100 {, Te). }\p
ar\pard\sect\sectd\sbknone\pgwsxn12240\pghsxn15840\marglsxn666\margrsxn133\cols3
\colno1\colw2440\colsr-0\colno2\colw653\colsr-0\colno3\colw8346\pard\li960\ri0\s
l-426\slmult0 \fs16\cf0\f0\charscalex100\i {x}\i0 \fs14\cf0\f0\charscalex100\i {
A}\i0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-133\
slmult0 \fs16\cf0\f0\charscalex100\i {*}\i0 \par\column\pard\li0\ri0\sl-426\slmu
lt0 \fs16\cf0\f0\charscalex100\i {T}\i0 \fs14\cf0\f0\charscalex100\i {e}\i0 \par
\pard\sect\sectd\sbknone\pgwsxn12240\pghsxn15840\marglsxn666\margrsxn133\cols3\c
olno1\colw1146\colsr-0\colno2\colw706\colsr-0\colno3\colw9586\pard\li986\ri0\sl520\slmult0 \fs44\cf0\f0\charscalex100 {\uc1\u8747X}\par\pard\li1000\ri0\sl-186\
slmult0 \fs16\cf0\f0\charscalex100 {1}\par\column\pard\li0\ri0\sl-360\slmult0 \f
s20\cf0\f0\charscalex100\i {d(ln x}\i0 {\sub \fs16\cf0\f0\charscalex100\i {A}\i0
}\fs20\cf0\f0\charscalex100\i {)}\i0 \par\column{\trowd\trleft0\trkeep\trftsWid
th1\trpaddl0\trpaddr0\trpaddfl3\trpaddfr3 \clvertalt\clbrdrt\brdrnone\clbrdrl\br
drnone\clbrdrb\brdrnone\clbrdrr\brdrnone\cltxlrtb\clNoWrap\clftsWidth3\clwWidth1
786\clpadt0\clpadr0\clpadft3\clpadfr3\cellx4173 \pard\li0\ri0\sl-306\widctlpar\i
ntbl \fs20\cf0\f0\charscalex100 {= \uc1\u8722X}\fs20\cf0\f0\charscalex100 {\uc1\
u916X}\fs20\cf0\f0\charscalex100\i \ul {H}\i0 \ul0 \fs16\cf0\f0\charscalex100\i
\ul {A}\i0 \ul0 \fs18\cf0\f0\charscalex100\i {( vap )}\i0 \fs20\cf0\f0\charscale
x100\i {dT}\i0 \par\pard\li0\ri0\sl-186\widctlpar\intbl \fs20\cf0\f0\charscalex1
00\i {R}\i0 \fs20\cf0\f0\charscalex100\i {T}\i0 \fs16\cf0\f0\charscalex100 {2}\c
ell\row}\pard\li1306\ri0\sl-160\slmult0 \fs14\cf0\f0\charscalex100\i {*}\i0 \par
olno1\colw2306\colsr-0\colno2\colw9133\pard\li920\ri0\sl-440\slmult0 \*\tx2026\f
s22\cf0\f0\charscalex100 {suponemos}\tab \fs20\cf0\f0\charscalex100\ul {\uc1\u91
6X}\ul0 \fs20\cf0\f0\charscalex100 {H}{\sub \fs16\cf0\f0\charscalex100 {A}}\par\
column\pard\li760\ri0\sl-226\slmult0 \fs16\cf0\f0\charscalex100\i {T}\i0 {\sub \
fs14\cf0\f0\charscalex100\i {e}\i0 }\par\pard\li0\ri0\sl-293\slmult0 \*\tx160\fs
16\cf0\f0\charscalex100 {*}\tab \fs20\cf0\f0\charscalex100 {(vap)}{ }\fs20\cf0\f
0\charscalex100 {\uc1\u8800X}{ }\fs20\cf0\f0\charscalex100 {f (T),}{ }\fs22\cf0\
f0\charscalex100 { en el intervalo (Te-Te*)}\par\pard\sect\sectd\sbknone\pgwsxn1
2240\pghsxn15840\marglsxn666\margrsxn133\cols7\colno1\colw2680\colsr-0\colno2\co
lw160\colsr-0\colno3\colw653\colsr-0\colno4\colw253\colsr-0\colno5\colw1213\cols
r-0\colno6\colw120\colsr-0\colno7\colw6360\pard\li1973\ri0\sl-253\slmult0 \fs20\
cf0\f0\charscalex100\i {*}\i0 \par\pard\li946\ri0\sl-493\slmult0 \fs22\cf0\f0\ch
arscalex100\i {ln x}\i0 {\sub \fs18\cf0\f0\charscalex100\i {A}\i0 }\fs22\cf0\f0\
charscalex100 {=}{ }\fs22\cf0\f0\charscalex100 {\uc1\u916X}\fs22\cf0\f0\charscal
ex100\i \ul {H}\i0 \ul0 {\sub \fs18\cf0\f0\charscalex100\i \ul {A}\i0 \ul0 }\fs2
2\cf0\f0\charscalex100\i {( vap )}\i0 \par\column\pard\li0\ri0\sl-466\slmult0 \f
s24\cf0\f0\charscalex100 {\uc1\u9115X}\par\column\pard\li0\ri0\sl-213\slmult0 \f
s18\cf0\par\pard\li0\ri0\sl-400\slmult0 \fs24\cf0\f0\charscalex100 {1}{ }\fs24\c
f0\f0\charscalex100 {\uc1\u8722X}{\super \fs24\up2\cf0\f0\charscalex100 {1}}\par
\column\pard\li0\ri0\sl-466\slmult0 \fs24\cf0\f0\charscalex100 {\uc1\u9118X}\par
\column\pard\li506\ri0\sl-253\slmult0 \fs20\cf0\f0\charscalex100\i {*}\i0 \par\p
ard\li0\ri0\sl-346\slmult0 \fs22\cf0\f0\charscalex100 {=}{ }\fs22\cf0\f0\charsca
lex100 {\uc1\u916X}\fs22\cf0\f0\charscalex100\i \ul {H}\i0 \ul0 {\sub \fs18\cf0\
f0\charscalex100\i \ul {A}\i0 \ul0 }\fs22\cf0\f0\charscalex100\i {( vap )}\i0 \p
ar\column\pard\li0\ri0\sl-466\slmult0 \fs24\cf0\f0\charscalex100 {\uc1\u9115X}\p
ar\column\pard\li133\ri0\sl-600\slmult0 \fs20\cf0\f0\charscalex100\i {*}\i0 { }\
fs24\cf0\f0\charscalex100 {\uc1\u8722X}{ }\fs24\cf0\f0\charscalex100\i {T}\i0 {\
sub \fs20\cf0\f0\charscalex100\i {e}\i0 }\fs24\cf0\f0\charscalex100 {\uc1\u9118X
}\par\pard\li0\ri0\sl-306\slmult0 \fs24\cf0\f0\charscalex100\i {T}\i0 {\sub \fs
20\cf0\f0\charscalex100\i {e}\i0 }\par\pard\sect\sectd\sbknone\pgwsxn12240\pghsx
n15840\marglsxn666\margrsxn133\cols8\colno1\colw2333\colsr-0\colno2\colw346\cols
r-0\colno3\colw560\colsr-0\colno4\colw1133\colsr-0\colno5\colw586\colsr-0\colno6
\colw226\colsr-0\colno7\colw560\colsr-0\colno8\colw5693\pard\li2093\ri0\sl-253\s
lmult0 \fs24\cf0\f0\charscalex100\i {R}\i0 \par\column\pard\li0\ri0\sl-213\slmul
t0 \fs18\cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-173\s
lmult0 \fs18\cf0\f0\charscalex100\i {*}\i0 \par\column\pard\li0\ri0\sl-466\slmul
t0 \fs24\cf0\f0\charscalex100 {\uc1\u9116X}\fs24\cf0\f0\charscalex100 {\uc1\u911
7X}{ }\fs24\cf0\f0\charscalex100\i {T}\i0 {\sub \fs20\cf0\f0\charscalex100\i {e}
\i0 }\par\column\pard\li133\ri0\sl-466\slmult0 \fs20\cf0\f0\charscalex100\i {*}\
i0 { }\fs24\cf0\f0\charscalex100 {\uc1\u9120X}\fs24\cf0\f0\charscalex100 {\uc1\u
9119X}\par\pard\li0\ri0\sl-306\slmult0 \fs24\cf0\f0\charscalex100\i {T}\i0 {\sub
\fs20\cf0\f0\charscalex100\i {e}\i0 }\par\column\pard\li0\ri0\sl-253\slmult0 \f
s24\cf0\f0\charscalex100\i {R}\i0 \par\column\pard\li0\ri0\sl-466\slmult0 \fs24\
cf0\f0\charscalex100 {\uc1\u9116X}\fs24\cf0\f0\charscalex100 {\uc1\u9117X}\par\c
olumn\pard\li320\ri0\sl-213\slmult0 \fs20\cf0\f0\charscalex100\i {*}\i0 \par\par
d\li0\ri0\sl-306\slmult0 \fs24\cf0\f0\charscalex100\i {T}\i0 {\sub \fs20\cf0\f0\
charscalex100\i {e}\i0 }\fs24\cf0\f0\charscalex100\i {T}\i0 {\sub \fs20\cf0\f0\c
harscalex100\i {e}\i0 }\par\column\pard\li0\ri0\sl-466\slmult0 \fs24\cf0\f0\char
scalex100 {\uc1\u9119X}\fs24\cf0\f0\charscalex100 {\uc1\u9120X }\par\pard\sect\s
ectd\sbknone\pgwsxn12240\pghsxn15840\marglsxn666\margrsxn133\cols2\colno1\colw54
80\colsr-0\colno2\colw5960\pard\li1080\ri0\sl-426\slmult0 \*\tx2480\fs18\cf0\f0\
charscalex100\i {*}\i0 { }\fs22\cf0\f0\charscalex100 {\uc1\u8722X}{ }\fs22\cf0\f
0\charscalex100\i {T}\i0 \fs18\cf0\f0\charscalex100\i {e}\i0 {\super \fs22\up1\c
f0\f0\charscalex100 {=}}\fs22\cf0\f0\charscalex100\i {T}\i0 \fs18\cf0\f0\charsca
lex100\i {e}\i0 \fs22\cf0\f0\charscalex100\i {T}\i0 \fs18\cf0\f0\charscalex100\i
{e}\i0 \tab \fs22\cf0\f0\charscalex100\i { R}\i0 \par\column\pard\li0\ri0\sl-1
06\slmult0 \fs18\cf0\f0\charscalex100\i {*}\i0 \par\pard\sect\sectd\sbknone\pgws
xn12240\pghsxn15840\marglsxn666\margrsxn133\cols2\colno1\colw1880\colsr-0\colno2
\colw9560\pard\li946\ri0\sl-280\slmult0 \fs22\cf0\f0\charscalex100\i {T}\i0 \fs1
8\cf0\f0\charscalex100\i {e}\i0 \par\column\pard\li306\ri0\sl-493\slmult0 \fs18\
cf0\f0\charscalex100\i {*}\i0 { }\fs22\cf0\f0\charscalex100\i {( vap )}\i0 { }\f
s22\cf0\f0\charscalex100\i {ln x}\i0 { }\fs18\cf0\f0\charscalex100\i {A}\i0 { }\
fs22\cf0\f0\charscalex100\i {
como x}\i0 { }\fs18\cf0\f0\charscalex100\i {A
}\i0 {\super \fs22\up1\cf0\f0\charscalex100 {<}}\fs22\cf0\f0\charscalex100 {1}\f
s22\cf0\f0\charscalex100\i { y }\i0 { }\fs24\cf0\f0\charscalex100 {\uc1\u916X}
\fs22\cf0\f0\charscalex100\i \ul {H}\i0 \ul0 { }\fs18\cf0\f0\charscalex100\i {A}
\i0 { }\fs22\cf0\f0\charscalex100\i {( vap )}\i0 { }\fs22\cf0\f0\charscalex100 {
>}{ }\fs22\cf0\f0\charscalex100 {0}\fs22\cf0\f0\charscalex100\i { )}\i0 \par\par
d\li0\ri0\sl-333\slmult0 \fs24\cf0\f0\charscalex100 {\uc1\u916X}\fs22\cf0\f0\cha
rscalex100\i \ul {H}\i0 \ul0 {\sub \fs18\cf0\f0\charscalex100\i {A}\i0 }\par\par
d\li1520\ri0\sl-200\slmult0 \fs18\cf0\f0\charscalex100\i {*}\i0 \par\pard\sect\s

ectd\sbknone\pgwsxn12240\pghsxn15840\marglsxn666\margrsxn133\cols2\colno1\colw98
66\colsr-0\colno2\colw1573\pard\li946\ri0\sl-346\slmult0 \*\tx2466\fs22\cf0\f0\c
harscalex100 {\uc1\u8658X}{ }\fs22\cf0\f0\charscalex100\i { T}\i0 \fs18\cf0\f0\
charscalex100\i {e}\i0 {\super \fs18\up5\cf0\f0\charscalex100\i {*}\i0 }\fs22\cf
0\f0\charscalex100 {\uc1\u8722X}{ }\fs22\cf0\f0\charscalex100\i {T}\i0 \fs18\cf0
\f0\charscalex100\i {e}\i0 {\super \fs22\up1\cf0\f0\charscalex100 {<}}\fs22\cf0\
f0\charscalex100 {0}\tab \fs22\cf0\f0\charscalex100 {\uc1\u8658X}{ }\fs22\cf0\f0
\charscalex100\i { T}\i0 \fs18\cf0\f0\charscalex100\i {e}\i0 {\super \fs22\up1\
cf0\f0\charscalex100 {>}}\fs22\cf0\f0\charscalex100\i {T}\i0 \fs18\cf0\f0\charsc
alex100\i {e}\i0 \par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\ri0
\sl-213\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-386\slmult0 \fs18\cf0\f0\charsca
lex100 {Laboratorio de Qumica Fsica(09-10), Grupo Innovacin, P8 }\par\column\pard\l
i0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-346\slmult0 \fs22\cf0\f0\cha
rscalex100 {4}\par\pard\sect\sectd\sbknone\pgwsxn12240\pghsxn15840\marglsxn666\m
argrsxn133\pard\sect\sectd\sbkpage




0 {es decir, la temperatura de ebullicin de la disolucin es mayor que la temperatu
ra de ebullicin del}\par\pard\li920\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100
{disolvente puro.}\par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\r
i0\sl-400\slmult0 \fs22\cf0\f0\charscalex100 {La ecuacin que nos d la T}\fs14\cf0\
f0\charscalex100 {eb}\fs22\cf0\f0\charscalex100 { de la disolucin en funcin de la
concentracin es:}\par\pard\sect\sectd\sbknone\pgwsxn12240\pghsxn15840\marglsxn666
\margrsxn133\cols6\colno1\colw2680\colsr-0\colno2\colw160\colsr-0\colno3\colw653
\colsr-0\colno4\colw360\colsr-0\colno5\colw1413\colsr-0\colno6\colw6173\pard\li1
973\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1973\ri0\sl-213\slmult0 \fs18\cf0\pa
r\pard\li1973\ri0\sl-26\slmult0 \fs18\cf0\f0\charscalex100\i {*}\i0 \par\pard\li
946\ri0\sl-466\slmult0 \fs20\cf0\f0\charscalex100\i {ln x}\i0 {\sub \fs16\cf0\f0

\charscalex100\i {A}\i0 }\fs20\cf0\f0\charscalex100 {=}{ }\fs22\cf0\f0\charscale
x100 {\uc1\u916X}\fs20\cf0\f0\charscalex100\i \ul {H}\i0 \ul0 { }\fs16\cf0\f0\ch
arscalex100\i \ul {A}\i0 \ul0 \fs20\cf0\f0\charscalex100\i {( vap )}\i0 \par\col
umn\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-440\slmult0 \fs22\
cf0\f0\charscalex100 {\uc1\u9115X}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\
cf0\par\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-360\slmult0 \*
\tx213\fs22\cf0\f0\charscalex100 {1}\tab \fs22\cf0\f0\charscalex100 {\uc1\u8722X
}{\super \fs22\up1\cf0\f0\charscalex100 {1}}\par\column\pard\li0\ri0\sl-213\slmu
lt0 \fs18\cf0\par\pard\li0\ri0\sl-440\slmult0 \fs22\cf0\f0\charscalex100 {\uc1\u
9118X}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-213\
slmult0 \fs18\cf0\par\pard\li0\ri0\sl-346\slmult0 \*\tx453\fs22\cf0\f0\charscale
x100 {\uc1\u8594X}\tab \fs22\cf0\f0\charscalex100\i { R ln x}\i0 { }\fs18\cf0\f
0\charscalex100\i {A}\i0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\p
ard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-360\slmult0 \fs22\cf0\f
0\charscalex100 {=}{\super \fs22\up1\cf0\f0\charscalex100 {1}}\fs22\cf0\f0\chars
calex100 {\uc1\u8722X}{\super \fs22\up1\cf0\f0\charscalex100 {1}}\par\pard\sect\
sectd\sbknone\pgwsxn12240\pghsxn15840\marglsxn666\margrsxn133\cols8\colno1\colw2
080\colsr-0\colno2\colw280\colsr-0\colno3\colw320\colsr-0\colno4\colw560\colsr-0
\colno5\colw986\colsr-0\colno6\colw1240\colsr-0\colno7\colw440\colsr-0\colno8\co
lw5533\pard\li1013\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1013\ri0\sl-440\slmul
t0 \fs22\cf0\f0\charscalex100 {1}{\sub \fs22\cf0\f0\charscalex100 {=}}\fs22\cf0\
f0\charscalex100 {1}\par\column\pard\li0\ri0\sl-240\slmult0 \fs22\cf0\f0\charsca
lex100\i {R}\i0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\r
i0\sl-253\slmult0 \fs22\cf0\f0\charscalex100\i {R}\i0 \par\column\pard\li0\ri0\s
l-440\slmult0 \fs22\cf0\f0\charscalex100 {\uc1\u9116X}\fs22\cf0\f0\charscalex100
{\uc1\u9117X}{ }\fs22\cf0\f0\charscalex100\i {T}\i0 {\sub \fs18\cf0\f0\charscal
ex100\i {e}\i0 }\par\column\pard\li120\ri0\sl-440\slmult0 \fs18\cf0\f0\charscale
x100\i {*}\i0 { }\fs22\cf0\f0\charscalex100 {\uc1\u9120X}\fs22\cf0\f0\charscalex
100 {\uc1\u9119X}\par\pard\li0\ri0\sl-293\slmult0 \fs22\cf0\f0\charscalex100\i {
T}\i0 {\sub \fs18\cf0\f0\charscalex100\i {e}\i0 }\par\column\pard\li0\ri0\sl-346
\slmult0 \fs24\cf0\f0\charscalex100 {\uc1\u916X}\fs22\cf0\f0\charscalex100\i \ul
{H}\i0 \ul0 {\sub \fs18\cf0\f0\charscalex100\i {A}\i0 }\fs18\cf0\f0\charscalex1
00\i {*}\i0 { }\fs22\cf0\f0\charscalex100\i {( vap )}\i0 \par\column\pard\li0\ri
0\sl-293\slmult0 \fs22\cf0\f0\charscalex100\i {T}\i0 {\sub \fs18\cf0\f0\charscal
ex100\i {e}\i0 }\par\column\pard\li120\ri0\sl-200\slmult0 \fs18\cf0\f0\charscale
x100\i {*}\i0 \par\pard\li0\ri0\sl-293\slmult0 \fs22\cf0\f0\charscalex100\i {T}\
i0 {\sub \fs18\cf0\f0\charscalex100\i {e}\i0 }\par\pard\sect\sectd\sbknone\pgwsx
n12240\pghsxn15840\marglsxn666\margrsxn133\cols4\colno1\colw1560\colsr-0\colno2\
colw373\colsr-0\colno3\colw306\colsr-0\colno4\colw9200\pard\li973\ri0\sl-333\slm
ult0 \*\tx1426\fs22\cf0\f0\charscalex100\i {T}\i0 \fs18\cf0\f0\charscalex100\i {
e}\i0 \tab \fs20\cf0\f0\charscalex100\i {T}\i0 \fs16\cf0\f0\charscalex100\i {e}\
i0 \par\column\pard\li0\ri0\sl-373\slmult0 \fs18\cf0\f0\charscalex100\i {*}\i0 {
\super \fs22\up3\cf0\f0\charscalex100 {+}}\par\column\pard\li0\ri0\sl-333\slmult
0 \fs24\cf0\f0\charscalex100 {\uc1\u916X}\fs22\cf0\f0\charscalex100\i \ul {H}\i0
\ul0 { }\fs18\cf0\f0\charscalex100\i {A}\i0 \par\column\pard\li0\ri0\sl-453\slm
ult0 \fs18\cf0\f0\charscalex100\i {*}\i0 { }\fs22\cf0\f0\charscalex100\i {( vap
)}\i0 { }\fs22\cf0\f0\charscalex100\i {ln x}\i0 \fs18\cf0\f0\charscalex100\i {A}
\i0 \par\pard\sect\sectd\sbknone\pgwsxn12240\pghsxn15840\marglsxn666\margrsxn133
\pard\li920\ri0\sl-400\slmult0 \fs22\cf0\f0\charscalex100 {Todo lo que hemos obt
enido es consecuencia de aplicar la ley de Raoult que se cumple para }\par\pard\
li920\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100 {disoluciones muy diluidas,
x}\fs14\cf0\f0\charscalex100 {A}{ }\fs22\cf0\f0\charscalex100 {\uc1\u8776X}\fs22
\cf0\f0\charscalex100 { 1. }\par\pard\li920\ri0\sl-360\slmult0 \fs22\cf0\f0\char
scalex100 {En estas condiciones: }\par\pard\li960\ri0\sl-386\slmult0 \*\tx5280\f
s22\cf0\f0\charscalex100\i { ln x}\i0 {\sub \fs16\cf0\f0\charscalex100\i {A}\i0
}\fs22\cf0\f0\charscalex100 {=}{ }\fs22\cf0\f0\charscalex100\i {ln(1}\i0 \fs22\
cf0\f0\charscalex100 {\uc1\u8722X}{ }\fs22\cf0\f0\charscalex100\i {x}\i0 {\sub \
fs16\cf0\f0\charscalex100\i {B}\i0 }\fs22\cf0\f0\charscalex100\i {)}\i0 { }\fs22
\cf0\f0\charscalex100 {\uc1\u8776X \uc1\u8722X}{ }\fs22\cf0\f0\charscalex100\i {
x}\i0 {\sub \fs16\cf0\f0\charscalex100\i {B}\i0 }\fs22\cf0\f0\charscalex100\i {

ya que x}\i0 {\sub \fs16\cf0\f0\charscalex100\i {B}\i0 }\fs22\cf0\f0\charsc
alex100 {<<}{ }\fs22\cf0\f0\charscalex100\i {1
}\i0 \tab \fs22\cf0\f0\charsca
lex100\i {Suposicin 1}\i0 \par\pard\li960\ri0\sl-426\slmult0 \*\tx2640\fs22\cf0\f
0\charscalex100\i {
T}\i0 {\sub \fs16\cf0\f0\charscalex100\i {e}\i0 }\fs22\cf
0\f0\charscalex100 {\uc1\u8776X}{ }\fs22\cf0\f0\charscalex100\i {T}\i0 {\sub \fs
16\cf0\f0\charscalex100\i {e}\i0 }\fs16\cf0\f0\charscalex100\i {*}\i0 { }\fs22\c
f0\f0\charscalex100 {\uc1\u8658X}{ }\fs22\cf0\f0\charscalex100\i { T}\i0 {\sub
\fs16\cf0\f0\charscalex100\i {e}\i0 }\fs22\cf0\f0\charscalex100\i {T}\i0 {\sub \
fs16\cf0\f0\charscalex100\i {e}\i0 }\fs16\cf0\f0\charscalex100\i {*}\i0 \tab \fs
22\cf0\f0\charscalex100 {\uc1\u8776X}{ }\fs22\cf0\f0\charscalex100\i {T}\i0 {\su
b \fs16\cf0\f0\charscalex100\i {e}\i0 }\fs16\cf0\f0\charscalex100\i {* }\i0 \fs1
6\cf0\f0\charscalex100\i {2}\i0 { }\fs22\cf0\f0\charscalex100\i {
Suposicin 2}\i0 \par\pard\li973\ri0\sl-280\slmult0 \fs22\c
f0\f0\charscalex100\i {por tan to}\i0 \par\pard\sect\sectd\sbknone\pgwsxn12240\
pghsxn15840\marglsxn666\margrsxn133\cols4\colno1\colw2493\colsr-0\colno2\colw106
\colsr-0\colno3\colw2466\colsr-0\colno4\colw6373\pard\li1866\ri0\sl-160\slmult0
\fs16\cf0\f0\charscalex100\i {*}\i0 \par\pard\li946\ri0\sl-453\slmult0 \fs20\cf0
\f0\charscalex100 {\uc1\u8722X}{ }\fs20\cf0\f0\charscalex100\i {x}\i0 {\sub \fs1
4\cf0\f0\charscalex100\i {B}\i0 }\fs20\cf0\f0\charscalex100 {=}{ }\fs20\cf0\f0\c
harscalex100 {\uc1\u916X}\fs20\cf0\f0\charscalex100\i \ul {H}\i0 \ul0 {\sub \fs1
4\cf0\f0\charscalex100\i \ul {A}\i0 \ul0 }\fs20\cf0\f0\charscalex100\i {(vap)}\i
0 \par\column\pard\li0\ri0\sl-346\slmult0 \fs22\cf0\f0\charscalex100 {\uc1\u9115
X}\par\column\pard\li133\ri0\sl-466\slmult0 \fs16\cf0\f0\charscalex100\i {*}\i0
{ }\fs22\cf0\f0\charscalex100 {\uc1\u8722X}{ }\fs22\cf0\f0\charscalex100\i {T}\i
0 {\sub \fs16\cf0\f0\charscalex100\i {e}\i0 }\fs22\cf0\f0\charscalex100 {\uc1\u9
118X}\par\pard\li0\ri0\sl-266\slmult0 \fs22\cf0\f0\charscalex100\i {T}\i0 {\sub
\fs16\cf0\f0\charscalex100\i {e}\i0 }\par\column\pard\li853\ri0\sl-200\slmult0 \
fs16\cf0\f0\charscalex100\i {*}\i0 \fs16\cf0\f0\charscalex100\i {2}\i0 \par{\tro
wd\trleft0\trkeep\trftsWidth1\trpaddl0\trpaddr0\trpaddfl3\trpaddfr3 \clvertalt\c
lbrdrt\brdrnone\clbrdrl\brdrnone\clbrdrb\brdrnone\clbrdrr\brdrnone\cltxlrtb\clNo
Wrap\clftsWidth3\clwWidth1040\clpadt0\clpadr0\clpadft3\clpadfr3\cellx6640 \pard\
li0\ri0\sl-266\widctlpar\intbl \fs16\cf0\f0\charscalex100\i {*}\i0 \par\pard\li0
\ri0\sl-120\widctlpar\intbl \fs22\cf0\f0\charscalex100\i {)}\i0 \fs22\cf0\f0\cha
rscalex100\i {RT}\i0 \fs16\cf0\f0\charscalex100\i {e}\i0 \cell\row}\pard\sect\se
ctd\sbknone\pgwsxn12240\pghsxn15840\marglsxn666\margrsxn133\cols5\colno1\colw249
3\colsr-0\colno2\colw213\colsr-0\colno3\colw520\colsr-0\colno4\colw2266\colsr-0\
colno5\colw5946\pard\li1946\ri0\sl-240\slmult0 \fs22\cf0\f0\charscalex100\i {R}\
i0 \par\column\pard\li0\ri0\sl-200\slmult0 \fs22\cf0\f0\charscalex100 {\uc1\u911
6X}\par\pard\li0\ri0\sl-253\slmult0 \fs20\cf0\f0\charscalex100 {\uc1\u9117X}\par
\column\pard\li120\ri0\sl-173\slmult0 \fs16\cf0\f0\charscalex100\i {* }\i0 \fs16
\cf0\f0\charscalex100\i {2}\i0 \par\pard\li0\ri0\sl-266\slmult0 \fs22\cf0\f0\cha
rscalex100\i {T}\i0 {\sub \fs16\cf0\f0\charscalex100\i {e}\i0 }\par\column\pard\
li0\ri0\sl-306\slmult0 \*\tx346\*\tx706\fs22\cf0\f0\charscalex100 {\uc1\u9119X}\
tab \fs22\cf0\f0\charscalex100 {\uc1\u8594X}\tab \fs22\cf0\f0\charscalex100 {\uc
1\u916X}\fs22\cf0\f0\charscalex100\i {T}\i0 {\sub \fs16\cf0\f0\charscalex100\i {
e}\i0 }\fs22\cf0\f0\charscalex100 {=}{ }\fs22\cf0\f0\charscalex100\i {(T}\i0 {\s
ub \fs16\cf0\f0\charscalex100\i {e}\i0 }\fs22\cf0\f0\charscalex100 {\uc1\u8722X}
{ }\fs22\cf0\f0\charscalex100\i {T}\i0 {\sub \fs16\cf0\f0\charscalex100\i {e}\i0
}\par\pard\li0\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100 {\uc1\u9120X}\par\
column\pard\li293\ri0\sl-413\slmult0 \fs16\cf0\f0\charscalex100\i {*}\i0 { }\fs2
2\cf0\f0\charscalex100\i {(vap)}\i0 {\super \fs22\up6\cf0\f0\charscalex100\i {x}
\i0 }\fs16\cf0\f0\charscalex100\i {B}\i0 \par\pard\li0\ri0\sl-306\slmult0 \fs22\
cf0\f0\charscalex100 {\uc1\u916X}\fs22\cf0\f0\charscalex100\i \ul {H}\i0 \ul0 {\
sub \fs16\cf0\f0\charscalex100\i {A}\i0 }\par\pard\sect\sectd\sbknone\pgwsxn1224
0\pghsxn15840\marglsxn666\margrsxn133\pard\li920\ri0\sl-386\slmult0 \fs22\cf0\f0
\charscalex100 {La frmula que se acaba de deducir no hace referencia a la identid
ad del soluto, solamente a su}\par\pard\li920\ri0\sl-386\slmult0 \fs22\cf0\f0\ch
arscalex100 {fraccin molar. Esto caracteriza la elevacin del punto de ebullicin com
o una propiedad coligativa. }\par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\p

f0\f0\charscalex100 {El valor de}{ }\fs22\cf0\f0\charscalex100 {\uc1\u916X}\fs22
\cf0\f0\charscalex100 {T depende de las propiedades del disolvente y los mayores
cambios se producen con }\par\pard\li920\ri0\sl-386\slmult0 \fs22\cf0\f0\charsc
alex100 {disolventes que tienen un punto de ebullicin alto, }\fs22\cf0\f0\charsca
lex100 {pero una entalpa molar de vaporizacin baja. }\par\pard\li920\ri0\sl-400\s
lmult0 \fs22\cf0\f0\charscalex100 {El aumento de T se expresa normalmente en fun
cin de m}\fs14\cf0\f0\charscalex100 {B}\fs22\cf0\f0\charscalex100 {, la molalidad
del soluto: }\par\pard\sect\sectd\sbknone\pgwsxn12240\pghsxn15840\marglsxn666\m
argrsxn133\cols2\colno1\colw1440\colsr-0\colno2\colw10000\pard\li960\ri0\sl-546\
slmult0 \fs20\cf0\f0\charscalex100\i {n}\i0 {\sub \fs16\cf0\f0\charscalex100\i {
A}\i0 }\fs20\cf0\f0\charscalex100 {=}{\super \fs20\up4\cf0\f0\charscalex100\i {w
}\i0 }\fs16\cf0\f0\charscalex100\i \ul {A}\i0 \ul0 \par\pard\li960\ri0\sl-600\sl
mult0 \fs18\cf0\f0\charscalex100\i {m}\i0 {\sub \fs14\cf0\f0\charscalex100\i {B}
\i0 }\fs18\cf0\f0\charscalex100 {=}{\super \fs18\up4\cf0\f0\charscalex100\i {n}\
i0 }\fs14\cf0\f0\charscalex100\i \ul {B}\i0 \ul0 \par\column\pard\li0\ri0\sl-213
\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-493\slmult0 \fs20\cf0\f0\charscalex100\i
{M}\i0 {\sub \fs16\cf0\f0\charscalex100\i {A}\i0 }\fs20\cf0\f0\charscalex100 {\u
c1\u8594X}{ }\fs20\cf0\f0\charscalex100\i { w}\i0 {\sub \fs16\cf0\f0\charscalex
100\i {A}\i0 }\fs20\cf0\f0\charscalex100 {=}{ }\fs20\cf0\f0\charscalex100\i { n
}\i0 {\sub \fs16\cf0\f0\charscalex100\i {A}\i0 }\fs20\cf0\f0\charscalex100\i {M}
\i0 {\sub \fs16\cf0\f0\charscalex100\i {A}\i0 }\par\pard\li1226\ri0\sl-146\slmul
t0 \fs20\cf0\f0\charscalex100\i {n}\i0 \par\pard\sect\sectd\sbknone\pgwsxn12240\
pghsxn15840\marglsxn666\margrsxn133\cols2\colno1\colw2160\colsr-0\colno2\colw928
0\pard\li1466\ri0\sl-453\slmult0 \fs20\cf0\f0\charscalex100\i {w}\i0 {\sub \fs16
\cf0\f0\charscalex100\i {A}\i0 }\fs20\cf0\f0\charscalex100 {=}\par\column\pard\l
i626\ri0\sl-173\slmult0 \fs16\cf0\f0\charscalex100\i {B}\i0 \par\pard\li0\ri0\sl
-426\slmult0 \fs20\cf0\f0\charscalex100\i {(n}\i0 {\sub \fs16\cf0\f0\charscalex1
00\i {A}\i0 }\fs20\cf0\f0\charscalex100\i {M}\i0 {\sub \fs16\cf0\f0\charscalex10
0\i {A}\i0 }\fs20\cf0\f0\charscalex100\i {) / 1000}\i0 { }\fs20\cf0\f0\charscale
x100\i {
si M}\i0 {\sub \fs16\cf0\f0\charscalex100\i {A}\i0 }\fs20\cf0\f0
\charscalex100\i {(g / mol)}\i0 \par\pard\sect\sectd\sbknone\pgwsxn12240\pghsxn1
5840\marglsxn666\margrsxn133\cols3\colno1\colw3613\colsr-0\colno2\colw120\colsr0\colno3\colw7706\pard\li960\ri0\sl-440\slmult0 \fs20\cf0\f0\charscalex100\i {n}
\i0 {\sub \fs16\cf0\f0\charscalex100\i {B}\i0 }\fs20\cf0\f0\charscalex100 {=}{\s
uper \fs20\up4\cf0\f0\charscalex100\i {m}\i0 }\fs16\cf0\f0\charscalex100\i \ul {
B}\i0 \ul0 {\super \fs20\up1\cf0\f0\charscalex100\i {(n}\i0 }\fs16\cf0\f0\charsc
alex100\i \ul {A}\i0 \ul0 {\super \fs20\up1\cf0\f0\charscalex100\i {M}\i0 }\fs16
\cf0\f0\charscalex100\i \ul {A}\i0 \ul0 {\super \fs20\up1\cf0\f0\charscalex100\i
{)}\i0 }\par\pard\li1786\ri0\sl-400\slmult0 \*\tx2533\fs20\cf0\f0\charscalex100
\i {1000}\i0 \tab \fs20\cf0\f0\charscalex100\i { si x}\i0 {\sub \fs16\cf0\f0\
charscalex100\i {B}\i0 }\fs20\cf0\f0\charscalex100 {=}\par\column\pard\li0\ri0\s
l-146\slmult0 \fs20\cf0\f0\charscalex100\i {n}\i0 \par\column\pard\li0\ri0\sl-32
0\slmult0 \fs16\cf0\f0\charscalex100\i {B}\i0 \par\pard\sect\sectd\sbknone\pgwsx
n12240\pghsxn15840\marglsxn666\margrsxn133\cols3\colno1\colw1933\colsr-0\colno2\
colw1133\colsr-0\colno3\colw8373\pard\li960\ri0\sl-213\slmult0 \fs18\cf0\par\par
d\li960\ri0\sl-546\slmult0 \fs20\cf0\f0\charscalex100\i {x}\i0 {\sub \fs16\cf0\f
0\charscalex100\i {B}\i0 }\fs20\cf0\f0\charscalex100 {\uc1\u8773X}{\super \fs20\
up4\cf0\f0\charscalex100\i {n}\i0 }\fs16\cf0\f0\charscalex100\i \ul {B}\i0 \ul0
\par\column\pard\li0\ri0\sl-360\slmult0 \fs20\cf0\f0\charscalex100\i {m}\i0 {\su
b \fs16\cf0\f0\charscalex100\i \ul {B}\i0 \ul0 }\fs20\cf0\f0\charscalex100\i {(n
}\i0 {\sub \fs16\cf0\f0\charscalex100\i \ul {A}\i0 \ul0 }\fs20\cf0\f0\charscalex
100\i {M}\i0 {\sub \fs16\cf0\f0\charscalex100\i \ul {A}\i0 \ul0 }\fs20\cf0\f0\ch
arscalex100\i {)}\i0 \par\pard\li266\ri0\sl-240\slmult0 \fs20\cf0\f0\charscalex1
00\i {1000}\i0 \par\column\pard\li333\ri0\sl-440\slmult0 \fs20\cf0\f0\charscalex
100\i {n}\i0 {\sub \fs16\cf0\f0\charscalex100\i {A}\i0 }\fs20\cf0\f0\charscalex1
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7;32768}}
7;32768}}

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3\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\r
i0\sl-213\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-426\slmult0 \fs22\cf0\f0\chars
calex100\b {Mtodo experimental.}\b0 \fs22\cf0\f0\charscalex100\b { }\b0 \par\pard
\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-440\slmult0 \fs22\cf0\
f0\charscalex100 {OBTENCIN DE LA CONSTANTE EBULLOSCPICA DE LA ACETONA }\par\pard\l
i1040\ri0\sl-386\slmult0 \*\tx1306\fs22\cf0\f0\charscalex100 {1.}\tab \fs22\cf0\
f0\charscalex100 {Limpie, con un poco de acetona, el matraz de fondo redondo con
un imn y 8 9 perlas de }\par\pard\li1333\ri0\sl-386\slmult0 \fs22\cf0\f0\charsc

alex100 {ebullicin en su interior. Una vez seco pese, sobre una base de corcho, e
l matraz tapado con }\par\pard\li1333\ri0\sl-400\slmult0 \fs22\cf0\f0\charscalex
100 {dos tapones. Este peso constituye m}\fs14\cf0\f0\charscalex100 {V. }\par\p
ard\li1040\ri0\sl-386\slmult0 \*\tx1306\fs22\cf0\f0\charscalex100 {2.}\tab \fs22
\cf0\f0\charscalex100 {Aada al matraz unos 40 mL de acetona y colquelo }\fs22\cf0\
f0\charscalex100 {en el sistema de reflujo adaptando el tapn}\par\pard\li1333\ri0
\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {de rosca con la sonda de temperatura
. }\par\pard\li1040\ri0\sl-386\slmult0 \*\tx1306\fs22\cf0\f0\charscalex100 {3.}\
tab \fs22\cf0\f0\charscalex100 {Encienda el ordenador e inicie el programa Measu
re. Haga click sobre el botn,
,}\par\pard\li1333\ri0\sl-386\slmult0 \fs22\
cf0\f0\charscalex100\b {continuar e iniciar la medida;}\b0 { }\fs22\cf0\f0\chars
calex100 {aparecer en la pantalla representada la temperatura en funcin }\par\pard
\li1333\ri0\sl-400\slmult0 \fs22\cf0\f0\charscalex100 {del tiempo. Encienda la p
laca calefactora y el agitador ambos en la posicin 1 }\fs22\cf0\f0\charscalex100\
b {(agitacin}\b0 \par\pard\li1333\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100\b
{moderada y que el imn no toque el termopar)}\b0 \fs22\cf0\f0\charscalex100 { y
mantenga la ebullicin hasta que la}\par\pard\li1333\ri0\sl-386\slmult0 \fs22\cf0\
f0\charscalex100 {temperatura permanezca constante durante al menos un cuadrante
. Presione el botn "finalizar }\par\pard\li1333\ri0\sl-386\slmult0 \fs22\cf0\f0\c
harscalex100 {la medida". En este instante aparecer en la pantalla la grfica reesc
alada. Si la temperatura}\par\pard\li1333\ri0\sl-386\slmult0 \fs22\cf0\f0\charsc
alex100 {obtenida no es la temperatura de ebullicin de la acetona (56.3 C) calibre
el aparato. }\par\pard\li1053\ri0\sl-400\slmult0 \fs22\cf0\f0\charscalex100 {4.
}{ }\fs22\cf0\f0\charscalex100\b {Calibrado}\b0 \fs22\cf0\f0\charscalex100 {: In
icie una nueva medida presionando sobre el botn de inicio,
, a continuacin}\p
ar\pard\li1346\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {presione sobre \u
c1\u8221Xcalibrar\uc1\u8221X}{ }\fs22\cf0\f0\charscalex100\b {(abajo)}\b0 \fs22\
cf0\f0\charscalex100 {, introduzca la temperatura de ebullicin de la acetona pura
y }\par\pard\li1346\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {presione el
botn \uc1\u8220Xcalibrar\uc1\u8221X }\fs22\cf0\f0\charscalex100\b {(cuadro derec
ha) y OK}\b0 \fs22\cf0\f0\charscalex100 {.}\par\pard\li1320\ri0\sl-386\slmult0 \
fs22\cf0\f0\charscalex100 {Vuelva a iniciar la medida. Cuando la temperat}\fs22\
cf0\f0\charscalex100 {ura se mantenga constante durante al menos un }\par\pard\l
i1320\ri0\sl-386\slmult0 \fs20\cf0\f0\charscalex100 {cuadrante, presione \uc1\u8
220Xfinalizar la medida\uc1\u8221X. Seleccione la zona de temperatura constante
con el }\par\pard\li1320\ri0\sl-400\slmult0 \*\tx2520\fs22\cf0\f0\charscalex100
{botn
}\tab \fs22\cf0\f0\charscalex100 {y obtenga la temperatura con el botn
}\fs22\cf0\f0\charscalex100 {
. Esta temperatura es la temperatura }\
par\pard\li1320\ri0\sl-480\slmult0 \fs22\cf0\f0\charscalex100 {de ebullicin de la
acetona, T}{\super \fs20\up5\cf0\f0\charscalex100 {*}}\fs20\cf0\f0\charscalex10
0 {eb}\fs22\cf0\f0\charscalex100 {. Con los datos de esta experiencia complete l
a tabla 1. }\par\pard\li9866\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li9866\ri0\sl
-213\slmult0 \fs18\cf0\par\pard\li9866\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li9
866\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li9866\ri0\sl-280\slmult0 \fs22\cf0\f0
\charscalex100 {6}\par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\ri
0\sl-386\slmult0 \fs18\cf0\f0\charscalex100 {Laboratorio de Qumica Fsica(09-10), G
rupo Innovacin, P8 }\par\pard\sect\sectd\sbknone\pgwsxn12240\pghsxn15840\marglsxn
666\margrsxn133\pard\sect\sectd\sbkpage
7;32768}}
7;32768}}

3);(173,66);(160,80);(146,93);(133,93);(120,106);(106,106);(93,120);(80,120);(66
,133);(53,133);(40,146);(40,146);(26,146);(13,146);(0,146);}}
824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45
824;1;45824;1;45824;1;45824;1;45824;1;45824;32768}}
7;32768}}

7;32768}}
7;32768}}


3);(173,66);(160,80);(146,93);(133,93);(120,106);(106,106);(93,120);(80,120);(66
,133);(53,133);(40,146);(40,146);(26,146);(13,146);(0,146);}}
824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45
824;1;45824;1;45824;1;45824;1;45824;1;45824;32768}}

7;32768}}
00 {5.}{ }\fs22\cf0\f0\charscalex100 {Retire el matraz de la placa y del reflujo

, quite la sonda y tape}{ }\fs22\cf0\f0\charscalex100\b {inmediatamente el matra
z (la }\b0 \par\pard\li1346\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100\b {ace
tona se evapora)}\b0 \fs22\cf0\f0\charscalex100 {. Enfre el matraz en el bao unos
segundos, squelo y pselo sobre la}\par\pard\li1346\ri0\sl-480\slmult0 \*\tx5120\fs
22\cf0\f0\charscalex100 {base de corcho. Este peso constituye }{ }\fs22\cf0\f0\c
harscalex100 { }\fs22\cf0\f0\charscalex100 {m}\fs18\cf0\f1\charscalex100 {ll}\ta
b \fs22\cf0\f0\charscalex100 {. }\par\pard\li1053\ri0\sl-333\slmult0 \fs22\cf0\
f0\charscalex100 {6.}{ }\fs22\cf0\f0\charscalex100 {Pese en un vaso de precipita
do un poco ms de un gramo de soluto (acetanilida) e introdzcalo }\par\pard\li1400
\ri0\sl-400\slmult0 \fs22\cf0\f0\charscalex100 {en el matraz mediante un embudo
de plstico. Vuelva a pesar el matraz tapado sobre la base de }\par\pard\li1346\ri
0\sl-453\slmult0 \*\tx4386\fs22\cf0\f0\charscalex100 {corcho. Este peso constitu
ye }\fs22\cf0\f0\charscalex100 { }\fs22\cf0\f0\charscalex100 {m}{ }\fs18\cf0\f1\
charscalex100 {ll}\tab \fs22\cf0\f0\charscalex100 {'. }\par\pard\li1053\ri0\sl360\slmult0 \fs22\cf0\f0\charscalex100 {7.}{ }\fs22\cf0\f0\charscalex100 {Vuelva
a colocar el matraz en el sistema de reflujo y comience una nueva medida. Cuand
o la}\par\pard\li1346\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {temperatura
se mantenga constante durante al menos un cuadrante, presione \uc1\u8220Xfinali
zar la }\par\pard\sect\sectd\sbknone\pgwsxn12240\pghsxn15840\marglsxn666\margrsx
n133\cols2\colno1\colw8506\colsr-0\colno2\colw2933\pard\li1346\ri0\sl-386\slmult
0 \fs22\cf0\f0\charscalex100 {medida\uc1\u8221X. Seleccione la zona de temperatu
ra constante con el botn
}\par\column\pard\li0\ri0\sl-386\slmult0 \fs22\cf0\f
0\charscalex100 {y obtenga la }\par\pard\sect\sectd\sbknone\pgwsxn12240\pghsxn1
5840\marglsxn666\margrsxn133\pard\li1346\ri0\sl-386\slmult0 \fs22\cf0\f0\charsca
lex100 {temperatura de ebullicin con el botn
. Anote esta temperatura
, es la temperatura de }\par\pard\li1346\ri0\sl-493\slmult0 \fs22\cf0\f0\charsc
alex100 {ebullicin de la disolucin, T}\fs20\cf0\f0\charscalex100 {eb.}\par\pard\li
1053\ri0\sl-413\slmult0 \fs22\cf0\f0\charscalex100 {8.}{ }\fs22\cf0\f0\charscale
x100 {Repita cinco veces los pasos 5, 6 y 7 }\fs22\cf0\f0\charscalex100\b {(exp
eriencias 2, 3, 4, 5 y 6).}\b0 \par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\
0 \fs22\cf0\f0\charscalex100 {DETERMINACION DE MASAS MOLECULARES POR EBULLOSCOPA}
\par\pard\li1053\ri0\sl-386\slmult0 \*\tx1453\fs22\cf0\f0\charscalex100 {1.}\tab
\fs22\cf0\f0\charscalex100 {Repita los pasos 1 a 4 del apartado anterior. }\pa
r\pard\li1053\ri0\sl-386\slmult0 \*\tx1453\fs22\cf0\f0\charscalex100 {2.}\tab \f
s22\cf0\f0\charscalex100 {Retire el matraz de la placa y del }\fs22\cf0\f0\chars
calex100 {reflujo, quite la sonda y tape}{ }\fs22\cf0\f0\charscalex100\b {inmedi
atamente el matraz (la}\b0 \par\pard\li1453\ri0\sl-400\slmult0 \fs22\cf0\f0\char
scalex100\b {acetona se evapora)}\b0 \fs22\cf0\f0\charscalex100 {. Enfre el matra
z en el bao unos segundos, squelo y pselo sobre la }\par\pard\li1453\ri0\sl-480\slm
ult0 \*\tx5226\fs22\cf0\f0\charscalex100 {base de corcho. Este peso constituye }
{ }\fs22\cf0\f0\charscalex100 { }\fs22\cf0\f0\charscalex100 {m}{ }\fs18\cf0\f1\c
harscalex100 {ll}\tab \fs22\cf0\f0\charscalex100 {. Con los datos obtenidos comp
lete la tabla 2. }\par\pard\li1053\ri0\sl-333\slmult0 \*\tx1400\fs22\cf0\f0\cha
rscalex100 {3.}\tab \fs22\cf0\f0\charscalex100 {Pese en un vaso de precipitados
un poco ms de}\fs22\cf0\f0\charscalex100 { 3.5 gramos de la sustancia desconocida
X e}\par\pard\li1400\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {introdzcala
en el matraz mediante un embudo de plstico. Pese el matraz tapado sobre la base }
\par\pard\li1400\ri0\sl-466\slmult0 \*\tx4693\fs22\cf0\f0\charscalex100 {de corc
ho. Este peso constituye }{ }\fs22\cf0\f0\charscalex100 { }\fs22\cf0\f0\charscal
ex100 {m}{ }\fs18\cf0\f1\charscalex100 {ll}\tab \fs22\cf0\f0\charscalex100 {'.
}\par\pard\li1320\ri0\sl-346\slmult0 \fs22\cf0\f0\charscalex100 {Vuelva a coloca
r el matraz en el sistema de reflujo y comience una nueva medida. Cuando la }\pa
r\pard\li1320\ri0\sl-400\slmult0 \fs22\cf0\f0\charscalex100 {temperatura se mant
enga constante durante al}\fs22\cf0\f0\charscalex100 { menos un cuadrante presio
ne \uc1\u8220Xfinalizar la }\par\pard\sect\sectd\sbknone\pgwsxn12240\pghsxn15840
\marglsxn666\margrsxn133\cols2\colno1\colw5253\colsr-0\colno2\colw6186\pard\li13
20\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {medida\uc1\u8221X. Seleccione
la zona de }\par\column\pard\li0\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {

temperatura constante con el botn y obtenga la}\par\pard\sect\sectd\sbknone\pgwsx
n12240\pghsxn15840\marglsxn666\margrsxn133\pard\li1320\ri0\sl-386\slmult0 \fs22\
cf0\f0\charscalex100 {temperatura con el botn
. Anote esta }\fs22\cf0\f
0\charscalex100 {temperatura, es la temperatura de ebullicin de la }\par\pard\li
1320\ri0\sl-493\slmult0 \fs22\cf0\f0\charscalex100 {disolucin, T}\fs20\cf0\f0\cha
rscalex100 {eb. }\par\pard\li1053\ri0\sl-413\slmult0 \*\tx1453\fs22\cf0\f0\chars
calex100 {4.}\tab \fs22\cf0\f0\charscalex100 {Repita todo el procedimiento para}
{ }\fs22\cf0\f0\charscalex100\b {obtener otra medida}\b0 \fs22\cf0\f0\charscalex
100 {.}\par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-213\sl
mult0 \fs18\cf0\par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li920\ri0\s
l-213\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-320\slmult0 \fs22\cf0\f0\charscale
x100 {DETERMINACIN DE COEFICIENTES DE VANT HOFF }\par\pard\li1586\ri0\sl-386\slmu
lt0 \fs22\cf0\f0\charscalex100 {Como se indic anteriormente, las propiedades coli
gativas dependen del nmero de}\par\pard\li920\ri0\sl-386\slmult0 \fs22\cf0\f0\cha
rscalex100 {partculas de soluto en una masa dada de disolvente. Una disolucin de u
n electrolito 1:1 que se }\par\pard\li920\ri0\sl-386\slmult0 \fs22\cf0\f0\charsc
alex100 {disocia totalmente, genera el doble de partculas en la disolucin, por lo
que el aumento del punto}\par\pard\li9866\ri0\sl-213\slmult0 \fs18\cf0\par\pard\
li9866\ri0\sl-333\slmult0 \fs22\cf0\f0\charscalex100 {7}\par\pard\li920\ri0\sl-2
13\slmult0 \fs18\cf0\par\pard\li920\ri0\sl-386\slmult0 \fs18\cf0\f0\charscalex10
0 {Laboratorio de Qumica Fsica(09-10), Grupo Innovacin, P8 }\par\pard\sect\sectd\sb
knone\pgwsxn12240\pghsxn15840\marglsxn666\margrsxn133\pard\sect\sectd\sbkpage
7;32768}}
7;32768}}


3);(173,66);(160,80);(146,93);(133,93);(120,106);(106,106);(93,120);(80,120);(66
,133);(53,133);(40,146);(40,146);(26,146);(13,146);(0,146);}}
824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45
824;1;45824;1;45824;1;45824;1;45824;1;45824;32768}}

7;32768}}

7;32768}}

7;32768}}
7;32768}}

3);(173,66);(160,80);(146,93);(133,93);(120,106);(106,106);(93,120);(80,120);(66
,133);(53,133);(40,146);(40,146);(26,146);(13,146);(0,146);}}
824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45824;1;45
824;1;45824;1;45824;1;45824;1;45824;1;45824;32768}}
0 {de ebullicin de la disolucin debera ser el doble que el de una disolucin de no el
ectrolito. }\par\pard\li920\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {Real
mente esto sucede si la disolucin es infinitamente diluida. En cualquier otro cas
o la propiedad}\par\pard\li920\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {co
ligativa no es exactamente el doble, sino algo }\fs22\cf0\f0\charscalex100 {meno
r debido a la existencia de \uc1\u8220Xasociacin inica\uc1\u8221X}\par\pard\li920\
ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {que reduce el nmero total de partcu
las de soluto.}\par\pard\li1586\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {U
na medida de la disociacin del electrolito la }\fs22\cf0\f0\charscalex100 {da el
\uc1\u8220Xfactor de Vant Hoff\uc1\u8221X que se define}\par\pard\li920\ri0\sl-4
00\slmult0 \fs22\cf0\f0\charscalex100 {como el cociente entre la propiedad colig
ativa re}\fs22\cf0\f0\charscalex100 {al y la que se observara si no hubiera disoc
iacin.}\par\pard\li920\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {En el caso
del aumento de la temperatura de ebullicin, el factor de Vant Hoff (i) ser: }\par\
pard\li2946\ri0\sl-533\slmult0 \*\tx3333\fs22\cf0\f0\charscalex100\i {i}\i0 { }\
fs22\cf0\f0\charscalex100 {=}\tab \fs22\cf0\f0\charscalex100 {\uc1\u916X}\fs22\c
f0\f0\charscalex100\i {T}\i0 \fs18\cf0\f0\charscalex100\i {real}\i0 \par\pard\se
ct\sectd\sbknone\pgwsxn12240\pghsxn15840\marglsxn666\margrsxn133\pard\li3253\ri0
\sl-320\slmult0 \fs22\cf0\f0\charscalex100\ul {\uc1\u916X}\ul0 \fs22\cf0\f0\char
scalex100\i {T}\i0 \fs18\cf0\f0\charscalex100\i {noelec}\i0 \par\pard\li1053\ri0
\sl-213\slmult0 \fs18\cf0\par\pard\li1053\ri0\sl-293\slmult0 \*\tx1400\fs22\cf0\
f0\charscalex100 {1.}\tab \fs22\cf0\f0\charscalex100 { Limpie, con un poco de ag
ua, el matraz de fondo redondo con un imn y 8 9 perlas de }\par\pard\li1400\ri0\
sl-386\slmult0 \fs22\cf0\f0\charscalex100 {ebullicin en su interior. Una vez seco
pese, so}\fs22\cf0\f0\charscalex100 {bre una base de corcho, el matraz tapado c
on }\par\pard\li1400\ri0\sl-400\slmult0 \fs22\cf0\f0\charscalex100 {dos tapones.
Este peso constituye m}\fs14\cf0\f0\charscalex100 {V. }\par\pard\li1173\ri0\sl

-386\slmult0 \*\tx1586\fs22\cf0\f0\charscalex100 {2.}\tab \fs22\cf0\f0\charscale
x100 {Aada 30 mL de agua y conecte el matraz al sistema de reflujo. Ponga el sele
ctor de}\par\pard\li1453\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {temperat
ura de la placa calefactora en la posicin 2. Inicie la medida. Cuando la temperat
ura}\par\pard\li1453\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {se mantenga
constante durante al menos un cuadrante}\fs22\cf0\f0\charscalex100\b {,}\b0 \fs2
2\cf0\f0\charscalex100 { presione \uc1\u8220Xfinalizar la medida\uc1\u8221X. }\
par\pard\li1440\ri0\sl-386\slmult0 \*\tx7360\fs22\cf0\f0\charscalex100 {Seleccio
ne la zona de temperatura constante con el botn
}\tab \fs22\cf0\f0\charscalex
100 {y obtenga la temperatura con }\par\pard\li1440\ri0\sl-493\slmult0 \fs22\c
f0\f0\charscalex100 {el botn
.
Esta temperatura }\fs22\cf0
\f0\charscalex100 {es la temperatura de ebullicin del agua, T}{\super \fs20\up5\c
f0\f0\charscalex100 {*}}\fs20\cf0\f0\charscalex100 {eb}\fs22\cf0\f0\charscalex10
0 {. Si es}\par\pard\li1440\ri0\sl-426\slmult0 \fs22\cf0\f0\charscalex100 {neces
ario se calibra el aparato (punto 4 de}\fs22\cf0\f0\charscalex100 {l apartado: d
eterminacin de la constante}\par\pard\li1440\ri0\sl-386\slmult0 \fs22\cf0\f0\char
scalex100 {ebulloscpica de la acetona). Con los datos de esta experiencia complet
e la tabla 3. }\par\pard\li1200\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {
3.}{ }\fs22\cf0\f0\charscalex100 {Una vez determinada la temperatura de ebullicin
del agua retire el matraz con el agua de la }\par\pard\li1506\ri0\sl-386\slmult
0 \fs22\cf0\f0\charscalex100 {placa calefactora }\fs22\cf0\f0\charscalex100\b {
(Cuidado: quema!)}\b0 { }\fs22\cf0\f0\charscalex100 {y enfrelo, mantenindolo tapado
, durante dos o tres}\par\pard\li1506\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex
100 {minutos, en un bao de agua. Cuando el matraz se haya enfriado, pselo tapado s
obre la base}\par\pard\li1506\ri0\sl-506\slmult0 \*\tx4853\fs22\cf0\f0\charscale
x100 {de corcho. Este peso constituye }{ }\fs22\cf0\f0\charscalex100 { }\fs22\cf
0\f0\charscalex100 {m}{ }\fs20\cf0\f1\charscalex100 {ll}\tab \fs22\cf0\f0\charsc
alex100 {.}\par\pard\li1186\ri0\sl-333\slmult0 \*\tx1533\fs22\cf0\f0\charscalex1
00 {4.}\tab \fs22\cf0\f0\charscalex100 {Pese en un vaso de precipitado la cantid
ad de sal necesaria para obtener una disolucin 0.5 }\par\pard\li1533\ri0\sl-386\s
lmult0 \fs22\cf0\f0\charscalex100 {molal. Introdzcala en el matraz mediante un }\
fs22\cf0\f0\charscalex100 {embudo de plstico y pese el matraz tapado }\par\pard\l
i1533\ri0\sl-466\slmult0 \*\tx6053\fs22\cf0\f0\charscalex100 {sobre la base de c
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calex100 {m}{ }\fs18\cf0\f1\charscalex100 {ll}\tab \fs22\cf0\f0\charscalex100 {'
. }\par\pard\li1200\ri0\sl-346\slmult0 \*\tx1533\fs22\cf0\f0\charscalex100 {5.}
\tab \fs22\cf0\f0\charscalex100 {Coloque el matraz en el sistema de calefaccin e
inicie una nueva medida. Cuando la}\par\pard\li1533\ri0\sl-386\slmult0 \fs22\cf0
\f0\charscalex100 {temperatura se mantenga constante durante al menos un cuadran
te presione \uc1\u8220Xfinalizar }\par\pard\sect\sectd\sbknone\pgwsxn12240\pghs
xn15840\marglsxn666\margrsxn133\cols2\colno1\colw9866\colsr-0\colno2\colw1573\pa
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eccione la zona de temperatura constante con el botn
}\par\column\
pard\li0\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {y }\par\pard\sect\sectd\
sbknone\pgwsxn12240\pghsxn15840\marglsxn666\margrsxn133\pard\li1533\ri0\sl-400\s
lmult0 \fs22\cf0\f0\charscalex100 {obtenga la temperatura con el botn
.
Esta temperatura es la temperatura de ebullicin }\par\pard\li1533\ri0\sl-480\slmu
lt0 \fs22\cf0\f0\charscalex100 {de la disolucin, T}\fs20\cf0\f0\charscalex100 {eb
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nto con las otras sales.}\par\pard\li9866\ri0\sl-213\slmult0 \fs18\cf0\par\pard\
li9866\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li9866\ri0\sl-213\slmult0 \fs18\cf0
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pard\li920\ri0\sl-386\slmult0 \fs18\cf0\f0\charscalex100 {Laboratorio de Qumica Fs
ica(09-10), Grupo Innovacin, P8 }\par\pard\sect\sectd\sbknone\pgwsxn12240\pghsxn1
5840\marglsxn666\margrsxn133\pard\sect\sectd\sbkpage

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rscalex100 {m}{\sub \fs16\cf0\f0\charscalex100 {B}}\fs22\cf0\f0\charscalex100 {
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lex100\i {(kg)}\i0 \par\pard\sect\sectd\sbknone\pgwsxn12240\pghsxn15840\marglsxn
666\margrsxn133\pard\li920\ri0\sl-453\slmult0 \fs22\cf0\f0\charscalex100 {T}\fs1
4\cf0\f0\charscalex100 {eb}\fs22\cf0\f0\charscalex100 { (C) es la temperatura de
ebullicin de la disolucin.
}\par\pard\li920\ri0\sl-440\slmult0 \fs22\cf0\f0\ch
arscalex100 {\uc1\u8710X}\fs22\cf0\f0\charscalex100 {T}\fs14\cf0\f0\charscalex10
0 {eb }\fs22\cf0\f0\charscalex100 {= T}\fs14\cf0\f0\charscalex100 {eb}\fs22\cf0\
f0\charscalex100 {-T}{\super \fs14\up4\cf0\f0\charscalex100 {*}}\fs14\cf0\f0\cha
rscalex100 {eb }\par\pard\li920\ri0\sl-453\slmult0 \fs22\cf0\f0\charscalex100 {T
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n funcin de m}\fs14\cf0\f0\charscalex100 {B}{ }\fs22\cf0\f0\charscalex100 {y dete
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pard\li1106\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1106\ri0\sl-306\slmult0 \*\t
x1453\fs22\cf0\f0\charscalex100 {2.}\tab \fs22\cf0\f0\charscalex100 {Representar
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er la constante}\par\pard\li1453\ri0\sl-413\slmult0 \fs22\cf0\f0\charscalex100 {
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liografa. }\par\pard\li1106\ri0\sl-493\slmult0 \*\tx1453\fs22\cf0\f0\charscalex10
0 {3.}\tab \fs22\cf0\f0\charscalex100 {Demostrar las suposiciones 1, 2 y 3 que s
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scalex100 {e}{ }\fs22\cf0\f0\charscalex100 {=}{ }\fs22\cf0\f0\charscalex100 {K}\
fs20\cf0\f0\charscalex100 {e}\par\pard\li1453\ri0\sl-413\slmult0 \fs22\cf0\f0\ch
arscalex100 {m}\fs14\cf0\f0\charscalex100 {B}\fs22\cf0\f0\charscalex100 {, para
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lmult0 \fs18\cf0\par\pard\li1586\ri0\sl-413\slmult0 \fs22\cf0\f0\charscalex100 {
ln}\par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li0\ri0\sl-413\slm
ult0 \fs22\cf0\f0\charscalex100\i {x}\i0 \par\pard\li93\ri0\sl-133\slmult0 \fs12
\cf0\f0\charscalex100\i {A}\i0 \par\column\pard\li0\ri0\sl-213\slmult0 \fs18\cf0
\par\pard\li0\ri0\sl-413\slmult0 \*\tx493\*\tx973\fs22\cf0\f0\charscalex100 {=}\
tab \fs22\cf0\f0\charscalex100 {\uc1\u8722X}{ }\fs22\cf0\f0\charscalex100\i {x}\
i0 \tab \fs22\cf0\f0\charscalex100 {\uc1\u8776X}{ }\fs22\cf0\f0\charscalex100 {\
uc1\u8722X}\par\pard\li373\ri0\sl-226\slmult0 \*\tx853\*\tx1266\fs22\cf0\f0\char
scalex100 {ln(}\fs22\cf0\f0\charscalex100 {1}\tab \fs22\cf0\f0\charscalex100 {)}
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\fs18\cf0\par\pard\li0\ri0\sl-413\slmult0 \fs22\cf0\f0\charscalex100\i {Suposic
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slmult0 \fs22\cf0\f0\charscalex100 {1}\par\pard\sect\sectd\sbknone\pgwsxn12240\p
ghsxn15840\marglsxn666\margrsxn133\cols2\colno1\colw3413\colsr-0\colno2\colw8026
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2760\ri0\sl-186\slmult0 \*\tx3173\fs12\cf0\f0\charscalex100 {*}\tab \fs12\cf0\f0
\charscalex100 {*}{\super \fs12\up1\cf0\f0\charscalex100 {2}}\par\column\pard\li
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}\par\column\pard\li0\ri0\sl-253\slmult0 \fs22\cf0\f0\charscalex100 {\uc1\u8776X
}\par\pard\sect\sectd\sbknone\pgwsxn12240\pghsxn15840\marglsxn666\margrsxn133\co
ls2\colno1\colw5146\colsr-0\colno2\colw6293\pard\li1573\ri0\sl-226\slmult0 \*\tx
3026\fs22\cf0\f0\charscalex100\i {T}\i0 {\sub \fs12\cf0\f0\charscalex100\i {e}\i

0 }\fs22\cf0\f0\charscalex100 {\uc1\u8776X}{ }\fs22\cf0\f0\charscalex100\i {T}\i
0 {\sub \fs12\cf0\f0\charscalex100\i {e}\i0 }\fs22\cf0\f0\charscalex100 {\uc1\u8
658X}\fs22\cf0\f0\charscalex100\i {T}\i0 {\sub \fs12\cf0\f0\charscalex100\i {e}\
i0 }\fs22\cf0\f0\charscalex100\i {T}\i0 \tab \fs22\cf0\f0\charscalex100\i {T}\i0
\par\pard\li2720\ri0\sl-133\slmult0 \*\tx3133\fs12\cf0\f0\charscalex100\i {e}\i
0 \tab \fs12\cf0\f0\charscalex100\i {e}\i0 \par\pard\li2306\ri0\sl-253\slmult0 \
fs22\cf0\f0\charscalex100 {\uc1\u8776X}\par\pard\li1586\ri0\sl-226\slmult0 \*\tx
2453\fs22\cf0\f0\charscalex100\i {n}\i0 {\sub \fs12\cf0\f0\charscalex100\i {A}\i
0 }\fs22\cf0\f0\charscalex100 {+}{ }\fs22\cf0\f0\charscalex100\i {n}\i0 \tab \fs
22\cf0\f0\charscalex100\i {n}\i0 \par\column\pard\li0\ri0\sl-226\slmult0 \fs22\c
f0\f0\charscalex100\i {Suposicin}\i0 { }\fs22\cf0\f0\charscalex100 {2}\par\pard\l
i66\ri0\sl-226\slmult0 \fs22\cf0\f0\charscalex100\i {Suposicin}\i0 { }\fs22\cf0\f
0\charscalex100 {3}\par\pard\sect\sectd\sbknone\pgwsxn12240\pghsxn15840\marglsxn
666\margrsxn133\pard\li2106\ri0\sl-133\slmult0 \*\tx2573\fs12\cf0\f0\charscalex1
00\i {B}\i0 \tab \fs12\cf0\f0\charscalex100\i {A}\i0 \par\pard\li1106\ri0\sl-213
\slmult0 \fs18\cf0\par\pard\li1106\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li1106\
ri0\sl-280\slmult0 \*\tx1453\fs22\cf0\f0\charscalex100 {4.}\tab \fs22\cf0\f0\cha
rscalex100 {Calcular la constante ebulloscpica \uc1\u8220Xterica\uc1\u8221X y comp
ararla con la experimental. }\par\pard\li1106\ri0\sl-386\slmult0 \*\tx1453\fs22\
cf0\f0\charscalex100 {5.}\tab \fs22\cf0\f0\charscalex100 {Sabiendo que la compos
icin centesimal de la sustancia X es 79.2% de C, 15.1 % de O y 5.7}\par\pard\li14
53\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {% de H y que M}\fs14\cf0\f0\ch
arscalex100 {molecular }{ }\fs22\cf0\f0\charscalex100 {= M}\fs14\cf0\f0\charscal
ex100 {emprica X}\fs22\cf0\f0\charscalex100 { n, determinar la frmula emprica de la
sustancia X. }\par\pard\li1453\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {D
eterminar n y la frmula molecular de X.}\par\pard\li1106\ri0\sl-400\slmult0 \*\tx
1453\fs22\cf0\f0\charscalex100\b {6.}\b0 \tab \fs22\cf0\f0\charscalex100 {Calcul
ar el coeficiente de Vant Hoff mediante la expresin 3. Comparar y discutir las }\p
ar\pard\li1453\ri0\sl-386\slmult0 \fs22\cf0\f0\charscalex100 {diferencias entre
los coeficientes de varias parejas.}\par\pard\li9760\ri0\sl-293\slmult0 \fs22\cf
0\f0\charscalex100 {10}\par\pard\li920\ri0\sl-213\slmult0 \fs18\cf0\par\pard\li9
20\ri0\sl-386\slmult0 \fs18\cf0\f0\charscalex100 {Laboratorio de Qumica Fsica(09-1
0), Grupo Innovacin, P8 }\par}

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