KIMIA ANALITIK 1

Kelompok 9
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Atma Istanami
Elsa Zulha
Intan Mailani
Radius Uly Artha
Sukamto
Wiwin Esti Sarwita

Soal no 20
The earliest determinations of elemental atomic
weights were accomplished gravimetrically. In
determining the atomic weight of manganese, a
carefully purified sample of MnBr2 weighing
7.16539 g was dissolved and the Br
precipitated as AgBr, yielding 12.53112 g.
What is the atomic weight for Mn if the atomic
weights for Ag and Br are taken to be 107.868
and 79.904, respectively?

Diketahui :
Massa MnBr2 = 7.16539 gram
Massa AgBr = 12.53112 gram
Ar Ag
= 107.868
Ar Br
= 79.904
Maka Mr dari AgBr = 107.868 + 79.904
= 187.772 gram/mol

PENYELESAIAN

Reaksi :
MnBr2+2AgNO3

2AgBr + Mn(NO3)2

7,16539 gram
12,53112 gram
1 mol MnBr2 = 2 mol AgBr
Mol AgBr =
= 0,06673582 mol
Jadi Mol MnBr2 = x mol AgBr
= x 0,06673582 mol
= 0, 0333679154 mol

Mol MnBr2 = 0.033367915 mol

Setelah diketahui mol MnBr2 maka
dapat di cari Mr dari MnBr2 :
Mr =

=
= 214,7389

gram/mol

Setelah Mr dari MnBr2 diketahui maka berat

atom Mn dapat dihitung :
MnBr2
= 214,7389 gram/mol
Mn + 2(Ar Br)
= 214,7389 gram/mol
Mn + 2(79,904) = 214,7389 gram/mol
Mn = 214,7389 -159,814 gram/mol
Mn = 54,92 gram/mol
Jadi nilai Ar dari Mn adalah 54,92 gram/mol

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