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Chapter 1: Some Basic Concepts of Atomic Structure & Periodicity Properties
Is 28 node
+ node
ls 2s
‘The shapes of the orbitals can be represented quite accurately with the help of boundary surface
diagram. The boundary surface diagram for's orbitals are spherical in shape. The size of orbital how-
ever inereases with increase in number of shell. The boundary surface diagram ofthe three 2p orbitals is
not spherical. Each 'p' orbital consists of two lobes which are separated bya region of zero probability
(node),
In three'p orbitals lobes lie on p, p, & p, axis respectively
y y y ’
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w », x, ,
um bel shape
Shape fd orbitals (double dumbel-
eyo, y y y
ea say dy 4 4
Out oF ived orbitals, only sod orbitals 4.2 & 4,2_,2 have theirlobes on the axis, rest all orbitals
have their lobes in betwoen the axis,
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Fle: EdveorerescurcesisounloadedDatacortonven’316010PSYpag 007 tl