Name:________________________

Form:_____________

SEKOLAH MENENGAH JK CHUNG LING BUTTERWORTH

PEPERIKSAAN AWAL TAHUN 2014

CHEMISTRY
FORM 5
2 HOURS

INFORMATION FOR CANDIDATES

1. This question paper consists of three sections: Section A, Section B and
Section C
2. Answer all questions
3. You may use a non-programmable calculator.

This question paper consists of 24 printed pages

Prepared by : Madam Tan Soo Ling

Checked by : Pn. Suhaida Binti Ismail

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Section A
[ 30 marks ]
Instruction: Question 1 to Question 30, are followed by four options A, B, C
and D. Choose the best option for each question and blacken the
corresponding space on the answer sheet.
1. Y is located in the same group as fluorine in the Periodic Table of elements.
Which of the following are the characteristic of Y?
I A monotomic particle
II A dwiatomic molecule
III gas at room temperature
IV conduct electricity
A. I

B. II

C.I and III

D.II and IV

2. What is the number of nitrogen atoms in 42.5 g of NaNO3?

[Avogadro constant: 6.02 x 1023 mol-1; molar mass of NaNO3 = 85 g mol-1]
A. 6.02 x 1023
B. 3.01 x 1023

C. 2.41 x 1023
D. 1.51 x 1023

3. A type of glass has the following characteristic:

Low melting point
Easily broken
Easily shaped
The glass above is suitable for the manufacture of
I
II
III
IV

beaker
mirrors
cookware
electric bulbs

A. I and II
B. I and III

C. II and III
D. II and IV

4. The boiling point of helium is lower than neon. Which statement best
explain this phenomena?
A.
B.
C.
D.

The atomic size of helium is smaller.

The number of electrons in helium is smaller.
The covalent bond between helium atoms is weaker.
The force of attraction between helium atoms is weaker.

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5. Compound Z has the following properties
Low melting and boiling points.
Soluble in organic solvents but insoluble in water.
Cannot conduct electricity in any state.
What is Z?
A. Sodium chloride
B. Acetamide

C. Hydrogen chloride
D. Ammonia

6. Table 1 shows the electron arrangement of element Y and element Z.

Element Y
2.1

Element Z
2.6

Table 1
What is the formula and the type of bond of the compound formed from the
reaction between Y and Z?
Formula
A.
B.
C.
D.

Type of bond

Y2Z
Y2Z
YZ2
TZ2

Ionic
Covalent
Ionic
Covalent

7. An atom of element E has 7 neutrons. The nucleon number of element E is

14. Atom E receives electrons to form ion E. How many electrons in ion E?
A. 10

B. 15

C. 16

D. 18

8. Element X reacts with sulphur to form a compound with formula, XS.

What is the correct proton number of X? [Proton number of S=16]
A. 2

B. 4

C. 6

D. 8

9. A patient is diagnosed of having cancer. Which isotope is used to treat the

patient?
A. Sodium-24
B. Carbon-14

C. Cobalt-60
D. Phosphorus-32

10. Which of the following is a composite material?

A. Photochromic glass
B. Perspex

C. Benzene
D. Cement

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11. Diagram 1 shows a chemical cell. The electrons move from electrode L to
electrode M through the circuit.

Which statement is correct about the reaction in the chemical cell?

A. M is more electropositive than L
B. M is negative terminal
C. L donates 2 electrons to form L2+ ion
D. L is zinc and M is magnesium
12. Table 2 shows information about three chemical cells.
Chemical cell
I
II
III

Pair of electrode Voltage (V)

Y and Z
0.7
Z and E
1.2
E and X
1.4
Table 2

Positive terminal
Z
E
E

Which is the correct arrangement in descending order of the metals in

tendency to donate electrons?
A. Y, X, Z, E
B. X, Y, Z, E
C. E, Z, Y, X
D. E, Z, X, Y
13. Brass (Alloy of copper) is harder than pure copper. Which statement is
correct about the alloy?
A. Spaces between atoms increase.
B. Attractive forces between copper atoms increase.
C. Layer of copper atoms are more difficult to slide.
D. Atoms are orderly arranged.

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14. Diagram 2 shows a simple voltaic cell.

Which pair of materials are suitable to be used as electrode X and Y?

X
Y
A. Silver and carbon.
B. Silver and silver
C. Carbon and carbon
D. Silver and magnesium
15. Diagram 3 shows the heating curve of solid acetamide.

Which statement can be deduced from Diagram 3?

A. Heat is released in the first 4 minutes.
B. Acetamide needs 10 minutes to melt completely.
C. Acetamide undergoes physical changes between 4th minute to 6th minute.
D. The attractive forces between particles of acetamide become weaker after
8th minutes.

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16. Gas Y causes the formation of acid rain in an industrial area. Name gas Y.
A. Hydrogen chloride
B. Sulphur dioxide

C. Ammonia
D. Nitrogen

17. Which pair of monomer and polymer is correct?

Monomer
A. Chloroethene
B. Methyl methacrylate
C. Propene
D. Isoprene

Polymer
Polyvinyl chloride
Ethane
Perspex
Polystyrene

18. Diagram 4 shows the structural formulae of two hydrocarbons.

Which property of both compounds is similar?

A. Density
B. Melting point

C. solubility
D. molar mass

19. The statement below is about organic compound X:

Organic compound X undergoes addition reaction
Which of the following represents the formula for compound X?
A. C2H5COOH

B. C2H5OH

C. C2H4

D. C2H6

20. Which of the following are true about butane and butene?
I soluble in water
II Exist as gas at room temperature
III Decolourise acidified potassium manganate(VII) solution
IV Burn completely in air to produce carbon dioxide and water
A. I and III
B. II and IV

C. I, II and IV
D. I, II, III and IV

21. Diagram 5 shows a process of preparing ethane from ethene through

process X.

What is process X?
A. Hydrogenation
B. Halogenation

C. Saponification
D. Oxidation

22. Which of the following hydrocarbons contains 85.71% carbon by mass?

[Relative atomic mass: H, 1; C, 12]
A.
B.
C.
D.

C2H2
C2H6
C3H6
C3H8

23. Which of the following is the characteristic of catalyst?

A.
B.
C.
D.

Catalyst decreases the quantity of the product.

Physical state of catalyst may change during reaction.
Catalyst used only in liquid form.
The mass of catalyst is changed after the reaction.

24. 0.5 mole of magnesium powder react with excess dilute sulphuric acid.
After 50 seconds, 0.05 mole of magnesium remain as residue. What is the
average rate of the reaction?
A. 1.0 x 10-2 mols-1
B. 1.0 x 10-3 mols-1

C. 5.0 x 10-3 mols-1

D. 9.0 x 10-3 mols-1

25. A compound of Q nitrite contains 72% of Q and 28% of nitrogen. What is

the empirical formula of Q nitrite? [Relative atomic mass: N, 14; Q, 24]
A.
B.
C.
D.

Q3N2
N2Q3
Q2N3
N3Q2

26. Which of the following contains the same number of atoms as in 8.8 g
carbon dioxide gas?
[Relative atomic mass: H, 1; C, 12; S, 32; I, 127]
A.
B.
C.
D.

7.2 g of water
76.2 g of iodine
3.2 g of oxygen gas
9.6 g of sulphur dioxide

27. 3.2 g of gas Y occupies 280 cm3 at standard temperature and pressure(STP).
What is the relative molecular mass of Y?
[Molar volume of gas at STP = 22.4 dm3 mol-1]
A. 0.256
B. 25.60

C. 256
D. 2560

28. Diagram 6 shows the results of experiment I and experiment II for

decomposition of hydrogen peroxide solution in the presence of a catalyst.

Experiment I uses 25 cm3 of 1 mol dm-3 of hydrogen peroxide solution at

temperature 25oC. What is used in experiment II to obtain the curve shown
in Diagram 6?

A.
B.
C.
D.

Hydrogen peroxide
Volume( cm3)
Concentration (mol dm-3)
25
0.5
25
1.0
50
0.5
50
1.0

Temperature ( oC)
30
35
35
30

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29. Table 3 show the condition of reactants used in experiment I and
experiment II.
Experiment
Condition of reactants
I
Excess zinc powder + 50 cm3 of 2.0 mol dm-3 hydrochloric
acid
II
Excess zinc powder + 50 cm3 of 2.0 mol dm-3 hydrochloric
acid + 5 cm3 of copper(II) sulphate solution
Table 3
Which graph shows the correct curve for experiment I and experiment II
A.

C.

B.

D.

30. The reaction between excess of zinc with hydrochloric acid is represented
by the following equation.
Zn + 2HCl ZnCl2 + H2
Which of the following represents the graph of mass of zinc against time?
A.

C.

B.

D.

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Name:________________________

Form:__________

Section A (30%)
1.

21.

2.

22.

3.

23.

4.

24.

5.

25.

6.

26.

7.

27.

8.

28.

9.

29.

10.

30.

11.

12.

13.

14.

15.

16.

17.

18.

19.

20.

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Section B
[ 50 marks]
Answer all questions by writing the answers in the spaces provided.
1. Sodium is known as a soft metal. Sodium is grey in colour with shiny
surface at room temperature. Carbon is a black powder at room temperature.
Sodium burns with a bright yellow flame in a gas far filled with oxygen,
producing white fumes which cool to form white powder. Carbon burns
brightly in a gas jar filled with oxygen with no white fumes.
[Relative atomic mass: Na, 23; C, 12; O,16; Avogadro constant: 6.02 x 1023]
(a) Write the chemical equation for the reaction between sodium and
oxygen.
..
[1]
(b) (i) What is the observation if the white powder formed by the burning
of sodium is dissolved in water and tested with red litmus paper?
..
..
[2]
(ii) Explain your answer in 2 (b) (i).
..
..
[1]
(iii) Write the chemical equation for the product formed by burning of
sodium with water.
..
[1]
(iv) If a small piece of sodium is dropped into a beaker of water,
bubbles of gas are given off. Name the gas given off.
..
[1]

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(c) (i) Explain why no white fumes are produced when carbon burns in
oxygen?
..
[1]
(ii) Write the chemical equation for the reaction between the carbon and
oxygen.
..
[1]
(iii) Predict the pH value of the solution of the product formed by the
burning of carbon is passed through distilled water in a test tube and
tested with a pH water.
..
[1]
2. Diagram 7 shows the electrolysis of 0.001 mol dm-3 sodium bromide
solution using carbon electrodes in an experiment.

(a) Write the formula of all the ions present in the electrolyte.
..
[1]
(b) The volume of gas produced at electrode X is twice that at electrode Y.
Name the gas produced at
(i) electrode X: ..

[1]

(ii) electrode Y: .

[1]

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(c) State how you would verify the gas produced at electrode X.
..
..
[2]
(d) Write the half-equation for the process that occurs in electrode X.
..
[1]
(e) After half an hour, 15 cm3 of gas was collected at room temperature in
the test tube X. Calculate the number of moles of gas collected in test
tube X.

[1]
-3

(f) If 2.0 mol dm sodium bromide solution is used in the experiment

(i) What is observed at the Y in the experiment?
..
[ 1]
(ii) Name the product formed at the Y in the experiment.
..
[1]
(iii) Write the half equation for the process that occurs in electrode Y.
..
[1]

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3. Diagram 8 shows the structures of substances P and Q which can be used to
form polymers.

(a) Name an example of natural polymer and synthetic polymer.

(i) Natural polymer: ..

[1]

(ii) Synthetic polymer : .

[1]

(b) Name the process of making polymers.

..
[1]
(c) (i) Name the polymer produced by monomer P.
..
[1]
(ii) State one property of the polymer formed by monomer P.

[1]
(iii) Give one use of this polymer based on the property mentioned in (c)
(ii).

[1]
(d) (i) Calculate the molecular mass of substance Q.
[Relative atomic mass: C, 12; H, 1]

[1]

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(ii) Draw the structure of polymer formed by polymerizing of monomer Q

[2]
(iii) Do monomer Q and its polymer have the same chemical properties?
Give a reason for your answer.
..
..
..
[2]
4. Figure 1 shows the apparatus set up to study the decomposition of hydrogen
peroxide to produre water and oxygen in the presence of different amounts
of manganese(IV) oxide

0.1g of manganese(IV) oxide is added to 50 cm3 of hydrogen peroxide

solution. The volume of oxygen gas liberated is recorded every 30 seconds.
The experiment is then repeated by using 0.4 g of manganese(IV) oxide.
The result are shown in Table 4.
Time / s
Volume of O2 gas
liberated / cm3

Experiment I (0.1 g MnO2)

Experiment II (0.4 g MnO2)

Table 4

0.0
0.00
0.00

30.0
6.00
15.00

60.0
12.50
25.00

90.0
18.50
34.50

120.0
24.00
40.50

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(a) Based on the information given, complete table 5 below.
Variables
Action to be taken
(i) Manipulated variable:
Method to manipulated the variable.

(ii)

..

....

..

Responding variable:

..
How the variable responds.

..

....

..

..
..
Method to maintain the controlled
variable.

(iii) Controlled variable:

.

..

....

..

Table 5
[6]

(b)Write the chemical equation for the decomposition of hydrogen peroxide.

[2]
(c) State the hypothesis for this experiment.
..
..
[3]

17

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(d) Using the same axes, draw graphs of total volume of oxygen gas
liberated against time for both experiments.
[3]
(e) Based on the graph, determine the instantaneous rate of liberation of
oxygen gas at 60 seconds for experiment I.

[3]
(f) Predict the total volume of oxygen gas liberated at 150 seconds for
experiment I.
..
[3]
Section C
[ 20 marks ]
Answer all questions in the spaces provided.
1. Ammonium sulphate is a type of chemical fertilizer used in agriculture.
Diagram 9 shows how the fertilizer produced in industry.

Describe the procedure how the ammonium sulphate can be prepared in the
laboratory.
[6]

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2. A student carried out three experiments I, II and III to study the factors
affecting the rate of reaction. Diagram 10 shows the apparatus set-up and
the temperature of the reaction used.
Experiment
I

Apparatus set-up

Temperature (oC)
Room temperature

II

Room temperature

III

50.0

Diagram 10

20
(a) Based on experiment I, II and III,
(i) state the definition of rate of reaction.
[1]
(ii) write a balanced chemical equation for the reaction that occurred.
[1]
(b) Calculate the total volume of gas collected in the experiment I.
[ 1 mole of any gas occupies the volume of 24 dm3 at room conditions]
[2]
(c) Sketch the graphs for the volume of hydrogen gas against time for
experiment I, II and III on the same axes.
[2]
(d) Based on Diagram 10, compare the rate of reaction between
(i) experiment I and experiment II
(ii) experiment II and experiment III
Explain your answer using the Collision Theory.
[8]

-----------------------------------------Good Luck ---------------------------------

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