Elementis HTS 10/31/2009 4:53:21 AM PAGE 3/011 Fax Server MATERIAL SAFETY DATA SHEET Revision date: 18-Aug-2009 ‘Supercedes: 23-Apr-2002 MSDS Number: 10490 ft. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product name: DAPRO® 7007 Product Use Description: Coating Drier Additive Company/Undertaking Elementis Specialties, Inc. Elementis Specialties, Inc. Identification 329 Wyckofis Mill Road pla Elements Service Centre NV Hightstown, NJ 08520 Pegasus Park Tel: (609) 443-2000 De Kleetlaan 12A - Bus 3 B-1831 Diegem, Belgium Tel: +32 (0}2 790 76 00 Fax: +32 (0)2 790 76 60 CHEMTREC Emergency Response Number: 1-800-424-9300 (1-703-527-3887) 'SGS Emergency Response Number: + 32 (0)8 575 55 55 Produet_Stewardship@elementis.com Emergency telephone number 2. HAZARDS IDENTIFICATION EMERGENCY. Appearance: Liquid Color: Amber Oder: Light WARNING, ‘Combustible material Harmful by inhalation and if swallowed Iritating to eyes and respiratory system May cause skin irritation and/or dermatitis Vapours may cause drowsiness and dizziness Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Potential health effects: Eye contact: Initating to eyes. Signs and symptoms include burning, tearing, redness and swelling. Skin contact: May cause skin irritation andlor dermatitis. Revision Number: 1 Page 1 of 9Elementis HTS 10/31/2009 4:53:21 AM PAGE 4/011 Fax Server 10490 DAPRO® 7007 Inhalation: Ingestion: Routes of exposure: Target Organs: See Sections 4 Environmental hazard: Harmful by inhalation. Irritating to respiratory system. Vapors may cause drowsiness and dizziness. Harmful if swallowed, Ingestion may cause gastrointestinal iritation, nausea, vomiting and diarhea, Inhalation, Skin, Ingestion Respiratory system, Central nervous system 1 & 12 for addi nal toxicological and ecological information ‘See Section 12, below B. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components = ‘Components CAS-No Weight % jethyiene glycol methyi ether T11-77-3 1% -Ethylhexanoic acid 149-57-5 2.5% f-10-Phenanthroline 66-71-7. 25-10% -Butanol 71-36-3, 25-10% [Stoddard solvent (< 0.1% Benzene) B052-41-3 25-10% Dipropylene glycol methyl ether 34590-94-8 50 - 100%, ‘This product is considered hazardous as defined under OSHA's Hazard Communication Standard (29 CFR 1910.1200). (4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: IF INHALED: Remove to fresh air and keop at rest in a position comfortable for breathing. If breathing is difficult, give oxygen. Wash off immediately with soap and plenty of water. If a person feels unwell or symptoms of skin initation appear, consult a physician Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes, If eye irritation persists, consult a specialist. If swallowed, seek mecical advice immediately and show this container or label. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person, Flash Point: Flash Point Method: Autoignition temperature: |. FIRE-FIGHTING MEASURES 167 °F 175°C ASTM 03278 Not selfigniting Revision Number: 1 Page 20f9Elementis HTS 10/31/2009 4:53:21 AM PAGE /011 Fax Server 10490 DAPRO® 7007 Explosive properties: LEL: 1.4 Vol% UEL: 10.4 Vol% Unusual Fire and Explosion Emits toxic fumes under fire conditions. Hazards: Reactivity Hazard: None known Suitable extinguishing media: Use water spray, aloohol-resistant foam, dry chemical or carbon dioxide Hazardous combustion products: Carbon monoxide, Carbon dioxide (C02). Special Fire Fighting Procedure: Firefighters should wear NIOSH/MSHA approved self-contained breathing apparatus, and full protective clothing (6. ACCIDENTAL RELEASE MEASURES Personal precautions: Evacuate personnel to safe areas. Keep people away from and upwind of spilileak. Use personal protective equipment. Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer systom. Clean-up methods: ‘Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Sweep up and shovel into suitable containers for disposal. Prevent product from entering drains, Clean spill area thoroughly. Local authorties should be advised if significant spillages cannot be containes. [7 HANDLING AND STORAGE Handling: Remove all sources of ignition. Avoid contact with skin, eyes and clothing. Avoid breathing mists, dusts, or vapors. Wash hands thoroughly after handling. Storage: Keep containers tightly closed in a cool, well-ventilated place. Keep product and empty container away from heat and sources of ignition. Additional Storage: Not required under normal use [8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures: Maintain adequate ventilation to keop hazardous ingredients below their PELs or ‘TLVs. Use NIOSHIMSHA approved respirator whenever exposure limits exceeded. Personal Protective Equipment Eye protection: Tightly fiting safety goggles Skin and body protection: Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place Revision Number: 1 Page 3of 9Elementis HTS 10490 10/31/2009 4:53:21 AM PAGE 6/011 Fax Server DAPRO® 7007 Respiratory protection: Hand protection: Hygiene measures: In case of mist, spray or aerosol exposure wear suitable personal respiratory protection and protective suit. Protective gloves, Solvert-resistant gloves Handle in accordance with good industrial hygiene and safety practice. Exposure controls ‘Components OSHA STEL OSHAPEL OSHA TWA_| AGGINSTEL [ACGIH TWA Ethyhexanoic acd ‘B mgim® (inhalable fraction, ‘and vapor) nBuanal 300 main 300 mein 20 ppm 400 ppm 400 pom Sioddard sonent (07% 2800 moi 525 mglm? 700 ppm Benzene) 500 ppm 100 ppm Dipropyiene glycol methyl] S00 mgin™ {00 gi 600 mol? TSO ppm 700 ppm ether 150 ppm 4100 ppm 4100 ppm ‘Componenis OSHA Ceiling ‘ACGIH Gelling WEEL Gelling m-Butanol 150 molm™ 50 ppm . PHYSICAL AND CHEMICAL PROPERTIES Appearance: Color: Odor: Physical state: Vapor pressure Vapor density: Boiling pointrange Solub Density: Bulk density: Flash Point: Ignition temperature: Solvent content: Percent Volatile: Water content: VOC content: Liquid Amber Light Liquie < 1.0 mm Hg @ 25° O.7 hPa @ 20°C 51 365 °F / 185°C Water Miscible 0.95 giem* 7.9 Ibs/gal 167 °F 178°C 205 (°C) 85-90% Not applicable 843 git. [10. STABILITY AND REACTIVITY Stable at normal conditions Heat, flames and sparks Revision Number: 1 Page 4 of 9Elementis HTS 10490 10/31/2009 4:53:21 AM PAGE 7/011 Fax Server DAPRO® 7007 Matorials to avoid: Hazardous decomposition products: Possibility of Hazardous Reactions: Oxidizing agents No decomposition if stored normally Will not occur [11. TOXICOLOGICAL INFORMATION Acute toxicity ‘Compenents TCS0/inhalation/4hiRat [DS0/DermalRat LDs0/OralRat ZEthyihexenoic acd 36 mg/l > 2000 mg/kg. 72000 - 3000 mg/kg 7,10-Phenanthroline No data available No data available "500 mg/kg (mouse) ‘-Butanol ‘8000 ppm. '3400 mg/kg _ "790 mg/kg, Disthylene glyco! methyl ether No data available ‘2500 pkg | 4 nl ‘Sra avant (= 0.1% > 5500 mg/m? No data available > 5000 maka (rat) Dipropyiene glycol methyl ether No data available "9500 maikg (rabbi) ‘5230 malka | Local effects si ritation: Eye irritation: Inhalation: Ingestion: Chronic toxicity: May cause skin intation andlor dermatitis Initating to eyes. Iritating to respiratory system. Ingestion may cause gastrointestinal iritation, nausea, vomiting and diarchea. Long-term chronic toxicity studies to evaluate the carcinogenic potential of this product have not been conducted; See table and/or data, below, of individual ‘components ‘Components, Ne TARC OSHA T10-Phenanthroline Group 3- Unclassifiable as to carcinogenicity to humans ‘Stoddard solvent (<0.1% Benzene) [Group 3 - Unciassifiable as ‘o| carcinogenicity to humans, Specific effects Revision Number: 1 Page 5 of 9Elementis HTS 10/31/2009 4:53:21 AM PAGE 8/011 Fax Server 10490 DAPRO® 7007 Carcinogenic effects: Vitamin K (1, 10-phenanthroline) has been reviewed by IARC. There is inadequate evidence in humans for the carcinogenicity of vitamin K, There is inadequate evidence in experimental animals for the carcinogenicity of vitamin K. Therefore, the ‘working group concluded that Vitamin K is not classifiable as to its carcinogenicity to humans (Group 3). Stoddard solvent has boon reviewed by IARC. There is inadequate evidence for the carcinogenicity of petroleum solvents in humans. No data were available on the carcinogenicity of special boiling range solvents or white spirits in experimental, animals. Therefore, the working group concluded that Petroleum solvents (stoddard solvent) are not classifiable as to their carcinogenicity to humans (Group 3). Target Organs: Respiratory system, Central nervous sysiem 2. ECOLOGICAL INFORMATION Aquatic toxicity: Components | LG50/S6hr/48hr/24hr | ECSO/GEhr/4Bhi/24hr | Bioaccumulation [No observable EWect Concentration Factor Concentration/96hr/48| het 24hr (NOEC) TEMnynexaTO Boe 20 mal. 54 moi No data available | _ No data available (fresh water, ish) | (Daphnia magna; 48hr) 61 mg/L, (S. subspicatus; 72hr) 44 mg. (S. subspicatus; 96h7) TButanol 1730 mae 2337 mg. No data available | No data available (fathead minnow) | (Daphnia magna; 48h) 500 mg/L (Aigea) Diethylene sheol methyl 7500 mall 5000 mg No data available ether (Lepomis macrochirus;| (water flea; 24hrs) 96hrs) 1192 mg/l 8744 mall (Daphnia magna; (Pimephales promelas aahrs) ‘S6hrs ) Seaaardsonert OTR] > 71000 mol. 5 F000 mel No data available | Nodata available enzene) (fish) Dipropylene glycol methyT 70 g/t 189 mg No data available | _ No data available ether (P. promelas; 96hr) _|(Daphnia magna: 48hr) Persistence and No data available degradability: No data available Revision Number: 1 Page 6 of 9Elementis HTS 10/31/2009 4:53:21 AM PAGE 10490 e011 Fax Server DAPRO® 7007 Biodegradability: No data available Bioaccumulative potential: No data available Physical / Chemical: No data available Bopicon: CoD-value: No data available BODS-value: No data available [13. DISPOSAL CONSIDERATIONS Waste from residues / unused Do not contaminate ponds, waterways or ditches with chemical or used container. products: Dispose of in accordance with Local and National regulations. RCRA Hazardous Waste: RCRA: Not listed [14. TRANSPORT INFORMATION U.S, Department of Transportation Ground (49 CFR): Proper shippingname: Not regulated i A on QCAQAATA): Proper shippingname: —_Not regulated International Maritime Organization (IMO/IMDG): Proper shipping name: Not regulated ‘Surface Shipments in Europe (ADRIRID): Proper shipping name: Not regulated ['5. REGULATORY INFORMATION Heavy metals: Heavy metals content (ppm): Not applicable International Inventories. Revision Number: 4 Page 7 of 9Elementis HTS 10/31/2009 4:53:21 AM PAGE 10/011 Fax Server 10490 DAPRO® 7007 TSCA Listed EINECS! Listed (usa) (Eu) Dsu/ Listed NDSL/ Not applicable (CANADA) (CANADA) ENcS/ Listed lecsc/ Listed (WAPAN) (CHINA) Piccs! Listed KECL Listed (PHILLIPINES) (KOREA) Alcs! Listed HSNO! Listed (AUSTRALIA) New Zealand: LS. Regulations ISCA Section 12(b) Exnort Notification Dipropyiene glycol methyl ether (CAS # 34590-94-8) Listed ‘SARA Title Il: Section 302 EHS: None Section 311/312: ‘Acute Health Hazard, Chronic Health Hazard Section 313: This product contains the following n-Butanol (CAS # 71-36-3) chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372): Listed California Prop. 65: Not listec Canada WHMIS hazard class: B3 Combustible liquid D1B Toxic materials D2B Skin or Eye imitation ‘This MSDS has been prepared according to the hazard criteria of the Controlled Producis Regulations (CPR) and the MSDS contains all of the information required by the CPR. 6. OTHER INFORMATION HMIS: Health: Flammability Reactivity: Revision Number: 1 Page 8 of 9Elementis HTS 10/31/2009 4:53:21 AM PAGE 11/011 Fax Server 10490 DAPRO® 7007 Previous Revision Date: 23-Apr-2002 Key/Legend: NIA: Not applicable NID: Not determined ppm: Parts per milion X: Listed Propared by: Product Stewardship The data set forth in these sheets are based on information provided by the suppliers of the raw materials and chemicals, used in the manufacture of the aforementioned product. ELEMENTIS SPECIALTIES makes no warranty with respect to the accuracy of the information provided by their suppliers, and declaims all liability of reliance thereon. ELEMENTIS SPECIALTIES warrants only that its products conforms with their published specifications, and no other express warranty is made with regards thereof. We do not guarantee favorable results, and we assume no liability in connection with the use of the producis. They are intended for use by persons having technical skill and knowledge, at their own discretion and risk. Revision Number: 1 Page 9 of 9