Jee Main 2014 Qpaper Key Solutions

Sri Chaitanya IIT Academy.
, India
JEE-MAIN
Corporate Office: Plot No:304,Kasetty Heights, Ayyappa Society, Madhapur - Hyd

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2014 JEE-MAIN
Q. PAPER WITH SOLUTIONS

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4.
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5.
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6.
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2014 JEE-MAIN
MATHEMATICS
1.
The image of the line

1)
x 3 y 5 z 2
3
1
5
2)
x 3 y5 z 2
3
1
5
3)
x 3 y 5 z2
3
1
5
4)
x 3 y 5 z2
3
1
5
x 1 y 3 z 4
in the plane 2x y + z + 3 = 0 is the line:

3
1
5
Key: 1
Sol :
x 1 y 3 z 4
is parallel to 2x y z 3 0
3
1
5
Image
h 1 k 3 l 4
2
2
1
1
h, k, l 3, 5, 2
Required equation
2.
x 3 y 5 z 2
3
1
5
If the coefficients of x 3 and x 4 in the expansion of 1 ax bx 2 1 2x in powers

18
of x are both zero, then (a, b) is equal to:

1)
251
16,
251
2) 14,
272
3) 14,
272
4) 16,
2014 JEE-MAIN
Key : 4
Sol : Equating coefficients of x 3 and x 4 is zero
32 17
17a b 0
3
16 15 32 a + 3b = 0
Solving (a, b) =
3.
272
16,
If a R and the equation 3 x x 2 x x a 2 0 (where [x] denotes the

2
greatest integer x ) has no integral solution, then all possible values of a lie in
the interval :
1) 1, 0 0, 1
2) (1, 2)
3) (-2, -1)
4) , 2 2,
Key : 1
Sol : 3f 2 2f a 2 0 where x x
1 1 3a 2
f
1 1 a 1; a 0
3
a 1, 0 0, 1
4.

If a b b c c a
a b c 2 then is equal to:
1) 2
2) 3
3) 0
4) 1
2014 JEE-MAIN
Key : 4
a b b c c a a b c 2

Sol :
5.
The variance of first 50 even natural numbers is :

1)
833
4
2) 833
3) 437
4)
437
4
Key : 2
n 2 1
Sol : Variance of first n even natural numbers is equal to
3
6.
502 1
833
3
A bird is sitting on the top of a vertical pole 20 m high and its elevation from a
point O on the ground is 450 . It flies off horizontally straight away from the
point O. After one second, the elevation of the bird from O is reduced to 300 .
Then the speed (in m/s) of the bird is:
1) 40 2 1
2) 40 3 2
3) 20 2
4) 20 3 1
2014 JEE-MAIN
Key : 4
450
Sol :
300
A 450 AB PB 20 mts and CQ 20

Tan 300
speed
20
BC 20
20 BC
dis tan ce
20
time
The integral
1 4sin 2
3 1 PQ
3 1 mts
7.
x
x
4sin dx equals:
2
2
1) 4
2)
2
4 4 3
3
3) 4 3 4
4) 4 3 4
Key : 4
Sol :
x
x
x
1 2sin dx 1 2sin dx 2sin 1 dx
2
2
2
0
3
x3
x
x 4 cos 4cos x 4 3 4

2 0
2
3
3
2014 JEE-MAIN
8.
The statement ~ p ~ q is :
1) equivalent to p q
2) equivalent to ~ p q
3) a tautology
4) a fallacy
Key : 1
Sol : The statement ~ p ~ q is
P
~q
p ~ q
~ p ~ q
pq
~ p ~ q is equivalent to p q
9.
If A is an 33 non-singular matrix such that AA ' A 'A and B A1 A ', then BB'
equals :
1) I + B
2) I
3) B1
4) B1
Key : 2
Sol : BB' A1A1 A 1 A1
A1A A1 A1 I. I I
2014 JEE-MAIN
10.
1 x 1x
The integral 1 x e dx is equal to :
1) x 1 e
2) xe
1
x
4) x e
3) x 1 e
x
1
x
1
x
1
x
Key : 2
Sol :
x 1
1 x 1 e x dx

x
1 x 1
1 x 1 2 e x dx
x
1
x
dx
By parts = xe
11.
1 x 1x
x 1 2 e dx
x
1
x
If z is a complex number such that | z | 2, then the minimum value of z
1) is equal to
1
:
2
5
2
2) lies in the interval (1, 2)

3) is strictly greater than
5
3
4) is strictly greater than
3
5
but less than
2
2
2014 JEE-MAIN
Key: 2
Sol : z r cis then | z | r 2
2
2
1
1
z
r cos r 2 sin 2
2
2
r 2 r cos
1
4
17
2cos which lies in

4
3
,
2
Minimum value
12.
9 25
,
4 4
3
lies in (1, 2)
2
If g is the inverse of a function f and f ' x
1
, then g ' x is equal to:
1 x5
1) 1 x 5
2) 5x 4
3)
1
1 g x
4) 1 g x
Key : 4
Sol : If g is the inverse of a function f, then x f g x f 'g x g ' x 1
g ' x
5
1
1 g x
f ' g x
2014 JEE-MAIN

1 f 1 1 f 2
13.
If , 0, and f n and 1 f 1 1 f 2 1 f 3 =
n
1 f 2 1 f 3 1 f 4
K 1 1 , then K is equal to :
2
1)
2)
3) 1
4) -1
Key : 3
1 1
Sol : Given determinant = 1
1 2
1 1 1 1
. 1 2
2 1
K 1
14.
Let f k x
1)
1
6
2)
1
3
3)
1
4
4)
1
12
1
sin k x cos k x where x R and k 1 . Then f 4 x f 6 x equals:
Key : 4
Sol : f 4 x f 6 x =
1
1
[1 2sin 2 x cos 2 x] 1 3sin 2 x cos 2 x
4
6
10
2014 JEE-MAIN
15.
Let and be the roots of equation px 2 qx r 0, p 0 . If p, q, r are in A.P

and
1 1
4, then the value of | | is :

1)
61
9
2)
2 17
9
3)
34
9
4)
2 13
9
Key : 4
Sol :
.
q
p
r
p
2q p q
By given condition
q
1 1
4 4
r

4
2
16.
Let A and B be two events such that

1
1
1
P A B , P A B and P A , where A stands for the complement of the
6
4
4
event A. Then the events A and B are :

1) mutually exclusive and independent
2) equally likely but not independent
3) independent but not equally likely
4) independent and equally likely
11
2014 JEE-MAIN
Key : 3
1 5
6 6
1 5
P A P B
4 6
3
1 5
P B
4
4 6
5 1 53 1
P B
6 2
6
3
3 1 1
P A .P B P A B
4 3 4
A, B are independent but not equally likely P A P B
Sol : P A B 1
17.
If f and g are differentiable functions in [0, 1] satisfying f(0) = 2 = g(1), g(0) = 0

and f(1) = 6, then for some c ]0, 1[ :
1) 2f 'c g 'c
2) 2f 'c 3g 'c
3) f 'c g 'c
4) f 'c 2g 'c
Key : 4
f 'c
f 1 f 0
for c 0, 1
Sol :
g 'c
18.
Let the population of rabbits surviving at a time t be governed by the
g 1 g 0
differentiable equation
dp t 1
p t 200 . If p(0) = 100, then p(t) equals :
dt
2
1) 400 300 et / 2
2) 300 200 et /2
3) 600 500 et / 2
4) 400 300 et /2
12
2014 JEE-MAIN
Key : 1
Sol :
dp 1
p t 200
dt 2
1
t
2
This is linear d.e in p p.e
1
t
2
400e
By given condition p(0) = 100, c = -300

p 400 300e
19.
1
t
2
Let C be the circle with centre at (1, 1) and radius = 1. If T is the circle
centred at (0, y), passing through origin and touching the circle C externally,
then the radius of T is equal to :
1)
3
2
2)
3
2
3)
1
2
4)
1
4
Key : 4
Sol :
c1 1, 1 c 2 0, y
r1 1, r2 y
c1c 2 r1 r2
1 y 1 1 y
2
1= 4y
13
2014 JEE-MAIN
20.
The area of the region described by A x, y :x 2 y 2 1 and y 2 1 x is

4
2 3
4
2)
2 3
2
3)
2 3
2
4)
2 3
1)
Key : 1
Sol.
4
Required area = 2 1 x dx
2
2 3
0
21.
Let a, b, c and d be non-zero numbers. If the point of intersection of the line

4ax + 2ay + c = 0 and 5bx + 2by + d = 0 lies in the fourth quadrant and is
equidistant from the two axes then :
1) 2bc 3ad = 0
2) 2bc + 3ad = 0
3) 3bc 2ad = 0
4) 3bc + 2ad = 0
Key : 3
Sol.
2ad 2bc 5bc 4ad

Equidistance from the both axis in
Point of intersection
,
2ab
2ab
fourth quadrant 3bc 2ad 0
14
2014 JEE-MAIN
22.
Let PS be the median of the triangle with vertices P(2, 2), Q(6, -1) and R(7, 3).
The equation of the line passing through (1, -1) and parallel to PS is
1) 4x 7y 11 0
2) 2x 9y 7 0
3) 4x 7y 3 0
4) 2x 9y 11 0
Key : 2
13
Sol : Mid point ,1

2
Slope PS
23.
lim
sin cos 2 x
x2
x 0
1)
2
9
is equal to :
2) 1
3)
4)
Key : 4
Sol : lim
x 0
sin sin 2 x
x2
sin sin 2 x sin 2 x

lim
11
x 0
sin 2 x
x2
24.
If X 4n 3n 1: n N and Y 9 n 1 :n N , where N is the set of natural

numbers, then X Y is equal to:
1) N
2) Y X
3) X
4) Y
15
2014 JEE-MAIN
Key : 4
Sol : X and Y are multiplies of 9 and X Y
XY Y
25.
The locus of the foot of perpendicular drawn from the centre of the ellipse
x 2 3y 2 6 on any tangent to it is :
1) x 2 y 2 6x 2 2y 2
2
2) x 2 y 2 6x 2 2y 2
2
3) x 2 y 2 6x 2 2y 2
2
4) x 2 y 2 6x 2 2y 2
2
Key : 3
Sol.
x 2 y2
1
Given that ellipse
6
2
B
P
Slope CP =
y1
x1
Slope of AB =
x1
=m
y1
Equation of the tangent is y mx 6m 2 2

By above equations we get x 2 y 2 6x 2 2y 2
2
16
2014 JEE-MAIN
26.
Three positive numbers from an increasing G.P. If the middle term in this G.P is
doubled, the new numbers are in A.P. Then the common ratio of the G.P is :
2 3
1)
2) 3 2
3) 2 3
4) 2 3
Key : 4
Sol : a, ar, ar 2 G.P .
2ar
a ar 2
2
4ar a ar 2
r 2 4r 1 0
4 16 4
2
r 2 3
r 2 3
27.
If 10 211 10 311 10 ..... 1011 k 10 , then k is equal to

9
1)
121
10
2)
441
100
3) 100
4) 110
17
2014 JEE-MAIN
Key : 3
Sol : S 10 211 10 311 10 .....10 11 (1)
9
11
2
3
6
10
S 11.108 2 11 107 311 10 .....9 11 11 (2)
10
(2) ... (1)
1
2
S 109 11.108 11 107 .... 119 1110
10
S 100 109
K 100
28.
The angle between the lines whose direction cosines satisfy the equations
l m n 0 and l 2 m2 n 2 is :
1)
2)
3)
4)
Key : 1
2
2
2
Sol : l m n 0
l m n
m n m2 n 2 0
2
2mn = 0
m = 0 (or) n = 0
If m = 0
l = -(0 + n)
l = -n
l : m : n = -n : 0 : n = -1 : 0 : 1
similarly if n = 0 then
l : m : n = -1, : 1 : 0 cos
1 0 0
2 2
18
2014 JEE-MAIN
29.
The slope of the line touching both the parabolas y2 4x and x 2 32y is :
1)
1
2
2)
3
2
3)
1
8
4)
2
3
Key : 1
Sol : Common tangent of y2 4ax and x 2 4by is a1/3 x b1/3 y ab 0
2/3
Here 4a = 4 and 4b = -32

Slope of the common tangent = 1/2
30.
If x = -1 and x = 2 are extreme points of f x log | x | x 2 x then:

1) 6,
1
2
2) 6,
3) 2,
4) 2,
1
2
1
2
1
2
Key : 3
Sol : f '1 0 and f '2 0
Solving above equations we get 2,
1
2
19
2014 JEE-MAIN
PHYSICS
31.
When a rubber-band is stretched by a distance x , it exerts a restoring force of

magnitude F ax bx2 where a and b are constants. The work done in stretching
the unstretched rubber-band by L is:
1 aL2 bL3
1)
2 2
3
2) aL2 bL3
3)
1
aL2 bL3
2
4)
aL2 bL3
2
3
Key: 4
L
Sol: w Fdx ax bx 2 dx
0
32.
aL2 bL3
2
3
The coercivity of a small magnet where the ferromagnet gets demagnetized is

3 103 Am1 . The current required to be passed in a solenoid of length 10 cm and
number of turns 100, so that the magnet gets demagnetized when inside the
solenoid, is:
1) 6A
2) 30 mA
3) 60 mA
4) 3 A
Key: 4
Sol:
nI H
100
I=3 103
0.1
I 3A
20
2014 JEE-MAIN
33.
In a large building, there are 15 bulbs of 40 W, 5 bulbs of 100 W, 5 fans of 80

Wand 1heater of 1 kW. The voltage of the electric mains is 220 V. The minimum
capacity of the main fuse of the building will be:
1) 14A
2) 8A
3) 10A
4) 12A
Key: 4
Sol:
P IV I
34.
1
40 15 100 5 80 5 1000
220
2500
11.4 A 12A
220
An open glass tube is immersed in mercury in such a way that a length of 8 cm

extends above the mercury level. The open end of the tube is then closed and
sealed and the tube is raised vertically up by additional 46cm. What will be
length of the air column above mercury in the tube now?
(Atmospheric pressure = 76 cm of Hg)
1) 6 cm
2) 16 cm
3) 22 cm
4) 38 cm
Key: 2
Sol:
76 8 x x 22
By trail and error method x 16
21
2014 JEE-MAIN
35.
A bob of mass m attached to an inextensible string of length l is suspended from

a vertical support. The bob rotates in a horizontal circle with an angular speed
rad/s about the vertical. About the point of suspension:
1) angular momentum changes both in direction and magnitude
2) angular momentum is conversed
3) angular momentum changes in magnitude but not in direction
4) angular momentum changes in direction but not in magnitude
Key: 4
Sol: Angular Momentum Changes in directions
36.
The current voltage relation of diode is given by I e1000V /T 1 mA, where the
applied voltage V is in volts and the temperature T is in degree Kelvin. If a
student makes an error measuring 0.01V while measuring the current of 5mA at
300 K, what will be the error in the value of current in mA?
1) 0.05 Ma
2) 0.2 mA
3) 0.02 mA
4) 0.5 mA
Key: 2
Sol: I+1 = e1000 V /T
ln I 1
1000V
T
I 1000
V
I+1
T
I=
1000
6 103 0.01
3
= 0.2 mA
22
2014 JEE-MAIN
37.
From a tower of height H, a particle is thrown vertically upwards with a speed u.

The time taken by the particle to hit the ground, is n times that taken by it to
reach the highest point of its path. The relation between H, u and n is:
1) gH n 2 u 2
2) 2gH n 2u 2
2
3) gH n 2 u 2
4) 2 gH nu 2 n 2
Key: 4
Sol:
Let t1 is the time taken to reach max height t1
u
g
Let t2 is the time taken to reach ground from tower equation

H ut2
2u 4u 2 8 gH u
1 2
u 2 2 gH
gt2 t2

2
2g
g
g2
Given that
t2 nt1
u2
u
u 2 2 gH nu u 2 2 gH
,
2
g
g2
g
g2
g
2
2 gH u 2 n 1 1
2 gH u 2 n 2 2n
2 gH u 2 n n 2
23
2014 JEE-MAIN
38.
3
A thin convex lens made from crown glass has focal length f . When it is
measured in two different liquids having refractive indices
4
5
and , it has the
3
3
focal lengths f1 and f 2 respectively. The correct relation between the focal lengths
is:
1) f1 and f 2 both become negative
2) f1 f 2 f
3) f1 f and f 2 becomes negative
4) f 2 f and f1 becomes negative
Key: 3
Sol: From
1
2
1
f
R
1 1
3 / 2
f R
f R
For medium 4 / 3
3
2
1 2
1
1
f 4 / 3 R 4R
f1 4 R
for medium M 5 / 3
1 3/ 2 2
1
f2 5 / 3 R
1
5R
f 2 5 R
24
2014 JEE-MAIN
39.
A parallel plate capacitor is made of two circular plates separated by a distance

of 5 mm and with a dielectric of dielectric constant 2.2 between them. When the
electric field in the dielectric is 3 104V / m , the charge density of the positive plate
will be close to:
1) 6 104 C / m2
2) 6 107 C / m2
3) 3 107 C / m2
4) 3 104 C / m2
Key: 2
Sol:
3 104
K 0
2.2 8.8 10 12 3 104
6 107
40.
In the circuit shown here, the point C is kept connected to point A till the
current flowing through the circuit becomes constant. Afterward, suddenly, point
C is disconnected from point A and connected to point Bat time t=0. Ratio of
the voltage across resistance and the inductor at t = L/R will be equal to:
B
1)
1 e
e
2)
e
1 e
3) 1
4) 1
Key: 4
Sol: VR VL 0 always for t 0
25
2014 JEE-MAIN
41.
Two beams, A and B, of plane polarized light with mutually perpendicular planes
of polarization are seen through a polaroid. From the position when the beam A
has maximum intensity (and beam B has zero intensity), a rotation of polaroid
through 30 makes the two beams appear equally bright. If the initial intensities
of two beams are I A and I B respectively, then
1)
IA
equals:
IB
1
3
2) 3
3)
3
2
4) 1
Key: 1
Sol: I 1A I B1 I Acos 2 30 I B cos 2 60
42.
I A cos 2 60 1
I B cos 2 30 3
There is a circular tube in a vertical plane. Two liquids which do not mix and of
densities d1 and d 2 are filled in the tube. Each liquid subtends 90 angle at centre.
d
Radius joining their interface makes an angle with vertical. Ratio 1 is:
d2
d2
d1
1)
1 sin
1 cos
2)
1 sin
1 sin
3)
1 cos
1 cos
4)
1 tan
1 tan
26
2014 JEE-MAIN
Key: 4
Sol:
PA PB
h1d1 g h2 d 2 g
R cos sin d1 R cos sin d 2
d1 cos sin 1 tan
d 2 cos sin 1 tan
h2
d2
h1
43.
d1
The pressure that has to be applied to the ends of a steel wire of length 10 cm to
keep its length constant when its temperature is raised by 100C is: (For steel
Youngs modulus is 2 1011 N m 2 and coefficient of thermal expansion is 1.1105 K 1 )
1) 2.2 106 Pa
2) 2.2 108 Pa
3) 2.2 109 Pa
4) 2.2 107 Pa
Key: 2
Sol: Pressure y 2 1011 1.1105 100 2.2 108
27
2014 JEE-MAIN
44.
A block of mass m is placed on a surface with a vertical cross section given by

y
x3
. If the coefficient of friction is 0.5, the maximum height above the ground
6
at which the block can be placed without slipping is:

1)
1
m
2
2)
1
m
6
3)
2
m
3
4)
1
m
3
Key: 2
Sol: At the instant of just sliding
H=?
tan
0.5
dy
dx
x2
x 1
2
H ' y ' at x 1
1
m
6
28
2014 JEE-MAIN
45.
Three rods of Copper, Brass and Steel are welded together to form a Y shaped
structure. Area of cross section of each rod 4cm2 . End of copper rod is
maintained at 100C where as ends of brass and steel are kept at 0C . Lengths of
the copper, brass and steel rods are 46, 13 and 12 cms respectively. The rods are
thermally insulated from surroundings except at ends. Thermal conductivites of
copper, brass and steel are 0.92,0.26 and 0.12 CGS units respectively. Rate of heat
flow through copper rod is:
1) 6.0 cal/s
2) 1.2 cal/s
3) 2.4 cal/s
4) 4.8 cal/s
Key: 4
Sol: Let T is the junction temperature then
H cu H Brass H steel
K cu A 100 T K B A T K S AT 0.96
0.26
0.12
,
T
T
100 T
lcu
lB
lS
46
13
12
200 5T
T 40C
Heat flow per sec through copper
KA 100 T 0.96 4 60
4.8 cal/sec
l
46
0C
el cm
Ste 12 .12
l= =0
k
l=46
k=0.96
T
Copper
l= Bra
k= 13 c ss
0.2 m
6
0C
100C
29
2014 JEE-MAIN
46.
A mass m is supported by a massless string wound around a uniform hollow

cylinder of mass m and radius R. If the string does not slip on the cylinder, with
what acceleration will the mass fall on release?
m
1) g
2)
2g
3
3)
g
2
4)
5g
6
Key: 3
Sol:
mg T ma
TR mR 2 mR 2 .
a
T ma
R
2ma mg or a g / 2
30
2014 JEE-MAIN
47.
Match List-I (Electromagnetic wave type) with List II (Its

association/application) and select the correct option from the choices given
below the lists:
List-I
List-II
(a) Infrared waves
(i) To treat muscular strain
(b)
Radio waves
(ii)
(c)
X-rays
(iii) To detect fracture of bones
(d)
Ultra violet rays
(iv) Absorbed by the ozone layer

of the atmosphere
(a)
(b)
(c)
(d)
1) (i)
(ii)
(iii)
(iv)
2) (iv)
(iii)
(ii)
(i)
3) (i)
(ii)
(iv)
(iii)
4) (iii)
(ii)
(i)
(iv)
For broadcasting
Key: 1
Sol: Conceptual
48.
The radiation corresponding to 3 2 transition of hydrogen atom falls on a

metal surface to produce photoelectrons. These electrons are made to enter a
magnetic field of 3 104 T . If the radius of largest circular path followed by these
electrons is 10.0 mm, the work function of the metal is close to:
1) 1.6 eV
2) 1.8 eV
3) 1.1 eV
4) 0.8 eV
31
2014 JEE-MAIN
Key: 3
Sol: In magnetic field , r
2 KE m
Bq
2
8
19
4
B 2 q 2 r 2 9 10 1.6 10 10
1
KE
31
2m
2 9 10
1.6 1019
0.8ev
1 1
E 13.6 1.89eV
4 9
W0 E KE 1.89 0.8 1.1eV
49.
During the propagation of electromagnetic waves in a medium:

1) Both electric and magnetic energy densities are zero
2) Electric energy density is double of the magnetic energy density
3) Electric energy density is half of the magnetic energy density
4) Electric energy density is equal to the magnetic energy density
Key: 4
Sol: Conceptual
50.
A green light is incident from the water the air water interface at the critical
angle . Select the correct statement.
1) The entire spectrum of visible light will come out of the water at various angles
to the normal
2) The entire spectrum of visible light will come out of the water at an angle of
90 to the normal
3) The spectrum of visible light whose frequency is less than that of green light
will come out to the air medium
4) The spectrum of visible light whose frequency is more than that of green light
will come out to the air medium
32
2014 JEE-MAIN
Key: 3
Sol: With increase in frequency, critical angle c decreases i.e., present angle of
incidence in water will be more than respective critical angles of high frequencies
radiation. Hence high frequency radiations will get TIR and low frequencies
radiations will come out in to air
51.
Four particles, each of mass M and equidistant from each other, move along a
circle of radius R under the action of their mutual gravitational attraction. The
speed of each particle is:
1)
1 GM
1 2 2
2 R
GM
R
2)
3) 2 2
GM
R
GM
1 2 2
R
4)
Key: 1
V
R 2
Sol:
mv 2
1
1
1
Gm 2 2
2 2
R
4R
2
2R
v2
1 Gm
2 2 1
4 R
1 Gm
2 2 1
2 R
33
2014 JEE-MAIN
52.
A particle moves with simple harmonic motion in a straight line. In first s ,

after starting from rest it travels a distance a, and in next s it travels 2a, in
same direction, then:
1) time period of oscillations is 6
2) amplitude of motion is 3a
3) time period of oscillations is 8
4) amplitude of motion is 4a
Key: 1
a
Sol:
53.
a
0
T
6
A conductor lies along the z axis at 1.5 z 1.5m and carries a fixed current of
10.0 A in a z direction (see figure). For a field B 3.0 104 e0.2 x a y T , find the power
required to move the conductor at constant speed to x 2.0m , y 0m in 5 103 s .
Assume parallel motion along the x axis.
1.5
I
B
2.0
1.5
1) 29.7 W
2) 1.57 W
3) 2.97 W
4) 14.85 W
34
2014 JEE-MAIN
Key: 3
Sol:
PInstant BV 3 104 3
P
12
101 e0.2 x
5
Prange
54.
2
e 0.2 x
3
5 10
pdx 2.97W
dx
The forward biased diode connection is:

2V
2V
1)
2V
2V
2)
3V
3V
3)
2V
4V
4)
Key: 2
Sol: Conceptual
55.
Hydrogen 1 H 1 , Deuterium 1 H 2 , singly ionized Helium

ionized lithium
Li 6
He4
and doubly
all have one electron around the nucleus. Consider an
electron transition from n 2 to n 1 . If the wavelengths of emitted radiation are

1 , 2 , 3 and 4 respectively then approximately which one of the following is
correct?
1) 1 22 33 44
2) 41 22 23 4
3) 1 22 23 4
4) 1 2 43 94
35
2014 JEE-MAIN
Key: 4
Sol:
1
1
1
Rz 2 1 2
z
4
1 2 as
z 1 for both 1 H1 and 1 H 2
1 z32
4 1 43
3 z12
1 z42
9 1 94
4 z12
56.
1 2 43 94
On heating water, bubbles being formed at the bottom of the vessel detach and
rise. Take the bubbles to be spheres of radius R and making a circular contact of
radius r with the bottom of the vessel. If r R, and the surface tension of water
is T, value of r just before bubbles detach is: (density of water is w )
2r
1) R 2
3 w g
T
2) R 2
w g
3T
3) R 2
w g
6T
4) R 2
w g
T
36
2014 JEE-MAIN
Key: 3(This is an ambigious Question, so expected key is 3)

Sol: Tdl sin buoyancy force on bubble
r
r
r 4
T 2 r R 3 w g
R 3
4
2 R w g
r2
3 T
2 w g
r R2
3 T
57.
A pipe of length 85 cm is closed from one end. Find the number of possible
natural oscillations of air column in the pipe whose frequencies lie below 1250
Hz. The velocity of sound in air is 340 m/s.
1) 4
2) 12
3) 8
4) 6
Key: 4
Sol: From n
V
340
100 HZ
4l 4 85 102
Possible frequencies in closed pipe is odd harmonics only So

100 HZ ,300 HZ ,500 HZ ,700 HZ ,900HZ
and 1100 HZ ,1300 HZ ,1500 HZ ..... etc below
1250HZ , 6 natural oscillations are possible
37
2014 JEE-MAIN
58.
2
Assume that an electric field E 30 x i exists in space. Then the potential
difference VA VO , where VO is the potential at the origin and VA the potential at

x 2m is:
1) 80 J
2) 120 J
3) 120 J
4) 80 J
Key: 4
VA
Sol:
dv Edx V
V0
59.
2
A
V0 30 x 2 dx 80 J
0
A student measured the length of a rod and wrote it as 3.50 cm. Which
instrument did he use to measure it?
1) A screw guage having 50 divisions in the circular scale and pitch as 1mm
2) A meter scale
3) A vernier calipers where the 10 divisions in vernier scale matches with 9
division in main scale has 10 divisions in 1cm
4) A screw guage having 100 divisions in the circular scale and pitch as 1mm
38
2014 JEE-MAIN
Key: 3
Sol: Least count of vernier
60.
1
mm
10
One mole of diatomic ideal gas undergoes a cyclic process ABC as shown in
figure. The process BC is adiabatic. The temperatures at A, B and C are 400 K,
800 K and 600 K respectively. Choose the correct statement:
B 800 K
P
A
400 K
600 K
C
1) The change in internal energy in the process BC is 500R

2) The change in internal energy in whole cyclic process is 250 R
3) The change in internal energy in the process CA is 700 R
4) The change in internal energy in the process AB is 350R
Key: 1
3R
Sol: 1) du for isochoric process nCV dT 1 400 600 R
2
2) for Process BC du
nR T1 T2
1 r
R 200
1 7 / 5
500 R
3) for whole process du 0
39
2014 JEE-MAIN
CHEMSITRY
61.
Which one is classified as a condensation polymer?

1) Acrylonitrile
2) Dacron
3) Neoprene
4) Teflon
Key: 2
Sol: Dacron is the condensation polymer
Neoprene
n
Add polymers
Teflon
62.
Which one of the following properties is not shown by NO?

1) Its bond order is 2.5
2) It is diamagnetic in gaseous state
3) It is a neutral oxide
4) It combines with oxygen to form nitrogen dioxide
Key: 2
Sol: NO is paramagnetic
40
2014 JEE-MAIN
63.
Sodium phenoxide when heated with CO2 under pressure at 1250 C yields a product
which on acetylation produces C.
ONa
125
H
B
CO2
C
5 Atm
AC2O
The major product C would be:
1)
OCOCH 3
COOH
2)
OCOCH3
COOH
3)
OH
COCH3
COCH 3
4)
OH
COOCH 3
Key: 2
41
2014 JEE-MAIN
Sol:
ONa
OCOCH3
OH
COOH
125 C
CO2
5atm
COOH
AC2 O
(B)
(C)
Aspirin
64.
Given below are the half-cell reactions:

Mn 2 2e Mn; E 0 1.18 V
2 Mn3 e Mn 2 ; E 0 1.51 V
The E 0 for 3Mn2 Mn 2Mn3 will be:

1) - 0.33 V; the reaction will occur
2) 2.69 V; the reaction will not occur
3) 2.69 V; the reaction will occur
4) 0.33 V; the reaction will not occur
Key: 2
Sol:
E 0 1.18 1.51
= 2.69 V
42
2014 JEE-MAIN
65.
For complete combustion of ethanol. C2 H 5OH l 3O2 g 2CO2 g 3H 2O l , the

amount of heat produced as measured in bomb calorimeter, is 1364.47 kJmol 1 at
250 C . Assuming ideally the Enthalpy of combustion, c H , for the reaction will be:
R 8.314kJmol
1
1) 1350.50kJmol 1
2) 1366.95kJmol 1
3) 1361.95kJmol 1
4) 1460.50kJmol 1
Key: 2
Sol:
H U nRT
1364 1 8.314 298 10 3
66.
For the estimation of nitrogen, 1.4 g of an organic compound was digested by

Kjeldahl method and the evolved ammonia was absorbed in 60 mL of
sulphuric acid. The unreacted acid required 20 mL of
M
10
M
sodium hydroxide for
10
complete neutralization. The percentage of nitrogen in the compound is:

1) 5%
2) 6%
3) 10%
4) 3%
43
2014 JEE-MAIN
Key: 3
Sol: Meq of H 2SO 4 60
1
2 12
10
Meq of base used for back titration 20
1
2
10
= Meq of acid left

Meq of acid reacted with liberated
Ammonia = 12-2 = 10 meq
= meq of NH3
Millimoles of NH3 liberated = 10 [ n-factor = 1]
Moles of NH 3 10 103
Moles N 10 103
Wt of N 10 103 14
10 103 14
% of N in the organic compound
100 10%
1.4
67.
The major organic compound formed by the reaction of 1, 1, 1 trichloroethane

with silver powder is:
1) 2 Butene
2) Acetylene
3) Ethene
4) 2 Butyne
Key: 4
44
2014 JEE-MAIN
Sol:
Cl
2CH3 C Cl 6 Ag CH C C CH + 6 AgCl
3
Cl
68.
2-Butyne
The ratio of masses of oxygen and nitrogen in a particular gaseous mixture is 1 :

4. The ratio of number of their molecule is:
1) 3 : 16
2) 1 : 4
3) 7 : 32
4) 1 : 8
Key: 3
Sol: Ratio of the molecules =
69.
1 4
: = 7: 32
32 28
The metal that cannot be obtained by electrolysis of an aqueous solution of its salt
is:
1) Cr
2) Ag
3) Ca
4) Cu
Key: 3
Sol: Ca cannot be obtained by the electrolysis of aqueous solution of its salt.
45
2014 JEE-MAIN
70.
The equivalent conductance of NaCl at concentration C and at infinite dilution

are C and , respectively. The correct relationship between C and is given as
(where the constant B is positive)
1) C B C
2) C B C
3) C B C
4) C B C
Key: 4
Sol:
71.
C B C
The correct set of four quantum numbers for the valence electrons of rubidium
atom (Z=37) is:
1
2
1
2) 5,0,0,
2
1
3) 5,1,0,
2
1
4) 5,1,1,
2
1) 5,0,1,
Key: 2
Sol: 5s1
72.
Consider separate solutions of 0.500 M C2 H 5OH aq , 0.100 M Mg 3 PO4 2 aq ,

0.250M KBr aq and 0.125M Na3 PO4 aq at 250 C . Which statement is true about these
solutions, assuming all salts to be strong electrolytes?

1) 0.500 M C2 H 5OH aq has the highest osmotic pressure
2) They all have the same osmotic pressure
3) 0.100 M Mg 3 PO4 2 aq has the highest osmotic pressure
4) 0.125 M Na3 PO4 aq has the highest osmotic pressure
46
2014 JEE-MAIN
Key: 2
Sol:
iCST
73.
The most suitable reagent for the conversion of R CH 2 OH R CHO is:

1) PCC (Pyridinium Chlorochromate)
2) KMnO4
3) K 2Cr2O7
4) CrO3
Key: 1
Sol: Most suitable reagent for the conversion of 10 alcohol to aldehyde is PCC
74.
CsCl crystallises in body centred cubic lattice. If a is its edge length then which
of the following expressions is correct?
1) rCs rCl 3a
2) rCs rCl 3a
3) rCs rCl
4) rCs rCl
3a
2
3
a
2
Key: 4
Sol:
3a 2(rc ra )
rc ra
3a
2
47
2014 JEE-MAIN
75.
In which of the following reactions H 2O2 acts as reducing agent?

(a) H 2O2 2 H 2e 2 H 2O
(b) H 2O2 2e O2 2 H
(c) H 2O2 2e 2OH
(d) H 2O2 2OH 2e O2 2 H 2O
1) (b), (d)
2) (a), (b)
3) (c), (d)
4) (a), (c)
Key: 1
Sol: While acting as reducing agent it gives up electrons and release oxygen gas.
76.
For which of the following molecule significant 0 ?

CN
Cl
a)
Cl
b)
CN
SH
OH
c)
OH
d)
SH
1) (c) and (d)

2) Only (a)
3) (a) and (b)
4) Only (c)
Key: 1
48
2014 JEE-MAIN
Cl
CN
0 ;
Cl
CN
H
0 ;
Sol:
"SH"
But dipole moment of
77.
SH is less than dipolemoment of
OH
OH , but is significant
On heating an aliphatic primary amine with chloroform and ethanolic potassium

hydroxide, the organic compound formed is:
1) an alkyl isocyanide
2) an alkanol
3) an alkanediol
4) an alkyl cyanide
Key: 1
Sol:
R NH 2 CHCl3 KOH R NC alkylisocyanide
49
2014 JEE-MAIN
78.
In S N 2 reactions, the correct order of reactivity for the following compounds:

CH 3Cl , CH 3CH 2 Cl , CH 3 2 CHCl and CH 3 3 CCl is
1) CH 3 2 CHCl CH 3CH 2 Cl CH 3Cl CH 3 3 CCl

2) CH 3Cl CH 3 2 CHCl CH 3CH 2 Cl CH 3 3 CCl
3) CH 3Cl CH 3CH 2 Cl CH 3 2 CHCl CH 3 3 CCl
4) CH 3CH 2 Cl CH 3Cl CH 3 2 CHCl CH 3 3 CCl
Key: 3
Sol:
CH 3Cl CH 3CH 2 Cl CH 3 2 CHCl CH 3 3 CCl
79.
The octahedral complex of a metal ion M 3 with four monodentate ligands

L1 , L2 , L3 and L4 absorb wavelengths in the region of red, green, yellow and blue,
respectively. The increasing order of ligand strength of the four ligands is:
1) L1 L2 L4 L3
2) L4 L3 L2 L1
3) L1 L3 L2 L4
4) L3 L2 L4 L1
Key: 3
Sol: Order of wavelength of colours
Red >Yellow > Green > Blue
50
2014 JEE-MAIN
80.
The equation which is balanced and represents the correct product(s) is:
1) CuSO4 4 KCN K 2 Cu CN 4 K 2 SO4
2) Li2 O 2 KCl 2 LiCl K 2 O
3) CoCl NH 3 5 5 H Co 2 5 NH 4 Cl
2
excess NaOH
4) Mg H 2 O 6 EDTA
Mg EDTA 6 H 2 O
Key: 3
Sol:
CoCl NH 3 5 5H Co 2 5NH 4 Cl
81.
LiAlH 4
PCl5
Alc. KOH
A
B
C, the product C is:
In the reaction, CH 3COOH
1) Acetyl chloride
2) Acetaldehyde
3) Acetylene
4) Ethylene
Key: 4
O
Sol:
82.
PCl5
LiAlH 4
Alc .KOH
CH 3 C OH
CH 3 CH 2 OH
CH 3 CH 2 Cl
CH 2 CH 2
The correct statement for the molecule, CsI 3 , is:

1) it contains Cs , I and lattice I 2 molecule
2) it is a covalent molecule
3) it contains Cs and I 3 ions
4) it contains Cs 3 and I ions
51
2014 JEE-MAIN
Key: 3
Sol:
CsI 3 contains Cs and I3 ions
83.
1
SO3 , if K p K c RT x where the symbols have
For the reaction SO2 O2

g
usual meaning then the value of x is: (assuming ideality)

1) 1
2) 1
3)
4)
1
2
1
2
Key: 3
Sol:
K P K C (RT) n
n 1
84.
3 1
2 2
For the non-stoichiometre reaction 2 A B C D, the following kinetic data

were obtained in three separate experiments, all at 298 K.
Initial
Initial Concentration
Concentration
(B)
(A)
0.1M
0.1 M
0.1 M
0.2 M
0.2 M
0.1 M
The rate law for the formation of C is?
1)
dc
k A
dt
2)
dc
k A B
dt
3)
dc
2
k A B
dt
4)
dc
2
k A B
dt
Initial rate of formation

of C mol L S
1.2 103
1.2 103
2.4 103
52
2014 JEE-MAIN
Key: 1
Sol: r K(A) m (B) m
85.
Resistance of 0.2 M solution of an electrolyte is 50 . The specific conductance of

the solution is 1.4 S m1 . The resistance of 0.5 M solution of the same electrolyte is
280 . The molar conductivity of 0.5 M solution of the electrolyte in S m2 mol 1 is:
1) 5 102
2) 5 104
3) 5 103
4) 5 103
Key: 2
Sol:
l
a
1 l
50
1.4 a
280 (70)
R
K = 0.25
86.
l
70
a
4
103 0.25
5 104
0.5
Among the following oxoacids, the correct decreasing order of acid strength is:
1) HClO2 HClO4 HClO3 HOCl
2) HOCl HClO2 HClO3 HClO4
3) HClO4 HOCl HClO2 HClO3
4) HClO4 HClO3 HClO2 HOCl
Key: 4
Sol: With increase in unprotonated oxygen atoms acidic strength increases
53
2014 JEE-MAIN
87.
Which one of the following bases is not present in DNA?

1) Thymine
2) Quinoline
3) Adenine
4) Cytosine
Key: 2
Sol: Qunoline is the base which is not present in DNA
88.
Considering the basic strength of amines in aqueous solution, which one has the
smallest pK b value?
1) C6 H 5 NH 2
2) CH 3 2 NH
3) CH 3 NH 2
4) CH 3 3 N
Key: 2
Sol:
CH
3
NH Stronger base in aqueous medium than Me 3 N . So its pKb value is
smallest
89.
If Z is a compressibility factor, vander Waals equation at low pressure can be

written as:
1) Z 1
Pb
RT
2) Z 1
RT
Pb
3) Z 1
a
VRT
4) Z 1
Pb
RT
54
2014 JEE-MAIN
Key: 3
Sol:
90.
P 2 V RT
V
a
PV RT
V
a
Z 1
RTV
Which series of reactions correctly represents chemical relations related to iron

and its compound?
0
O , heat
CO ,600 C
CO ,700 C
1) Fe
Fe3O4
FeO
Fe
2
dil H SO
H SO ,O
heat
FeSO4
Fe2 SO4 3
Fe
2) Fe
2
O , heat
dil H SO
heat
3) Fe
FeO
FeSO4
Fe
2
Cl , heat
heat , air
Zn
4) Fe
FeCl3
FeCl2
Fe
2
Key: 1
Sol:
O 2 heat
CO
CO
Fe
Fe3 O 4
600 FeO
700 Fe
55

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