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Energy From Biomassa
Energy From Biomassa
I44sI
BANK
TECHNICA'L
PAPER
422
NO.
Energy Series
WTP422
1999
March
Work in progress
discussion
for public
WORLD
LgX.vao~~~~~',
PeterQuaak
HarrieKnoef
Hubert Stassen
Allison and Ringold, Labor Markets in Transition in Central and Eastern Europe, 1989-1995
No. 353
Ingco, Mitchell, and McCalla, GlobalFood Supply Prospects, A Background Paper Preparedfor the World Food
Summit, Rome, November 1996
No. 354
No. 355
No. 356
Aryeetey, Hettige, Nissanke, and Steel, Financial Market Fragmentation and Reforms in Sub-Saharan Africa
No. 357
Adamolekun, de Lusignan, and Atomate, editors, Civil Service Reform in Francophone Africa: Proceedings of
a Workshop Abidjan, January 23-26, 1996
No. 358
Ayres, Busia, Dinar, Hirji, Lintner, McCalla, and Robelus, Integrated Lake and Reservoir Management: World
Bank Approach and Experience
No. 360 Salman, The Legal Frameworkfor Water Users' Associations: A Comparative Study
No. 361
Laporte and Ringold, Trends in Education Access and Financing during the Transition in Central and Eastern
Europe.
No. 362
Foley, Floor, Madon, Lawali, Montagne, and Tounao, The Niger Household Energy Project: Promoting Rural
Fuelwood Markets and VillageManagement of Natural Woodlands
No. 364 Josling, Agricultural Trade Policies in the Andean Group: Issues and Options
No. 365
Pratt, Le Gall, and de Haan, Investing in Pastoralism: Sustainable Natural Resource Use in Arid Africa and the
Middle East
No. 366
Carvalho and White, Combining the Quantitative and Qualitative Approaches to Poverty Measurement and
Analysis: The Practice and the Potential
No. 367
Colletta and Reinhold, Review of Early Childhood Policy and Programs in Sub-Saharan Africa
No. 368
Pohl, Anderson, Claessens, and Djankov, Privatization and Restructuring in Central and Eastern Europe:
Evidence and Policy Options
No. 369
Costa-Pierce, From Farmers to Fishers: Developing Reservoir Aquaculturefor People Displaced by Dams
No. 370
Dejene, Shishira, Yanda, and Johnsen, Land Degradation in Tanzania: Perceptionfrom the Village
No. 371
No. 372
Cleaver and Schreiber, Inverser la spriale:Les interactions entre la population, I'agriculture et l'environnement
en Afrique subsaharienne
No. 373
Onursal and Gautam, Vehicular Air Pollution: Experiencesfrom Seven Latin American Urban Centers
No. 374
No. 375
Francis, Milimo, Njobvo, and Tembo, Listening to Farmers: Participatory Assessment of Policy Reform in
Zambia's Agriculture Sector
No. 376
No. 377 Walsh and Shah, Clean Fuelsfor Asia: Technical Options for Moving toward Unleaded Gasoline and Low-Sulfur
Diesel
No. 378 Shah and Nagpal, eds., Urban Air Quality Management Strategy in Asia: Kathmandu Valley Report
No. 379 Shah and Nagpal, eds., Urban Air Quality Management Strategy in Asia: Jakarta Report
No. 380
Shah and Nagpal, eds., Urban Air Quality Management Strategy in Asia: Metro Manila Report
No. 381 Shah and Nagpal, eds., Urban Air Quality Management Strategy in Asia: Greater Mumbai Report
No. 382
Barker, Tenenbaum, and Woolf, Governance and Regulation of Power Pools and System Operators: An
International Comparison
No. 383
Goldman, Ergas, Ralph, and Felker, TechnologyInstitutions and Policies: Their Role in Developing
TechnologicalCapability in Industry
No. 384
Kojima and Okada, Catching Up to Leadership: The Role of TechnologySupport Institutions in Japan's Casting
Sector
No. 385
No. 386
No. 387
Oskarsson, Berglund, Seling, Snellman, Stenback, and Fritz, A Planner's Guidefor Selecting Clean-Coal
Technologiesfor Power Plants
No. 388 Sanjayan, Shen, and Jansen, Experiences with Integrated-Conservation Development Projects in Asia
(List continues on the inside back cover)
EnergySeries
PeterQuaak
HarrieKnoef
HubertStassen
The WorldBank
Washington,D.C.
Copyright K 1999
The International Bank for Reconstruction
and Development/THE WORLD BANK
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Washington, D.C. 20433,U.S.A.
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First printing March 1999
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ISSN:0253-7494
Peter Quaak, Harrie Knoef, and Hubert Stassen work for the Biomass Technology Group, Enschede,
the Netherlands.
Libraryof Congress Cataloging-in-Publication Data
Quaak, Peter.
Energy from biomass: a review of combustion and gasification
technologies / Peter Quaak, Harrie Knoef, Hubert Stassen.
p. cm. - (World Bank technical paper; 422. Energy series)
ISBN 0-8213 4335-1
1. Biomass energy. I. Knoef, Harrie. II. Stassen, Hubert E.,
1942- . III. Title. IV.Series.
TP339.Q23 1998
662'.88-dc2l
98-31271
CLP
ENERGY SERIES
No. 240 Ahmed, RenewableEnergyTechnologies:
A Reviewof the Status and Costsof S electedTechnologies
No. 242 Barnes, Openshaw, Smith, and van der Plas, WhatMakesPeopleCookwith ImprovedBiomassStoves?A Comparative
InternationalReviewof Stove Programs
No. 243 Menke and Fazzari, ImprovingElectricPowerUtility Efficiency:Issuesand Recommendations
No. 244 Liebenthal, Mathur, and Wade, SolarEnergy:Lessonsfromthe PacificIslandExperence
No. 271 Ahmed, Technological
Developmentand PollutionAbatement:A Study of How EnterprisesareFindingAlternativesto
Chlorofluorocarbons
No. 278 Wijetillekeand Karunaratne, Air QualityManagement:ConsiderationsforDevelopingCountries
No. 279 Anderson and Ahmed, The CaseforSolarEnergyInvestments
No. 286 Tavoulareas and Charpentier, CleanCoalTechnologiesforDevelopingCountries
No. 296 Stassen, Small-ScaleBiomassGasifiersforHeat and Power:A GlobalReview
No. 304 Foley, PhotovoltaicApplicationsin RuralAreasof the DevelopingWorld
No. 308 Adamson and others, EnergyUse,Air Pollution,and EnvironmentalPolicyin Krakow:Can EconomicIncentivesReally
Help?
No. 325 Bacon,Besant-Jones,and Heidarian, EstimatingConstructionCostsand Schedules:Experiencewith PowerGeneration
Projectsin DevelopingCountries
No. 362 Foley,Floor, Madon, Lawali, Montagne, and Tounao, TheNiger HouseholdEnergyProject:PromotingRural
FuelwoodMarketsand IrllageManagementof Natural Woodlands.
No. 421 Bom, Foster, Dijkstra, and Tummers, EvaporativeAir-Conditioning:Applicationsfor EnvironmentallyFriendly
Cooling
Contents
Foreword .x.....
Abstract ..
..
xiii
Acknowledgments.........................
xv
Abbreviationsand Acronyms.........................
xvi
xvii
I.
Introduction .1
2.
Biomass as a Fuel
Typesand Sourcesof Biomass
ThermalPropertiesof Biomass
MoistureContent
Ash Content.3
VolatileMatter Content
ElementalComposition
Heating.Value.3
BulkDensity.4
FuelCharacteristics
BiomassCharacteristicsRelatedto the Environment
Contaminants
NitrogenContent
VolatileHydrocarbons
3.
.2
.2
.2
.2
.3
.3
.4
.4
.4
.5
.5
.8
15
20
20
21
21
22
22
23
24
25
4.
GasificationSystems.........................................................
26
Introduction .........................................................
26
FixedBedGasifiers.........................................................
27
Updraftor CountercurrentGasifiers.........................................................
27
Downdraftor CocurrentGasifiers.........................................................
28
Cross-DraftGasifiers.........................................................
28
Open-CoreGasifier.........................................................
28
Comparisonof Fixed-BedGasifiers.........................................................
29
Developmentsin Fixed-BedGasifiers.........................................................
29
Technicaland OperationalProblemswith Fixed-BedGasifiers.....................................................
31
Fluidized-BedGasifiers.........................................................
31
Principles.........................................................
31
PressurizedFluidized-BedGasification.........................................................
32
Comparisonof Fixed-Bedand Fluidized-BedGasifiers..............................
........................... 33
GasTreatment.........................................................
33
Tar Removal.........................................................
33
Dust Removal.........................................................
34
GasEngines.........................................................
34
GasTurbines.........................................................
35
Combined-CycleSTIGand STEG.........................................................
38
Heat Generation.........................................................
39
5.
6.
Conclusions .........................................................
vi
52
Energyfrom Biomass
References .........................................................................
54
56
56
56
57
.........................
58
........................................ 60
61
vii
EnergyfromBiomass
3.20 An Inclined-Grate Combustor with a Connected Three-Draft Firetube Boiler .............. ....................
21
3.21 Water-Tube Boiler .................................................................
21
3.22 Isentropic EfficiencyVersus Capacity for Small-ScaleTurbines ...........................................................22
3.23 Cycle with Steam Reheating After the First Turbine ........................................
......................... 23
3.24 Cycle with Feed Water and Air Preheaters .................................................................
24
4.1 Updraft or Countercurrent Fixed-Bed Gasifier .........................
........................................ 27
4.2 Downdraft or Cocurrent Fixed-Bed Gasifier ....................
.............................................
28
4.4 Open-Core Gasifier .................................................................
29
4.3 Cross-Draft Fixed-Bed Gasifier.................................................................
29
4.5 Downdraft Gasifier with V-Shaped Throat and Internal Heat Exchange...................... .......................
29
4.6 Small-Diameter Gasifier.................................................................
30
4.7 Gasifier with Tar Collection .................................................................
30
4.8 Delacotte Gasifier .................................................................
30
4.9 Fluidized-Bed Gasifier .................................................................
32
4.10 Tar Accumulation on Valveand ValveStem .................................................................
34
4.11 T-Type Mixing System for Mixing Producer Gas with Combustion Air ....................... .......................
35
4.12 Basic Gas Turbine (A) and Two-Shaft (B) Configurations ................................................................. 36
4.13 Gas Turbine with Exhaust Gas Heat Recovery.................................................................
36
4.14 Gas Turbine with Heat Recovery,Intercooling, and Reheat .................................................................37
5.1 SensitivityAnalysis of Concepts in the 1 MWeRange .....................................................
............ 46
5.2 SensitivityAnalysis of Concepts in the 5 MW, Range ......................................................
........... 50
Tables
2.1 Elementary Composition of Typical Biomass as Derived from Ultimate Analyses ............. ..................
3
2.2 Typical Characteristics of Different Biomass Fuel Types Presently Used Commercially
for Energy Generation .................................................................
5
2.3 Sulfur and Chloride Content of Some Biomass Materials .................................................................. 6
3.1 Comparison of Fixed-Bed Combustion Systems...........................
...................................... 13
3.2 Advantages,Drawbacks, and Energy Use of Flue-Gas Treatment Systems .................... ......................
19
4.1 Characteristics of Different Types of Gasifiers.................................................................
31
4.2 Typical Characteristics of Fixed-Bed and Fluidized-Bed Gasifiers....................................................... 33
4.3 Specifications for Use of Producer Gas in Engines ....................................
............................. 35
4.4 Gas Turbines Suitable for Low-CalorificGases.................................................................
37
4.5 Quality Requirements for Gas Turbine Fuel Gas ...........................
...................................... 38
5.1 Gasifier/Engine Concept in 1 MWeRange with Indicative Capacities ............................ .....................
42
5.2 Steam-Cycle Concept in 1 MWe Range with Indicative Capacities ......................................................43
5.3 Characteristic Data of Gasifier/Engine and Steam-CycleConcept .......................................................44
5.4 Operational Aspects of Gasifier/Engine and Steam Cyde ................................................................... 45
5.5 Electricity Production Costs: Steam versus Gasifier (Range: < 1 MWJ) ........................ ......................
45
5.6 Electricity Production Costs: Steam versus Gasifier for SmallApplications
Based on CHP Concepts (Range: < 1MW1l) .........................
....................................... 45
5.7 Steam Cycle Concept, 5 MW , with Indicative Capacities ................................................................ 48
5.8 Gasifier/STEGConcept with Indicative Capacities ................................
................................ 48
5.9 Characteristic Data of Gasifier/STEGand Steam-CycleConcepts in the 5 MWe Range ........... ..........
49
5.10 Electricity Production Costs Based on CHP Concepts in the 5 MWd Range .................. .....................
49
................................ 49
5.11 Electricity Production Costs in the 5 MWeiRange ................................
A4.1 Composition of Gas From Commercial Wood and Charcoal Gasifiers ...............................................62
A5.1 Steam Cycle (Appr. 1 MWe;Power generation/vacuum condenser) .....................................................63
viii
Energyfrom Biomass
A5.2
A5.3
A5.4
A6.1
A6.2
A6.3
A6.4
65
67
69
71
73
75
77
ix
Foreword
Energy,essentialfor development,is oftenin short supplyin countrieswith the greatestbiomassresources.
However,biomassis a renewableenergyresourcewhosepotentialhas not been fullyexploited.
Thereare severaleconomicbenefitsin developingcountriesto the use of biomassresources.The scarcityof
hard currencyin the indebtedcountries obligesthem to look for indigenous,cost-effectivefuelsubstitutes
that reducethe needfor fuelimports.Conversionof crop residuesinto energyincreasesthe valueof agricultural output.Thecostsof gettingrid of municipalwastesarenot negligibleand are mountingin themegacities
of the developingworldwhere land resourcesare constrained.
Abenefitof usingbiomassin placeof fossilfuelsis that CO2 emissionsare cut as a result.Thisis becausethe
biomassactsas a carbonsink when it is growing.Replacingfossilfuelswith sustainablebiomassfuelis thus
one option that countriesmaywishto considerin restrainingCO2 emissions.
The use of biomassresiduesas an energyresourcefacesimpedimentsto larger-scaledeployment.Seasonal
availabilityand high costsof handling are reasonsin someplacesas are the costsof competingfuels.
Another reason,and whythis report waswritten, is that informationon modern technologiesthat convert
biomassto usefulenergyhas not been sufficientlywidelydisseminated.This report thereforereviewsthe
state of the art ofbiomasscombustionand gasificationsystems,alongwith their advantagesand drawbacks.
Bydisseminatingthis informationmorewidely,the reportcan helpbring about a surgein investmentin the
use of thesetechnologiesand thus enabledevelopingcountriesto exploittheir biomassresourcesbetter and
help closethe gap betweentheir energyneeds and their energysupply.
JamesBond
Director
Energy,Mining and
TelecommunicationsDepartment
xi
Abstract
Biomassmaterialshavepropertiesthat differfrom those of conventionalsolid fuels such as coal.A major
differenceis the high content ofvolatilematterin biomassmaterials(up to 80percent),whereascoalhasless
than 20 percent (anthracitecoal sometimesevenhas a negligiblevolatilecontent).The designof a combustion or gasificationsystemdepends heavilyon the specificbiomass material-its morphology,moisture
content,and mixof contaminants.Thelast determineswhich flue-gascleaningsystemswillbe applied.
Combustionsystemsbased on steam cyclesare technicallymature and commerciallyavailable.Eventhe
most advancedconcepts(basedon fluidized-bedcombustion)are technicallyproven.
Gasificationsystemsare commerciallyavailable.However,small-scaleapplicationsneed much supervision
and sufferfrom frequent interruptions. Current developmentof gasificationsystemsis directedtoward
increasingtheir performanceand reliability.
Advancedintegratedgasificationand combinedheat and powerconceptsare promisingbut still not demonstrated.Ademonstrationplant has been built but is not yet in fiiuloperation.
Comparisonshavebeen made betweengasifier/engineand steam-cycleconceptswith capacitiesof 1 MWe.
Production costsfor the gasifier/enginecapacitiesfor the consideredbase are lowerthan that of the steam
cycle.However,some uncertaintyis involvedin assumptionsof the base case,and sensitivityanalysesshow
that changein those assumptionsis largerthan the differencein costsbetweenthe two concepts.Therefore,
on cannot concludein generalthat on conceptis more attractivethan the other. Rather,feasibilitystudies
must be performedin each caseto determinewhich systemis most suitable.
xii
Acknowledgments
BTGpreparedthis report withinthe frameworkof the ESMAPprogrammeof the WorldBank.The authors
wouldliketo thankWlllemFloorand his colleaguesof the WorldBankfor their support and for providing
valuablecommentson the draft report.Thanksalso go to the followingcolleaguesof BTGwho haveassisted
in gatheringinformation:WolterPrins,RolandSiemons,ReneVenendaal,Eric v.d. Heuvel,JohnVos,Bert
Wagenaar,Bertv.d.Beld,and HansJurgenKoele.Wearealso gratefulto Mrs. MarjaBakkerfor her secretarial
assistance.Prof.dr.ir.W.P.M.vanSwaayofTwenteUniversityand Prof.dr.ir.A.A.C.M.Beenackers
of Groningen
Universityareacknowledgedfor their advice.Finally,the authorswouldliketo thankthe NetherlandsOrganizationfor Energyand Environment,Novem,for guidingthe ideaof this projectin the initialstages.
xv
Abbreviations
andAcronyms
General
CEE
Technicalterms
AC
CHP
LHV
HHV
MC
Ti
efficiency
excessair factor
(p
mass flow
t}
phi
Subscripts
boil
boiler
comb combustion
d
on a dry basis
daf
e, el
electric
gen
generator
th
thermal
on a wet basis
wt
on basis of weight
xvi
UnitsandPrefixes
Length
Temperature
OC
meter
Area
m2
degreesCelsius
Prefixes
square meter
mili (10-3)
Volume
c
k
centi (10-2)
kilo (103 )
liter
Mega (106)
m3
cubic meter
Giga (109)
Weight
g
gram
kg
kilogram
tonne (1,000kg)
T
Tera(1012)
norN before m3 (with gas volume), indicates
norm condition of a gas (i.e.,1 bar, 0C)
Time
d
day
hour
second
yr
year
Energy
J
joule (newton-meter)
kWh
Power
W
Watt (=J/s)
xvfii
1.Introduction
Use of wood and other forms of biomassas fuels
for generatingelectricityand heat has become a
focusof renewedinterestin manyparts of theworld.
Biomassis an indigenous,often cheap, and above
allrenewablefuel.Theincreasingavailabilityof biomass, combined with the recent developmentof
technologiesto use it efficientlyand with lowlevels
of emissions,promiseto makebiomassan increasinglyattractivefuel option.
Althoughbiomassis beingusedin industrialapplications in Centraland Eastern Europeand in developing countries, the systems in operation are
oftenold,inefficient,and poorlymaintained,resulting in wasteand pollution.Yetbiomass,in contrast
to fossilfuels,has a unique potentialfor makinga
positiveenvironmentalimpact. That is, in a plan
for sustainablebiomass production and use, the
carbon dioxide(CO2 ) emitted wouldbe absorbed
by the growthof new biomass.
2. Biomassasa Fuel
An assessment of the use of biomass as a fuel requires a basic understanding of the types and
sources of suitable biomass and of their basic composition, characteristics, and performance.
of biomassare as follows:
energymaycreatenewincentivesto growcropsthat
*
*
*
*
*
*
Moisture content
Ash content
Volatile matter content
Elemental composition
Heating value
Bulk density
Figure2.1: BiomassComposition
ae
Wet
Ash
Dryand
matst-ere
basis
Dyand
bais
Source:BTG (1995).
Moisture Content
The moisture content of biomass is the quantity of
water in the material, expressed as a percentage of
the material's weight. This weight can be referred
EnergyfromBiomass
Elemental Composition
The composition of the ash-free organic component
of biomass is relativelyuniform. The major components are carbon, oxygen, and hydrogen. Most biomass also contains a small proportion of nitrogen.
Table2.1 presents the averagerange of percentages.
Ash Content
The inorganic component (ash content) can be expressed in the same way as the moisture contenton a wet, dry, or dry-and-ash-free basis. In general,
the ash content is expressed on a dry basis.
The inherent ash value-an integral part of the plant
structure, which consists of a wide range of elements-represents less than 0.5 percent in wood, 5
to 10 percent in diverse agricultural crop materials,
and up to 30 to 40 percent in rice husks and milfoil.
The total ash content in the biomass and the chemical composition of the ash are both important. The
composition of the ash affects its behavior under
the high temperatures of combustion and gasifica-
Heating Value
The heating value of a fuel is an indication of the
energy chemically bound in the fuel with reference
to a standardized environment. The standardization
involvesthe temperature, state of water (vapor or liquid), andthe combustion products (CO2, H20, etc.).
These standard conditions are widelyavailablein the
literature on the measurement of heating values.
The energy chemically bound in the fuel is given by
the heating value of the fuel in energy (J) per
amount of matter (kg). This energy cannot be measured directly, but only with respect to a reference
state. Reference states may differ, so a number of
different heating values exist. The best known are
Symbol
Carbon
44-51
Hydrogen
Oxygen
Nitrogen
Sulfur
H
0
N
S
5.5-6.7
41-50
0.12-0.60
0.0-0.2
EnergyfromBiomass
20,000-
'
10,000
-.
;;
*.
Moisture
content
(%/6)
similar with regard to higher heating values, biomass fuels have large differenceswith respect
to physical (moisture content and bulk density),
chemical (volatile matter content and ash content),
and morphological (size and size distribution) characteristics.These fuel characteristicsaffectthe choice
of conversion technology: "easy' fuels such as char-
LHV
,Although
.
Note
Fuel Characteristics
;;2"*.
-5,000
-
20
40
60
------
so
100
HHV
varietyof equipment,whereas"difficult"fuelssuch
LHVLowerheatingvalue;
HHV=higherheatingvalue. as ricehusksor bagassecallfor veryspecificand of-
high-quality coal.
.2
BulkDensity
Figure2.2:CslorlflcVaiue of Bblmas
(Lower and Higher HeatingValue)asa
Functionof MoistureContent
g
15,X00
-
BiomassCharacteristicsRelatedto the
Environment
Contaminants
Fresh-biomass-materials
contain very few components that can cause environmental problems.
Sulfurrandchlorine,however,maybe present in small
amounts, and may contribute to the formation of
Enrg fromBlomass
Nitrogen Content
Nitrogen oxides (NO and NO2 , collectivelyreferredto as NOX)also contributeto the formation
of acidrain.Twotypes ofNO. formationtakeplace
during combustion:ThermalNO.formation takes
place at temperatures above 9500 C from the nitrogen containedin the combustion air. FuelNO.
formation occurs at lower temperatures from the
nitrogen contained in the fuel. In general, the
Volatile Hydrocarbons
In combustion and gasificationprocesses,volatile
hydrocarbons,
referredto collectivelyas CxHr,are
formed.These components can be burned when
they are containedover time in a hot combustion
zone.In well-designedcombustionsystems,emissionsof CxHyare very low.However,in poorly designedcombustiondevicesor openfires,CxH emissionsmaybe considerable.
LHVw (kJ/kg)
MCw (%)
ACd (%)
Bagasse
Cocoahusks
Coconutshells
Coffeehusks
Cottonresidues
Stalks
Gin trash
Maize
Cobs
Stalks
7,700-8,000
13,000-16,000
18,000
16,000
40-60
7-9
8
10
1.7-3.8
7-14
4
0.6
16,000
14,000
10-20
9
0.1
12
13,000-15,000
10-20
2
3-7
5,000
11,000
15,000
15,000
9,000-15,000
14,000
12,000
8,400-17,000
25,000-32,000
63
40
15
15
13-15
9
10
10-60
1-10
Palm-oilresidues
Fruit stems
Fibers
Shells
Debris
Peat
Ricehusks
Straw
Wood
Charcoal
1-20
19
4.4
0.25-1.7
0.5-6
SourceAuthor.
EnergyfromBiomass
BiomassMaterial
Maize
Wood
Bark
Straw
Grass
Source:
Schmidtandothers,1993.
Sulfur
Chlorine
0.05
0.01
0.05
0.07
0.18
1.48
0.01
0.02
0.49
0.88
3. Combustion
Systems
andthe SteamCycle
Combustion is the most direct process for converting biomass into usable energy, and it is used in
many applications.Ignition of biomass materials requires high temperatures (at least 550'C; TNO
1992), so the most difficult aspect of the combustion process is to start it. Once ignition has taken
place, however, assuming sufficient air supply is
guaranteed, combustion will proceed. In fact, it may
be difficult to stop the process before complete combustion of the material has taken place.
Despite its apparent simplicity, combustion is a
complex process from a technological point of view.
High reaction rates and high heat release and many
reactants and reaction schemes are involved.
Fundamental research has provided some insight
into the chemical reactions governing the combustion process, and recent applications of the basic
principles have led to new technologies designed to
Figure3.1:BasicProcessFlowfor Biomass
Combustion
Flue gas
Principles
Fumace
Boiler
Fuel
Ar
Thermalenergy
Source:Authors.
The Furnace
In the combustion process, which takes place in the
furnace, chemical-bound energy in the fuel is converted into thermal energy, which becomes available in the form of hot flue gas. This hot flue gas is
thus the useful output of the furnace.
The energy contained in the fuel that is not transferred to the flue gas (in the form of thermal energy)
is lost. Such losses derive from the followingfactors:
Energy
fromBiomass
* Heat losses to the environment (by heat transmission through the furnace walls).
* Release of hot ash (the thermal energy stored in
the ash thus is not used).
* Unburned particles in the ash (the chemical energy in these particles is not released).
* Unburned pyrolysis gases and carbon monoxide (CO) in the flue gas (these still contain chemical energy).
Figure3.2: AdiabaticFlameTemperature
asa Functionof BiomassMoisture
Content and ExcessAir Factor(X)
(AssumedAsh
Content /0 Percent)
2,000
E
(D
C
0
Equation I
flcomb
-s_
01.0
1.5
2.5
3.0
3.5
4.0
4.5
Mc,
0.1
-
2.0
. .
-0.4
0.2 --------
0.3
0.5
Energy
fromBiomass
MoistureContent,and ExcessAir
efficiencies.
The main losses of the boiler are in the hot flue gas
exiting from the stack. Without specially designed
2,000-
i*
EL
9^*
1,000
oo
E
heat gas
exchangers,
temperature
the departing
cannot bethetoo
low since itofcontains
water
vapor,NO., HCI,SO2, and (if the fuelcontainssulfur) some tar components. If the flue gasin the boiler
is cooled too much, water vapor will condense, absorbing HCI, S02, and NO. In such cases,the latter
two compounds form acid components such as
MC, 10%
Mc. 0%flue
....
Mc,,=40%
8:
.o
.0
.0
11.5
,0
2.0
,.0
2.5
3.0
5
3.5
4.0
4.5
be-
Source:Authors.
Ash Content
ACd=1%
ACd= 20%
act fuel composition (determined by a final chemical analysis) and the applied excessair (X).
The difference between the flue-gas inlet and outlet temperatures determines the fraction of the heat
contained in the flue gases that is transferred to water or steam. Consequently, the higher the boiler
inlet temperature of the flue gases (which results in
a large temperature difference between inlet and
outlet), the greater the energy transferred to the water or the steam, and the higher the boiler efficiency.
Figure 3.4 shows the theoretically calculated boiler
efficiency (based on HHV) as a function of moisture content and lambda for a stack temperature of
200C. The more excess air, the more sensitive the
calculated efficiency is to the stack temperature.
Special heat exchangers are discussed in the section
on components of the steam cycle. These are applied to cool the flue gases to temperatures below
100C (down to 50C) in order to minimize heat
loss through the stack. They are even capable of recovering some condensation heat from water vapor contained in the flue gas.
At this point, it is important to note that the efficiency for specific boilers depends not only on the
EnergyfromBiomass
>~
0
5,
c80
o
70
60
--
_._
Systems
Fixed-Bed
-. .
40 -
stack temperature but also on the flue-gas inlet temperature (determined by lambda and moisture content of the fuel). When comparing boiler efficiencies,one should always check to see that the data in
question refer to the same process conditions. Otherwise,it is impossibleto compare the performances
of the boilers.
In most applications, the furnace and boiler are
closelyintegrated, and, in practice, such installations
are referred to jointly as the boiler. The efficiency
of such combined devices is the average of the combustion (or furnace) efficiency (as described in
equation 1) and the boiler efficiency (as described
in equation 2).
Furnace
Types
Combustion systems are of either fixed-bed or fluidized-bed varieties. Fixed-bed technologies date
from the firststeam systems;fluidized-bedtechnologies, in contrast, have only become availableduring
the last 25 years.Fixed-bed systemsare basicallydistinguished by the types of grates and the way the fuel
is supplied to or transported through the furnace.
I0
EnergyfromBiomass
Figure3.6:Suspension
Burnerfor
PulverizedCoal
tarat burer
e inlet
Airduct
Ashscraper
systems.
Ash
t ^
Figure
~~~~~~~~~Air
Inlet
Ashdischarge'
outlet
valve
System
Source: TNO (1992).
Hogluel
2
Tefiary
iI
Screw
alr \
| t;
feeder
1
h/
JiBd^ /
2
1 l,
ai
...
3sp
dumpsectlon
Fixed,bared-tube
slopinggrate
. I
ograte
Crying Gasificatlon
and
zone
bumingzone
Finalburnout
zone
ReciprocatingDump
grate
Figure3.7:Spreader-StokerSystemwith
an Integrated Water Tube Boiler
grateI
SUPER
HEATER
sresa
STEAM
DRUM
OU0T
STACK
FUELW
CNVER
MULTIPLE
FUEL
AIR
/HET
FUELCHUTE._
FUEL
s
ASRU
HA
OVERFIRE
AETER
t
-1
Ai
F.
FA
Source:TNO (1992).
11
Energyfrom Biomass
Lessthan5 MW*,
With regard to enhancing combustion, some special techniques have been developed for more or
less dedicated applications. For example, cyclonic
combustionsystemsare suitable for burning particulate waste wood and agricultural residues, typically
of regular size and shape and relatively low moisture content. The systems comprise a cylindrical
chamber into which the combustion air is introduced. The cyclonic combustion air mixes the suspended particulates, allowing efficient combustion.
The hot combustion gases pass from the cylindrical chamber through the boiler or other heat removal devices. The flue gas is cleansed of ash before passing through an exhaust stack and into the
atmosphere (Figure 3.9).
Figure3.8:CombustionSystemwith UnderscrewFeedingSystem
A. CROSS-SECTIONBOILER
13~~~~~~~~1
~~~~~~~~~~~~1
.Stokerscrew
2-
S::-10
B. TOP-VIEWBOILER
p9
_IBIZI~D
_. _)
-
Source:TNO (1992).
12
2. FireValve
3. Primaryair inlet
D 4.J Secondary
1 iI_14
air inlet
5. Secondaryair inlets
6. Fuelgasoutlet
7. Watersupply
8. Waterreturn
9. Ashdoor
10. Sprinklerconnection
11. Inspectionhatch
12. Explosionvalveand connection
oil or gas bumer
13. Fuelgascleaningfilter
4
__
-7
Energy
fromBiomass
System
Fuelsize (mm)
Maximum
moisture
content (percent)
Staticgrate
Underscrew
50
40
40
40
50
20
50
Throughscrew
Movingbed/inclinedgrate
Suspensionburning a
Spreader-stoker
Fuel supply
Ash removal
manual/automatic
automatic
automatic
automatic
automatic
automatic
automatic
manual/automatic
manual/automatic
manual/automatic
automatic
automatic
manual/automatic
manual/automatic
Source:TNO (1992).
Fluidized-BedSystems
heating) and power (which is supplied to the national
grid). In Denmark, research has alsobeen carried out
for small- and large-scale combustion of straw that
includes grate burning systems, suspension bumers,
and fluidized-bed combustion systems (the last two
are still at the pilot stage).
Flue-Gas Condensation
In Denmark and Finland, flue-gas cooling systems
havebeen developed that can be installed before the
stack. In these systems, gas is both cooled and
cleaned (TNO 1992; Nussbaumer 1991;VTT Energy 1994). Flue gas is cooled to temperatures as low
13
Energy
fromBiomass
2"
3~~
i-i
1.
2.
3.
4.
5.
6.
7.
Straw storage
Automatic feed system
Fuel supply canal
Supply of combustion air
Combustion room
Ash removing system
Heat exchanger/steam production
8.
9.
10.
11.
12.
13.
aas ;
Biomass
feedFlue
1~A
AAA
Air
XBecause
of the intensive mixing in fluidized beds,
Economizer
the heat exchange rates are high, and complete combustion can be realized using low excessair factors
(1 = 1.2 to 1.4). The furnace and heat exchanger
_VCIo
\v.ater
77<
wX
\ /Cyc/one
_
y
;
Ash
14
Energy
fromBiomass
EmissionsReduction
If flue gases from combustion processes contain
unwanted polluting contaminants, reduction of
emissions can be realized by (a) process-integrated
measures that safeguard against the production of
contaminants, or (b) secondary, end-of-pipe
(postcombustion) technologies to remove contaminants from the flue gas.
Process-Integrated Measures
Process-integrated measures are addressed to optimize the combustion process and minimize production of unwanted contaminants.
At temperatures lower than 850C,incomplete combustion occurs, resulting in the unwanted emissions
of CXHy,including tars. If the moisture content of
the fuel is higher than 50 percent and the combustion air is not preheated, problems may occur in
reaching the required combustion temperature.
Drying of the fuel improves combustion performance but may entail additional costs if natural drying (on the field, for example) is not used.
The size of the fuel pieces, apart from moisture content, also determines the quality of the combustion
process. When the fuel is not uniform in size, it is
should be shredded into small, uniformly sized
pieces. Shredding, however, implies additional costs
that must be weighed against the expected benefits.
Emissions
from Fluidized-BedSystems
Because of the nature of the fluidized-bed system,
the flue gas is intensively mixed with dust and particles. Removal of particles and dust from the flue
gases is therefore an essential part of a fluidizedbed system. Circulating fluidized-bed systemshave
one or more cyclones that are a standard means for
removing the heavy (bed material and fuel)particles
from the flue-gas stream. In bubbling fluidized-bed
installations, the basic dust removal from the flue
gases is performed by cyclones. For the final treatment, bag filters may be used.
The stagedair supply and the application of flue-gas
recirculation result in low levels of NO, production.
NOXcan be reduced by injecting NH3 into the bed.
This is similar to the selectivenoncatalytic reduction
(SNCR) reaction schemes applied in deNO, systems
(seesubsection,SecondaryMeasuresto ReduceEmissions, below).
Continuous operation at designed load levels results in the highest system performance and the fewest emissions (Nussbaumer 1991). Extra emissions
occur because of variations in load or frequent
startups and shutdowns. If load variations cannot
be avoided, proper control of the system is required.
Not only should the fuel supply should be controlled, but the primary and secondary air flows
must be adjusted properly. Control systems meant
for improving combustion conditions in systems
that operate under varying loads became available
only recently and development work on this topic
is still going on.
The capacity of a system that must operate under
varying loads should not be too large. It is advisable to consider the actual peak capacity requirements to avoid installing systems that will run at
less than full load much of the time. If the process
15
EnergyfromBiomass
account the effectsof residencetime distribution) in the combustion zone should be longer
than 1.5 seconds.
* Control systems that properly adapt the combustion air/fuel ratio during load changes should
be used.
* Good mixing of fuel and combustion air is essential.
Thermal NOXistypically formed in combustion systems at temperatures higher than 1,400C.Since the
temperatures attained in most biomass combustion
systems range from about 900 to 1,200C,the systems produce only small amounts of NO.. However, nitrogen available in the fuel can be oxidized
into NO during the combustion process, and it is
this that causes the relatively high NOx emissions
from biomass combustion systems.
Techniquesto reduce emissions of NO, are currently
under development. These techniques are based on
staged combustion in physically separated rooms
(Nussbaumer 1991, 1994). This enables lowering
emissions of CO and CxHymore effectivelythan in
conventional systems.An experiment using an electricallyheated reduction chamber has achievedsome
reduction of NOX,but whether this can be realized
practically (i.e.,without resorting to additional electric heating) is still not satisfactorily proven.
The staged combustion process may nonetheless be
of interest because of its potential. In it, the total
combustion process is divided into two or even
three physically separated parts (reactors), shown
in Figure 3.12.
16
-Y
Source:TNO (1992).
EnergyfromBiomass
Figure3.14:Electrostatic Precipitator
C:t
Cleaeldgma
Conaminatedgas
ASp=raelecroe
,
ePrecplatl
electrode
C
A
C. Isolators
D. Sedimeentremoval
Source:.NO (1992).
followsa winding trajectory, passingbetween the elements of the tray. The inertia of the droplets force
their movement more or less in a straight line, causing them to be caught by the tray elements.
'IO
/dust I.0
Source:TNO (1992).
I
drIp tray
..
prIued
alr
ahing liquid
4
(a) .r
washlnglqd
(b)
Ltodriptray
Source:TNO (1992).
17
Energy
fromBiomass
sewy
w 8;;
ro -
IAl
m A
w
----- t ;>. X
:t
ltreatment
systems.
St.k
(77 P25
/12
Selective and nonselective catalytic reduction systems (SCR and SNCR, respectively) are being considered for reducing NO. and are currently under
investigation. For these systems, a reducing agent
(NH3 ) is needed. The SNCRprocess takes place between 8500 and 950C with a high excess of NH3
supply (excess factor = 5). The NO, reduction is
approximately 50 percent. The deNOxperformance
of the SNCRcan be improved when it is integrated
in the reduction stage of the three-stage combusK 4 Verfl.o,tion process.Using an acceptable excessof NH3 (rest
emission NH3 is 30 mg/Nm 3 , 11 percent 02), an
NO, reduction of 80 percent can be realized.
_
The SCRprocess takes place at a temperature of approximately 300C in a catalyst bed. With
stochiometric NH3 supply, a reduction of NOXof 90
percent can be achieved.Becauseof the required temperature, the SCR device must be installed between
the heat exchangers,where the thermal energy from
the flue gasesis exchanged for a process medium.
_pwcmeJThe SteamCycle
_
Ch.an Mroutht
Ut
Wnlemte
_..
~i.
-.
An important application of thermal energy obtained from a combustion system is to generate elecwaZl
11 using
p Tub aplsteam
latricity cycle.The whole chain of enOV
V"
ergy transformation involved in a steam cycle is
I 1lbne
UVlshown
in Figure 3.18. A simplified process scheme
Indmse L1ais presented in Figure 3.19.
S.Wid
-ft
I8
Energy
fromBiomass
Advantages
Drawbacks
Highefficiency(approx.95 %)
Resistantto 300C
flue-gas quantity
Bagfilter
High efficiency(95-99.9%)
Lowpressuredrop (0.6-1 kPa)
Scrubber
Multicyclone
2-3 years)
High energy consumption
Efficiency < 95%
Need for water treatment
Low efficiency
Efficiencydependent on
flue-gas quantity
Constant flue-gas
conditions required
Energy
consumption
per 1,000 m3
0.2-0.4kWh
0.2-0.4 kWh
3-10 kWh
0.2 kWh
Source: Author.
19
Energy
fromBiomass
Thermal
energy
Thermal
energy
I _ Boller
hot flue
T1 boll
~~~~gas
Losses:
* hotash
* unbumed
fuel
* heatlossto the
environment
Electric
energy
Mechanical
energy
steam
Generator
shaft
_power
Losses
* fluegasto thestack
* heatlossto the
environment
T1 gen
Losses
* heatreleased
by
thecondenser
* turbineloss
Losses
* internal
heat
production
in
thegenerator
Source:Authors.
Combustion
air fan
(F*
Ocf
1.
Fumace
[!t
~~
LF1
'_ J
Economizer
Superheater
Fuel
Evaporator
FuelBlow
down
Blwdonpump
Load
Kate
r Condenser
Feed-water Condensate
pump
Source:Authors.
Equation3
Fire-tube boilers contain a larger water volume in
net electricoutput
-
______fiuel_inpu
1O$~
fuel input
net electricoutput
Fuelinput
=Tcomb
XXf,LHVy,,
,el
Ilboil
Tlgen
Pparositic
20
x LHVf,,
with:
=
ing steam demands than water-tube boilers. Furthermore, they usually have lighter requirements
Fire-tube boilers (Figure 3.20) are used to produce steam in relatively low steam conditions. The
steam pressure ranges from 1 to 35 bar; the steam
Energy
fromBiomass
Figure3.20:An Inclined-GrateCombustor
with a ConnectedThree-Draft Firetube
Figure3.21:Water-Tube Boiler
Boiler
STEAM
DRUM
SUPER
HEATER
~~
CHUTE
STEAM
EOVERI
RFIRE
ASHREMOVALDUMPING BOILER
SCREW
GRATE
SHELL
FIREUBES
Source:
NV(1992).
Source:ATNO(1992).
SteamEngines
temperature is limited to approximately 450C.
The capacities range from small (1 to 10 kW) to
large (25 MW). Fire tubes in the boilers are arranged either vertically (as in the boiler in Figure
3.20) or horizontally.
Water-tube boilers (Figure 3.21) are designed for
high steam pressures and temperatures (up to 150
bar and 580C, respectively) and large capacities.
To compensate for large fluctuations in the demand,
water-tube boilers (for control and safety reasons)
should have a relatively large steam drum. Capacities range from about 2 MW up to 2,000 MW, or
even higher for fossil fuel applications. (Because of
the restrictions in biomass fuel availability, the capacity of biomass fueled boilers will in practice be
limited to 100 to 200 MW.) However, no firm rules
can be given in terms of type and capacity of steam
boilers, since the final selection will be governed by
many variables.
The installation of a (chemical) feed water treatment plant is usually necessary for reliable boiler
operation, because the boiler feed water must conform to certain standards. Ideally,the water should
have as few salts, alkaline materials, oil, carbon dioxide, iron, and copper as possible. It should also
be free of oxygen.
21
EnergyfromBiomass
Capacityfor Small-ScaleTurbines
Isentropic
efficiency
(%)
_Mi__tn
Singlestageradialturbine
70
Singlestageaxialturbine
(Curts)
__.
low-pressuresection)maythereforemeanconsiderablylowerinvestments.The resultis that the fullexpansion potential of the steam is not used, leading to
lower power production and lowerelectric efficiency.
This type of turbine maybe utilized in cogeneration
concepts, where heat delivery at temperatures between 100and 150C is required.
A steam turbine is best expressedin terms of its isentropic efficiency.Apart from the thermodynamic
meaning, this can be interpreted as the actual power
obtained from steam expansion in the turbine, divided by the maximum power that can be theoreticallyobtained from the steam expansion. This theoretical maximum depends on the inlet steam pressure and temperature and the outlet steam pressure.
Small-scaleturbines contain only one stage (one row
of blades), in which complete expansion of the
steam takes place. Because of this relatively simple
construction the isentropic efficiencyof these single
stage turbines is relatively low. Application of multiple stages make the turbine more efficient but also
expensive, especially in at small scales. In Figure
3.22,the isentropic efficiencyversus the scale is presented for different types of small-scale turbines.
Small single- or multiple-stage back pressure and
condensing steam turbines in a capacity range from
100 to 5,000 kWe, are available from manufactures
in France,Germany,Great Britain, Japan,the United
States, Russia, Sweden, and several other countries.
Condensers
During power generation, steam that leaves the turbine is condensed in a condenser at very low pressures (approximately 0.1 to 0.2 bar) and tempera-
22
0.5
1.0
2.0
30
4.0
Capacity(MW)
EnergyfromBiomass
tvent
Deaerator mTI
air fan
Fumace
Make-up
Load
eheater
Superheater Evaporator
Economizer
Fuel
COnoo
water/air
aater
V
Btow down
Feed-water
pump
Condenser
Condensate
pump
Source:Authors.
23
EnergyfromBiomass
in feed-waterpreheaters.Advanced steam cyclescontain turbines from which steam is extracted at different temperature levels to meet the distinct heat
requirements of the feed-water preheaters (see Figure 3.23). From a thermodynamic viewpoint, this
method of feed-waterheating is optimal, since steam
is put to maximum use, first for electricity production then for heating function.
smaller scale (< 5 MWe) the cycletends to be complicated and therefore comparatively inconvenient.
Complexity of steam cycles, in particular, is caused
by many auxiliaries, including the following:
Fresh water supply and the need for water treatment; for closed cycles, only a small supply of
extensively treated water is needed. For open
cycles,it is just the reverse.
A deaerator or a deaerating condenser is needed
continuously to remove gases from the water.
However,deaeration requirements decreasewith
lower steam pressures.
Cooling water or an air-cooled condenser or
cooling tower (requiring a continuous fresh water supply to compensate for the evaporated
water) is needed.
Combustion
airfan
Evaporator
Furnace
Fu[+
h
L1
Exhaust
-
Superrheater
Load
Blowdown
Feed-water
pump
Deaerator
tvent
tMake-up
water
iCooling
water/air
Condensate
pump
Source:Authors.
24
EnergyfromBiomass
25
4. Gasification Systems
Introduction
The production of a combustible gas from carboncontaining materials is already an old technology.
So-called dry distillation or pyrolysis (heating of
feedstock in absence of oxygen, resulting in thermal decomposition of the fuel into volatile gases
and solid carbon) was first practiced on a commercial scale in 1812by a gas company in London.
The first commercial gasifier (of the up-draft type;
see below) for continuous air-blown gasification of
solid fuels was installed in 1839, yielding what is
currently known as "producer gas." Gasifiers were
then developed for different fuels and industrial
power and heat applications up to the 1920s,when
oil-fueled systems gradually took over systems fueled by producer gas.
In anticipation of unreliable petroleum supplies,
compact gasifier systems (of the more advanced
down-draft type; see below) for automotive applications were developed in Europe between 1920and
1940. During World War II, tens of thousands of
these gasifierswere in use in Europe and elsewhere;
they were largely decommissioned after the war,
when inexpensive liquid fuels once again became
widely available.
The energy crisis of the 1970s brought renewed interest in gasification. The technology was perceived
as a relatively cheap indigenous alternative for
small-scale industrial and utility power generation
in developing countries that suffered from high
petroleum prices prevailing on the world market
and that had sufficient sustainable biomass resources. In the beginning of the 1980s, at least 10
(mainly European) manufacturers
offered
small-scale wood and charcoal-fueled power plants
(of up to approximately 250 kWe,), and at least four
developing countries (Philippines, Brazil, Indonesia, and India) started gasifierimplementation programs based on locally developed technologies.
Dozens, perhaps hundreds, of biomass gasification
systems were installed through donor-financed
26
EnergyfromBiomass
L
> Gas
Dryingzone
Dsiltozn
Reduction
zone
Hearthzone
Grate
Ash
Source:FAO (1986).
27
EnergyfromBiomass
Downdraftor CocurrentGasfifers
In a downdraftreactor,biomassis fedat thetop, and
the airintakeis at the top or the sides.Thegasleaves
at the bottom of the reactorand movesin the same
direction(figure4.2).Thezonesare similarto those
in the updraft gasifier,but the order is somewhat
different.The biomassis dried in the drying zone,
then pyrolizedin the distillationzone.Thesezones
are mainlyheated by radiation(and partlyby convection)heat from the hearth zone,wherea part of
the charis burned.Pyrolysisgasesalsopassthrough
thiszoneand areburned aswell.Theextentto which
the pyrolysisgasesare actuallyburned dependson
design,biomassfeedstock,and the skillsof the operator.Afterthe oxidationzone,the remainingchar
and the combustionproducts-carbon dioxideand
watervapor-pass to the reductionzonewhereCO
and H2 areformed (seeAnnex4).
Hence,the main advantageof a downdraftgasifier
is productionof a gaswith low tar contentsuitable
for engines.In practice,however,a tar-free gas is
seldomif everachievedduring the operatinglife of
the equipment.The main reason seemsto be that
Figure4.2:Downdmftor CocurrentFixedBedGasif4er
Feed
Drying
zone
Distillation
zone
Open-CoreGasifler
-Hearth zone
Hearth
zone
Air
Air
signed to gasifyfine materialswith low bulk density (for example, rice husks). Because of the low
------
Reduction
zone
Grate
Gas
28
EnergyfromBiomass
DevelopmentsIn Fixed-BedGasifiers
Dryingzone
_____
iS
pThe
Distillation
zone
Hearthzone
_ !2+ zone
Hearth
3
Air
c----
. _
Gas
Reduction
zone
Grate
-
-.
Burningchar
Ash pit
Source:FAO(1986).
zone is in the narrowest part of the throat. The purpose of the throat is to create a concentrated high-
Feed/ air
temperature zone and force through it all pyrolysis gases to crack the tar. Air is fed directly into
this zone by either a central air-supply pipe or air
inlet nozzles located in the walls of the throat. In
choosing throat diameter, a balance must be struck
Dryingzone
Distillationzone
Hearthzone
Figure4.3:DowndraftGasifierwith
V-ShapedThroat and Internal Heat
Exchange
Reduction
zone
Rotatinggrate
Gas4-
11 c
Fee
Ash
7-Water
lock
Gas+
Source:Authors.
Dryingzone
Distillationzone
Hearthzone
Air
LIGrt
Reduction
zone
A
port
P
Source.
Authors.
29
Energyfrom Biomass
Gas
Tar
ryingzone
Distillation zon,
zone
Hearthzone
-Reduction zon(
S ~~Grate
Ash port
Ash pit
Figure4.6:Small-DiameterGasifier
Feed
Source:Authors.
Gas4-1
Dryingzone
zone
Distillation
Hearthzone
Air~~~~~~~
~Air
zone
Reduction
Fe
~~~Gas r
Source:Authors.
Dryingzone
Distillation
zone
Hearthzone
Air
30
Reduction
zone
Grate
\or
Ash pit
Source:Authors.
EnergyfromBiomass
TechnicalandOperationalProblemswith
Fixed-BedGasifiers
Despite different ingenious gasifierdesigns, a fixedbed gasifier that produces a tar-free producer gas
still does not exist. Although Table4.1 shows a turndown ratio for each basic type of gasifier, the partial operation is unsatisfactory for most gasifiers.
Explosions. Explosions may occur when combustible gasesleak through the fuel feeding system, the
ash discharge system, or any other leakage point.
After shutdown of a gasifier,combustible gaseswill
remain in the equipment. If the gasifier is ignited
again without firstventing the equipmentwith fresh
air, the combustible gases still present may explode.
To reduce such risks, gasifiers should be located in
well-vented rooms or in the open air. Operators
should be taught about the risks of gasification
equipment, especiallyduring startup and shutdown.
Fuel Blockages. Fuel blockages may occur in the
throat of the gasifier.These blockages are caused by
an inappropriate combination of fuel properties
(such as morphology), size distribution, ash content and behavior, bulk density, and the flow properties of the derived char.The gasifierdesign should
be adapted to the fuel properties.
Fluidized-Bed Gasifiers
Principles
Fluidized-bed gasification was originally developed
to overcome operational problems of fixed-bed gasification of fuels with high ash content, but it is suitable for the larger capacities (larger than 10 MWth)
in general.The features of fluidized-bed gasification
are comparable with those of fluidized-bed combustion. Compared with fixed-bed gasifiers,the gasification temperature is relativelylow-approximately
750 to 900C. In fixed-bed gasifiers, the tempera-
Downdraft
Updraft
Open-core
Fuel (wood
Moisture content (% wet basis)
Ash content (% dry basis)
Size (mm)
Gas exit temp (oC)
Tar (g/Nm3 )
12(mac. 25)
0.5 (max. 6)
20-100
700
0.015-0.500
43 (max. 60)
1.4 (max. 25)
5-100
200-400
30-150
sensitive
not sensitive
not sensitive
Turndown ratio
hHG filll load (%)a
hCGfull load (%)b
Producer gas LHV (kJ/Nm3)
3-4
85-90
65-75
4.5-5.0
5-10
90-95
40-60
5.0-6.0
5-10
70-80
35-50
5.5-6.0
a. hHGHot gas efficiency.Thistakes into accountthe heat containedin the gas;for heat applications.
b. hCGCold gas efficiency.The gas willbe cooled afterleavingthe gasifierto ambienttemperature;for engineand powerapplications.
Source:Van Swaayand others (1994);BTG(1995).
31
EnergyfromBiomass
Figure4.9: Fluidized-BedGasifier
-~
Gas
The advantages of fluidized-bed reactors in comparison with fixed-bed reactors are as follows:
* Compact construction because of high heat exchange and reaction rates due to intensive mixing in the bed
* Flexibility to changes in moisture and ash content and other fuel characteristics; ability to deal
with fluffy and fine-grained materials that have
high ash content, low bulk density, or both
* Relativelylow ash melting points due to the low
reaction temperatures.
Biomass
l
Ash
T
Air, oxygen, or steam
Source:Authors.
PressurizedFluidized-BedGasification
The carbon burnout in circulating fluidized-bed
gasifiersis considerably better than in bubbling fluidized beds.
The flexibility in particle size of the fuel is not
high compared with fluidized-bed combustion.
For gasification, relatively fine fuel particle sizes
are preferred.
A schematic of a fluidized bed gasifieris givenin figure 4.9.In the figure,steam or pure oxygeninstead of
air are shown as fluidizingand gasifyingagents.If gasification is done with pure oxygen,the caloricvalue of
the producer gas will be higher becauseof the absence
of nitrogen (which of course is present in air). However, production of pure oxygen is expensive,and
32
For power production in relativelylarge-scale applications (>= 5 MWe) gas turbines seem to be attractive prime movers. When used in a gas turbine, the
producer gas has to be fed into the combustor at high
pressures (10 to 25 bar, depending on the gas turbine design). As a consequence,the hot producer gas
from an atmospheric gasifier must be cooled and
compressed,resultingin a high levelof internal power
consumption. The cooling of the gas is necessary
because (a) the temperature of the gas increasescompression, (b) the temperature resistance of compressors is limited, and (c) hot gases take up large volumes, requiring additional work for compression.
The alternative is to gasify under pressurized conditions, delivering producer gas at the pressure of
EnergyfromBiomass
Tar Removal
The drawbacks are as follows:
* The process of feeding fuel into the gasifier is
complex.
* The approach requires high-temperature producer gas cleaning devices;this technology is still
under development and unproven commercially.
* The installation is complex and consequently requires substantial investment for low capacity.
Both pressurized and atmospheric gasifiersare currently used in advanced biomass gasificationdesigns.
Fixed-bed downdraft
Fluidized-bed
10-100
<6
800-1,400
simple
4
mild + refractory
<2.5
minutes
low
<3
4.5
0-20
<25
750-950
average
3
heat-resistantsteel
1-50
hours
average
<5
5.1
Source:
VanSwaayandothers(1994);BTG(1993).
33
Energyfrom Biomass
Dust Removal
Dust-removal equipment for combustion flue gas
such as cyclones, bag filters, and electrostatic precipitators can also be used for cleaning producer
gas. Depending on the upstream processing of the
producer gas, the fabric of bag filters could become
clogged by tars and should be replaced regularly.
An alternative may be ceramic filters, which have a
high temperature and chemical resistance. One
drawback of ceramics is their sensitivity to varying
temperatures in different locations of the same object. Such variations may occur as a result of rapid
changes in the heat load, for example.
Packed beds filled with fine granular particles such
as sand, sawdust, and rice husks are also used for
dust removal. These beds are not as efficient as fabric filters but are relatively cheap and insensitive
to tar deposits. Furthermore, biomass filter materials may ultimately be used as fuel when the filter
bed is renewed.
The most common composition of a producer gas
cleaning chain is a cyclone, followed by a tar condenser, a packed filter bed, and (optionally) a fabric filter.
Gas Engines
Producer gas can be used both in spark ignition
("Otto") and injection ignition ("diesel") engines.
Engine-quality producer gas must have sufficient
heating value for technical and economic reasons
34
%~~~~~~~~
Energyfrom Biomass
Unit of measure
Level
Heating value
Dust content
kJ/Nm3
mg/Nm3
Dust size
Tar content
puM
mg/Nm3
>4,200
<50
<5
<10
<500
<100
<50
<500
Hydrochloric acid
Acetic acid
ppm
ppm
Comment
acceptable
preferable
acceptable
preferable
Air
Airfilter
Filter
F=uel-
vXs;
3g
,a32
rotational speeds.
Particulates
Source: Van Swaayand others (1994).
cific engine characteristics. The efficiency of a diesel engine operating in dual-fuel mode is as much
as 25 percent less than in a single (diesel) fuel mode.
35
EnergyfromBiomass
Combustor
Fuel
Combustor
Compresso
Compresso
Powerturbine
~~~~~~~~~Load
Load
Air
Exhaust
Air
Exhaust
Source:Authors.
Efficiency of simple-cycle gas turbines can be increased by recovering heat from the exhaust gases.
This is done by heating the compressed combus-
36
Fuel
Combustor
Regene
Compressor
Exhaust
Turbine
Shaft
Load
Air
Source:Authors.
EnergyfromBiomass
Fuel
Regenerator{,
Fuel
Combustor
Combustor
Compressors
Exhaust
Shaft
Load
Turbine
Turbine
IntercoolerIntercooler
Source:Authors.
The high level of inerts in the fuel gas tends to reduce the range of stable air to fuel mass ratios. However, this is offset by the high concentration of hydrogen in the flue gas, which burns over a much
wider range of air-to-fuel ratios than other combustible components.
Furthermore, the high level of inerts reduces combustion temperature in a wayanalogous to steam injection or flue gas recirculation in natural-gas-fired
turbines, thus suppressing thermal NO, formation.
Unfortunately, the low thermal NO, formation is
offset by the formation of NO, from combustion of
Becauseof the limited experience with biomass producer-gasturbines, gas quality requirements are still
PowerMWei
Simple-cycleefficiency(percent)
5
21
43
50
70
28
24
33
33
31
Source:Author.
37
Energyfrom Biomass
Unit of
measure
MinimumLHV
Particles
Alkalimetals
MJ/Nm3
ppm
ppm
Source:
Author.
Level
For these reasons, and the fact that the water and
steam are kept in a closed cycle,the STEG, despite
higher investment costs, is preferable to the STIG.
In modern gas plants, overall efficiency of a STEG
3-11
may be more than 55 percent, with and 60 percent
<2-30
reachable within a few years. This progress is made
<0.2-1.0
possible by using dedicated materials and advanced
Source. Authorbladecooling systems to raise the inlet temperature
of gas turbines.
Application of pressurized gasifiers with gas turbines is advantageous because it forestalls the need
for a large producer gas compressor. The gasification air can simply be extracted from the combustion air compressed by the gas turbine. However,
the full advantages of such a system are obtained
only when high-temperature gas treatment systems
(ceramic filters, for example) are applied. These systems are still in the development phase, and a reliable system is currently not commercially available.
The absence of effectivehot-gas treatment systems
is one of the major bottlenecks in the development
of pressurized-gasifier/gas-turbine systems.
38
The efficiencyof steam expansion in a steam turbine is higher than that of steam expansion in a
gas turbine.
Energyfrom Biomass
be 6 MWe.Althoughtheplantisfinished,it is stillnot
operationalbecauseof technicalproblems.
Heat Generation
Usingproducergas in heat applicationis more or
lesscomparableto two-stagecombustion.The differenceis that somedistanceis createdbetweenthe
first stage(gasifier)and the secondstage (burner).
The hot producergasesareconductedthrough gas
pipes to the burner(s). To prevent problemswith
condensationof tar, it is important that the piping
is wellinsulatedand that the transport distanceis
not too long. The advantagesof the gasification/
combustionroute comparedwith direct combustion of the fuelare as follows:
Lowoverall(gasificationplus combustion)excess
airfactors,allowingfor relativelyhighefficiencies
* Lowlevelsof NOXemissions
x Lessfoulingof the heat exchangeequipment or
heatedproducts(in direct heatapplicationssuch
as drying or baking) as a resultof lessfly ash in
the combustiongases.
*
39
5. Combustion
VersusGasification
Heat Applications
In chapter 3, different aspects of combustion of biomass are presented and discussed in relation to different types of furnaces. Basically,the hot flue gases
leaving the furnace can be used directly or indirectly.
Direct combustion heat is used for baking (e.g.,
stones, bakery products, and cement) and drying
(e.g., food, wood, paper, and painted objects). Indirect heating processes use heat exchangers such
as boilers for the production of steam or hot water.
Designs based on direct heating may be cheaper
because of the absence of these heat exchangers.
However, direct contact between the product and
the hot flue gases may limit possible applications
of the direct heating process, because the contact
may result in physical or chemical interactions between the flue gases and the product. To some extent, this problem may be solved by using cleaning
equipment to reduce the levels of contaminants.
However, the temperature resistance of the available cleaning systems is limited, so the flue gases
would have to be cooled first to the operating temperature of the cleaning systems (approximately
3000 to 400C). This, of course, would result in a
considerable loss of the contained heat.
Gasification of biomass may be advantageous if direct heating by flue gases is considered. The advantages of using producer gas are as follows:
* A producer gas flame can easily be burned with
low NOXemissions.
* When strict emission levels on flue gas contaminants are required, producer gas can be cleaned
before use.
* A gas flame can easily be directed to a certain
heating zone.
* Each burner can be controlled easily (the process is similar to cooking on a gas stove).
The energy in the producer gas is to a large extent
chemicallybound energy (about 80 percent). If the
cleaning system requires cooling of the producer
gas, only thermal energy, which represents approximately 20 percent of the contained energy,
40
gets lost. By using an intensive gas-cleaning system in combination with a well-designed burner,
a clean flow of hot flue gases can be produced for
direct heat applications.
If the heat is applied in an indirect heating system
using heat exchangers (e.g., boilers), both gasification and combustion systems can be used.
In general, direct combustion systems may offer the
highest overall efficiency,whereas gasification may
offer the highest controllability.
Retrofittingof Fossil-Fuel-Fired
Furnaces
In some cases it can be attractive to convert fossilfuel-fired furnaces to biomass fuel rather than to
construct new biomass-fueled devices. When no
alternative exists, fossil-fuel conversion may be the
most effectiveway to prevent waste of capital goods.
A clear reason for such a conversion may be a sudden scarcityof fossilfuels that makes them extremely
expensive.This applies particularly to some Central
and Eastern European countries that can no longer
accesscheap fossilfuels from Russian resources and
now must import them. Some such countries, such
as Estonia (BTG 1995a) and the other Baltic states,
also have large biomass resources available in the
form of wood and peat. For these countries, retrofitting to biomass fuel is a serious option to decrease
dependency on foreign fossil fuels.
Policies for sustaining energy resources can also
stimulate conversion of equipment. In the United
States, the government offers tax credits if biomass
fuels are used.
The basic principles for boiler conversion are described below.
Installationof a Prefurnace
An additional furnace, the prefurnace, can be installed in front of the existing boiler/furnace device. This prefurnace is especially designed to
Energyfrom Biomass
EnergyfromBiomass
Powergeneration and
CHP
Remarks
t/h
1.5
n.a.
MW
Nm3 /h
m3/h
MWth
4.1
3,100
n.a.
n.a.
n.a.
usefulheat in CHP option
Scrubber
m3/h
MWe
MWth
4,200
I
Component
Fuel supplysystem
Gasifier:
Capacity
Gas production
Multicyclone:gas treatment capacity
Producer-gascooler
42
9,900
1.2
2.2
n.a.
n.a.
usefulheat in CHP option
EnergyfromBiomass
Unit of measure
Powergeneration
CHP
Fuel suppysystem
Furnacewith staged combustion
Fire-tubeboiler:steamproduction
tVh
1.8
1.8
MWth
t/h
7.3
7.3
9.7
9.7
m3/h
18,000
18,000
Mwe
MwU
m3/h
1
5.5
0.1
0.8
5.7
0.1
m3/h
m3/h
9.7
18,000
9.7
18,000
Source:Author.
43
EnergyfromBiomass
Steam cycle
Unit of measure
Power
CHP
Power
CHP
Investment
Specificinvestment
$1,000
2,975
2,975
4,000
3,800
$/kWe
2,975
2,975
4,000
4,911
Expectedlifetime
Labor
Efficiency
year
person*year
10
1
10
1
15
1
15
1
0.17
-
0.17
0.58
0.14
0.11
0.79
Electric
Heat
Capacity
Electric
Heat
Maintenance
-
MWIAe
MWth
$1,000/year
0.8
3.4
5.7
85
85
100
95
Not applicable.
Note:Generaldataandassumptions
areasfollows:
Intereston loans
Laborcost
LHVfuel(wetbasis)
Fuelprice
Annualoperation
8 percent
$50,000
per personperyear
14.2MJ/kg
$40/tonne(i.e.,$2.82/GJ:
approximately
50percentof fossilfuelprice)
6,000h/year
Source: Author.
44
In CHP mode, steam can be condensed at a constant temperature (in the presented case 100C),
while the gasifier/engine delivers heat by warming
up water (in principle, other fluids are alsopossible)
from, for example, 70 up to 105C(for the engine).
The heat from the gas cooler is released at higher
temperatures, and its use increases the potential of
the gasifier engine unit to heat a fluid from, say, 700
up to 1200or 125C.
The design of a steam cyclecan easily be adapted to
deliver heat at higher temperatures (150C, for example, is common in process industries). However,
this will reduce electricity production.
In the case presented, the applied boiler steam pressure and temperature are modest because of the
application of a fire-tube boiler. A water-pipe boiler
would allow higher steam temperatures and pressures, resulting in higher electric efficiency.But investments would also increase significantly.
In Annex 5, a complete financial analysis is presented
for both the gasification and the steam-cycle-based
EnergyfromBiomass
Gasifier/engine
Steam cycle
3-4
Poorto reasonable
Moderate
CO danger
High,at medium frequencies
0.2-1 h
Difficult:skilledpersonnelrequired
5-10
High
High
High-pressuresteam
High,at high frequencies
1-3
Straightforward:skilledpersonnelrequired
Source:
Author.
Table 5.5:ElectricityProductionCosts:
Steam versus Gasifier (Range:
u
I MWCs
)
Cost element
Capitalcost
Fuelcost
Labor
Maintenance
Total
Source:Author.
Steam cycle
($/kWhe)
Gasifier/engine
0.08
0.07
0.01
0.03
0.19
0.07
0.06
0.01
0.01
($kwhe)
0.15
Steam cycle
($/kwhd)
Gasifier/engine
($/kwhe)
0.10
0.09
(0.06)
0.01
0.04
0.18
0.07
0.06
(0.03)
0.01
0.01
0.12
45
EnergyfromBiomass
CHP(capacity
1 MW
0)
0.25 -
0.25 -
~_
0.20 -
_0.20-
0.15 -
010 -
0.OS -
0.10 -
0.05-
0.05 -
Operating
Hours
Operating
Hours
Steamcycle
- - - - Gasifierengine
Steamcycle - - - - Gasifierengine
Powergeneration
(capacity
1 MW0)
CHP(capacity
1 MW
0)
0.25 -
0.25 -
0.20 -
020 -
0.15
0.15
0.10 -
0.10 -
0.05 -
0.05 -
OM
1,000
2,000
3,000
0.00
4,000
5,000
6,000
1,000
Specific
investment
($/kW,)
U
SteamcycAe
Basecasesteamcycle
2,000
3,000
4,000
5,000
6,000
Specific
investment
($/kW,)
Steamcycle
* Basecasesteamcyde
- - -Gasifierengine
Basecasegasifierengine
Powergeneration
(capacity
1 MW0)
--*
- Gasifierengine
Basecase gasifierengine
CHP(capacity
1 MW0)
0.25 -
0.25 -
0.20 -
0.20 -
0.15 -0.15
0.0
0.1
0.05 -
0.05
0.00 -
0 .Q00
10
20
30
40
50
60
70
80
Fuelprice($/ton)
Steamcycle
- - - - Gasffierengine
10
20
30
Steamcycle
Note:The basecasefor operationhours is 6,000hours per year;for fuel priceit is $40per ton
Source:Authors.
46
40
50
60
70
s0
Fuelprice($/ton)
- - - -
Gasifierengine
Energyfrom Biomass
47
EnergyfromBiomass
Unit of measure
Powergeneration
CHP
MWth
t/h
t/h
m3 /h
MWe
MWth
18.2
4.6
19.1
47,000
5
11.3
18.2
4.6
19.1
47,000
4
12.3
m3 /h
0.3
0.3
m3 /h
19.1
19.1
m3 /h
50,000
50,000
Source:Author.
Unit of measure
Powergeneration
CHP
Nm3/h
t/h
MWe
t/h
MWe
MWth
7,500
3.6
3.2
15
1.6
7,500
3.6
3.2
15
0.9
8.2
Not applicable.
Source:Author.
48
SensitivityAnalysis
A sensitivity analysis is performed using the same
parameters and bandwidths employed for the 1
MWe concepts: annual operating hours, fuel price,
and specific investment (Figure 5.2). As seen from
the figure, the differences between gasifier/STEG
and steam cycles are negligible in all graphs. As
EnergyfromBiomass
Specificdata
Unitof measure
Steam cycle
Power
CHP
Power
CHP
Investment
Specific investment
$1,000
$/kW,
14,000
2,800
13,400
3,350
13,000
2,600
12,000
3,064
Expectedlifetime
Labor
year
person*year
15
3
15
3
15
3
15
3
0.35
-
0.28
0.58
0.28
0.22
0.68
Efficiency
Electric
Heat
Capacity
Electric
Heat
Maintenance
MWe
MIWth
$1,000/year
3.9
8.3
12.3
350
335
325
300
Not applicable.
Note:Generaldata and assumptionsare as follows:
Intereston loans
8 percent
Laborcost
$50,000per person per year
LHVfuel (wetbasis) 14.2MJlkg
Fuelprice
$40/tonne(i.e.,$2.82/GJ:approximately50 percent of fossilfuel price)
Annualoperation
6,000h/year
Source:Author.
-
Table 5.10:ElectricityProductionCosts
Basedon CHP ConceptsIn the 5 MW 1
Range
Costelement
Steamcycle
Gasifier/engine
($/kWhe)
($IkWhi)
Table 5.11:ElectricityProductionCostsin
the 5 MW., Range
Costelement
Capitalcost
Steamcycle
($/kWh)
Gasifier/engine
($/kWh)
0.05
0.05
0.04
(0.00)
0.03
(0.00)
Capitalcost
Fuelcost
0.06
0.05
0.06
0.05
Fuelcost
Omittedfuelcost
Omittedfuel cost
(0.03)
(0.03)
Labor
0.01
0.01
Maintenance
Total
Source:Author.
0.01
0.10
0.01
0.10
Labor
0.01
0.01
Maintenance
0.01
0.01
Total
0.10
0.10
Note:Actual
poweroutputapproximately
4MWe
Source:Author.
This price sensitivityis less for CHP conceptsbecauseheat salesare coupledto the fuelprice.
Sensitivityto specificinvestmentcostsis high,but it
is thesameforpowerand CHP concepts.Production
costs(whichcanbe identifiedwhenspecificinvestment is equalto zero) are somewhatlower for the
CHPconceptsbecauseof the additionalsaleofheat.
49
EnergyfromBiomass
0.25 -
0.25 -
0.20 -
0.20 -
0.15 -
0.15_
0.10 -
.1
0.05 -
0.05 -
0.00
0.00
4,000
4,500
5,000
5,500
6,000
6,500
7,000
7,500
8,000
4,000
4,500
5,000
OperatingHours
Steamcycle - - - - STEG
5,500
Powergeneration(capacity5 MW0)
6,500
7,000
7,500
8,000
CHP(capacity4 MW,)
0.25 -
0.25 -
0.20 -
0.20
0.15
0.15_
--
3,0.10
0.10
0.05 -
0.05 -
0.00
0.00
0
1,000
2,000
3,000
4,000
5,000
6,000
1,000
2,000
3,000
Specificinvestment($lkW,)
Steam cycle
* Basecasesteamcycle
STEG
- --
Steam cycle
* BasecaseSTEG
* Basecasesteamcycle
5,000
6,000
STEG
- --
* BasecaseSTEG
0.25 -
0.25 - ________________________
0.20-
0.20-
0.15 -
0.15 0.10
I.CO
4,000
Specificinvestment($/kW,)
Powergeneration(capacity5 MW0)
0.1~~-0
0.05 -
0.05 -
0.00 0
10
20
30
40
0.0050
60
70
Fuel price($1ton)
Steamcycle - - - - STEG
80
10
20
30
40
50
60
70
Fuel price($tton)
Steamcycle - - - - STEG
so
6,000
OperatingHours
Steamcycle - - - - STEG
80
Energyfrom Biomass
also lower,except for specificinvestments.(Sensitivity of the gasifier/engineconcept is higher becauseof its shorter life span.)
sI
6. Conclusions
Biomass mateTialshave properties that differ from
those of conventional solid fuels such as coal. A
major difference is the high content of volatile matter in biomass materials (up to 80 percent), whereas
coal has less than 20 percent (anthracite coal sometimes even has a negligible volatile content). The
design of a combustion or gasification system depends heavily on the specific biomass material-its
morphology, moisture content, and mix of contaminants. The last determines which flue-gas cleaning
systems will be applied.
Combustion systemsbased on steam cyclesare technicallymature and commercially available.Even the
most advanced concepts (based on fluidized-bed
combustion) are technically proven.
Gasification systems are commercially available.
However, small-scale applications need much supervision and suffer from frequent interruptions.
Current development of gasification systems is directed toward increasing their performance and
reliability.
Advanced integrated gasification and combined
heat and power concepts are promising but still not
demonstrated. A demonstration plant has been built
but is not yet in full operation.
The main difficulties are in the gas-cleaning systems
(preferably at high temperatures) and meeting all
requirements set by gas-turbine manufacturers in
adapting gas turbines to low calorific gases.
The limited availability of biomass means that
small-scalepower plants will be preferred. However,
the smaller the cycle,the lower the overall efficiency.
Development work with steam cyclesaims to downgrade large steam-cycle systems to ranges between
1 and 10MWeand to increase the efficiencyof small
systems.Currently, fluidized-bed systemswithin this
range operate at mature steam conditions and reach
acceptable efficienciesof from 25 to 35 percent.
52
Comparisons have been made between gasifierlengine and steam-cycle concepts with capacities of 1
MWe. Production costs for the gasifier/engine capacities for the considered base are lower than that
of the steam cycle. However, some uncertainty is
involved in assumptions of the base case, and sensitivity analyses show that change in those assumptions is larger than the difference in costs between
the two concepts. Therefore, one cannot conclude
in general that one concept is more attractive than
the other. Rather, feasibility studies must be performed in each case to determine which system is
most suitable.
The steam cycle has a higher operational reliability
but requires higher investments. The gasifierengine
has a higher efficiency but lower reliability.
The CHP concepts for the steam cyclelead to derating maximum power output compared to pure
power generation. The derating depends on the
temperature level of the delivered steam. A CHP
concept based on the gasifierlengine concept requires no derating, but heat delivery is restricted by
the limited cooling temperature of the engine. A
common application might be heating a fluid from
700 to 1250C.
In the 5 MWe range, a steam-cycle concept and a
gasifier/STEG have been compared. The efficiency
of the gasifier/STEG is higher, but electricity production costs are comparable. The efficiency of
gasification-based systems is higher than that of
steam cycles, but the investment costs are also
higher. The steam-cycle concept is currently commercially available, whereas the gasifier STEG
demonstration phase was expected in 1995. Full
commercial availability of the STEG concept is
expected within five years.
The electricity production costs of the 5 MWe concepts are roughly 30 percent lower than those of
the 1 MWe concepts.
Energyfrom Biomass
The sensitivityto variationsin the number of annual operating hours and fuel price is lower than
that of the 1 MWeconcepts.
53
References
AED. 1994. "Commercialization of Biomass
Projects: A Case Study of the Design, Development, and Application of a Biomass Gasifier to a Large Retrofit Market." Paper presented at the Sixth National Bioenergy Conference, Reno/Sparks, Nevada, October 2-6.
BTG (Biomass Energy Technologies). 1987."Thermochemical Conversion of Biomass to Energy."Prepared for UNIDO, Vienna, Austria.
_.___
1993."VerslagstudiereisbiomassaCFBver-
Nussbaumer,
54
Energyfrom Biomass
55
MCW=
WHO
WHZO
0.15
Ash Content
The inorganic component of biofuels varies widely.
The inherent ash value, which is an integral part of
the plant structure and consists of a wide range of
elements, represents less than 0.5 percent in wood,
5 to 10percent in many agricultural crop materials,
and up to 30 to 40 percent in-for example-rice,
husks, and milfoil.
The ash content can be expressed in the way the
moisture content is expressed:on a wet and dry basis
or on a dry-and-ash-free basis. If we take the same
figure for the water, ash, and dry biomass weights
as given in chapter 2, the different ash contents will
be as shown in the equations 4, 5, and 6. In general,
the ash content is given on a dry basis.
Wwm
W.,h
Wh
=0.15 = 15%
ACw0
WH2O
Wdaf + W,.h
WH20
Wwm - Wh - WHO2
= 0.05 = 5.0%
0.80 + 0.05 + 0.15
0=0.17617.6%
M
0.80 + 0.05
(3) Moisturecontent on a dry-and-ash-free
basis(MCda)
Wwm
A.
ACd =
Wah
Wdaf+ Wash
__
_=
0.80+ 0.05
Wwm + WH2 O
0.059 = 5.9%
WH20
WH20
Wdf
0.15
=
M0daf -
MGdf
56
=0.188 =18.8%wm
0
(ACdaf)
ACd
W
Wf=
Wah
wdf
ACd = 0.05
af6~.80
= 0.063 = 6.3%
Energyfrom Biomass
Heating Values
If moisture content, ash content, and hydrogen content of a fuel are known, all six heating values
(LHVwLHVd,LHVdWf,HHVd,
andHHVdf)
can be derived from each other. The various formulas to calculate the higher heating values are
given in equation 7, applied to the numeric examples from chapter 1.
LHVd
HHVdaf X
wash
HHVdfX X
= LHVdaf X
Waff
Wdaf + Wah
= LHVdf(
= LHVdaf X (1
Wdaf+ Wah
LHVdaf = HHVdaf- [-
Wdaf+ Wah)
- ACd)
= 18,757 X (1 - 0.059)
\
)
LHVW
17,650 kJ/kg
= LHVdaf X
= 20,400 X (1 - 0.059)
=
19,196 kJ/kg
= LHVdaf X
+ Wh + WH2 O
WWm
HHVW
= HHVdafx
Wdaf=
MC,)
= HHVdaf X
+ Wah + WHO=
= HHVdaf
X (1 - ACW - MCw)
= HHVdgf
X (1 - ACd) X (1 -MC,)
16,317 kJlkg
57
Annex2: Stoichiometric
Air Requirements
in the CombustionProcess
Amount of Air to Be Suppliedto the
Combustion
Process
For air supplya distinctioncanbe madebetween
primaryair aupplyand secondaryair supply.Primaryairissupplieddirectlyto thefuelbed,whereas
secondaryair mixeswith the volatilegasesabove
the fuelbed.
PrimaryAir
PrimaryAiris requiredforthe combustionof the
solidsin thefuelbed-for example,thenonvolatile
(or fixed)fractionof carbon,or charcoal.
The followingreactionoccurswhen charcoalis
burnedin thefuelbed:
Thestoichiometric
amountof airneededis:
32 100.0
-_
1 moleCO2
xX -X-kg
e
Ultimateanalysis:
- Carbon(C) p kg/kgfuel
- Hydrogen
(H) q kg/kgfuel
- Oxygen(0)
rkg/kgfuel
- Ash:
s kg/kgfuel
* Proximateanalysis:
- Charcoal:
x kg/kgfuel
Volatiles:
y kg/kgfuel
- Ash:
skg/kgfuel
12 23.3
Includingthe excessair factorfor primaryair Xp
equation4 becomes:
X 00.0kgair
ApX x X
3
23.3
Secondary
Air
At combustionof the volatiles,two reactionsare
involved:
Reaction
2:Combustion
ofhydrogenfractionofthe
biomas,or
32
qX - = 8 X q kgO2
58
2 mole H2 + 1 mole02
-e
2 mole H20
I+
xX
Co2
X
X xx XX
: A X
N2
X 132
~~~~~N
2
kgO2
8 X q-r 8Xq-r
kgO2
76.7 kg
-X-
12
32
12: kg
(Xp-)XxXy
combustionof hydrogenis:
100.0
23.3
23.3 X (8 X q - r) kg
H20
: 9 X q kg
76.7
100.0
XSX 23.3 X (8 X q-r)
kg
s-2
X
X q-r) kg
N2
02
: (Xs - 1) X (8 X q - r) kg
X (8
23.3
1 mole GO2
-*
From this reaction it can be concluded that the total amount of air needed for the combustion of car-
-X
T
23.3
N2
kgprimaryair
12
kg
CO2 :4
kg
1223X(p-1)Xx-(S-1
100.0
- x)s x
8 X q-r)
kg
Thus, by combining the three reactions, the following combustion products can be distinguished:
~~23.3
76.7
X- 2-
44
100.0
8 X 2 5 T XXp Xx
3 X (p-x)
12
32
{8
X-
32
kg
To summarize, for the combustion of 1 kg of biomass, the primary and secondary air requires:
(p -x)
kg
100.0
32
12
44
CO 2
kgsecondary air
H20:
8
:TX(Xp-l)
X x (-1
-X(p-x)
+8 X q -
kg
J
9 X q kg
CombustionProducts
The data of the previous section supply sufficient
information for determining the amount of the
combustion products generated by burning 1 kg of
biomass.The products are: CO2 , N2 , H2 0, and 02-
N
N
8
76.7 X ;
-XP3
(8
76.7 X X
23.3
X(p-x) +8 X q -
kg
59
Annex3: Conversion
of Heat into Power
An important application of thermal conversion of
biomass is to produce mechanical power from the
generated combustion heat. The effectivenessof this
conversion is governed by thermodynamic laws.
These laws say that it is impossible to convert allheat
completely into power. The limitations are quantified by the Carnot efficiency,related to a theoretical
cycle producing power from heat. When the heat is
supplied at a constant (high) temperature (Th), and
heat is releasedat a constant (low) temperature (TI),
the maximum power output is given by:
Power output = (1 - Th/Tl) x heat supply.
60
Equation 6
C + 2H2
"
CH4
Equation 7
Equations 3 and 4 are the main reactions of the reduction stage and require heat. As a result, the tem-
and hydrogen (H2 ) is fixed by the value of the water-gas equilibrium constant (Kwe).Kw,is given as:
Equation I
Equation 8
(CO) X (H120)
K = (
(C02) X (H2 )
oxide (CO) and water vapor (H 2 0) and the product of the concentration of carbon dioxide (GO2)
Equation3
then remainsunchanged.
Equation 5
position from a gasifier that has reached equilibrium at a given temperature. Table A4.1 presents
typical gas compositions obtained from commercialwood and charcoal downdraft gasifiersthat run
on low- to medium-moisture-content fuels (wood,
C + H2 + 42.3 kJ/mol - CO + H2 0
C + H2 0 + 122.6 kJ/mol
CO+ H2
C
61
-gywrBn.
TableA4.1:Compositionof GasFrom CommercialWood and CharcoalGasiflers
Component
Nitrogen
Carbon monoxide
Carbon dioxide
Hydrogen
Methane
Gas heating value (kJ/m3 )
Source:FAO(1986).
62
50-54
17-22
9-15
12-20
2-3
55-65
28-32
1-3
4-10
0-2
5,000-5,900
4,500-5,600
Annex5:Financial
Analysis
of I MWm
Systems
TableA5.1:SteamCycle(Appr.I NW, Power n at
um condense)
Unit of measure
Variant:powergeneration/vacuumcondensor
Boilerefficiency
Steam28 bar/saturated:H=
Condensor 0.2bar 60 C: H=
CondensateH=
Isentr.Enthalpydrop turbine (delta H)
Turbineisentrop.efficiency
Generatorefficiency
Electricityproduction
Heat releasecondensor
Fuel supply
Efficiencyelectricity
Efficiencyheat
Capacity1 MW.
kj/kg
kJ/kg
kJ/kg
kJ/kg
kJJkg
kJ/kg
kj/kg
0.9
2,800
2,050
251
750
0.55
0.95
392
2,157
2,832
0.14
0.76
Assumptions
Interest
Economiclifetime
%
a
8
15
$/ton
40
Biomassmoisturecontent
Ashcontent dry basis
LHVdaf biomass(MC=O)
ActualLHV
Labor
Number fullload operation hours
%
%
MJ/kg
MJ/kg
S/app
1/a
20
1
18.5
14.2
50,000
6,000
Investment
Investmentequipment
Totalplant cost/equipment
Investmenttotal plant
Operationaldata
Capacity
Efficiencyelectricityproduction
Efficiencyheat production
Heat utilization (percentof heat produced)
Efficiencybiomassfueledheat only boiler
Labor
Maintenance(percentof investmentequipment)
Electricityproduction
Usefulheat production
Fuel consumption
Omitted fuelconsumptionheat production
Fuel consumption/kWhe
'NV/MW,,
$1,000
$1,000
MWe
%
person*a
%
MWh,/a
MWhth/a
ton/a
ton/a
kg/kWh.
2,000
2
4,000
2,000
4,000
1
0.14
0
0
0.9
1
5
6,000
0
0
0
1.84
(table continues
on foL7owing
page)
63
Energyfrom Biomass
(TableA5.1 continued)
Unit of measure
Cost
Capital cost
Fuel cost
Omitted fuel cost heat
Labor
Maintenance
Note:H-specificenthalpysteam.
Source:Author.
64
$/a
$/kWh,
467,318
440,929
0
50,000
100,000
netto
0.08
0.07
0.00
0.01
0.02
0.18
EnergyfromBiomass
Capacity1 MWe
kJ/kg
kJ/kg
kJ/kg
kJ/kg
kJJkg
kJ/kg
kJ/kg
%
a
$/ton
%
%
MJ/kg
MJ/kg
$/a pp
I/a
INVIMWe
$1,000
$1,000
MWe
%
person*a
%
MWhlia
MWhth/a
ton/a
ton/a
kg/kWh,
0.9
2,800
2,240
251
560
0.57
0.95
303
2,246
2,832
0.11
0.79
8
15
40
20
1
18.5
14.2
50,000
6,000
1,900
2
3,800
2,456
4,911
0.77
0.11
0.79
75
0.9
1
5
4,643
25,789
11,023
7,284
2.37
(tablecontinuesonfollowingpage)
65
Energyfrom Biomass
(TableA5.2 continued)
Unit of measure
Cost
Capital cost
Fuel cost
Omitted fuel cost heat
Labor
Maintenance
Note:H-specific enthalpysteam.
Source:Author.
66
$/a
$/kWhe
443,978
440,929
291,356
50,000
95,000
netto
0.10
0.06
0.06
0.01
0.02
0.16
EnergyfromBiomass
TableA5.3: Gasifier/Engine
(Appr. I MW.; Powergeneratlon)
Unit of measure
Variant 1:Powergeneration
Gasifierhot gas efficiency
Gasifiercold gas efficiency
Engineefficiencyelectric
Engineefficiencyheat
Generatorefficiency
Overallelectricefficiency
Overallheat efficiency
Assumptions
Interest
Economiclifetime
Biomassfuel price
Biomassmoisture content
Ash contentdry basis
LHVdaf biomass(MC=0)
0.9
0.7
0.25
0.55
0.95
0.17
0.39
%
a
$/ton
%
%
MJ/kg
8
10
40
20
I
18.5
LHV actual
MJ/kg
14.2
Labor
Number fullload operation hours
$/a pp
1/a
50,000
6,000
Investment
Investmentequipment
Totalplant cost/equipment
Investmenttotal plant
INVIM%We
$1,000
$1,000
1,700
1.75
2,975
1,700
2,975
Operationaldata
Capacity
Efficiencyelectricityproduction
Efficiencyheat production
Heat utilization (percentof heat produced)
Efficiencybiomassfueledheat only boiler
Labor
Maintenance(percentof investmentequipment)
Electricityproduction
Usefulheat production
Fuelconsumption
Omitted fuel consumptionheat production
Fuel consumption/kWhe
Mwe
%
person*a
%
MWhe/a
MWhth/a
ton/a
ton/a
ton/MWh,
0.17
0.39
0
0.9
1
5
6,000
0
9,174
0
1.53
(tablecontinuesonfollowingpage)
67
Energyfrom Blomass
(TableA5.3 continued)
Unit of measure
Cost
Capital cost
Fuel cost
Omitted fuel cost heat
Labor
Maintenance
Note:H-specificenthalpysteam.
Source:Author.
68
$/kWhe
443,363
366,967
0
50,000
85,000
netto
0.07
0.06
0.00
0.01
0.01
0.16
EnergyfromBiomass
TableAS.4:Gasifier/Engine
(Appr. I MWe;CHP)
Unit of measure
Variant 2: CHP
Gasifier hot gas efficiency
Gasifier cold gas efficiency
Engine efficiency electric
Engine efficiency heat
Generator efficiency
Overall electric efficiency
Efficiency heat recovery gas cooling
Overall heat efficiency
Assumptions
Interest
Economic lifetime
Biomass fuel price
Biomass moisture content
Ash content dry basis
LHV daf biomass (MC=0)
LHV actual
Labor
Number full load operation hours
Investment
Investment equipment
Total plant cost/equipment
Investment total plant
Operational data
Capacity
Efficiency electricity production
Efficiency heat production
Heat utilization (percent of heat produced)
Efficiencybiomass fueled heat only boiler
Labor
Maintenance (percent of investment equipment)
Electricity production
Useful heat production
Fuel consumption
Omitted fuel consumption heat production
Fuel consumption/kWhe
0.90
0.70
0.25
0.55
0.95
0.17
0.80
0.55
%
a
$/ton
%
%
MJ/kg
MJ/kg
$/a pp
1/a
8
10
40
20
1
18.5
14.2
50,000
6,000
INV/MWe
$1,000
$1,000
Mwe
%
person*a
%
MWh/a
PWhth,/a
ton/a
tonla
ton/MWhe
1,700
1.75
2,975
1,700
2,975
1
0.17
0.55
75
0.9
1
5
6,000
14,752
9,174
4,167
1.53
(table continues onfollowingpage)
69
(TableA5.4 continued)
Unit of measure
Cost
Capital cost
Fuel cost
Omitted fuel cost heat
Labor
Maintenance
Note:H-specificenthalpysteam.
Source:Author.
70
$/kWhe
443,363
366,967
166,664
50,000
85,000
netto
0.07
0.06
0.03
0.01
0.01
0.13
Annex6: Financial
Analysisof 5 MWe,
Systems
TableA6. 1:Steam Cycle(Appr. 5 MWe; Powergenertion/vacuumcondenser)
Unit of measure
Variant:power generation/vacuumcondensor
Boilerefficiency
Steam60 bar/530 C: H=
Condensor0.2 bar 60 C: H=
CondensateH=
Isentr.Enthalpydrop turbine (deltaH)
Turbineisentrop.efficiency
Generatorefficiency
Electricityproduction
Heat releasecondensor
Fuel supply
Efficiencyelectricity
Efficiencyheat
Assumptions
Interest
Economiclifetime
Biomassfuelprice
Biomassmoisturecontent
Ashcontent dry basis
LHV daf biomass(MC=o)
ActualLHV
Labor
Number full load operation hours
Investment
Investmentequipment
Totalplant cost/equipment
Investmenttotal plant
Operationaldata
Capacity
Efficiencyelectricityproduction
Efficiencyheat production
Heat utilization(percentof heat produced)
Efficiencybiomassfueled heat onlyboiler
Labor
Maintenance(percentof investmentequipment)
Electricityproduction
Usefulheat production
Fuel consumption
Omittedfuel consumptionheat production
FuelconsumptionlkWhe
Capacity5 MWe
kJ/kg
kj/kg
kJ/kg
kJ/kg
kJe/kg
kJ/kg
kJ/kg
0.9
3,500
2,225
251
1.275
0.82
0.95
993
2,256
3,610
0.28
0.62
a
$/ton
%
%
MJ/kg
$/a pp
l/a
15
40
20
1
14.2
50,000
6,000
INVIMWe
$1,000
$1,000
MWe
%
person*a
%
MWhe/a
MWhth/a
ton/a
ton/a
kg/kWh,
6,500
2
13,000
1,300
2,600
5
0.28
0
0
0.9
3
5
30,000
0
27,718
0
0.92
(tablecontinuesonfollowingpage)
71
EomBbm
(TableA6.1 continued)
Unit of measure
Cost
Capitalcost
Fuel cost
Omitted fuelcost heat
Labor
Maintenance
Note:H-specificenthalpysteam.
Source.Author.
72
$/a
1,518,784
1,108,712
0
150,000
325,000
netto
$ikWhe
0.05
0.04
0.00
0.01
0.01
0.10
rfrom
kuma
Investment
Investment equipment
Total plant cost/equipment
Investment total plant
Operational data
Capacity
Efficiency electricity production
Efficiency heat production
Heat utilization (percent of heat produced)
Efficiency biomass fueled heat only boiler
Labor
Maintenance (percent of investment equipment)
Electricity production
Useful heat production
Fuel consumption
Omitted fuel consumption heat production
Fuel consumption/kWhe
kJelkg
kj/kg
kJ/kg
%
a
$/ton
%
%
MJlkg
MJ/kg
$/a pp
I/a
0.9
3,500
2,525
251
975
0.84
0.95
778
2,471
3,610
0.22
0.68
8
15
40
20
1
18.5
14.2
50,000
6,000
INVIMWe
$1,000
$1,000
MWe
%
person*a
%
MWhe/a
MWhth/a
ton/a
ton/a
kg/kWhe
6,001
2
12,001
1,532
3,064
3.9
0.22
0.68
75
0.9
3
5
23,501
55,976
27,718
15,810
1.18
(tablecontinuesonfollowingpage)
73
-nwymrmB
(TableA6.2 continued)
Unit of measure
Cost
Capitalcost
Fuel cost
Omitted fuel costheat
Labor
Maintenance
Note:H-specific enthalpysteam.
Source:
Author.
74
$/a
1,402,075
1,108,712
632,403
150,000
300,000
netto
$/kWhe
0.06
0.05
0.03
0.01
0.01
0.10
-omBbn_
TableA6.3: Gasifierand STEG(Appr. 5 MW,, PowergenerationSTEG)
Unit of measure
Variant1: STEGPowergenerationSTEG
Gasifierhot gas efficiency
Gasifiercoldgas efficiency
Engineefficiencyelectric
Engineefficiencyheat
Generatorefficiency
Overallelectricefficiency
Overallheat efficiency
Assumptions
Interest
Economiclifetime
Biomassfuelprice
Biomassmoisturecontent
Ashcontent dry basis
LHV daf biomass(MC=o)
LHV actual
Labor
Numberfull load operation hours
Investment
Investmentequipment
Totalplant cost/equipment
Investmenttotal plant
Operationaldata
Capacity
Efficiencyelectricityproduction
Efficiencyheat production
Heat utilization (percentof heat produced)
Efficiencybiomassfueledheat only boiler
Labor
Maintenance(percentof investmentequipment)
Electricityproduction
Usefulheat production
Fuelconsumption
Omittedfuel consumptionheat production
Fuel consumption/kWhe
Capacity5 MWe
0.9
0.07
0.35
%
a
$/ton
%
%
MJ/kg
MJ/kg
$/a pp
1/a
INVWMWe
$1,000
$1,000
8
15
40
20
1
18.5
14.2
50,000
6,000
7,000
2
14,000
MW.
5
0.35
0
0.9
3
5
30,000
0
21,789
0
0.73
person*a
%
MWhJa
MWhth/a
ton/a
ton/a
ton/MWhe
1,400
2,800
(tabk continuesonfollowingpage)
75
EwyronWwim
(TableA6.3 continued)
Unit of measure
Cost
Capital cost
Fuel cost
Omitted fuel cost heat
Labor
Maintenance
Note: H-specificenthalpysteam.
Source:Author.
76
$
1,635,614
871,548
0
150,000
350,000
netto
$/kWhe
0.05
0.03
0.00
0.01
0.01
0.10
omBWmass
0.28
0.58
%
a
$/ton
%
%
MJ/kg
MJ/kg
$/a pp
1/a
INVIMWe
$1,000
$1,000
MWe
%
personf*a
%
MWh,/a
MWhth/a
ton/a
ton/a
tonl/Mwhe
8
15
40
20
1
18.5
14.2
50,000
6,000
6,700
2
13,400
1,675
3,350
4
0.28
0.58
75
0.9
3
5
24,000
37,286
21,789
10,531
0.91
(tablecontinuesonfollowingpage)
77
from BWn
(TableA6.4 continued)
Unit of measure
Cost
Capital cost
Fuel cost
Omitted fuel cost heat
Labor
Maintenance
Note: H-specificenthalpysteam.
Source:Author.
78
$
1,565,516
817,548
421,248
150,000
335,000
netto
$/kWhe
0.07
0.04
0.02
0.01
0.01
0.10
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