JEE Advanced Full Test I Paper 1 Answers

JEE(Advanced)-2014
ANSWERS, HINTS & SOLUTIONS

FULL TEST I
(Paper-1)
ALL INDIA TEST SERIES
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FIITJEE
Q.
No.
PHYSICS
CHEMISTRY
MATHEMATICS
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
1.
(A) (r, s), (B) (r, s),

(C) (q, s), (D) (p, s)
A (q, r) B (q, r)
C (p, s) D (p, s)
(A) (s), (B) (p),

(C) (q), (D) (r)
(A) (p, s), (B) (p,

s),
(C) (q, s), (D) (p, s)
A (r, s) B (r, s)
2.
(A) (q), (B) (s),

(C) (p), (D) (r)
(A) (p, q, r, s),

(B) (q, s) (C) (q, s),
(D) (p, q, r, s)
A (q) B (r)
3.
C (p, r) D (p, q)
C (s) D (p)
(A) (q), (B) (s),

(C) (p), (D) (r)
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AITS-FT-I-(Paper-1)-PCM(S)-JEE(Advanced)/14
Physics
1.
PART I
Now downward force on the right block is

more.
mg
2.
3.
mg
IC = I0 + M(OC)2 = I0 + M(OB2 + BC2) = IB + M(BC)2

Potential difference across AC is zero as
IAC = 0
5 2I = 0
I = 2.5 A
Let the resistance of part BC be r
Applying KVL
10 + 5 2I Ir I = 0
2.5r = 7.5 r = 3
As resistance of part AB = 9
Length AC = 66.7 cm
E1 = 10V
r1 = 1
E2 = 5V
r2 = 2
5.
Initial energy of electron = 2eV

Energy after formation of hydrogen atom in the ground state
= 13.6 eV.
Energy released = 2 (13.6) = 15.6 eV
hc
793
15.6
6.
Threshold wavelength = 5000

hc
Work function =
= 2.48 eV
K.E. = eV = 3 eV
hC
2258
5.48
7.
V 2 3002
V2
R= 2
900
R
P
100
V 300
1
current i
= A
R 900
3
Let L be the required inductance, then
500
500 1
1
or
=
2
2
z
3
3
(900) x 2
P
XL 1200
L
1200 1200
W
2f
1200
4H
150
2
8.
In steady state potential difference across each capacitor = E
9.
H=
14.
15.
E2
0 R dt
6t
12
dt
= 64 J
q1 + q2 = 0
kq kQ kq2
vA = 1
R 2R 4R
kq1 kQ kq2
vC =
4R 4R 4R
vA = vC
q1 = Q/3 and q2 = Q/3
q2
Q
q1
A
C
B
Q
Q
Q Q
vA = k
3R 2R 12R 160R
Q
5Q
Q Q
vB = k
48 R
6R
2R
12R
0
di
17-19. When current is maximum
0
dt
emf across L = 0 and potential difference across the capacitor will be same.
V
From conservation of charge
V
+ +
3CV + CV = 6CV0 CV0
C
3C
5CV0
L
V=
4
Loss in energy of capacitor = energy stored in inductor
3V0 3C
Imax =
2
L
16.
Chemistry
1.
PART II
Ag I AgI e
Eo 0.152 V
Ag e Ag
Eo 0.800 V
Ag I AgI
Ecell = 0. 952 V
At eqm, Eo
2.303RT
1
Ag I K SP
2.303RT
logK SP 0.059 logK SP
F
16.13
0.952
logK SP
2.
3.
A 2 t
on differentiating the equation we get:
dA
1
2AdA dt or
A
dt
2A 2
Hence order is -1.
rA 1
0.5 . As it lies in the range 0.414 to 0.732. AB has octahedral structure like that of NaCl.
rB 2
a 2 rA rB 2 1 2 6 pm
3
4.
Volume = a = (6 pm)3 = 216 pm3

2
BaF2 s
Ba aq 2F aq
K sp Ba2 F
Again K sp 2 Ba2 F
F
5.
Co3
K sp
Ba2
K sp
2 Ba2
1s2 2s2 2p6 3s2 3p6 3d6

3d6
4p
4s
4d
sp3 hybridisation
6.
Bond order of N2 ,N2 ,NO ,NO,CN and CN are 3, 2.5, 3, 2.5, 3, 2.5 respectively. Higher is bond
order smaller is bond length. Bond order of CO and CO+ are 3 and 3.5.
Br
7.
MgCl
Br2 /h
Cl2 /h
CH4
CH3 Cl
8.
C
KCN
COOH
H3 O
O
CH3 CH2 O
Br
C6H5
O
O
Br
Br
C6H5
CH3
C6H5
C6H5
9.
O
O3 / Zn H2O
15.
O K
Ho H CaSO 4 . H2 O s H H2O g
2
1
H CaSO 4 .2H2 O s 833 kJ mol
= + 484 kJ for 1 kg
Ho Ho So
= 17920 J mol-1
Go 2.303RTlogK p
Go
7.22 10 4 pH2O
2.303RT
8.1 10 3 atm
logK p
pH2 O
16.
OH
KOH
Cannizzaro reaction
14.
3
2
pH2O 1, K p 1
Go 0 at eqm.
Ho TSo T
Ho
380 K
So
= 107oC
Mathematics
1.
PART III
x2 + y2 2x 2y 1 = 0
x 2 + y2
1=0
Common chord is 2x 2y = 0 2x + 2y = 0
y = x
1
1
Points of intersection of circles are
,
2
2
k
k 1
8
10 2 5
8 7 14
2.
P(E)
3.
The line can be written as y = mx and curve as x 2 + y2 = 4
C2
Let, C(h, k) be a point on the circles and A 3, 1 be

given point then,
B
1
h2 3
3, 1 A
h 3 2 3
k2
m
3
k = 3m 2
Now, this point (h, k) lies on the circle
2
C(h, k)
(, m)
(0, 0)
y = mx
3 2 3 3m 2 4
2
9 2 12 12 3 9m2 2 4 12m 4
9 1 m2 2 12 3 m 12 0
3 1 m2 2 4 3 m 4 0
2
16 3 m 4 3 1 m2 4 0
3 m 3 1 m2 0
3 m2 2 3m 3 3m2 0
2 3m 2m2 0
2m2 2 3m 0
m 0,
4.
Suppose m is an integer root of x4 ax3 bx2 cx d = 0 as d 0

m0
(I) m > 0
m4 am3 bm2 cm = d
d = m(m3 am2 bm c)
dm
Also, m4 am3 = bm2 + cm + d
3
2
m (m a) = bm + cm + d
m > a contradiction
(II) m < 0
m = n
n4 + an3 bn2 + cn d = 0
n4 + n2(an b) + (cn d) > 0

So, contradiction
Hence, equation has no integral solution
5.
(I)
1
3
2 2
+
+
1
(II) x 3x + 2
1
3
2 2
1
3
2
2
1
3
2 2
1
1
x 1
2
4
1
2
x2 x
+
1
+
+
1
1
3
2
2
2
2x
1
1
(III) x 1 x 1
2
1
3
set x can be ,
4
4
1
2
1
x
4
/2
6.
Required area, A 4
/2
= 4
1
1
1
2
3
x
4
2x
2x
dx
dt
dt
(0, a)
0
a sin t a cos2 t dt
sin t
(0, a)
/2
= 4a
cos
t dt a
7.
Distance from origin, D x2 y2 z2 where P(x, y, z) is any point on the curve

D2 = x2 + y2 + z2 = x2 + y2 +
2
2
2xy
4
xy
xy
D = 2 and occurs at point(s) 1, 1, 2 and 1, 1, 2 , 1, 1, 2 , 1, -1, 2
8.
Differentiating w.r.t. r, 2r dr = 2a cos 2 d, a

rdr
r
r2
sin 2
r2
cos 2 d
sin 2
d
tan2
dr
So, differential equation of orthogonal trajectory, r
d
cot 2
dr
dr
r
ln(cos 2) = 2 ln r + k r2 = c cos 2
Solving tan 2 d
9.
Let f x x 3 bx 2 cx 1.
f 0 1 0, f 1 b c 0
So, 1,0 . So, 2 tan1 cosec tan1 2sin sec 2
1 1
1
1 2sin
1
2 tan1
tan
2 tan
tan sin
2
sin
sin
1 sin

2 as sin 0
2
10.
is continuous every where except where 1 + z = 0

1 z2
z = i so when |z| < 1 then above points are excluded so f(z) is continuous
11.
Continuity : for any point z, lim f z lim x x 0 f z0 . Non differentiable : for any point z,
z z0
f ' z lim
f z z f z
z 0
12.
y1 cos m sin 1 x
lim
z z0
z 0
x
x
x
0 and lim
1
now lim
x 0 x iy
y 0 x iy
x iy
y 0
x 0
m
1 x2
1 x2 y1 mcos msin1 x
1 x 2 y 2 xy1 m2 y 0
n n 1
2
2 yn xyn1 n.1.yn m2 yn 0
1 x yn 2 n 2x yn1
2
Simplifying we get, 1 x y n 2 2n 1 yn1 n2 m2 yn 0

13.
dy 3at 2 t 3
dt
1 t 3 2
1 3
t
dx
6a 2
2
dt
3
1 t
Now
dy
1/3
at t (2)
dx
14.-16. Here, Pv P2 PK so Pv will make acute angle with all the vectors from P2 , P3 , ....., Pk
Pn2
Pn1
Pn
Pk
Pm
P3
P2
P1
So, OPv OP2 OP3 ..... OPk 1 0
Again, if n is odd n = 2k 1

OP1 OP2k 1 OPk
Now OPk will make acute angle with all the vectors from OP1, OP2 ..... OP2k 1

OPk OP1 OP2 ..... OPk OPk 1 ..... OP2k 1 OPk OPk 1

Now, OPk OP1 OP2 ..... OP2k 1 OPk OP1 ..... OP2k 1 = OP1 OP2 ..... OPn

Again, V makes acute angle with all the vectors OP1, OP2 , ....... OP7

So, V S OP1 + OP2 +.......+ OP7 1 V S 1

17.
Eigen values are roots of the equation A X = 0 (A I)X = 0

|A I| = 0
8 4
0
2
2
( 4)( 6) = 0
= 4, 6
18.
When = 6
8 6 4 x1 2 4 x1 0

2
2 6 x 2 2 4 x2 0
2x1 4x2 = 0 x1 = 2x2

2
X C
1
19.
|A I| = 0
1
0
1
1
2
1 0
2
2
3
3
2
6 + 11 6 = 0 = 1, 2, 3,
For = 3
1
X C 1 which is orthogonal
2
SECTION B
1.
(A) Assume sphere as, x + y + z + 2ux + 2vy + 2wz = 0

Now P, Q, R are (2u, 0, 0), (0, 2v, 0), (0, 0, 2w)
x
y
z
So, equation of plane is
1
2u 2v 2w
1
2
3
Since it passes through (1, 2, 3)
1
2u 2v 2w
If centre is (x, y, z) (u, v, w)
1 2 3
locus is 2
x y z
2
2
(B) Assume equation of sphere as, x + y + 2ux + 2vy + 2wz = 0
10
It passes through (, 0, 0), (0, , 0), (0, 0 )
r
u , v= ,
2
2
2
2

1
2 2 2
2
2
2
+ + = 4 if (x, y, z) are coordinates of centroid
4
x , y , z x 2 y 2 z2
3
3
3
9
(C) P (, 0, 0), Q (0, , 0), OPQ = 15
tan 15 =
.. (1)
Now if sphere is made with PQ as diameter (x )x + (y )y + z2 = 0

2
2
2
x + y + z = ax + by
.. (2)
A plane through PQ parallel to zaxis is
x y
1
.. (3)

x y
Using (1), (2), (3) we get x 2 + y2 + z2 = (x + y)

Radius = 1
z2
0
2
(D) Using family of planes any plane through line of intersection is x + y 6 + (x 2z 3) = 0
1
6 3
Now, its distance from centre of sphere is radius
3 , = 1,
2
2
2
1 1 4
z2 = xy(tan 15 + cot 15) 2xy
Equation is x + 2y + 2z = 9; 2x + y 2z = 9
2.
y z , sin (y z) 0
2
1
1
p cos z sin x y sin x y cos2 z
2
2
As, sin (x y) 0 and sin (x + y) = cos z
1
1
2 3
p 1 cos 2z 1 cos
4
4
6
8
(A) Let p = cos x sin y cos z. As,
(B) The equation can be written as 3u2 8u 3 0 u1

Clearly, u1, u2 are negative so
8 2 7
8 2 7
u2
6
6
x1, x2
2
< x1 + x2 < 2 as cot x tan x = 1 = cot x cot x = cot x cot

x
2
3
7
x1 x 2
and another pair, x '1 x '2
x '1, x'2 2
2
2
x1 + x '1 + x2 + x '2 = 5
11
(C) |EF| |E1F1| = a [|BF| cos B + |CF| cos C]

|DE| C [|AE| cos A + |BD| cos B]
|FD| b [|CD| cos C + |AF| cos A]
1
|DC| + |CE| = |EA| + |AF| = |FB| + |BD| = a b c
3
|DE| + |EF| + |FD|
1
1
a b c a b c cos A cosB cosC a b c
3
2
1
So, minimum value is
2
2
2
2
(D) sin x1 + sin x2 + .. + sin x10 = 1
cos xi
sin
A
E
F
B
F1
E1
xj
j 1
sin x
For each 1 i 10 we have cos xi
sin
xj
j i
10
i1
3.
10
cos xi
i1 j i
sin x j
3
10
9
i1
j i
sin x i
3
cos x1 cos x 2 ..... cos x10

3
sin x1 sin x 2 ..... sin x10
(A) Property of ellipse

(B) Normal chord is made between points A 2, 2 2 and B 8, 4 2 so its length is 6 3
(C) Q (4, 2), S : (x 4)2 + (y 2)2 = 16 then required circle is (x 1)2 + (y 1)2 + (x y) = 0
162
Here, = 9 and radius =
2
2
3y
(D) x 2
c
2
5
5
e
(c > 0) and e
(c < 0)
3
2

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JEE(Advanced)-2014

ANSWERS, HINTS & SOLUTIONS

ALL INDIA TEST SERIES

(A) (r, s), (B) (r, s),

(A) (s), (B) (p),

(A) (p, s), (B) (p,

(A) (q), (B) (s),

(A) (p, q, r, s),

(A) (q), (B) (s),

Now downward force on the right block is

IC = I0 + M(OC)2 = I0 + M(OB2 + BC2) = IB + M(BC)2

Initial energy of electron = 2eV

Threshold wavelength = 5000

In steady state potential difference across each capacitor = E

Volume = a = (6 pm)3 = 216 pm3

1s2 2s2 2p6 3s2 3p6 3d6

The line can be written as y = mx and curve as x 2 + y2 = 4

Let, C(h, k) be a point on the circles and A 3, 1 be

Suppose m is an integer root of x4 ax3 bx2 cx d = 0 as d 0

n4 + n2(an b) + (cn d) > 0

Distance from origin, D x2 y2 z2 where P(x, y, z) is any point on the curve

D = 2 and occurs at point(s) 1, 1, 2 and 1, 1, 2 , 1, 1, 2 , 1, -1, 2

Differentiating w.r.t. r, 2r dr = 2a cos 2 d, a

So, differential equation of orthogonal trajectory, r

So, 1,0 . So, 2 tan1 cosec tan1 2sin sec 2

is continuous every where except where 1 + z = 0

Simplifying we get, 1 x y n 2 2n 1 yn1 n2 m2 yn 0

So, OPv OP2 OP3 ..... OPk 1 0

So, V S OP1 + OP2 +.......+ OP7 1 V S 1

Eigen values are roots of the equation A X = 0 (A I)X = 0

2x1 4x2 = 0 x1 = 2x2

(A) Assume sphere as, x + y + z + 2ux + 2vy + 2wz = 0

It passes through (, 0, 0), (0, , 0), (0, 0 )

Now if sphere is made with PQ as diameter (x )x + (y )y + z2 = 0

(A) Let p = cos x sin y cos z. As,

(B) The equation can be written as 3u2 8u 3 0 u1

< x1 + x2 < 2 as cot x tan x = 1 = cot x cot x = cot x cot

(C) |EF| |E1F1| = a [|BF| cos B + |CF| cos C]

cos x1 cos x 2 ..... cos x10

(A) Property of ellipse

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