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SOLUTIONS
MODEL TEST PAPER
AIEEE–2010
BOOKLET CODE (A)
PHYSICS
PART − A
0m2h 2 m2
rn = (0.53 ) Å
Me 2 Z Z
m 2 (0.53) Å
(rn)Fm = (0.53 Å) n
100
For Z = 100, m = 5
25 1
n = (d)
100 4
is correct
6. Electric lines of force emerge radially outwards from the charge and are not
present inside the conductor, as field is zero there.
(b) is correct
7. Potential energy is
U = MB cos = i AB cos
U1 = i AB cos 180° = + i AB
U2 = i AB cos 90° = 0
i AB
U3 = i AB cos 135° =
2
i AB
and U4 = i AB cos ( 45°) =
2
l1
or A
l2 S
l1 A
or =
l1 l2 A S
(d) is correct
10. c
12. Since the gravitational field is conservative in nature, therefore work done is path
independent. Thus work done in the three cases will be equal
i.e. W1 = W 2 = W 3 (a) is correct
F sin 60° g
1
F cos 60° = (F sin 60 3 g)
2 3
1
= F 3 3 10
F
5
2 3
2
4
F F
5
2 4
F
5
4
F = 20 N (b) is correct
17. The loop will expand due to radially outward magnetic force. (d) is correct
1 1 1
30 v
v = 30 cm
This image acts as object for concave lens. Therefore the distance of object from
concave lens
= 30 26 = 4 cm
5
h2 = 2 = 2.5 cm (a) is
4
correct
21. The given situation can be represented as
v 22 m/s
22. Plane of motion must be perpendicular to at least one of the component of the
magnetic field, and since it is non-circular hence electric field must be there along
x-axis.
Only E a î , B ck̂ a î fulfill these two conditions.
(b) is correct
vl l4
or 2
2 4
v
(b)
l
is correct
24. Since, L + e =
4
0.1 + e =
4
3
0.35 + e =
4
3 L
0.35 + e = (4 + 4e)
4
0.35 + e = 0.3 + 3e
(i) (ii)
0.05 = 2e
e = 0.025 (a) is
correct
= 1.728 106 m3
Since l has two significant figures, hence v will also have two significant figures
i.e. v = 1.7 106 m3 .
(a) is correct
28. (b ) i E / R (a) is correct
29. 2R (c) is correct
30. i1 i0 e t / 3 RC
i2 i0 e t / RC
2t
i1
e 3 RC i.e. increasing with (t) (b) is correct
i2
CHEMISTRY
PART − B
108
= 6.023 1023 = 6.023 1023 atoms (a) is
108
correct
32. Freezing point of a liquid substance is defined as the temperature at which the
vapour pressure of its liquid is equal to the vapour pressure of the corresponding
solid. The addition of non-volatile solute always lowers the freezing point. At the
freezing point, liquid and solid are in equilibrium. On cooling a solution of a non-
volatile solute below the freezing point of solution, some of liquid will separate as a
solid solvent.
(a) is correct
33. Me2SiCl2 on hydrolysis will produce Me 2Si(OH)2 which ultimately, upon loss of
water, will form Me2Si=O. But silicon atom, because of its very large size in
comparison to oxygen, is unable to form -bond. Thus, the product of hydrolysis is
polymeric in nature.
Me Me
MeSiOSi
MeSiOSi
Me Me
(c) is correct
34. When optically active acid reacts with racemic mixture of an alcohol, it forms two
types of isomeric esters. In each the configuration of the chiral centre of acid will
remain the same. So the mixture will be optically active.
(a) is correct
35. SO2 and H2S are both reducing agents. H2S is obtained by the action of acid upon
sulphide while SO2 is obtained by the action of acid upon sulphite. The option (d) is
correct because SO2 is a colourless gas with irritating smell. However H 2S has
rotten egg like smell. The reactions involved are
SO 32 + H2SO4 SO2 + H2O + SO 24
[A] [B]
3SO2 + K2Cr2O7 + H2SO4 K2SO4 + Cr2(SO4)3 + H2O
(d) is correct
36. The given reaction can be completed as
H3C
(CH3)2NH
N NO2
DMF ,
H3C
F NO2
(A)
H3C
(i) NaNO2 + HCl / 0 5C
N NH2
(ii) H2 / Ni
H3C
(B)
(a) is correct
Number of electrons in CO 32 = 6 + 24 + 2 = 32
Both have same number of electrons. So they are isoelectronic.
Total number of valence electrons in NO 3 = 5 + 6 3 + 1 = 24
CH2OH OOC CH2OH HOOC
(d) is correct
40. The reaction of Ethyl exter with CH3MgBr is excess, can be expressed as
O :O OC2H5
CH3 + CH3MgBr
OC2H5 CH3 CH3
O XMgO CH3
CH3MgX
CH3 + C2H5O
CH3 CH3 CH3
HO CH3
HOH / H+
41. Heat of formation is the amount of heat evolved or absorbed when one mole of the
compound is formed from its elements. When all the substances are taken in their
standard state i.e. 298 K and 1 atm pressure, it is called standard heat of formation
( H of ) .
Thus in given thermochemical equations, (b) represents the standard heat of
formation of HF.
1 1
H2(g) + F2(g) HF(g) ; H of , standard heat of formation of HF(g)
2 2
(b) is correct
42. The dipole moment of a polar molecule depends on its geometry and shape. A
symmetrical molecule is non-polar even though it contains polar bonds. CH 4 being
symmetrical has zero resultant dipole moment. The bond dipole moment of C H
bond and that of CCl bond reinforce one-another.
Cl Cl Cl H
C Resultant C Resultant
Cl H Cl H
Cl H
C Resultant
H H
CH3Cl (1.86 D)
In CHCl3, the resultant of CH and CCl dipoles opposes the resultant of two CCl
dipoles while in CH2Cl2, the resultant of CH dipoles adds to the resultant of two
CCl dipoles. In case of CH3Cl, the resultant of two CH dipoles adds to the
resultant of CH and CCl dipoles . Thus dipole moment of CH3Cl is highest among
the given compounds. The molecule (CCl 4) again becomes symmetrical and dipole
moment reduces to zero.
(c) is correct
43. The acidic strength of the attached groups are in the following order.
NO2
Two moles of amide ions will attract two moles of most acidic hydrogen and the
obtained product will be
OOC
OH
O2N
CH
(a) is correct
O
44. The physical adsorption occurs readily at low temperature and increases with
decreasing temperature as the adsorption process is exothermic (Le-Chatelier’s
principle). Since the activation energy in the physical adsorption is more or less
zero, the rate of adsorption is not affected even at low temperature.
(b) is correct
45. Acid hydrolysis of P and Q can be expressed as
OCOCH3 OH O
H2O / H+
CH3 CH3 CH3
(P)
H3C
H3C
H2O / H+
OH
OCOCH5
(Q)
H3C
CHO
24 23
47. 21 N decays into 11 Na via radioactive decay. The decay reactions are
48. The salt with lower value of K sp precipitates first. Here HgS has the lowest value of
Ksp hence it will precipitate first.
(c) is correct
49. The desired reaction is
H P OH
OH
There are only two OH groups which means that at the most two hydrogen atoms
can be replaced and hence it is dibasic. Here the oxidation number of P is +3. P
may also have +5 oxidation state in some compounds. Increase in oxidation number
represents that H3PO3 can be oxidised and hence it is a reducing agent.
(c) is correct
51. After examining the four given structures we can easily see that only (a) has the
desired hybridization.
H 2C CH C N
(from left to right)
sp2 sp2 sp sp
(a) is correct
52. C2H5O will abstract proton from phenol, converting the phenol into phenoxide ion.
This would then make nucleophilic attack on the methylene carbon of alkyl iodide.
But C2H5O is in excess. C2H5O is better nucleophile than C6H5O (phenoxide) ion,
since in the former the negative charge is localised over oxygen and in the latter it is
delocalised over the whole molecular framework. So it is C 2H5O ion that would
make nucleophilic attack at ethyl iodide to give diethyl ether (Williamson’s
synthesis).
H 3C H3C
+ I H3C O CH3 + :I
O
53. The extent of deviation of a real gas from an ideal behaviour is expressed in terms of
compressibility factor, Z, defined as
PV
Z=
nRT
For positive deviation, Z > 1. (a) is
correct
54. The AgNO3 and BaCl2 in excess releases Ag+ and Ba++ respectively, in solution in
excess and the two salts of mixture release Br and SO 4 respectively. The
reaction can be represented as
Ag+ + Br AgBr
Excess 0.01 mole 0.01 mole
Ba2+ + SO 24 BaSO4
Excess 0.01 mole 0.01 mole (d) is correct
+
Ph
PhC
H H O
2
CH3 CH3
H3C +
OCH3 OH O
Ph Ph Ph
56. The central boron atom in H3BO3 is electron-deficient. Therefore it accepts a pair of
electrons, hence weak Lewis acid. There is no d-orbital of suitable energy in boron
atom. So, it can accommodate only one additional electron pair in its outermost
shell. Thus it is monobasic weak Lewis acid.
B(OH)3 + H2O [B(OH)4] + H+ (c) is correct
59. ( d ) is correct
60. (d ) is correct
MATHEMATICS
PART − C
correct
2n n
I (m, n) = I [(n 1), (m + 1)] (c)
m 1 m 1
is correct
63. Given parabola is
x2 y2
=1
cos 2 α sin 2 α
Eccentricity = 1 tan 2 α = sec
= 0 1 a = 1 a + a3
a 0 1
dV
0 3a 2 1
da
1
a =
3
1
Thus V will be minimum at a = (c) is
3
correct
Sum of intercepts,
3 3 1
l =
cos sin
dl
3 3 sec tan cot cosec 0
d
3 3 sin cos
or 2
0
cos sin 2
3 3 tan3 1 = 0
1
or tan2 =
3 3/2
1
tan =
3
=
6
(a) is correct
Since BD AC
D
3
Slope of BD =
4
B (4, 0) C (3, 4)
Equation of BD is 3x + 4y 12 = 0 E
Similarly AE BC ……(i)
1
Slope of AE =
4
Equation of AE is x 4y = 0 ……..(ii)
By equations (i) and (ii),
3
x = 3, y =
4
3
Thus the orthocentre of the triangle is 3, (d) is correct
4
68. Since we know that
1
x + 2; x>0
x
1
x
or x 1
2
tan 2 α
x2 x
x2 x
tan 2 α
2
tan 2 α
x2 x 2 tan (c) is correct
x2 x
69. Since A2 = B
0 0 2 0 1 0
A =2
1 1
1 1
1 1
5 1
Comparing, we get
2 = 1 or = 1 ………(i)
and +1=5 or =4 ………(ii)
Since the two values of do not match, thus no real value of exists
(d) is correct
70. Let the equation of the chord be
y = m (x 4)
Length of perpendicular dropped from (6, 0) = 2
(4, 0)
2
m ( 6 4) 0
2
1 m2
( 2m) 2 4m 2
2 or =2
1 m2 1 m2
2m2 = 2
m = 1 (a) is
correct
correct
3 1 1
P (B C) =
4 3 3 A B
9 8 1
= C
12 12
(a) is correct
73. Eliminating x between the two given equations, we get
(9, 3)
y= 2y 3
y 2y 3 = 0
2
(y 3) (y + 1) = 0
(0, 0) (3, 0)
Area bounded by the curve
9
= x dx
0
9
x 3/2 2
= 9 3/2
3/ 2 0
3
2
27 18 (b)
3
is correct
x2 1
2
74. Given function f (x) = 2 e t dt
x
On differentiation, we get
f (x) = 2x e
(x 2 1) 2 2 )2
e (x
(x 4 1 2x 2 ) 2 1
= 2x e (1 e 2 x )
(1 y) ( y 1) 2 4 ( y 1) ( y 2)
x=
2 ( y 1)
or (y 1)2 4 (y 1) (y 2) > 0
7
y > 1, y
3
7
Thus the range of f (x) is 1, (d) is correct
3
76. If a function obeys mean value theorem then it must be differentiable in the interval
on which it is defined.
correct
dy t 1
y
dt t 1 t 1
t 11
I.F. = e t 1
dt
e t log e ( t 1)
e t . ( t 1)
y (et) (t + 1) = e 1 dt c
e t c
or y = t
e ( t 1)
or c=0
e t
Thus y=
e t ( t 1)
1
or y=
t 1
1
y (1) = (b) is correct
2
78. Given pair of straight lines is
y2 14y + 45 = 0 y=9
(y 5) (y 9) = 0 (4, 7)
y=5
and x2 8x + 12 = 0
(x 6) (x 2) = 0
The given square is shown in figure. x=2 x=6
f ( 2 2 h h 2 ) f ( 2)
Lim
h 0 f (1 h h 2 ) f (1)
f ( 2) ( h 2) 6
Lim .2 = 3 (c) is
h 0 f (1) (1 h ) 4
correct
81. Since, (1 + t2)12 (1 + t12) (1 + t24) = (1 + t2)12 (1 + t12 + t24 + t36 )
Hence required coefficient is 12
C6 + 2 (d) is correct
z 1 z 1
82. Re () =
2 z 1 z 1
| z |2 1
= =0 (d)
| z 1 |2
is correct
0 1 a = 0
a 0 1
1 + a3 = 0
a = 1 (c) is
correct
84. Number of ways of selecting two numbers, such that both numbers are greater than
4 is 3C2 .
6
Total number of ways of selection of two numbers is C2
3
C2 4
Required probability = 1 6
(a) is
C2 5
correct
85. Given ellipse is
x2 y2
+ = 1
9 5
The equation of tangent at (x1, y1) can be written as
xx 1 yy1
2
1 Q
a b2
( ae, b2/a) (ae, b2/a)
R O
P
5 4
e2 = 1
9 9
2
e =
3
one end point of latus rectum
(2, 5/3)
Equation of the tangent at (2, 5/3) is
2x y
= 1
9 3
1 9 27
Area of triangle OPQ = 3
2 2 4
Area of quadrilateral PQRS
27
= 4 Area of triangle OPQ = 4 = 27 sq. units.
4
(a) is correct
86. The given limit is
sin nx [(a n ) nx tan x ]
Lim = 0
x 0 x2
sin nx tan x
or Lim
nx ( a n ) n x n = 0
x 0
an n2 1 = 0
1
a = n+ (d) is correct
n
87.(d) is correct
90.(a) is correct