Introduction

SF6 is a combination of sulfur and fluorine its first synthesis was

realized in 1900 by French researchers of the Pharmaceutical
Faculty of Paris.
It was used for the first time as insulating material,
In the United States about 1935.
In 1953, the Americans discovered its properties for extinguishing
the
electric arc. This aptitude is quite remarkable.
Physical properties
It is about five times heavier than air, and has a density of 6.1 4kg / m3.
It is colorless, odorless and non-toxic.
Tests have been carried out replacing the nitrogen content of air by SF6 (the gaseous mixture
consisted of 79 % SF6 and 24 % oxygen): five mice were then immersed in this atmosphere for
24 hours, without feeling any ill effects.
It is a gas which the speed of sound propagation is about three times less than in air, at
atmospheric pressure. The interruption of the arc will therefore be less loud in SF6 than in air.
The dielectric strength of SF6 in on average 2.5 times that of air, and, by increasing pressure, it
can be seen that the dielectric strength also increases and than around 3.5 bar of relative
pressure, SF6 has the same strength as fresh oil.
The principal characteristics of the gas are as follows:
Molar mass
146.078
Critical temperature
45.55C
Critical pressure
37.59 bars
In short, SF6 at atmospheric pressure is a heavier gas than air, it becomes liquid at - 63.2C and
in which noise propagates badly.
SF6 on the market
SF6 which is delivered in cylinders in liquid phase, contains impurities (within limits imposed
by IEC standards No. 376)
Carbon tetra fluoride
(CF4) 0.03 %
Oxygen + nitrogen
(air) 0.03 %
Water
15 ppm
C02
traces
HF
0.3 ppm
SF6 is therefore
99.99 % pur.
Chemical properties
SF6 is a synthetic gas which is obtained as we have just explained by combination of six atoms
of fluorine with one atom of sulfur:

S 2 6 F 2 2SF 6 524 Kcal

You can see therefore that this reaction is accompanied by an important release of heat.
This approximately similar to coal combustion.
Given that the energy released during synthesis is the same as is needed in order to dissociate
the final element, it can immediately be seen that:

- SF6 is a stable gas

- 524 k. calories are necessary for molecular breakdown, we can there fore already expect
that it will be a powerful cooling agent:

6 F 2 S 2 2SF 6 524 Kcal

The dissociation products before interruption of the arc

At normal temperature, the gas is stable, and does not react with its environment. In contact
with the parts where electric currents circulate, the gas is heated to temperatures of around four
hundred degrees SF6 gives the following decomposition products:
Thionyl fluoride
SOF2
Sulfur fluoride
SO2F2
Sulfur tetra fluoride
SF4
Sulfur deca fluoride
S2F10
Thionyl tetra fluoride
SOF4
SF6 also reacts with the materials that are found in its environment:
With water (impurity in the gas), it gives hydrofluoric acid HF,
With air dioxide (impurity in the gas), it gives sulfur dioxide SO2,
With carbon dioxide (impurity in the gas), it gives carbon tetra fluoride CF4,
With the araldite casings which are high in silicon dioxide, it gives silicon tetra fluoride SF4.
The dissociation products after interruption of an arc.
An electric are develops high temperatures which can reach 15000 C.
At these temperatures, many dissociation products that we have previously studied disappear. It
is thus that, besides the impurities of the gas (water, air, carbon, and dioxide), there only
remain:
Sulfur fluoride
SO2F2
Carbon tetra fluoride
CF4
Silicon tetra fluoride
SIF4
Sulfurous anhydride
SO2.
You can therefore see that a large number of products have been dissociated by the electric arc.
The importance of the remaining products may be lessened by adding a powder (alumina
silicate).
All these gases are heavier than air, and May, under certain conditions is poisonous.
SF6 Safety precautions:
Today there is no known dielectric and breaking agent combined better than SF6 gas.
Initial state
In its initial state, before it has undergone thermal stress (usually the electric arc); SF6 is
perfectly safe in normal conditions:
- It is non-toxic,
- It is uninflammable,
- It will not explode.
This does not mean that no precautions need to be taken: because of its lack of oxygen, this gas
will not support life.
However, the concentration of SF6 would have to be high, since the International electro
technical Commission (IEC) has shown that five mice left for 24 hours in an atmosphere of 79

% SF6 and 21 % oxygen will not only remain alive but will show no signs of abnormal
behavior.
Man dies when the oxygen level of the gas he is breathing falls below 12 %.
Precautions and hygiene
The first recommendation is not to smoke when SF6 gas is around. The heat given off by the
cigarette may decompose the gas. Your cigarette would then take on a very strange taste also
avoid operating combustion engines in this gas.
When the work positions are indoors, have ventilation and / or a system for detecting this
halogen placed at the lowest points of the installations.
Remember that SF6 is a very heavy gas. This device will warn you any gas leaks.
Post-breaking state
As we seen at the beginning of this Chapter, the heat from the arc modifies the SF6.This creates
gaseous and solid decomposition products.
It is these products that need to be spoken about. Certain of these gases are medically defined as
being violent irritants of the mucous membranes and of the lungs. In extreme cases, they may
cause pulmonary edema.
The solid decomposition products (whitish powder) an aggressive when the react with the
humidity of the mucous membranes and of the hands.
Following this rather unpleasant description of the SF6 after breaking we may reassure
ourselves on two counts:
- For reasons of quantity
- For reasons of probability.
Quantity.
The volume of decomposed is microscopic. This means that dangerous thresholds are rarely
reached, thanks in part to the molecular sieve which regenerates the decomposition products to
form pure SF6. This sieve is present in all extinguishing chambers. Regeneration time is short,
but depends on the number of ampere being broken.
The presence of hydrogen sulphide, noticeable through its sickening smell, makes an excellent
alarm signal. The smell detection threshold is ten times lower than the toxic threshold (1 ppm is
detected by smell).
Probability.
In normal operation, electric Switchgear using SF6 has a leak rate guaranteed to be less than 1
% of the mass per year. This makes any danger impossible in normal operation.
The abnormal situation is the risk of an appliance exploding. This is fortunately extremely
infrequent. And if by chance such an incident accrued, the putrid smell would make us aware of
it immediately.
Precaution and hygiene.
If you were to find yourself in contact with decomposed SF6 gas, you must leave your post and
ensure that the gas is eliminated by means of powerful ventilation.
Once the polluted gas has disappeared (when the smell becomes bearable) you are still in
contact with solid decomposition products.
Operations on the equipment must be carried out with a gas mask, gloves and appropriate
clothing. All this - together with the powders themselves - shall be sent to a factory for dealing

with dangerous products.

Any damage to the hands caused by these powders can be neutralized by limewater.

Conclusion
It is important to point out that sulfur hexafluoride does not bring about an increase in the risks
entailed in the work stations. This lack of specific danger is furthermore confirmed by the fact
that we have not had to record any accident since 1960, the year in which SF6 was first used as
a breaking agent. As a matter of interest SF6 does not harm the ozone layer. This is partly due
to its weight.

The electric arc

The creation of an arc
Everyone has noticed that, when placing ones hand near to a television screen, one feels a
force which attracts.
There exists, in fact, in this apparatus, what one calls an electric field. The latter is the source of
an electric current, for it is this that displaces the electrons in the conductors.
An electric field appears at the separation of the live contacts. Such a field of a very great
intensity will draw electrons at the hot points of contacts.
The electric arc has been born. If its own energy is not sufficient, the arc will extinguish rapidly
itself. If, on the other hand, it is crossed by a strong current, it draws throughout its own energy,
which ensures the survival of the arc.
The electric arc:
We have seen that the electric field was at the origin of the displacement of electrons. When the
contacts separate, the electric field draws electrons to the hot points. These electrons are going
to circulate in surroundings which are not conductive, which one calls dielectric, and will cause
the temperature of the surroundings to increase, if they are in sufficient number.
All bodies, under the influence of temperature, end up by reaching their threshold of ionic
dissociation. At this moment, it parts with electrons, and becomes conductive. These electrons
themselves, and for the same reasons, will create others. We have an avalanche, that is to say,
creation of electrons, which will accelerate. One can reach temperature of 15000 C. The value
of the thermal power can be 10MW.
The electric arc is thus going to follow the variations of alternating current, and thus, at regular
intervals, the arc will disappear and reappear immediately, if the electrons have not been
eliminated because in this case, the surroundings remain conductive.
In order to eliminate these electrons, one could:
- Rid oneself of them by some physical means, like blow-out for example,
- use dielectric with a very high speed of recuperation (the case of SF6)
- use a process to reduce the temperature of the element (decompression, blow-out,
etc.)
Out-off a current
If we perfect a system which allows cooling the arc (turning arc, magnetic blow-out,
mechanical or thermodynamic blow-out, etc ...). One can well understand that the arc
increasing to temperatures of 1500C.
Under the effect of current passing through it, will see a temperature decrease as soon as the
alternating current starts its descent towards 0.
The temperature will decrease all the more rapidly as:

- SF6 has two states of conduction, and appearance of the resistive arc will bring about a fall in
the intensity, and thus its temperature,
- SF6, as we have seen in its physical properties, is a gas which Absorbs large quantities of
energy when it dissociates.
The blow out of the arc will thus (mean) evacuate a large quantity of energy.
This lowering of temperature will make the ionic recombination of the bodies and the dielectric
will recover its insulating properties which thus ensure interruption of the current.
Lastly the hydrofluoric acids attack all metals giving metallic fluorides which are all very
hydroscopic insulating powders.

Fig (1) Disruptive voltage versus pressure

Fig (2) SF6 absolute pressure versus temperature with constant volume mass
(density)

Sf6 gas:
SF6 is used in the electrical industry as a gaseous dielectric medium for high-voltage
circuit breakers, switchgear, and other electrical equipment, often replacing oil filled
circuit breakers (OCBs) that can contain harmful PCBs. SF6 gas under pressure is
used as an insulator in gas insulated switchgear (GIS) because it has a much higher
dielectric strength than air or dry nitrogen. This property makes it possible to
significantly reduce the size of electrical gear. This makes GIS more suitable for
certain purposes such as indoor placement, as opposed to air-insulated electrical
gear, which takes up considerably more room. Gas-insulated electrical gear is also
more resistant to the effects of pollution and climate, as well as being more reliable
in long-term operation because of its controlled operating environment. Although
most of the decomposition products tend to quickly re-form SF 6, arcing or corona
can produce disulfur decafluoride (S2F10), a highly toxic gas, with toxicity similar to
phosgene. S2F10 was considered a potential chemical warfare agent in World War II
because it does not produce lacrimation or skin irritation, thus providing little
warning of exposure.
SF6 is also commonly encountered as a high voltage dielectric