Sol Aits 2013 FT I Jeea Paper 1

AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/13
JEE(Advanced)-2013
FIITJEE
ANSWERS, HINTS & SOLUTIONS

FULL TEST I
(Paper-1)
ALL INDIA TEST SERIES
From Long Term Classroom Programs and Medium / Short Classroom Program 4 in Top 10, 10 in Top 20, 43 in Top
100, 75 in Top 200, 159 in Top 500 Ranks & 3542 t o t a l s e l e c t i o n s i n I I T - J E E 2 0 1 2
Q. No.
1.
PHYSICS
C
CHEMISTRY
A
MATHEMATICS
D
2.
3.
4.
5.
6.
7.
8.
9.
C, D
A, C, D
A, C
10.
A, C
A, C
A, B
11.
A, C
A, B, C
B, C, D
12.
A, B, C, D
A, C
13.
A, B
B
14.
15.
16.
17.
18.
(A) (s)
(B) (p)
(C) (p)
(D) (q, r)
(A) (r)
(B) (q)
(C) (q)
(D) (s)
(A) (p, r, t)
(B) (q)
(C) (r, s)
(D) (r, s)
(A) (p, q, s)
(B) (p, s)
(C) (r, s)
(D) (q, t)
(A) (p, q, r, s)
(B) (p)
(C) (q, s)
(D) (p, r)
(A) (s)
(B) (t)
(C) (q)
(D) (s)
1.
2.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
Physics
PART I
SECTION A
1.
E2 = VR2 + (VL VC )2 = VR2 + 0

As, E = VR
VR = V = 220 V
E 220
I=
=
= 2.2 amp
R 100
3.
Equivalent circuit can be drawn as

79
Equivalent capacitance =
C.
30
C
2C
2/3C
C
C
2C
8/3C
C
2C
2C
19C/11
C
This is simply discharging of a capacitor.
q = Q 0e t / CR where C = 40r
5.
6.
When the circuit will reach to steady state the inductor will given zero resistance. Hence the entire
current will only pass through it.
H + 2H 3H
=
X=
2
2
8.
Here V 1/r
r distance between Sun and Planet.
9.
(y h) + x 2 + h2 = A
dy
+
dt
dx
=0
x + h dt
dy
x
dx
=
2
2 dt
dt
x +h
2
dt
= v 2A
aB = v 2A
dy
3
= vA
dt
5
3
| uB |= v A
5
d2 y
hh=4cm
=4m
4.
hx=3cm
=3m
(i)
h2
(x 2 + h2 ) 3
16
(5)3
aB =
10.
16 2
vA
125
Mg T = Ma
T = ma
Solving (i) and (ii)
Mg
a=
(M + m)
FBD of man
Mg N = Ma
Mmg
N=
(M + m)
(ii)
(i)
(ii)
N
a
Mg
11.
2m
T=
= 3.14 s.
qB
Chemistry
PART II
SECTION A
O
1.
(1) O3
Et
OH
Et
( ) 2
4
( 2 ) NaBH4
Et
2 Ag O/NH OH
2.
C
PCl5
Cl
CHO
COO
3.
HO
H
H
1
C
2
H C
3
HO C
H 4C
5
H C
HO
OH
CH2OH
PCC
OH
LiAlH 4
Cl
CHO
CH2OH
OH
Et
OH
1
C
2
C
3
C
4
C
5
C
and
OH
6CH OH
2
CH2OH
H
OH
H
OH
Cyclic forms of diastereomers that differ

only in the configuration of C1, are known
as anomers.
6CH OH
2
The configuration differ only at carbon no. 1.

4.
For equimolar solutions, n1 = n2

x1 = 0.5 and 0.5
PB = xB PBo = 0.5 160 = 80 mm
PT = x T PTo = 0.5 60 = 30 mm
PTotal = 80 + 30 = 110 mm
Mole fraction of toluene in vapour phase =

5.
PT
30
=
= 0.27
PTotal 110
Entropy is a state function, i.e. the change entropy depends upon the initial and final states of the
system and not on how that change is brought about.
7.
0.6 o
d orbitals in symmetrical
0.4 o
field of ligands
high spin d4 configuration

in an octahedral field
CFSE = 3(- 0.4) o + 0.6 o = - 1.2 o + 0.6 o = -0.6 o

Given (K sp )
8.
AgBr
= 5 1013
KBr + AgNO3
AgBr + KNO3
Given, [AgNO3] = 0.05 M

Ag+ = NO3 = 0.05M
Ag+ Br = (K sp ) AgBr 0.05 Br = 5 10 13

5 10 13
Br =
= 1 10 11M
0.05
Br = [KBr ] = 1 10 11M
wt. of KBr = 1 1011 120 = 1.20 109 gm / litre
10.
H H
Br Br
Plane of symmetry
11.
(A)
anh.ZnCl2
Ph CH2 OH
Ph CH2 Cl + Zn ( OH) Cl ( immediate )
conc.HCl
( white turbidity )
CH3 CH2 OH CH3 CH2 Cl + Zn ( OH) Cl
( slow )
Lucas reagent
(B)
Lucas
Ph CH2 OH
PhCH2 Cl + Zn ( OH) Cl
reagent
(immediate )
( White turbidity )
Ph OH
No reaction under normal condition
Lucas
reagent
(C)
Lucas
( CH3 )2 CH Cl + Zn ( OH) Cl
( CH3 )2 CH OH
reagent
( White turbidity )
(Moderate rate )
Lucas
CH3 CH2 CH2 CH2 OH
CH3 CH2 CH2 CH2 Cl + Zn ( OH) Cl
reagent
( Slow )
( White turbidity )
12.
H2S + O3
H2O + S + O2
PbS + 4O3
PbSO4 + 4O2
3SO2 + O3 3SO3
3SnCl2 + 6HCl + O3
3SnCl4 + 3H2O
13.
Zn + Fe+2
Fe + Zn+2
0.0591
logK eq
n
Given, E = 0.2905
0.0591
0.01
0.2905 = Eo
log
2
0.001
0.02905 + 0.0295 log10
= 0.2905 + 0.0295
= 0.32
0.0591
Eo =
logK eq
2
0.0591
0.32 =
logK eq
2
E = Eo
0.32
K eq = 10 0.0295
14.
For 1 mole of O2
2
O 2 2O2 i.e. 3O2

3
4
Or mol of Al to change into Al+3 ions.
3
n=4
Thus, G = nEF
E=
G +827000
=
= 2.14 volt
nF 4 96500
0.059
1.1 2
logK eq
= 37.2881 = logK eq
2
0.059
K eq = 1.9 10 37
15.
Eocell =
16.
Copper sulphate when reacts with hypophosphorus acid, gets reduced to cuprous hydride.
4CuSO 4 + 3H3PO 2 + 6H2 O 2Cu2H2 + 3H3PO 4 + 4H2 SO 4
17.
3Ba ( OH)2 + 2P4 + 6H2O

3Ba (H2PO2 )2 + 2PH3
( J)
(L )
(K )
BaSO4 + 2H3PO2
Ba (H2PO2 )2 + H2 SO4
(L )
( N)
( M)
gives apple
green colour in
the flame
7
18.
H4P2O7 (pyrophosphoric acid) is a tetrabasic acid, i.e. 4-hydroxyl groups are present. It is
prepared by removing one water molecule from two molecules of orthophosphoric acid. Each
phosphorus atom lies in same tetrahedral environment, so called isopolyacid.
O
O
O
O
HO
HO
OH
H2 O
OH
HO
OH
OH
OH
OH
OH
SECTION-B
1.
(A)
H3C
CH
(1) OH
COOH
H3C
( 2 ) H+
CH
Br
(B)
H3C
COOH
OH
CH
CH2
COOH
(1) OH
( 2 ) H+
H3C
CH
CH
COOH
Br
O
(C)
C
H 2C
CH2
CH2
OH
H2 C
OH
Br
CH2
CH2
Br
(D)
C
H2C
CH2
CH2
CH2
Br
OH
OH
Reactions A, C, and D show SN2 reactions.

2.
In case of (A), compound given in (A) exchanges H with D and becomes racemic.
In case (B), compound in (B) reacts through a carbocation and gives racemic mixture.
In case of (C), no bond attached to the stereocentre breaks in reaction of (C), so retention.
In case of (D), compound in (D) gives Hoffmann elimination and it is an example of antielimination. Product does not have any stereogenic centre.
D
Reaction (B ) gives H3C
OH
( d, A form )
C2 H 5
D
Reaction ( C ) gives H3C
COOH
C2H5
H3C
Re action (D ) gives
CH3
(No stereocentre )
Mathematics
PART III
SECTION A
1.
We must have f(a2 + 2a + 5) > f(a + 11)

a2 + 2a + 5 < a + 11
a (3, 2)
a can take values 2, 1, 0, 1
2.
ABC is equilateral
a=b=c
3.
AC2 = AB2 + BC2

.. (1)
BD2 = BC2 + CD2
.. (2)
CA2 = CD2 + DA2
.. (3)
.. (4)
DB2 = DA2 + AB2
Equation (1) + (3) and (2) + (4) gives AC = BD
So, equation (1) and (2) give AB = CD and equation (2) and (3) give BC = AD
So s CBD and ADB are congruent CBD = ADB = 90 ABD
CBD + ABD = CBA DB lies in the plane of ABC, so the points are coplanar
4.
Let a d = 3t; then bc = (d + zt)(d + t) = d2 + 3td + 2t2

a
3t
3t
Also = 1 + , so hk = d2 1 + = d2 t + 3td < bc
d
d
d
bc > hk
5.
Clearly P (1, 2)
Equation of tangent at P is 4x(1) + y(2) = 8
A (2, 0) and B (0, 4)
Similarly normal at P is 2x 4y = 6
3
A '( 3, 0) and B ' 0,
2
P
A
A
0 4 1
1
5
Area BPB' = 1 2 1 = and Area APA ' = 5
2
4
3
0
1
2
Ratio = 4
6.
As sin x + sin y cos cos x x R
Let x = sin y 1 sin y = 1

2
1 + sin x cos cos x
cos cos x sin x 1
cos2 + 1 = 1 cos = 0 sin y + cos = 1 + 0 = 1
7.
I=
sin x
x
I<
dx <
2
and J =
3
x
x
1
dx =
cos x
x
2
3
1
< x 1/ 2 dx = 2
0
J<2
8.
2c
Equation of tangent x + t 2 y = 2ct T (2ct, 0) and T 0,

1
1
Equation of normal t 3 x ty = c ( t 4 1) ; N c t 3 , 0 ; N 0, c t 3
t
t

c
c
NT = 3 + ct; N' T ' = ct 3 +
t
t
1 c
c
1
2t 4
1
c
=
ct
+
and ' = ct 3 + ct
3
2
4
c (1 + t )
2
t
2 t
t
1 1
2
1
2
=
=
+
' c2
' c 2 (1 + t 4 )
=
9.
10.
We have 2 sin2 cos2 x = 2 sin2 sin 2x

2
2
cos x = sin 2x cos x(cos x 2 sin x) = 0
1 2 tan x = 0 as cos x 0
1
3
and cos 2x =
tan x =
5
2
Clearly, the point lies on 7x y = 5

A
Also, centre of the circle must lie on the bisectors of the
lines
x + y + 13 = 0 and 7x y 5 = 0 given by
C(h, k)
x + y + 13
7x y 5
=
x 3y = 35 and 3x + y + 15 = 0
B
2
50
Let (h, k) be the centre of the circle, then h 3k = 35 ..
(1)
and 3h + k = 15
.. (2)
k2
7 = 1 h + 7k 15 = 0
Clearly CB is perpendicular BP
h 1
On solving, we get centres as C1 (29 2) and C2 (6, 3)
r12 = 800 and r12 = 50 smaller circle has radius = 50
x + y + 13 = 0
P(1, 12)
7x y 5 = 0
.. (3)
Therefore area of quadrilateral ACBP = 2 50 200 sq. units

2
11.
Let f(x) = ax 2 + bx + c and f(1) = a + b + c < 0 f(x) < 0 for all x R f(2) < 0 4a 2b + c <
0
Again f(3) + f(2) < 0 13a + 5b + 2c < 0
Also f(5) < 0 25a 5b + c < 0 5b 25a c > 0
12.
10
(x x) ( x ) = 0 ; x < 0
f(x) =
2
; x0
( x + x ) x = 2x
f is continuous and differentiable
0 ; x < 0
Again f '(x) =
4x ; x 0
f(x) is continuous but not differentiable at x = 0
13.
14.
15.
Taking B as origin, BC as xaxis and A as (h, k) and

C(4, 0)
h+ 4 k
We have D (2, 0) and E
,
2
2
K2 + (h + 4)(h 2) = 0
.. (1)
.. (2)
Also AC = 3 (h 4)2 + k2 = 9
1
And area = 4 K = 2K
2
11
3
Solving (1) and (2), we get h = and K =
2
2
ABC = 11
A(h, k)
E
B (0, 0)
C(4, 0)
AB BD
c = 2b
=
AC DC
Now b + c > a b + c > 6 b + 2b > 6 b > 2
b2 + 4b2 6
Again
< 1 b < 6 b (2, 6) and consequently c (4, 12)
4b2
Let AD be angle bisector
BE 3
= , take BE = 3K and EC = 4K
EC 4
A must be (3K, 6)
6
Now equation of line BA is y =
x
3K
Ky 2x = 0
Since perpendicular from c on AB = 7
0 14K
4
= 7 K2 =
2
3
K +4
2
A(3K, 6)
E
C(7K, 0)
Now c 2 = ( 6 0 ) + ( 3K 0 ) = 36 + 9K2 = 36 + 12
c = 48 = 4 3
1
1618. Let 12 yf(y)dy = a and 20

0
( y f(y)) dy + 4 = b
2
f(x) = ax + bx f(y) = ay2 + by

1
a b
a b
f(x) = 12x 2 y ( ay 2 + by ) dy + 20x y 2 ( ay 2 + by ) dy + 4x = 12x 2 + + 20x + + 4x
4 3
5 4
a = 3a + 4b a = 2b
and 4a + 5b + 4 = b a + b = 1
a = 2, b = 1
f(x) = 2x 2 + x
.. (1)
.. (2)
11
SECTION B
1.
2 ; x [ 2, 1)
Clearly we have f(x) = 1 ; x [ 1, 0) and g(x) = sec x; x R (2x + 1)

2
x ; x [0, 2]
2 ; sec x [ 2, 1)
We have fog ( x ) = 1 ; sec x [ 1, 0)

secx ;
secx [0, 2]
2 2 4
4
2 ; x 3 , 3 3 , 3 {, }
x = ,
fog ( x ) = 1 ;

secx ;
x ,
3 3
Limit of fog exist at x = , , 1, points of discontinuity of fog are , and points of

5
differentiability of fog are 1,
6
{ }
sec( 2) ; x [ 2, 1)
2
x [ 1, 0)
Again g(f(x)) = sec( 1) ;
secx
;
x [0, 2]
2
Limit of g(f(x)) does not exist at x = 1
{}
2.
(A) Let Ei ; i = 1, 2, 3, 4 represents the events that the bag contains I white balls: Clearly
1
P (Ei ) = . Let W be the event that the ball drawn is white then,
4
W 1 1 2 3 4 5
P(W ) =
P (Ei ) P = + + + =
Ei 4 4 4 4 4 8
E P (E 4 ) P ( W / E 4 ) 1/ 4 2 p
Now P 4 =
p=6
=
= =
W
P(W )
5 / 8 5 15
(B) Required number of ways
= 12 C1 + 12 C2 ( 2 C1 + 2 2 C2 ) + 12 C3 ( 3 C1 + 2 3 C2 ) + ..... +
=
12
C1 + 2
12
12
r
r =1
12
C2 + 3
12
C3 + ..... + 12
12
Cr + 12
10
12
C2 ) + 2 ( 12 C2 2 C2 +
12
12
C12 ( 12 C1 + 2
C3 3 C2 + ..... +
12
12
C2 )
C2
12
C2 )
Cr 2 = 12 211 + 12 11 210
r =2
= 13 210 12 = 13 210 m m = 12
5x
5y
5z
y
z
x
(C)
+
+
= 5
+
+
2x 2y 2z
2
x
2
y
2
1
1
x 2 + 2 y 2 + 2 z 2 + 2
1
+
+
= 5 3 + 2
+
+
= 5
2y
2z
2x
2 x 2 y 2 z
Now apply A.M H.M on 2 x, 2 y and 2 z
12
2x+2y+2z
3
1
1
1
9
+
+
1
1
1
2x 2y 2z 5
+
+
2x 2y 2z
5x
5y
5z
9
+
+
5 3 + 2 = 3
Hence
2x 2y 2z
5
Least value = 3
n
(D)
12 K
K =1
12
CK
11
CK 1 = 122
12
11
K =1
= 12
CK 1 ) = 122
2
22!
11! 11!
21 19 17.....3
212 6 p = 6
11!

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AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/13

ANSWERS, HINTS & SOLUTIONS

ALL INDIA TEST SERIES

E2 = VR2 + (VL VC )2 = VR2 + 0

Equivalent circuit can be drawn as

This is simply discharging of a capacitor.

Cyclic forms of diastereomers that differ

The configuration differ only at carbon no. 1.

For equimolar solutions, n1 = n2

Mole fraction of toluene in vapour phase =

high spin d4 configuration

CFSE = 3(- 0.4) o + 0.6 o = - 1.2 o + 0.6 o = -0.6 o

Given, [AgNO3] = 0.05 M

Ag+ Br = (K sp ) AgBr 0.05 Br = 5 10 13

O 2 2O2 i.e. 3O2

3Ba ( OH)2 + 2P4 + 6H2O

Reactions A, C, and D show SN2 reactions.

We must have f(a2 + 2a + 5) > f(a + 11)

AC2 = AB2 + BC2

Let a d = 3t; then bc = (d + zt)(d + t) = d2 + 3td + 2t2

As sin x + sin y cos cos x x R

Let x = sin y 1 sin y = 1

cos2 + 1 = 1 cos = 0 sin y + cos = 1 + 0 = 1

Equation of tangent x + t 2 y = 2ct T (2ct, 0) and T 0,

We have 2 sin2 cos2 x = 2 sin2 sin 2x

Clearly, the point lies on 7x y = 5

Therefore area of quadrilateral ACBP = 2 50 200 sq. units

Taking B as origin, BC as xaxis and A as (h, k) and

Let AD be angle bisector

1618. Let 12 yf(y)dy = a and 20

f(x) = ax + bx f(y) = ay2 + by

Clearly we have f(x) = 1 ; x [ 1, 0) and g(x) = sec x; x R (2x + 1)

We have fog ( x ) = 1 ; sec x [ 1, 0)

Limit of fog exist at x = , , 1, points of discontinuity of fog are , and points of

Now apply A.M H.M on 2 x, 2 y and 2 z

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