NGUYN ANH PHONG

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CHNH THC

THI TH QUC GIA LN 5 NM 2016

MN : HA HC
Ngy thi : 01/01/2016
thi gm 50 cu trc nghim

Cho bit nguyn t khi ca cc nguyn t (theo vC):

H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52;
Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Ba = 137.
H v tn th sinh:
Cu 1: Kh Cl2 c mu
A. Vng lc
B. Lc nht
C. en tm
D. nu
Cu 2: Phenol khng phn ng vi cht no sau y?
A. NaOH.
B. Br2.
C. NaHCO3.
D. Na.
Cu 3: Thnh phn ho hc chnh ca qung boxit l
A. FeCO3.
B. Al2O3.2H2O.
C. Fe3O4.nH2O.
D. AlF3.3NaF.
Cu 4: Axit fomic c cng thc l:
A. CH3COOH
B. HCHO
C. HCOOH
D. HOOC
Cu 5: Kim loi st khng tan trong dung dch no sau y?
A. FeCl3.
B. H2SO4 long, ngui.
C. AgNO3.
D. HNO3 c, ngui.
Cu 6: Ancol v amin no sau y cng bc?
A. (CH3)2CHOH v (CH3)2CHNH2.
B. (C2H5)2NH v C2H5CH(OH)CH3.
C. (C2H5)2NH v C2H5CH2OH.
D. (CH3)3COH v (CH3)3CNH2.
Cu 7: iu kin thng, kim loi no sau y khng phn ng vi nc?
A. Li.
B. K.
C. Sr.
D. Be.
Cu 8: Cho anehit acrylic (CH2=CH-CHO) phn ng hon ton vi H2 (d, xc tc Ni, to) thu c
A. CH3CH2CH2OH.
B. CH3CH2CHO.
C. CH3CH2COOH.
D. CH2=CH-COOH.
Cu 9: Cho 0,78 gam kim loi M ho tr II phn ng ht vi dung dch H2SO4 long, d th thu c
268,8 cm3 kh khng mu (ktc). Kim loi M l
A. Ca.
B. Mg.
C. Pb.
D. Zn.
Cu 10: Cho cc cht HCl (X); C2H5OH (Y); CH3COOH (Z); C6H5OH (phenol) (T). Dy gm cc cht
c sp xp theo chiu tnh axit tng dn l:
A. (Y), (Z), (T), (X).
B. (X), (Z), (T), (Y).
C. (Y), (T), (Z), (X).
D. (T), (Y), (Z), (X).
Cu 11: Trong cng nghip, amoniac c iu ch t nit v hiro bng phng php tng hp theo
phng trnh ho hc sau: N2(k) + 3H2(k) 2NH3(k)
H <0
cn bng ho hc trn chuyn dch theo chiu thun ta phi
A. Gim nhit , tng p sut
B. Tng nhit , gim p sut
C. Gim nhit , gim p sut
D. Tng nhit , tng p sut
Cu 12: Phn ng no di y thuc loi phn ng oxi ha - kh?
A. 2NaOH + SO2 Na2SO3 + H2O.
B. AgNO3 + HCl AgCl + HNO3.
C. 2NO2 + 2NaOH NaNO3 + NaNO2 + H2O. D. Ca(OH)2 + 2CO2 Ca(HCO3)2.
Cu 13: Kim loi c nhit nng chy thp nht l
Ra : Nguyn Anh Phong N.A.P

A. Vng
B. vonfram
C. Nhm
D. Thu ngn
Cu 14: Cho hn hp X gm 0,02 mol C2H2 v 0,03 mol H2 i qua bt Ni, nung nng. Dn sn phm t
t qua dung dch Br2 d thy c 0,02 mol hn hp kh Y i ra khi bnh. T khi hi ca Y i vi H 2
bng 4,5. Khi lng bnh brom tng l
A. 0,40g
B. 0,58g
C. 0,62g
D. 0,76g
Cu 15: Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH d, sau khi phn ng kt thc
th lng NaOH phn ng l 12 gam v tng sn phm hu c thu c l 29,7 gam. S ng phn cu
to ca X tho mn cc tnh cht trn l
A. 2.
B. 4.
C. 5.
D. 6.
Cu 16: un nng 7,2 gam CH3COOH vi 6,9 gam C2H5OH (xc tc H2SO4) th thu c 7,04 gam este.
Hiu sut ca phn ng este ho l:
A. 66,67%.
B. 50,0%.
C. 53,33%.
D. 60,0%.
Cu 17: Cho 0,78 gam kim loi M ho tr II phn ng ht vi dung dch H2SO4 long, d th thu c
268,8 cm3 kh khng mu (ktc). Kim loi M l
A. Ca.
B. Mg.
C. Pb.
D. Zn.
Cu 18: Dn lng kh CO d i qua ng s ng m gam oxit st t nung nng. Sau khi phn ng xy ra
hon ton th thu c 5,88 gam st. Gi tr ca m l
A. 12,18.
B. 8,40.
C. 7,31.
D. 8,12.
Cu 19: Cng thc phn t ca triolein l
A. C54H104O6.
B. C57H104O6.
C. C57H110O6.
D. C54H110O6.
Cu 20: Trong cht no sau y nit va c tnh oxi ho, va c tnh kh ?
A. NH4Cl.
B. HNO3.
C. NH3.
D. NO2.
Cu 21: Cho 24,4g hn hp Na2CO3, K2CO3 tc dng va vi dung dch BaCl2. Sau phn ng thu
c 39,4g kt ta. Lc tch kt ta, c cn dung dch thu c m(g) mui clorua. Gi tr ca m l
A. 2,66g
B. 22,6g
C. 26,6g
D. 6,26g
Cu 22: Nguyn t nhm (Al) c 13 ht proton v 14 ht ntron. S khi ca Al l
A. 13
B. 27
C. 14
D. 1
Cu 23: Limonel l cht hu c c mi thm du c tch t tinh du chanh v c cng thc cu to
nh sau:

Phn t khi ca limonel l

A. 136.
B. 142.
C. 140.
D. 138.
Cu 24: Phng trnh in li vit ng l
A. NaCl Na2+ + Cl2B. Ca(OH)2 Ca2+ + 2OHC. C2H5OH C2H5+ + OHD. C A,B,C
Cu 25: Nhng chai, l bng thy tinh khng c ng trong dung dch axit no sau y?
A. HI.
B. HBr.
C. HF.
D. HCl.
Cu 26: Cht no sau y l thnh phn chnh trong phn bn supephotphat kp?
A. Ca(H2PO4)2 v CaSO4.
B. Ca3(PO4)2.
C. Ca(H2PO4)2.
D. CaHPO4.
Cu 27: Ha tan hon ton m gam Fe bng dung dch HCl va thu c dung dch Y. C cn dung
dch Y thu c 25,4 gam mui khan. Gi tr ca m l
A. 6,5.
B. 5,6.
C. 16,8.
D. 11,2.
Ra : Nguyn Anh Phong N.A.P

Cu 28: Cho 5,376 lt kh Cl2 (ktc) tc dng ht vi 44,8 gam Fe (nung nng) thu c hn hp rn
cha m gam mui clorua. Gi tr ca m l:
A. 30,48
B. 26,0
C. 61,84
D. 42,16
Cu 29: Trong phng th nghim, kh C c iu ch bng b dng c nh hnh v:

Kh C c th l dy cc kh no sau y?
A. H2, CO2, C2H6, Cl2.
B. N2O, CO, H2, H2S.
C. NO2, Cl2, CO2, SO2.
D. N2, CO2, SO2, NH3.
Cu 30: Cho cc pht biu sau:
(a) Phn ng nhit phn hon ton cc mui natrat sn phm lun thu c cht rn.
(b) C th tn ti dung dch cc cht: Fe(NO3)2, H2SO4, NaCl.
(c) SO3 ch c tnh oxi ha.
(d) Cc nguyn t thuc nhm IA gi l kim loi kim.
(e) Tro thc vt cha K2CO3 l mt loi phn bn.
S pht biu ng l:
A. 1
B. 2
C. 3
D. 4
Cu 31: Cho phng trnh phn ng sau:
CH2=CH CH = CH2 + KMnO4 + H2O CH2(OH) CH(OH) CH(OH) CH2(OH) + KOH + MnO2
Sau khi cn bng vi h s nguyn, nh nht th tng h s ca cc cht trong phng trnh l:
A. 32
B. 26
C. 24
D. 28
Cu 32: Cho cc pht biu sau:
(1). nhit thng, Cu(OH)2 c th tan trong dung dch glucoz.
(2). Anilin l mt baz, dung dch ca n lm giy qu tm chuyn thnh mu xanh.
(3). nhit thng, axit acrylic phn ng c vi dung dch brom.
(4). iu kin thch hp, glyxin phn ng c vi ancol etylic.
(5). iu kin thng, etilen phn ng vi dung dch AgNO3/NH3 cho kt ta mu vng.
S pht biu ng l
A. 3.
B. 4.
C. 5.
D. 2.
Cu 33: Cho cc pht biu sau:
(1). Sc kh H2S vo dung dch FeCl3 thu c kt ta en.
(2). Tch nc (xc tc H2SO4 c, 1700C ) cc ancol no, n chc, mch h, bc mt, s C ln
hn 1 u c th cho sn phm l anken.
(3). Vi cc cht NaNO3, Al, Zn, Al2O3, ZnO c 4 cht tan ht trong dung dch NaOH d.
(4). Trong cng nghip ngi ta sn xut H2S bng cch cho S tc dng vi H2.
S pht biu sai l:
A. 1
B. 2
C. 3
D. 4
Cu 34: Cho cc th nghim v nhn nh sau:
2Fe2 S
(1). Sc kh H2S vo Fe(NO3)3 c: S2 2Fe3
H 2O
(2). Cho NaOH vo dung dch CH3COOH c: OH H
Ra : Nguyn Anh Phong N.A.P

(3). Cho Al vo dung dch HNO3 (c, ngui) d thy Al tan ht.
(4). Phn ln photpho sn xut ra c dng sn xut axit photphoric.
S pht biu (nhn nh) ng l:
A. 1
B. 2
C. 3
D. 4
Cu 35: Hn hp X l hai amin no, n chc, mch h, hn km nhau 2 nguyn t C trong phn t. Cho
5,46 gam X tc dng hon ton vi dung dch HCl (d) thu c 10,57 gam hn hp mui. Phn trm
khi lng amin c khi lng phn t ln trong X l:
A. 56,78%
B. 34,22%
C. 43,22%
D. 65,78%
Cu 36: in phn 500 ml dung dch hn hp gm NaCl 0,1M v AlCl3 0,3M trong iu kin c mng
ngn, in cc tr ti khi anot xut hin 2 kh th ngng in phn. Sau in phn, lc ly kt ta ri
nung nhit cao n khi lng khng i c m gam cht rn. Gi tr ca m l
A. 7,65.
B. 5,10.
C.15,30.
D.10,20.
Cu 37: Ha tan hon ton m gam hn hp X gm Al, Al2O3 v K2O trong nc d thu c dung dch
Y v 3,36 lt kh (ktc). Nh t t dung dch HCl vo Y thy lng kt ta bin thin theo th (hnh v)
.
(mol)
Gi tr ca m l :
A. 18,24
n
B. 20,38
C. 17,94

0,15

D. 19,08
0,04

x 0,39

nHCl

(mol)

Cu 38: Cho m gam hn hp (X) gm cc ancol no mch h ng ng ca nhau chy hon ton trong
O2 th thu c 0,5 mol CO2 v 0,7 mol H2O. Cng m gam X tc dng vi Na d th thu c a gam
mui. Gi tr ca a c th t c n gi tr ln nht :
A. 20,4.
B. 23,4.
C. 26,2.
D. 22,6.
Cu 39: Cho m gam Fe tc dng ht vi H2SO4 (c/nng).Sau khi cc phn ng xy ra hon ton thu
10
c
m (gam) kh SO2 v dung dch X. Cho dung dch Ba(OH)2 d vo X thu c (m + 133,5 ) gam
7
kt ta. Gi tr ca m l :
A. 56,0
B. 28,0
C. 22,4
C. 16,8
Cu 40: t chy hon ton 1 mol andehit n chc, mch h X thu c 1 mol H2O v 3 mol CO2. Mt
khc, cho 7,56 gam X tc dng hon ton vi AgNO3/NH3 d thy c m gam kt ta xut hin. Gi tr
ca m l:
A. 25,92
B. 49,2
C. 43,8
D. 57,4
Cu 41: t chy hon ton 25,6 gam mt este thun chc X, mch h thu c 49,28 gam CO2 v 17,28
gam H2O. Thy phn hon ton 0,2 mol X bng mt lng va dung dch cha KOH th thu c 18,4
gam mt ancol v m gam mui. Gi tr ca m gn nht vi:
A. 26
B. 29
C. 32
D. 34
Cu 42: Cho hn hp X gm C3H7COOH, C4H8(NH2)2, HO-CH2- CH=CH-CH2OH. t chy hon ton
m gam hn hp X, sn phm chy hp th hon ton vo dung dch Ca(OH)2 thy to ra 30g kt ta v
dung dch Y. un nng dung dch Y thy xut hin kt ta. C cn dung dch Y ri nung cht rn thu
c n khi lng khng i thu c 8,4 gam cht rn. Gi tr ca m l
Ra : Nguyn Anh Phong N.A.P

A. 8,2
B. 5,4
C. 8,8
D. 13,2
Cu 43: Cho 5,52 gam hn hp X gm Cu, Fe3O4 tc dng vi dung dch HNO3 c, un nng v khuy
u. Sau khi cc phn ng xy ra hon ton, thu c 0,448 lt kh NO2 (sn phm kh duy nht, ktc),
dung dch Y v cn li 1,92 gam kim loi. C cn dung dch Y thu c m gam mui khan. Gi tr ca m
l:
A. 9,16
B. 8,72.
C. 10,14.
D. 10,68
Cu 44: Ha tan hon ton 10,1 gam hn hp X gm Mg, MgO, Al2O3 v Al trong dung dch cha HNO3
(va ) thu c dung dch Y v 1,12 lt (ktc) hn hp kh NO v N2O c t khi so vi H2 l 16,4. C
cn cn thn dung dch Y thu c 49,86 gam mui khan. Cho NaOH d vo Y thy c 0,83 mol NaOH
tham gia phn ng. Phn trm khi lng ca Oxi c trong X l:
A. 39,60%
B. 31,68%
C. 28,51%
D. 38,02%
Cu 45: Hn hp X gm hai peptit (c to bi Gly, Ala, Val), metylamin v axit glutamic. t chy
hon ton m gam X (trong s mol ca metylamin v axit glutamic bng nhau ) thu c 0,25 mol CO 2,
0,045mol N2 v 0,265 mol H2O. Gi tr ca m gn nht vi :
A. 7,42
B. 7,18.
C. 7,38.
D. 7,14
Cu 46: Ha tan hon ton 15,76 gam hn hp X gm Mg, MgO v Mg(NO3)3 bng dung dch hn hp
cha 1,14 mol HCl v x mol NaNO3. Sau phn ng thu c 0,04 mol N2 v dung dch Y ch cha 3
mui. Cho NaOH d vo Y th thy c a mol NaOH tham gia phn ng. Bit trong X phn trm khi
lng ca MgO l 20,30457%. Gi tr ca a l:
A. 1,0
B. 1,05
C. 1,10
D. 0,98
Cu 47: t chy hon ton m gam hn hp X gm CH3OH, C2H5OH, CH3CHO v C2H5CHO cn dng
va a mol O2, sinh ra b mol CO2. Nu cho m gam X trn phn ng vi lng d dung dch AgNO3
trong NH3 th khi kt thc cc phn ng thu c c mol Ag. Biu thc lin h no sau y ng:
A. c = 2(2b a)
B. c = 4(a + 0,5b)
C. c = 4(1,5b a)
D. Khng biu din c
Cu 48: Ha tan hon ton 42,4 gam hn hp gm CuS, FeS2, Cu2S trong dung dch HNO3 un nng.
Sau phn ng thu c 75,264 lt hn hp kh (ktc) gm NO2 v SO2 c tng khi lng l 158,88 gam.
Dung dch sau phn ng ch cha 86,56 gam cc mui trung ha. S mol HNO3 tham gia phn ng l:
A. 3,76
B. 3,24
C. 3,82
D. 3,42
Cu 49: X l hn hp cha mt axit n chc, mt ancol hai chc v mt este hai chc (u mch h).
Ngi ta cho X qua dung dch nc Br2 th khng thy nc Br2 b nht mu. t chy hon ton 0,09
mol X cn 10,752 lt kh O2 (ktc). Sau phn ng thy khi lng ca CO2 ln hn khi lng ca H2O l
10,84 gam. Mt khc, 0,09 mol X tc dng va ht vi 0,1 mol KOH. C cn dung dch sau phn ng thu
c m gam mui khan v mt ancol c 3 nguyn t C trong phn t. Gi tr ca m l:
A. 9,8
B. 8,6
C. 10,4
D. 12,6
Cu 50: Ha tan hon ton m gam hn hp X gm FeO, Fe3O4, FeS, FeS2, CuS v S trong dung dch
cha 0,25 mol H2SO4 c, nng (va ). Sau phn ng thu c dung dch Y v c 4,48 lt kh (ktc)
SO2 thot ra. Cho dung dch Ba(OH)2 d vo dung dch thu c 30,7 gam kt ta. Mt khc, ha tan ht
m gam X bng dung dch HNO3 c, nng thy thot ra hn hp cha a mol NO2 v 0,02 mol SO2. Dung
dch sau phn ng cha 15,56 gam hn hp mui. Gi tr ca a l:
A. 0,34
B. 0,36
C. 0,38
D. 0,32
..............................Ht..............................

Ra : Nguyn Anh Phong N.A.P