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Density(g/cc)
1.0-1.1
0.9-1.05
0.8-0.9
0.9-1.0
2500-3000m/s
4.8Gpa
970 ltr. /Kg
3.8 MJ/Kg
excellent
48 Hours
(d)
(e)
In todays context, with the explosive consumption of most noncoal mines at 150-300 T per year, use of ANFO, hand mixed in
their licensed mixing shed, is very common.
(2) SLURRIES: To improve the water resistant properties of ANbased explosives, slurry explosives were developed. Slurry explosives, with
jelly like constituency, are referred to as are made up of
- Oxidizers (ammonium nitrate, sodium nitrate, sodium
perchlorate or
calcium nitrate) (50-80%)
- Fuel (solid/liquid fuels) (1-10%)
- Water (5-20%)
- Sensitiser (explosive/non explosive sensitiser) (5-30%)
- Stabilizers or binder (hydrophilic colloid such as guar gum, hydrazine salt)
(0.1-5.0%)
- Density control agent mechanical aeration i.e. creation of voids, surfactants
(10-40%)
All these ingredients are non-explosive thus
boosting up the factors of safety of the explosive, as such.
Water resistance build up in the slurries is due to the
presence of the hydrophilic colloid (increase the viscosity) and the cross
linkers. The colloid released hydrated gum or polysaccharide molecules into
the sodium. The cross-linker gives off polyvalent metallic ion. A network of
bonds is formed involving both which not only provides a gelled network
but also reduces the influence of water.
Sensitization in slurries is largely dependent on production and
adiabatic compression of air bubbles as described.
Density control as described is mainly by creating voids or by
using surface acting agents which enhance the degree of intimacy in mixing.
Properties(a)
Density 1.05-1.25 g/cc
(b)
Detonation velocity 3000-4500 m/s
(c)
Water resistance highest among the other forms up to a
pressure of 20 Kg/cm2
(d)
Fume characteristic excellent
(e)
Initiation temperature as low as 150c
(f)
Shelf life 1year
(g)
Critical diameter 20mm (in unconfined state)
Slurry explosives, like ANFO, are booster sensitive and have to be initiated
after priming with small quantities of cast booster.
Market products
Slurries are generally available in two forms.
(a)
Cartridge
The explosive is packed in polyethylene bags and
tied with Al wires. They are available in various
diameters as per the requirements at site. In
general, following specification holds goodWeight of cartridge Diameter of cartridge Major manufacturers include IDL industries ltd.
IBP Ltd. ICI India ltd. IGEL, KEL, Maharashtra
Explosives Ltd. Navbharat Explosives Ltd etc.
(b) Bulk system: Due to their constitutional features, slurries are amenable to bulk mixing and
loading. The manufacturers include IBP Ltd. ICI India ltd. IGEL, IDL etc.
Important considerations
1. Slurry explosives offer greater safety during manufacture and
usage, and hence are leading to the gradual replacement of NG
based explosives in spite of possessing a lower strength.
2. They are completely insensitive to the various types of shock,
bullet, impact and friction stimuli.
3. Proper density control is very crucial for maximizing the
sensitivity characteristics of slurries, as they are critically
dependent on initiation mechanism, as they do not contain any
explosive ingredient.
4. Slurry explosives are amenable to bulk mixing and loading
procedures. This remarkable time controlled concept with its
successful field implementation has lead to its large flexibility,
reduction in costs and better performances with same explosive
compositions.
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(b)
Bulk systems: Due to their free flowing nature, emulsions are amenable to
bulk loading. The manufacturers include IBP, ICI, IGEL and
Anil chemicals Ltd etc.
Important considerations: (A) Unique property of emulsions are due to the minute size of nitrate
solution droplets and their tight VOD and unlike other AN based
explosives, they provide a shattering effect.
(B) They possess a excellent water resistance as every oxidizer droplet
is covered by a fuel film.
(C) Emulsions are ever booster insensitive if sensitizing voids are not
added into the mix. T6hils is due to the absence of any explosive
ingredient in the basic mix.
(4) HANFO: The AN-based explosives, as such, are very cost effective, with ANFO
riding the lowest seat having low manufacturing and usage costs
followed by emulsions and slurries. HANFO provides the user with a
high explosive having high comparable strengths, having the costs lower
than slurries and emulsions.
In the modern mining context HANFO is gaining wide
acceptance due to its versatility. It is an explosive that can comfortable
and manually be mixed in the approved ANFO mixing sheds if the per
annum explosive consumption large behinds 500 T mark. For dealing
with higher consumption levels, the user can opt for bulk mixing and
loading systems. And more importantly, it doesnt require any explosive
magazine for storage.
HANFO, which is presently used with bulk systems in general, can be
classifieds as per its composition.
Following are its types: (a) 30% ANFO with 70% emulsion: It is the most water resistant HANFO product with high
inherent strength but low sensitivity.
(b) 50% ANFO with 50% emulsion.
(c) 70% ANFO with 30% emulsion.
These compositions are selected as per the requirement of strata and
watery conditions of the holes. Also the bulk density of ANFO can be
increased from 0.9 g/cc to 1.3 g/cc by increasing emulsion.
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Density
g/cc
VOD
m/s
Strength
ANFO=1
Water
resistance
0.95-1.0
1.0-1.05
1.15-1.2
1.25-1.3
3000-4000
-do-do-do-
1.04
1.10
1.12
1.16
Fair
Satisfactory
Good
Very good
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(4)
(5)
(6)
Property wise comparison of AN-based explosive: (1) Strength: All AN-based explosives have larger bulk strength as
compared to their weight strength.
Following table shows the strength comparison of various products.
Explosive
Relative
bulk
strength
(ANFO=100)
ANFO
100
HANFO
110
Slurries
comparable with HANFO
Emulsion
130
(2) Sensitivity: Sensitivity decreases with increasing density hence, it follows that
maximum sensitivity is possessed by ANFO followed by slurries and
HANFO and the emulsions requiring maximum no. of blasting caps.
(3) V.O.D. (in m/s)
ANFO
2500 3000
HANFO
3000 4000
Slurries
3000 4500
Emulsion
4000 5500
(4) Density (in g/cc)
ANFO
0.80 1.05
HANFO
0.95 1.30
Slurries
1.05 1.25
Emulsion
1.15 1.35
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Case study: - charging and blasting carried out at south block by different
companys bulk explosive system and by cartridge explosive system. The
performance is attached. This shows the powder factor of the different
explosives. For the same hole depth, hole diameter, burden, spacing, bench
height and almost same type of strata.
15
25000
NFCL NOVA BOOST
NFCL NOVA BASE
COST (RS/T)
20000
10000
IBP SMS
NFCL SME
5000
0
1
EXPLOSIVES PRODUCT
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5.748024948
4.962836481
4.616226487
4.220976911
IBP (SMS)
NFCL(SME)
KEL(SME)
3
Cartridge Explosive
0
1
2
Explosive System
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Advantages of bulk explosive system: 1. Safety & Security: Never at any stage, an explosive ingredient is stored or
transported at the mining site. Further, they are insensitive to
initiation by shock, friction, impact, fire etc.
At present scenario the use of explosive & explosive
material in he Bailadila sector from the security point of view
there is always a fear of being robbed or taken away by misgive
and misuse of it. Form last two years many cases of misuse of
explosive materials has occurred in this region and the activities
of Naxalites is increasing and increasing. Keeping in mind all
these happenings, the storage of explosives and related material
in such remote place is not safe, although the security has
provided. The use of bulk explosives avoids the storage of such
huge quantity of cartridge explosive and other hazardous
material the use of bulk explosives avoids the misuse of
explosive.
2. Inventory: No inventory needs to be maintained and hence no
investments in large magazine are necessary only single
small magazine is sufficient for keeping detonator,
detonating fuse, safety fuse and other detonating
material. This will save the cost magazine security,
maintenance and license of the magazine.
3. Explosive Vans & Transportation of explosives: Large numbers of carrier vans are not required.
Due to the flexibility and fast operation of the trucks, a
single truck can serve the whole bench. Transportation of
explosives comprises always a risk of being exploded
due to any accident or shock. For transportation of
conventional explosives large number of explosive vans
is required. But in the case bulk explosive system only
one pump truck can serve the entire mine.
The most important aspect of the bulk explosive
system is that they are never carried as an explosive
through the mining area in the plump trucks. The actual
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explosive characteristics are rendered to the nonexplosive premix only at the site by means of
sensitization and density control.
4. Man Power: Considerable manpower savings are obtained with
less deployment of van drivers, helpers, blasting crew
and magazine staff. Also, due to the use of skilled
manpower (only) the performance is positively improved.
The manpower of the blasting crew can be deployed for
other mining purpose. And some of the security persons
deployed in the magazine area can be placed for security
of other part of the mine.
5. Speed of operation: Swift charging rates of about 250 300 Kg/min
are achieved by bulk trucks.
6. Explosive product: High flexibility, due to the tailor made products at
par with density and energy required, is achieved with
the bulk system. Also when ANFO, slurries, dynamite or
other gelatinous explosives.
7. Blasting Efficiency: Full borehole coupling is achieved with the bulk
system. This enables in expanding burden/spacing
parameters reducing drilling and blasting costs at the
same performance level.
8. Pilferage: As the trucks are non-explosive in nature
throughout the operation, no explosive pilferage results.
9. Effective Land use: As per a case study, for a plant dealing with
5000TPA explosive capacity, only 2 Acres of land is
consumed with bulk systems, which 275 Acres of land is
consumed with conventional system for the same
capacity.
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11.Present production target: Since the targets of our mines are high and
are highly mechanized. Therefore the daily production requirement of the
mine is high and to meet this requirement daily charging and blasting is
needed in huge amount. To meet the present production target of our mine,
charging operation can be met only with the bulk explosive system.
12.Energy characteristics: Large diameter explosives characteristics cannot be change
once they are manufactured. Whereas the energy characteristics of
bulk explosive we can obtain as we desire at the site itself.
The average chemical properties and performance of free flowing or
bulk explosives are as follows:
Expl. Type
ANFO
Al ANFO
NCNSlurries
Slurries
(sms)
Expl.
Density
(g/cc)
0.8-0.9
0.8-0.9
0.8-1.35
2000-5000
2000-4800
3000-4500
Detonation
pressure (K
bar)
10-60
10-60
20-80
0.65-1.55
80-135
4000-6000
50-150
Conclusion
Considering the advantages in respect of safety, security, anti-social element,
inventory, explosive vans & transportation, manpower, speed of operation,
explosive product, blasting efficiency, pilferage, effective land use, net cost
saving, present production target and energy characteristics over the
cartridge explosive system. We can conclude that the bulk explosive system
is more suitable for Bailadila Iron Ore Mine.
Statutory fulfillment: (1) All the pump trucks shall be within valid period of license.
(2) Earthling chain shall be provided in all pump trucks and explosive
vans.
(3) The length of the hose shall be not less than 40m, so that the pump
truck can be parked at a safe distance from charging site.
(4) While charging the hose shall be inserted in the borehole up to the
bottom and then it should be raised slowly the explosive will fill in
the bore hole.
(5) Proper running flow meter shall be provided.
References
1.
2.
3.
4.
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