Estimation of HSP using the Pythagorean Theorem

Appendix

C6

Table C6-1 Comparison of Results of Calculation of HSP Values From Equation C6-1 and from Dr. Hansens Published
Database (Boldface)
TOTAL

Disperse

Polar

H Bonding

MPa1/2

MPa1/2

MPa1/2

MPa1/2

Solvent
Dimethyl Ether

17.38

17.38

13.51

15.20

5.80

6.20

9.26

5.70

1,1-Dichloroethane

18.62

18.50

16.31

16.50

8.39

7.80

3.19

3.00

1,1,1-Trichloroethane

17.13

17.65

16.22

17.00

6.67

4.30

ERR

2.00

Acetone

19.98

19.94

16.28

15.50

11.35

10.40

2.35

7.00

Acetonitrile

24.10

24.40

17.10

15.30

20.24

18.00

ERR

6.10

Acetic Acid

26.01

21.37

17.27

14.50

7.61

8.00

17.90

13.50

Amyl Alcohol

20.64

21.67

16.43

16.00

5.93

4.50

11.01

13.90

Butyl Lactate

18.37

19.90

16.23

15.80

5.83

6.50

6.33

10.20

Carbon Tetrachloride

17.59

17.81

16.35

17.80

CFC-113

11.29

14.79

14.96

14.70

2.74

1.60

ERR

0.01

Chloroform

16.99

18.95

16.37

17.80

4.24

3.10

1.70

5.70

Cyclohexane

16.66

16.80

17.34

16.80

0.93

0.00

ERR

0.20

Cyclohexanol

21.36

22.40

16.96

17.40

6.23

4.10

11.39

13.50

Chloroform

16.99

18.95

16.37

17.80

4.24

3.10

1.70

5.70

Cyclohexanone

19.39

20.33

18.57

17.80

10.93

8.40

ERR

5.10

Cyclopentane

14.90

16.90

17.37

16.80

Diethylene Glycol Monomethyl Ether

19.34

22.20

16.88

16.10

6.13

9.20

7.19

12.20

Dimethyl Formamide

24.09

24.86

17.50

17.40

16.45

13.70

1.92

11.30

Dimethyl Carbonate

20.27

18.70

16.56

15.50

3.70

3.90

11.10

9.70

Dimethyl Sulfoxide

25.87

26.68

18.17

18.40

17.58

16.40

5.48

10.20

Ethanol

25.95

26.52

16.51

15.80

8.38

8.80

18.18

19.40

Ethyl Acetate

18.34

18.15

15.95

15.80

7.19

5.30

5.51

7.20

Ethylene Carbonate

31.87

29.55

18.75

19.40

23.62

21.70

10.31

5.10

Ethyl Formate

19.04

19.53

15.97

15.50

7.51

8.40

7.15

8.40

Ethylene Glycol Dimethyl Ether

(Monoglyme)

17.81

16.61

16.04

15.10

4.84

4.90

6.05

4.90

Ethylene Glycol Monomethyl Ether

23.12

24.82

17.00

16.20

9.93

9.20

12.13

16.40

Ethylene Glycol Monoethyl Ether

21.12

22.49

16.60

15.30

7.90

8.20

10.40

14.30

Ethyl Lactate

19.49

21.68

16.47

16.00

8.92

7.60

5.38

12.50

HFC-245fa

15.06

15.69

13.83

15.40

5.75

3.00

1.52

0.00

HFE-7100

12.18

13.91

14.08

13.70

7.00

2.20

ERR

1.00

HFE-7200

12.09

13.49

14.24

13.30

6.88

2.00

ERR

1.00

Isobutyl Acetate

16.29

16.77

15.83

15.10

6.16

3.70

ERR

0.60

1.80

6.30
(Continued)

617