Professional Documents
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Key Steps
1. Selection and proportioning of raw materials
2. Grinding and blending of raw materials
3. Clinkering
4. Grinding of clinker
5. Addition of gypsum
Raw Materials
Portland
cement is:
45-60% C3S
15-30% C2S
6-12% C3A
6-8% C4AF
Calcium
Iron
Silica
Alumina
Sulfate
Alkali waste
Aragonite
Calcite
Cement-kiln
dust
Cement rock
Chalk
Clay
Fullers earth
Limestone
Marble
Marl
Seashells
Shale
Slag
Blast-furnace
flue dust
Clay
Iron ore
Mill scale
Ore washings
Pyrite cinders
Shale
Calcium silicate
Cement rock
Clay
Fly ash
Fullers earth
Loess
Marl
Ore washings
Quartzite
Rice-hull ash
Sand
Sandstone
Shale
Slag
Traprock
Aluminum-ore
refuse
Bauxite
Cement rock
Clay
Copper slag
Fly ash
Fullers earth
Granodiorite
Limestone
Loess
Ore washings
Shale
Slag
Staurolite
Anhydrite
Calcium
sulfate
Gypsum
Raw Materials
Raw Materials
Raw Materials
Raw Materials
~5
~3/4
The more work done by crushing, the less work necessary during
further milling (energy savings)
powder (<90um)
Grinding mill
Sintering or Clinkering
1-4% inclined rotary kiln, 1-4 rev./min.
Wet process kilns can be up to 8m in diameter and as long as 230 m.
Typical dimensions are 50-100m long, and 3-10m diam.
Clinkering: Reactions
Clinkering: Reactions
Clinkering: Reactions
Clinkering: Reactions
Clinkering: Reactions
Dry Process
Grinding of Clinker
Upon exit from the kiln, the clinker, which is black and glistening, is
cooled and then interground with gypsum.
The rate of cooling affects the degree of crystallization of the material.
Modern cement plants rapidly cool the clinker to retain as much
amorphous material as possible.
Kiln
Grinding of Clinker
Red - C3S
Aqua - C2S
Green - C3A
Yellow - C4AF
Pale green - gypsum
White - free lime (CaO)
Dark blue (purple) - K2SO4
Light magenta- periclase
(magnesium containing
phase).
Image is 256 m x 200 m.
Two-dimensional processed SEM/X-ray image for cement 133 issued by the CCRL
(NIST) in June of 1999.
Addition of Gypsum
~ 5%Gypsum (CaSO42H2O) is added to prevent flash set of
cement
Slows the otherwise very fast reaction of the C3A phase
Interground with clinker in a ball mill (finish mill)
Clinker
Cement
Ball Mill
Gypsum
Question
Now that we have an understanding of how
cement is produced commercially, how might we
make it in the lab? Why would we want to do so?