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Low Density Polyethylene (LDPE) : HSC Chemistry - Lesson 2 Production of Materials
Low Density Polyethylene (LDPE) : HSC Chemistry - Lesson 2 Production of Materials
Production of Materials
1.1.6 Outline the steps in the production of polyethylene as an example of a commercially and
industrially important polymer
Polyethylene is an example of a commercially and industrially important polymer.
There are two different types of polyethylene.
In the production process for polyethylene there are three major steps:
Initiation
This is the first step of polyethylene production. It involves the production of a
free radical, usually through the decomposition of an initiator molecule using
heat. A free radical (as covered in year 11) is a molecule containing an unpaired
electron and so is highly reactive. In most cases the initiator molecule is a
peroxide molecule with the easily breakable O O bond. An example of this is
Benzoyl Peroxide:
Heat
The free radicals are represented by the dots on the end of their structure
showing the unpaired electrons. The free radicals produced here will then go
react with an ethylene molecule, and attract one electron from the double
covalent bond to attach to its unpaired electron. Once attached together the two
form an activated monomer. This
reaction can be shown as:
Note: the free radical can also be
represented as R O. where the R
stands for the rest of the chain.
Propagation
The second step of polyethylene production involves the activated monomer
attaching with numerous other ethylene molecules producing a larger radical.
The consistent formation of a free radical with an unpaired electron allows
ethylene molecules to continue to attach:
When this
reaction is
repeated
numerous times, a general equation can be devised:
Termination
The final step of polyethylene production involves two developing free radical
ethylene chains coming together to form a completed chain without an unpaired
electron. This process is random and this gives rise to a range of different
molecular weights for the ethylene chains which vary in size.
NOTE: in an exam situation there are two ways to talk about production of
polyethylene. Either the features and production of HDPE and LDPE can be
discussed or the information detailed in the three steps can be discussed. I
always preferred the latter as it involved more equations.
Use this space for making your own notes:
1.1.7 Identify the following as commercially significant monomers by both their systematic and
common names.
Vinyl Chloride
Systematic name: Chloroethene
Common name: Vinyl Chloride
Polymer produced: Polyvinyl Chloride (PVC)
Styrene
Systematic name: Phenylethene
Common name: Styrene
Polymer produced: Polystyrene.
1.1.8 Describe the uses of the polymers made from the
in terms of their properties
above monomers
Polyvinyl Chloride
PVC is impervious to most oils and organic materials which mean it can be
used for packaging for these materials.
Additives to PVC can help improve flexibility and thermal stability. This rigid
PVC is then used for water pipes, credit cards and kitchen utensils.
Flexible and less rigid forms of PVC can be used for upholstery covers for car
seats, and garden hoses.
Polystyrene
Polystyrene can be produced as either a clear brittle plastic (crystalline
polystyrene) or a lightweight foamy packaging material (expanded polystyrene).
1.2.2 Identify data, plan and perform a first-hand investigation to compare the reactivities of
appropriate alkenes with the corresponding alkanes in bromine water
1. Place 5 medium sized test tubes, precleaned into a test tube rack in the
absence of UV light
2. Using a clean measuring cylinder, add 5ml of bromine water into each of
the test tubes and record initial colour
3. Add 5ml of hexane using a clean 10ml measuring cylinder into one of the
bromine water test tubes.
4. Stopper the test tubes with a test tube stopper
5. Gently shake the test tube and record the colour change in the test tube
6. Repeat steps 4-6 with 5ml of hexane, cyclohexane and cyclohexene with
the remaining bromine water test tubes
7. 1 bromine water test tube should be left and this will act as the control
8. Repeat the experiment 10 times and if similar results are obtained then
the experiment can be deemed reliable
Use this space to record information about this prac:
1.2.3 Analyse information from secondary sources such as computer simulations, molecular model
kits or multimedia resources to model the polymerisation process.
1. Construct one initiator molecule (containing an O O bond in R O O
R)
2. Construct 10 monomer units (CH2 = CH2 )
3. Decompose the initiator molecule (by breaking the O O bond to create
.
4. React one of the free radicals with the first monomer. The double bond is
broken as the free radical initiator adds onto the molecule. An activated
.
6. Use the other RO Radical to repeat steps 4-6 with the other monomers
7. Using the two polymer chains, react their free ends to make one long
chain with the RO groups at either end, modelling termination
3 Marks
Identify the common and systematic name of the polymer shown above 2 Marks
Explain how the properties of the polymer made from this monomer as well as one other polymer you
may have studied in class relate to its uses
3 Marks
Draw the structure of the polymer made from the above monomer
1 Mark