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2008 Local Olympiad Exam
2008 Local Olympiad Exam
NATIONAL
CHEMISTRY OLYMPIAD
LOCAL SECTION EXAM
Prepared by the American Chemical Society Olympiad Examinations Task Force
Not valid for use as an ACS Olympiad Local Section Exam after March 29, 2008. STOCK CODE OL08
Distributed by the ACS DivCHED Examinations Institute, University of Wisconsin - Milwaukee, Milwaukee, WI.
All rights reserved. Printed in U.S.A.
ampere
atmosphere
atomic mass unit
atomic molar mass
Avogadro constant
Celsius temperature
centi prefix
coulomb
electromotive force
energy of activation
enthalpy
entropy
equilibrium constant
CONSTANTS
m
M
M
mol
h
P
k
Rf
s
T
t
V
R = 8.314 Jmol1K1
R = 0.0821 Latmmol1K1
1 F = 96,500 Cmol1
1 F = 96,500 JV1mol1
NA = 6.022 1023 mol1
h = 6.626 1034 Js
c = 2.998 108 ms1
0 C = 273.15 K
1 atm = 760 mmHg
EQUATIONS
E = Eo !
1
1A
1
H
RT
ln Q
nF
"k % E " 1 1 %
ln$$ 2 '' = a $$ ( ''
# k1 & R # T1 T2 &
18
8A
2
He
3
Li
2
2A
4
Be
13
3A
5
B
14
4A
6
C
15
5A
7
N
16
6A
8
O
17
7A
9
F
6.941
9.012
10.81
12.01
14.01
16.00
19.00
20.18
11
Na
12
Mg
13
Al
14
Si
15
P
16
S
17
Cl
18
Ar
22.99
24.31
26.98
28.09
30.97
32.07
35.45
39.95
19
K
31
Ga
32
Ge
33
As
34
Se
35
Br
36
Kr
1.008
4.003
10
Ne
20
Ca
3
3B
21
Sc
4
4B
22
Ti
5
5B
23
V
6
6B
24
Cr
7
7B
25
Mn
8
8B
26
Fe
9
8B
27
Co
10
8B
28
Ni
11
1B
29
Cu
12
2B
30
Zn
39.10
40.08
44.96
47.88
50.94
52.00
54.94
55.85
58.93
58.69
63.55
65.39
69.72
72.61
74.92
78.96
79.90
83.80
37
Rb
38
Sr
39
Y
40
Zr
41
Nb
42
Mo
43
Tc
44
Ru
45
Rh
46
Pd
47
Ag
48
Cd
49
In
50
Sn
51
Sb
52
Te
53
I
54
Xe
85.47
87.62
88.91
91.22
92.91
95.94
(98)
101.1
102.9
106.4
107.9
112.4
114.8
118.7
121.8
127.6
126.9
131.3
55
Cs
56
Ba
57
La
72
Hf
73
Ta
74
W
75
Re
76
Os
77
Ir
78
Pt
79
Au
80
Hg
81
Tl
82
Pb
83
Bi
84
Po
85
At
86
Rn
132.9
137.3
138.9
178.5
180.9
183.8
186.2
190.2
192.2
195.1
197.0
200.6
204.4
207.2
209.0
(209)
(210)
(222)
87
Fr
88
Ra
89
Ac
104
Rf
105
Db
106
Sg
107
Bh
108
Hs
109
Mt
110
Ds
111
Rg
112
Uub
114
Uuq
116
Uuh
118
Uuo
(223)
(226)
(227)
(261)
(262)
(263)
(262)
(265)
(266)
(269)
(272)
(277)
(2??)
(2??)
(2??)
Page 2
58
Ce
59
Pr
60
Nd
61
Pm
62
Sm
63
Eu
64
Gd
65
Tb
66
Dy
67
Ho
68
Er
69
Tm
70
Yb
71
Lu
140.1
140.9
144.2
(145)
150.4
152.0
157.3
158.9
162.5
164.9
167.3
168.9
173.0
175.0
90
Th
91
Pa
92
U
93
Np
94
Pu
95
Am
96
Cm
97
Bk
98
Cf
99
Es
100
Fm
101
Md
102
No
103
Lr
232.0
231.0
238.0
(237)
(244)
(243)
(247)
(247)
(251)
(252)
(257)
(258)
(259)
(262)
Not for use as a USNCO Local Section Exam after March 29, 2008
DIRECTIONS
When you have selected your answer to each question, blacken the corresponding space on the answer sheet using a soft, #2
pencil. Make a heavy, full mark, but no stray marks. If you decide to change an answer, erase the unwanted mark very carefully.
There is only one correct answer to each question. Any questions for which more than one response has been blackened will not
be counted.
Your score is based solely on the number of questions you answer correctly. It is to your advantage to answer every question.
(B) krypton
(C) phosphorus
(D) xenon
(A) Keep the eye level with the bottom of the meniscus
and record that reading.
(B) m . l . w
d
m
d. l . w
(C) d . l .w
m
(B) Keep the eye level with the top of the meniscus and
record that reading.
(C) Look down at the meniscus at an angle to obtain the
average reading directly.
(D) Read both the bottom and top of the meniscus and
average those readings.
7. A 1.0 gram sample of which substance contains the
largest number of molecules?
(A) COCl2
(B) CS2
(C) CH3Cl
(D) C2H2F2
(D) d . m
l.w
(A) 1.1
(B) 2.2
(C) 3.3
(D) 13
(A) 1.50
(B) 2.00
(C) 2.50
(D) 3.00
(A) 0.0175
(B) 0.233
(C) 0.275
(D) 0.550
(A) 43.8%
(B) 58.3%
(C) 66.7%
(D) 87.5%
(B) Ge
(C) P
(D) Si
Not for use as a USNCO Local Section Exam after March 29, 2008
Page 3
(C) incompressibility.
(B) 12.1 g
(C) 24.0 g
(D) 95.9 g
(B) 1.08/1
(C) 0.923/1
Hf / kJmol1
CuO 156.1
Cu2O 170.7
(B) 14.6
(C) 14.6
(D) 141.5
(D) 0.5/1
(B) metallic
(B) 38.3 kJ
(C) 28.8 kJ
(D) 25.7 kJ
Page 4
Not for use as a USNCO Local Section Exam after March 29, 2008
26. For the reaction, C3H8 + 5O2 r 3CO2 + 4H2O, how does
the rate of disappearance of O2 compare to the rate of
production of CO2? The rate of disappearance of O2 is
(B) one
(C) two
(D) three
(B) 0.50 M
(C) 1.0 M
(D) 1.4 M
(D) L2.mol2.min1
(B) H2SO4
(C) OH
(D) SO42
(B) 0 to +2
(C) +2 to +4
Not for use as a USNCO Local Section Exam after March 29, 2008
Page 5
(B) II only
(B) 3
(B) 0.61
(C) 4
(D) 5
Ered / V
Pb2+ + 2e r Pb 0.13
Cr3+ + 3e r Cr 0.74
(C) 0.61
(D) 1.09
(B) microwave
(C) ultraviolet
(D) X-ray
Page 6
(B) 3
(A) 1s22s22p63s23p63d7
(B) 1s22s22p63s23p63d9
(C) 1s22s22p63s23p63d84s1
(D) 1s22s22p63s23p63d74s2
46. Which equation represents the first ionization of
calcium?
(A) Ca(s) r Ca+(g) + e
(B) Ca(g) r Ca+(g) + e
(C) Ca+(g) r Ca2+(g) + e
(D) Ca2+(g) + e r Ca+(g)
47. Electronegativities change both down a group and across
a period. In general these changes are to:
down a group
(C) 1
(D) 0
(A) increase
increase
(B) increase
decrease
(C) decrease
increase
(D) decrease
decrease
48. When the atoms: Ba, Cs, Mg, Na are arranged in order of
increasing size, what is the correct order?
(A) Cs < Na < Mg < Ba
(A) 7
(B) 30
(C) 32
(D) 34
(B) SO2
(C) BrO2
(D) NO2
(B) OF4
(C) SF2
(D) SF4
Not for use as a USNCO Local Section Exam after March 29, 2008
(C) T-shaped
(D) tetrahedral
(B) 12
(C) 8
(D) 4
(B) esterification
(C) neutralization
(D) oxidation
(B) 3
(C) 4
(D) 5
(B) amides
(C) alcohols
(D) acids
(B) sp2
(C) sp3
(D) s2p2
(B)
(C)
(D)
END OF TEST
Not for use as a USNCO Local Section Exam after March 29, 2008
Page 7
Number
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
Answer
A
D
A
B
D
A
C
C
D
B
D
A
B
A
C
C
D
D
A
D
A
C
B
A
A
D
C
B
B
C
Number
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
Not for use as a USNCO Local Section Exam after March 29, 2008
Answer
A
D
D
B
B
A
C
A
B
D
B
A
D
C
D
B
C
B
C
A
B
C
C
B
A
D
B
C
B
A