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2009 Local Olympiad Exam
2009 Local Olympiad Exam
NATIONAL
CHEMISTRY OLYMPIAD
LOCAL SECTION EXAM
Prepared by the American Chemical Society Olympiad Examinations Task Force
Sherry Berman-Robinson, Consolidated HS, Orland Park, IL (retired) Preston Hays, Glenbrook South HS, Glenbrook, IL
Seth Brown, University of Notre Dame, South Bend, IN
Not valid for use as an ACS Olympiad Local Section Exam after March 31, 2009. STOCK CODE OL09
Distributed by the ACS DivCHED Examinations Institute, Iowa State University, Ames, IA.
All rights reserved. Printed in U.S.A.
amount of substance
ampere
atmosphere
atomic mass unit
atomic molar mass
Avogadro constant
Celsius temperature
centi prefix
coulomb
electromotive force
energy of activation
enthalpy
entropy
equilibrium constant
CONSTANTS
M
M
mol
h
P
k
Q
s
c
T
t
V
V
R = 8.314 Jmol1K1
R = 0.0821 Latmmol1K1
1 F = 96,500 Cmol1
1 F = 96,500 JV1mol1
NA = 6.022 1023 mol1
h = 6.626 1034 Js
c = 2.998 108 ms1
0 C = 273.15 K
EQUATIONS
E = Eo !
1
1A
1
H
RT
ln Q
nF
"k % E " 1 1 %
ln$$ 2 '' = a $$ ( ''
# k1 & R # T1 T2 &
18
8A
2
He
3
Li
2
2A
4
Be
13
3A
5
B
14
4A
6
C
15
5A
7
N
16
6A
8
O
17
7A
9
F
6.941
9.012
10.81
12.01
14.01
16.00
19.00
20.18
11
Na
12
Mg
13
Al
14
Si
15
P
16
S
17
Cl
18
Ar
22.99
24.31
26.98
28.09
30.97
32.07
35.45
39.95
19
K
31
Ga
32
Ge
33
As
34
Se
35
Br
36
Kr
1.008
4.003
10
Ne
20
Ca
3
3B
21
Sc
4
4B
22
Ti
5
5B
23
V
6
6B
24
Cr
7
7B
25
Mn
8
8B
26
Fe
9
8B
27
Co
10
8B
28
Ni
11
1B
29
Cu
12
2B
30
Zn
39.10
40.08
44.96
47.88
50.94
52.00
54.94
55.85
58.93
58.69
63.55
65.39
69.72
72.61
74.92
78.96
79.90
83.80
37
Rb
38
Sr
39
Y
40
Zr
41
Nb
42
Mo
43
Tc
44
Ru
45
Rh
46
Pd
47
Ag
48
Cd
49
In
50
Sn
51
Sb
52
Te
53
I
54
Xe
85.47
87.62
88.91
91.22
92.91
95.94
(98)
101.1
102.9
106.4
107.9
112.4
114.8
118.7
121.8
127.6
126.9
131.3
55
Cs
56
Ba
57
La
72
Hf
73
Ta
74
W
75
Re
76
Os
77
Ir
78
Pt
79
Au
80
Hg
81
Tl
82
Pb
83
Bi
84
Po
85
At
86
Rn
132.9
137.3
138.9
178.5
180.9
183.8
186.2
190.2
192.2
195.1
197.0
200.6
204.4
207.2
209.0
(209)
(210)
(222)
87
Fr
88
Ra
89
Ac
104
Rf
105
Db
106
Sg
107
Bh
108
Hs
109
Mt
110
Ds
111
Rg
112
Uub
114
Uuq
(223)
(226)
(227)
(261)
(262)
(263)
(262)
(265)
(266)
(269)
(272)
(277)
(2??)
!
58
Ce
Page 2
59
Pr
60
Nd
61
Pm
62
Sm
63
Eu
64
Gd
65
Tb
66
Dy
67
Ho
68
Er
69
Tm
70
Yb
71
Lu
140.1
140.9
144.2
(145)
150.4
152.0
157.3
158.9
162.5
164.9
167.3
168.9
173.0
175.0
90
Th
91
Pa
92
U
93
Np
94
Pu
95
Am
96
Cm
97
Bk
98
Cf
99
Es
100
Fm
101
Md
102
No
103
Lr
232.0
231.0
238.0
(237)
(244)
(243)
(247)
(247)
(251)
(252)
(257)
(258)
(259)
(262)
Not valid for use as a USNCO Local Section Exam after March 31, 2009
DIRECTIONS
When you have selected your answer to each question, blacken the corresponding space on the answer sheet using a soft, #2
pencil. Make a heavy, full mark, but no stray marks. If you decide to change an answer, erase the unwanted mark very carefully.
There is only one correct answer to each question. Any questions for which more than one response has been blackened will not
be counted.
Your score is based solely on the number of questions you answer correctly. It is to your advantage to answer every question.
1. Which salt is colorless?
(A) KMnO4
(B) BaSO4
(C) Na2CrO4
(D) CoCl2
(B) CuBr2
(C) Na2CO3
(D) C2H5OH
(B) chlorine
(C) bromine
(D) iodine
(B) chromatography
(C) colorimetry
(D) gravimetry
(C) 105
(D) 107
(B) 27.83%
(C) 29.16%
(D) 33.34%
(B) 0.25
(C) 0.40
(D) 0.80
(B) 103
(A) 11.2%
(B) 66.6%
(C) 79.9%
(D) 88.8%
(B) 0.127 M
(C) 0.190 M
(D) 0.634 M
(B) 75.0
(C) 100.
(D) 150.
(A)
P1P2
V1
(B)
P1V1
P2
(C)
P2V1
P1
(D)
P2
P1V1
!
!
Not valid for use as a USNCO Local Section Exam after March 31, 2009
!
!
Page 3
(D) n CH 4 = n CO 2 = n N 2
(A) ionic
(C) molecular
(B) metallic
1
2 N 2 (g) + 2 O 2 (g)
N 2O(g) + 1 2 O 2 (g)
2NO(g) "
Which relationship is correct?
!
!
#H1o
#H 2o
(A) H1 = H2
(B) Hf for NO(g) = H1
(C) Hf for N2O(g) = H2
(D) Hf for N2O(g) = H2 2H1
(B) 221
(C) 221
(D) 556
(A) point A
(B) point B
(C) point C
(D) point D
(B) II only
(B) 0.16
(C) 0.55
(A)
(B)
(C)
(D)
(D) 5.0
Page 4
(B) molL1
(C) molLs1
(D) Lmol1s1
Not valid for use as a USNCO Local Section Exam after March 31, 2009
(C) 1.4106 M
(D) 2.01012 M
(B) 45 minutes
(C) 60 minutes
(D) 80 minutes
2[CO]
[CO 2 ]
(B)
(D)
K eq =
K eq =
Ksp = 2103
(B) TlBr
Ksp = 4106
(C) MnCO3
Ksp = 21011
(D) Zn(OH)2
Ksp = 31017
(C) NaBr
(D) HIO4
2[C][CO]
[CO 2 ]
[C][CO]
[CO 2 ]
(A) AgC2H3O2
(A) I2
(B) 5.0103 M
29. The value of the rate constant for a gas phase reaction
can be changed by increasing the
[CO]
[CO 2 ]
(A) 7.1102 M
K eq =
(A) initial pH
(C)
K eq =
(A)
(A) 1 / 1
(B) 2 / 1
(C) 1 / 2
(D) 5 / 2
Not valid for use as a USNCO Local Section Exam after March 31, 2009
Page 5
(B) 0.93 V
(C) 0.67V
(D) 0.54 V
(B) Mg
(C) Al
(D) Ba
(B) n = 5 r n = 3
(C) n = 6 r n = 5
(D) n = 3 r n = 6
(C) 1s 2s 2p 3s
(B) 1s22s22p2
1
(D) 1s 2s 2p
(B) n = 3, l = 2
(C) n = 4, l = l
(D) n = 4, l = 2
(B) BrCl
(C) OCl2
(D) SCl2
(B) C2H4
(C) C3H8
(D) C6H12
(B) 28
(C) 30
(D) 32
(B) CO2
(C) SiO2
(D) P2O5
(A) Na+, K+
(B) Cl, Cl
(C) SF5
(B) SF4
C2
(A) sp2
sp2
(B) sp2
sp3
(C) sp3
sp2
(D) sp3
sp3
(D) XeF4
O
(B) ester.
(C) ether.
(D) ketone.
Page 6
(A) ClF5
3+
(C) Cr, Cr , Cr
(A) CO
2+
(A) 1s22s22p1
(A) N, O, F
(A) HCl
(A) ase
(B) ate
(C) one
(D) ose
(B) 1-hexene
(C) 1-hexyne
(D) benzene
Not valid for use as a USNCO Local Section Exam after March 31, 2009
(B) aldehyde
(C) amide
(D) amine
(A) Ha
Ha
(B) Hb
(C) Hc
O
O
c
(D) Hd
END OF TEST
Not valid for use as a USNCO Local Section Exam after March 31, 2009
Page 7
Number
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
Answer
B
D
C
A
B
A
B
C
C
D
B
A
B
D
A
A
D
C
C
B
D
D
C
A
C
A
B
D
C
A
Number
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
Not for use as a USNCO Local Section Exam after March 31, 2009
Answer
C
C
A
B
D
C
C
D
A
B
A
D
B
A
C
B
D
D
C
A
D
C
B
C
D
D
A
B
D
A