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Gas Turbine Emmissions and Control
Gas Turbine Emmissions and Control
GER-4211
GE Power Systems
ii
sions began to rise to measurable levels of concern. Based on these factors, alternative methods of emission controls have been developed:
Internal gas turbine
Multiple nozzle quiet combustors
introduced in 1988
Dry Low NOx combustors
introduced in 1990
External
Exhaust catalysts
This paper will summarize the current estimated emissions for existing gas turbines and the
effects of available emission control techniques
(liner design and water/steam injection) on gas
turbine emissions, cycle performance, and
maintenance inspection intervals. The latest
technology includes Dry Low NOx and catalytic
combustion. These topics are covered in other
GERs.
Emissions Characteristics of
Conventional Combustion Systems
Typical exhaust emissions from a stationary gas
turbine are listed in Table 1. There are two distinct categories. The major species (CO2, N2,
H2O, and O2) are present in percent concentrations. The minor species (or pollutants)
such as CO, UHC, NOx, SOx, and particulates
are present in parts per million concentrations.
In general, given the fuel composition and
machine operating conditions, the major
species compositions can be calculated. The
minor species, with the exception of total sulfur
oxides, cannot. Characterization of the pollutants requires careful measurement and semitheoretical analysis.
The pollutants shown in Table 1 are a function
of gas turbine operating conditions and fuel
composition. In the following sections, each
pollutant will be considered as a function of
1
Typical Concentration
(% Volume)
Source
Nitrogen (N2)
66 - 72
Inlet Air
Oxygen (O2)
12 - 18
Inlet Air
1-5
1-5
Minor Species
Pollutants
Typical Concentration
(PPMV)
Source
20 - 220
2 - 20
5 - 330
Trace - 100
Trace - 4
5 - 300
Trace - 25
Nitrogen Oxides
Low-Btu gases generally have flame temperatures below 3500F/1927C and correspondingly lower thermal NOx production. However,
depending upon the fuel-gas clean-up train,
these gases may contain significant quantities of
ammonia. This ammonia acts as FBN and will
be oxidized to NOx in a conventional diffusion
combustion system. NOx control measures such
as water injection or steam injection will have
little or no effect on these organic NOx
emissions.
Fuel
Stoichiometric
Flame Temp.
Carbon Monoxide
Carbon monoxide (CO) emissions from a conventional GE gas turbine combustion system are
less than 10 ppmvd (parts per million by volume dry) at all but very low loads for steadystate operation. During ignition and acceleration, there may be transient emission levels
higher than those presented here. Because of
the very short loading sequence of gas turbines,
these levels make a negligible contribution to
the integrated emissions. Figure 5 shows typical
NOx (ppmvd/ppmvw-Methane)
1765F/963C 2020F/1104C
Firing Time
NOx (ppmvd/ppmvw-Methane) @
15% O2, 1765F/963C 2020F/1104C
Firing Time
Methane
1.000
1.000/1.000
1.000/1.000
Propane
1.300
1.555/1.606
1.569/1.632
Butane
1.280
1.608/1.661
1.621/1.686
Hydrogen
2.067
3.966/4.029
5.237/5.299
Carbon Monoxide
2.067
3.835/3.928
4.128/0.529
Methanol
0.417-0.617
0.489/0.501
0.516/0.529
No. 2 Oil
1.667
1.567/1.647
1.524/1.614
ISO Conditions
200
3/4 Load
160
No. 2 Oil
1/2 Load
120
Full Load
1/4 Load
80
40
0
Natural Gas
GT25056
NOX (ppmvw)
240
1000
1200
1400
1600
1800
2000
(F)
540
650
760
870
980
1090
(C)
Firing Temperature
ISO Conditions
NOX (ppmvw)
240
3/4 Load
200
No. 2 Oil
160
1/2 Load
120
1/4 Load
Full Load
Natural Gas
40
0
GT25057
80
1000
1200
1400
1600
1800
2000
(F)
540
650
760
870
980
1090
(C)
Firing Temperature
200
ISO Conditions
NOX (ppmvw)
160
3/4 Load
No. 2 Oil
1/2 Load
120
1/4 Load
Full Load
80
40
Natural Gas
1/4 Load
1000
1200
1400
1600
1800 (F)
540
650
760
870
980 (C)
Firing Temperature
160
ISO Conditions
3/4 Load
NOX (ppmvw)
120
No. 2 Oil
1/2 Load
80
1/4 Load
Full Load
40
Natural Gas
0
1000
1200
1400
1600
1800
(F)
540
650
760
870
980
(C)
Firing Temperature
Unburned Hydrocarbons
Unburned hydrocarbons (UHC), like carbon
monoxide, are associated with combustion inefficiency. When plotted versus firing temperature, the emissions from heavy-duty gas turbine
GT25060
200
160
Natural Gas
120
1/4 Load
80
40
1/2 Load
Distillate
Oil
3/4 Load
Full Load
0
800
1000
1200
1400
1600
1800
2000
2200 (F)
430
540
650
760
870
980
1090
1200 (C)
Firing Temperature
GT25061
120
100
80
Natural Gas
60
1/4 Load
40
1/2 Load
3/4 Load
Full Load
Distillate
Oil
20
0
600
800
1000
1200
1400
1600
1800
2000
2200 (F)
320
430
540
650
760
870
980
1090
1200 (C)
Firing Temperature
Sulfur Oxides
The gas turbine itself does not generate sulfur,
which leads to sulfur oxides emissions. All sulfur
emissions in the gas turbine exhaust are caused
Particulates
Gas turbine exhaust particulate emission rates
are influenced by the design of the combustion
system, fuel properties and combustor operating conditions. The principal components of
the particulates are smoke, ash, ambient noncombustibles, and erosion and corrosion products. Two additional components that could be
considered particulate matter in some localities
are sulfuric acid and unburned hydrocarbons
that are liquid at standard conditions.
1600
1200
800
% Sulfur by Weight
0.6
0.4
400
60
40
SO3 (lb/hr)
20
12
16
20
40
80
120
GT25062
0.2
160
80
100
1.0
0.8
SO2 (lb/hr)
SO3 /SO2
0.0658 by Weight
51P
61B
71EA
91E
4.7 lb/sec
6.2 lb/sec
13.0 lb/sec
18.5 lb/sec
Smoke
Smoke is the visible portion of filterable particulate material. The GE combustor design coupled with air atomization of liquid fuels has
resulted in a nonvisible plume over the gas turbine load range for a wide variety of fuels. The
GE smoke-measuring unit is the Von Brand
Reflective Smoke Number (GEVBRSN). If this
number is greater than 93 to 95 for the
MS7001E, then the plume will not be visible.
For liquid fuels, the GEVBRSN is a function of
the hydrogen content of the fuel. For natural
gas fuel, the smoke number is essentially 99 to
100 over the load range and visible smoke is not
present.
Firing Temp.
F/C
Gas
Dist.
MS5001P
MS5001P-N/T
1730/943
1765/963
128
142
195
211
25
25
42
42
MS6001B
2020/1104
161
279
25
65/42
MS7001B
MS7001B Option 3
MS7001B Option 4
MS7001EA
1840/1004
1965/1074
2020/1104
2020/1104
109
124
132
160
165
191
205
245
25
25
25
25
42
42
42
42
MS9001B
MS9001B Option 3
MS9001B Option 4
MS9001E
MS9001E
1940/1060
1965/1074
2020/1104
2020/1104
2055/1124
109
124
132
157
162
165
191
205
235
241
42
42
42
42
42
65
65
65
65
65
6FA
7FA
7FA
9FA
2350/1288
2400/1316
2420/1327
2350/1288
Firing Temp.
F/C
S.C.
R.C.**
S.C.
S.C.
MS3002F
MS3002J
MS3002J-N/T
1575/1625/857/885
1730/943
1770/968
115
128
140
201
217
236
42
42
42
50
50
50
MS5002
MS5002B-N/T
1700/927
1770/966
125
137
220
255
42
42
50
50
H2O/Steam Inj.
Dry (Non-Abated)
GT23289E
Dry (Non-Abated)
Single Shaft Units
Model
NOx (ppmv)
500
Peak Load
1200
1000
Full Load
800
400
300
600
3/4 Load
200
1
100
2
3
0
800
430
1/4 Load
NOx (lb/hr)
600
temperatures for waste heat recovery equipment located in the gas turbine exhaust. As
shown in Figure 12, closing the inlet guide vanes
has a slight effect on the gas turbine NOx emissions. Figure 12 shows the effect on NOx ppmvd
@ 15% O2 and Figure 13 shows the effect on
NOx lb/hr. The figures show both MS5001P
and MS7001E characteristics. They also show
normalized NOx (% of base load value) vs. %
base load. Curves are shown for load reductions
by either closing the inlet guide vanes while
maintaining exhaust temperature control and
for load reductions by reducing firing temperature while keeping the inlet guide vanes fully
open.
400
1/2 Load
100
G
D
G
D
G
1000
1200
1400
1600
1800
2000
2200
540
650
760
870
980
1090
1200
Firing Temperature
(F)
(C)
GT25063
350
NOTES:
D - No. 2 Distillate
G - Methane Natural Gas
ISO Conditions
300
NOx (ppmv)
Peak Load
Full Load
600
250
500
3/4 Load
200
150
1/4 Load
700
400
1/2 Load
300
100
NOx (lb/hr)
400
200
50
100
G
D
G
0
800
1000
1200
1400
1600
1800
2000
2200
430
540
650
760
870
980
1090
1200
Firing Temperature
(F)
(C)
GT25064
Peak Load
Full Load
200
NOX (ppmv)
D
150
400
3/4 Load
1/4 Load
1/2 Load
300
NOTES:
D - No. 2 Distillate
G - Methane Natural Gas
ISO Conditions
100
200
NOX (lb/hr)
250
G
D
D
G
G
50
100
800
1000
1200
1400
1600
1800
(F)
430
540
650
760
870
980
(C)
Firing Temperature
GT25065
10
NOTES:
D - No. 2 Distillate
G - Methane Natural Gas
ISO Conditions
160
NOX (ppmv)
Peak Load
120
1/4 Load
400
360
Full Load
320
3/4 Load
280
1/2 Load
240
200
160
80
40
120
80
D
G
G
40
NOX (lb/hr)
200
0
800
1000
1200
1400
1600
1800
(F)
430
540
650
760
870
980
(C)
Firing Temperature
GT25066
105
ISO Conditions
100
1.
2.
3.
4.
95
90
1
85
2
80
GT25067
75
75
80
85
90
95
100
% Base Load
Figure 12. Inlet guide vane effect on NOx ppmvd @ 15% O2 vs. load
ture limit is reached. Once the exhaust isothermal limit is reached, the variation of NOx emissions with speed will become greater. In Figure 16
this exhaust isothermal temperature limit is
reached at approximately 84% speed. Two-shaft
gas turbines also vary the output turbine shaft
speed with load conditions. However the gas turbine compressor shaft and combustor operating
conditions are controlled independent of the
output shaft speed. On a two-shaft gas turbine, if
the gas turbine compressor shaft speed is held
constant by the control system while on exhaust
11
100
95
90
85
80
75
70
65
2
75
GT25068
105
85
80
90
95
100
% Base Load
Figure 13. Inlet guide vane effect on NOx lb/hour vs. load
110
Lb/Hr
100
ppmvd @ 15% O2
ppmvw
80
70
60
NOTES:
ISO Conditions
100% Compressor Speed = 5100 rpm
Natural Gas Fuel
Assumes Exhaust Isothermal Limit
Reached at 84 Percent Speed and Below
50
40
30
75
80
85
90
95
100
105
110
115
GT25069
NOX Values
90
120
gas turbine compressor speed is held at minimum until the turbine exhaust temperature
reaches the temperature control curve. With
further increase in load, the control system will
increase the gas turbine compressor speed
while following the exhaust temperature control curve. If the turbine has modulated inlet
guide vanes, the inlet guide vanes will open first
when the exhaust temperature control curve is
12
GT25070
220
200
180
160
140
NOTES:
ISO Conditions
Constant LP Shaft Speed
120
100
30
20
40
50
60
70
Percent Load
80
90
100
13
GT25071
250
200
150
NOTES:
ISO Conditions
Constant LP Shaft Speed
100
40
50
60
70
Percent Load
80
90
100
Figure 18. This figure is drawn at constant ambient pressure and 60% relative humidity with the
gas turbine operating constant gas turbine firing temperature. For an operating gas turbine
the actual NOx characteristic is directly influenced by the control system exhaust temperature control curve, which can change the slope
of the curves. The typical exhaust temperature
control curve used by GE is designed to hold
constant turbine firing temperature in the
59F/15C to 90F/32C ambient temperature
range. The firing temperature with this typical
curve causes under-firing of approximately
20F/11C at 0F/18C ambient, and approximately 10F/6C under-firing at 120F/49C
ambient. Factors such as load limits, shaft output limits, and exhaust system temperature limits are also not included in the Figure 18 curves.
Based on the actual turbine exhaust temperature control curve used and other potential limitations that reduce firing temperature, the estimated NOx emissions for an operating gas turbine are typically less than the values shown in
Figure 18 at both high and low ambients.
Relative Humidity. This parameter has a very
14
90
80
1
70
60
40
50
10
11
12
13
14
0.62
0.68
0.75
0.82
0.89
0.96
GT25073A
NOX Percentage
100
15 psia
1.03 bar
Ambient Pressure
90
2
80
70
60
50
40
GT25074A
NOX Percentage
100
20
40
60
80
100
120 (F)
-18
-7
16
27
38
49
(C)
Ambient Temperature
15
110
100
90
1. NOx
2. NOx
3. NOx
4. NOx
80
(lb/hr)/(lb/hr at 59F/15C)
(ppmvd @ 15% O2 )/(ppmvd @ 15% O2 at 59F/15C)
(lb/hr)/(lb/hr at 90F/32C)
(ppmvd @ 15% O2 )/(ppmvd @ 15% O2 at 90F/32C)
70
0
20
40
60
80
GT25075
NOX Percentage
130
120
100
16
CO
Combustor Design
Catalytic Reduction
Combustor Design
SOx
Fuel Composition
Smoke Reduction
Combustor Design
- Fuel Composition
- Air Atomization
Particulate Reduction
Fuel Composition
- Sulfur
- Ash
GT25092
NOx
GT11657B
300
High CO
Emissions
2000
3000
(K)
200
High Smoke
Emissions
(F)
1500
2000
Rate of Production
of Thermal NO
NOx
d NO
Flame Temperature
Temperature
2500
4000
dt
(ppmv/MS)
100
1000
0.5
1.0
1.5
Equivalence Ratio
Lean
Rich
17
Water/Steam Injection
Another approach to reducing NOx formation
is to reduce the flame temperature by introducing a heat sink into the flame zone. Both water
and steam are very effective at achieving this
goal. A penalty in overall efficiency must be
paid for the additional fuel required to heat the
water to combustor temperature. However, gas
turbine output is enhanced because of the additional mass flow through the turbine. By necessity, the water must be of boiler feedwater qual-
As a result,
more air is introduced in the head end
of the LHE combustor
NO x emissions decrease
18
nozzles have been designed with additional passages to inject water into the combustor head
end. The water is thus effectively mixed with the
incoming combustion air and reaches the flame
zone at its hottest point. In Figure 26 the NOx
reduction achieved by water injection is plotted
as a function of water-to-fuel ratio for an
MS7001E machine. Other machines have similar NOx abatement performance with water
injection.
GER 3751-19
Turbine Model
December-98
December-98
April-97
Fall 1999
to be determined
March-99
April-97
1986
September-97
Over 130 operating in field
February-99
February-99
to be determined
to be determined
S/C MS3002F
S/C MS3002G
S/C MS3002J
S/C MS5002B, C, & D
S/C MS5001 (All Models)
R/C MS3002J
R/C MS5002B & C
19
Standard
120
LHE
100
80
60
40
Good agreement
between lab and field
20
0
1200
1400
1600
1800
650
760
870
980
2000
(F)
1090 (C)
Standard, Field
Standard, Lab
250
CO Emissions (ppmvd)
LHE, Field
200
LHE, Lab
150
Good agreement
between lab and
field
100
50
0
1200
1400
1600
1800
2000 (F)
650
760
870
980
1090 (C)
20
CO
(ppmvddry,
@ 15%
15%OO22))
CO Emissions
Emissions (ppmv,
125
100
75
50
25
Standard
LHE (steam Off)
0
1700
1800
927
982Temperature (F)
Combustor Exit
Standard
LHE (steam Off)
20
15
10
1900 (F)
0
1700
1038 (C)
927
1800
1900 (F)
982
1038 (C)
30%
reduction
in NO
with with
negligible
increaseincrease
in CO. in CO.
30%
reduction
inxNOx
negligible
Injecting
steam
further
reduces
NOx . NOx.
Injecting
steam
further
reduces
1.0
0.9
0.8
0.7
0.6
GT25108
Figure 25. Field test data: simple-cycle MS3002J with steam injection for power augmentation
0.5
0.4
Natural Gas
0.3
Distillate Oil
0.2
0.1
0.2
0.4
0.6
0.8
1.0
21
2.2
Water
60-70% Load
Baseload
Peakload
2.0
1.8
Steam
Load
1.6
Distillate Fuel
1.4
Steam
1.2
1.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
1.6
1.8
2.0
22
50
40
1460/793
30
1260/682
1665/907
20
10
1870/1021
0.2
0.4
0.6
0.8
1.0
1.2
1.4
1.6
GT10284A
Figure 28. Carbon monoxide vs. water injection effect of firing temperature MS7001B
GT25080
200
Natural Gas With No Diluent Injection
160
120
80
40
0
800
1000
1200
1400
1600
1800
2000
2200 (F)
430
540
650
760
870
980
1090
1200 (C)
Firing Temperature
23
GT25081
120
Natural Gas with No Diluent Injection
100
80
60
40
20
0
600
800
1000
1200
1400
1600
1800
2000
2200 (F)
320
430
540
650
760
870
980
1090
1200 (C)
Firing Temperature
24
25
Oil Connection
GT25085
26
GT25086
GT25088
WATER/STEAM QUALITY
Total Dissolved Solids
Total Trace Metals
(Sodium + Potassium
+ Vanadium + Lead)
pH
6.5 7.5
Contaminant
Sodium + Potassium
Lead
Vanadium
Calcium
Max. Equivalent
Concentration
(ppm wt)
1.0
1.0
0.5
2.0
28
Maintenance Effects
As described previously, the methods used to
control gas turbine exhaust emissions have an
effect on the gas turbine maintenance intervals.
Table 7 provides the recommended combustion
inspection intervals for current design
Advanced Technology combustion systems used
in base load continuous duty gas turbines without NOx control systems and the recommended
combustion inspection intervals with the vari-
Performance Effects
As mentioned previously the control of NOx
can impact turbine firing temperature and
result in gas turbine output changes.
Additionally, the injection of water or steam also
impacts gas turbine output, heat rate, and
exhaust temperature. Figure 36 shows the
impact of NOx injection on these gas turbine
parameters when operating at base load for all
single shaft design gas turbines. Note that the
injection rate is shown as a percentage of the
gas turbine compressor inlet airflow on a weight
basis. The output and heat rate change is shown
on a percent basis while exhaust temperature is
Natural Gas/
No. 2 Distillate
ppmvd @ 15% O2
MS5001P N/T
Dry
NSPS
142/211
87/86
42/65
42/42
12,000/12,000
12,000/12,000
6,000/6,000
6,000/6,000
12,000/12,000
6,000/6,000
6,000/6,000
1,500/4,000
MS6001B
Dry
NSPS
148/267
94/95
42/65
42/42
12,000/12,000
8,000/8,000
8,000/8,000
8,000/8,000
12,000/12,000
6,000/6,000
8,000/8,000
4,000/4,000
MS7001E
Dry
NSPS
154/228
96/97
42/65
42/42
25/42
8,000/8,000
8,000/8,000
6,500/8,000
6,500/8,000
8,000/8,000
8,000/8,000
8,000/8,000
6,500/8,000
1,500/3,000
6,000/6,000
147/220
42/65
8,000/8,000
6,500/8,000
8,000/8,000
6,500/8,000
MNQC
MS9001E
Dry
Inspection Intervals reflect current hardware. Older units with earlier vintage hardware will have lower Inspection intervals.
Base Load Operation.
NSPS NOx levels are 75 ppm with heat rate correction included.
GT25093
The above values represent initial recommended combustion inspection intervals. The intervals are subject to change based on experience.
29
Summary
-1.1
-2
the effects on gas turbine maintenance and performance have also been presented. The minimum controllable NOx levels using LHE and
water/steam injection techniques have also
been presented. Using this information, emissions estimates and the overall effect of the various emission control methods can be estimated.
It is not the intent of this paper to provide sitespecific emissions. For these values, the customer must contact GE.
-2.2 -4
-3.3 -6
-4.4 -8
% Output Increase
4
2
0
-2
-4
1
10
0
Diluent Injection (% Compressor Inlet Flow)
Solid Line = Water Inj for 5001
Dashed Line = Steam Inj for 5001
Chaindashed Line = Water Inj for 61, 71, 91
Dotted Line = Steam Inj for 61, 71, 91
30
Figure 2.
Figure 3.
Figure 4.
Figure 5.
Figure 6.
Figure 7.
Figure 8.
Figure 9.
31
Table 2.
Table 3.
Table 4.
Table 5.
Table 6.
Table 7.
32