2nd Hour Exam

Griffin and Van Voorhis

USEFUL CONSTANTS and FORMULAS

1mW = 10-3W = 10-3 J s-1

1nm = 10-9m

h = 6.63 x 10-34 J s

1eV = 1.602 x 10-19 J

= 1.05 x 10-34 J s

c = 3.0 x 108 m s-1

hc = 2.0 x 10-25 J m

0 = 8.854 10 12 Cs 2 kg 1m 3

1 AMU=1.66 x 10-27 kg

me = 9.11 x 10-31 kg

e = 1.602 x 10-19 C

= c

E = h

= h/p

ln = mrv = n

rn = n2a0

a0 = 5.29 x 10-11 m

Particle in a box:

n2 h2 n2 h2 2
n2 h2 n2 h2 2
=
=
En =
E =
8ma 2
2ma 2 n 8ma 2
2ma 2

2
n 0 x a =
a

Harmonic Oscillator:

1
1
En = n + h = n + h
2
2

e x dx =
2

x =

0(

14

1
x =

8

2(

(4 x

x 2 e x dx =
2

1
2

1
1 x =

2

()

x2 2

14

km m
=
,
h
h

2 e

14

1 k
=
2 c

(2 x )e
12

,V=

h
x =
2m

12

2hm

(a+ + a )

a+ n = (n + 1) n+1
12

m 2 x 2

x2 2

()

1
2

1 3 5 (2n 1)

2 n+1 a n

14

(8

(mip + m x )
hm
p = i
2

x 12 1 2 x e x

32 3

Raising and Lowering Operators:

n x
sin
a

1/2

x 2n e x dx =2

1
3 x =

48

x2 2

12

12

(a+ a )

a n = n1 2 n1

2nd Hour Exam

Griffin and Van Voorhis

Angular Momentum Operators

L , L = ihL
k
i j

i, j , k x , y , z

L+ = Lx + iLy

L = Lx iLy

Rigid Rotor
1

Y0 =

Y2 =
0

(4 )

1 2

16
5

3
cos
4

Y1 =

1
2

(3cos 1)
2

h2
J J +1
EJ =
2I

Y2 =

15 2

h
8 I
2

3 2
i
sin e

Y1 =

sin cos e

(Hz)

Y2 =

32
15

1
2

sin e
2

h
8 cI
2

2 i

(cm-1)

Hydrogen atom
Three-dimensional operators in spherical coordinates
1
1
h2 1 2

2
+
+
H(r, , ) =
r
sin

+ V r , ,

r 2 sin 2 2
2 r 2 r r r 2 sin

1
1 2

L2 = h2
sin

sin 2 2
sin

U=

Ze2
,
4 0 r

En =

Lz = ih

Z 2 e2
Z 2
=
(atomic units) n = 1,2,3,... ,
8 0 a0 n2 2n2

0 x e

n x /a

a0 =

dx = n!a n+1

H atom spatial wavefunctions ( where = Zr / a0 . In atomic units a0 =1 and = Zr. )

4 0 h2

e2

2nd Hour Exam

Griffin and Van Voorhis

n=1
n=2

n=3

l=0
l=0

m=0
m=0

100

1 Z
= 1s =

a0

3/ 2

Z
=

32 a0
1

200 = 2s

210 = 2 p =

m=0

3/ 2

l =1

Z
m = 1 211 =

64 a0

3/ 2

l=0

Z
=

81 3 a0

300

3/ 2

Z

32 a0
1

l =1

m=0

(2 )e

/ 2

3/ 2

e / 2 cos

e / 2 sin e i

(27 18 + 2 )e
2

/ 3

= 3s