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Guofu Chen Oxygen Separation Liquefaction ASU Perry Exergy Thermodynamic Analysis
Guofu Chen Oxygen Separation Liquefaction ASU Perry Exergy Thermodynamic Analysis
4-12*
Point
P (bar)
T (K)
Composition
State
H (J/mol)
1
55.22
300
Air
Superheated
12,046
2
1.01
295
Pure O2
Superheated
13,460
3
1.01
295
91.48% N2
Superheated
12,074
4
55.22
147.2
Air
Superheated
5,850
5
1.01
79.4
91.48% N2
Saturated vapor
5,773
6
1.01
90
pure O2
Saturated vapor
7,485
7
1.01
300
Air
Superheated
12,407
*Properties on the basis of Miller and Sullivan, U.S. Bur. Mines Tech. Pap. 424 (1928).
T
Comp stage
Comp isentropic eff
Compressor
Ideal work
Compressor loss
Exchanger loss
Column loss
Note:
(K)
J
J
J
J
J
300
3
80%
15171
Compressor power
590
5221
2073
7288
15171
3.9%
34.4%
13.7%
48.0%
100.0%
S (J/mol/K)
82.98
118.48
114.34
52.08
75.82
83.69
117.35
Point
1
2
3
4
5
6
7
E means exergy, number means Point. Not mean excel cell reference
= E2 + E3 - E7
= Compressor power - (E1 - E7)
= E1 + E5 + E6 - E2 - E3 - E4
= E4 - E5 - E6
You can find this calculation in Perry's Chemical Engineers' Handbook (7th edition, Chapter 4 Thermodynamics, Page 4-36)
In the Perry's calculation, Exergy lost = T * S
While in my calculation, Exergy lost = Exergy in - Exergy out. It's easiler to understand and the calculations is also faster.
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Chen_Calculation / 272926105.xlsx