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CODE : 07A1BS05
I B.TECH
CSE, IT, ECE & EEE
UNIT-1: CHAPTER 2.1
NO. OF SLIDES :33
UNIT INDEX
UNIT-I
S.No.
Module
Lecture
No.
PPT Slide
No.
Introduction-space
lattice unit cell
L5
3-10
Lattice parameters.
bravais lattices
L6
11-27
28-30
8.
Miller indices.
31-33
L8-9
Lecture-5
INTRODUCTION
Matter is classified into three kinds, they are
solids, liquids and gases. In solids, all the atoms
or molecules are arranged in a fixed manner.
Solids have definite shape and size, where as in
liquid and gasses atoms or molecules are not
fixed and cannot form any shape and size.
On basis of arrangement of atoms or molecules,
solids are classified into two categories, they are
crystalline solids and amorphous solids.
3
CRYSTALLINE SOLIDS
AMORPHOUS SOLIDS
LATTICE POINTS :
SPACE LATTICE :
2D-SPACE LATTICE :
It is defined as an infinite array of points in 2D space in which every point has the same
environment w.r.t. all other points.
The dots represent the lattice points in which
atoms can be accommodated. Taking O as an
arbitrary origin in XY plane constructed.
b
The two translations vectors and are taken
OP
b The
along X-axis and Y-axis respectively.
resultant vector T can be represented as
T=n1 +n2 Where n1, n2 are arbitrary integers.
6
BASIS :
Certain atoms or molecules are attached
to each lattice point in the crystal structure.
These atoms or molecules attached to any
lattice point form the basis of a crystal
lattice. Hence, crystal structure = Lattice
+ Basis.
In order to convert the geometrical array
of points molecules are located on the
lattice points.
8
Unit Cell :
Unit cell of a crystal is the smallest volume of a
crystalline solid or geometric figure from which
the entire crystal is built up by translational
repetition in three dimensions.
Since the unit cell which reflects the structure of
the crystal structure of the crystal lattice has all
the structural properties of the given crystal
lattice, it is enough to study the shape and
properties of the unit cell to get the idea about
the whole crystal
10
Lecture-6
The angle between the axes Y and Z =
BRAVAIS LATTICES
A 3dimensional lattice is generated by
repeated translation of three non-coplanar
vectors a,b &c.
There are only 14 distinguishable ways of
arranging points in 3d space.
These 14 space lattices are known as
Bravais lattices.
13
SIMPLE CUBIC
14
15
16
TETRAGONAL
17
18
ORTHORHOMBIC
19
BODY CENTRED
ORTHORHOMBIC
20
BASE CENTRED
ORTHORHOMBIC
21
22
MONOCLINIC
23
24
TRICLINIC
25
RHOMBOHEDRAL
26
HEXAGONAL
27
Lecture-7
Atomic packing factor is the ratio of
volume occupied by the atoms in an unit
cell to the total volume of the unit cell. It
is also called packing fraction.
The arrangement of atoms in different
layers and the way of stacking of different
layers result in different crystal manner.
28
Lecture-8
MILLER INDICES
In a crystal orientation of planes or faces can be
described interms of their intercepts on the three
crystallographic axes.
Miller suggested a method of indicating the
orientation of a plane by reducing the reciprocal of
the intercepts into smallest whole numbers.
o These indices are called Miller indeces generally
represented by (h k l).
30
Lecture-9
33