4.

the following data were obtained for the hydrolysis of sugar in aqueous solution at 23oC
time/min
sugar consentration /
mol dm-3

60

130

180

0,807

0,63

0,531

Show that the reaction is first order and calculate the rate constant for the hydrolysis!
Answer:
Data, a = 1 mol/dm3
Substitution methode
[ A0 ] 2,303
2,303
a
k=
log
=
log
t
t
ax
[A]
sugar (mol/dm3)
Time (min)
a/(a-x)
log a/(a-x)
2,303/t
k
log (a-x)
(mol/dm3)

1
0
1
0
-

0,807
60
1,239157373
0,093126465
0,038383333
0,003574504

-0,093126465

0,63
130
1,587301587
0,200659451
0,017715385
0,003554759
0,200659451

0,531
180
1,883239171
0,274905479
0,012794444
0,003517263
-0,274905479

Gb 1. Plotting [sugar] vs t
200
150
Axis Title

f(x) = - 380.43x + 374.78

R = 0.99

100

Linear ()

50
0
0.5

0.6

0.7

0.8

Axis Title

0.9

1.1

Gb 2. Plotting Log (a-x) vs t

200
f(x) = - 654.01x - 0.48
R = 1

150
100

Axis Title

Linear ()

50
0
-0.3 -0.25 -0.2 -0.15 -0.1 -0.05

Axis Title

Reaksi ini termasuk orde satu karena linear

Nilai k adalah nilai rata-rata dari semua k:
0,003574504 +0,003554759+0,003517263
k=
=0,003548842
3

Gb 3. Plotting Log (a/a-x) vs t

200
f(x) = 654.01x - 0.48
R = 1

150
Axis Title

100

Linear ()

50
0
0

0.05 0.1 0.15 0.2 0.25 0.3

Axis Title

6.
time /
min
absorban
ce
a/ (a-x)
log a/ (ax)

18

57

130

240

337

398

2,19

2,06
1,063106
796
0,026576
894
0,127944
444
0,003400
366

1,83
1,125683
06
0,051416
131
0,040403
509
0,002077
392

1,506
1,215139
442
0,084626
118
0,017715
385
0,001499
184

1,198
1,257095
159
0,099368
154
0,009595
833
0,000953
52

1,051
1,139866
794
0,056854
102
0,006833
828
0,000388
531

0,98
1,072448
98
0,030376
64
0,005786
432

0,313867
22

0,262451
09

0,177824
972

0,078456
818

0,021602
716

1
0

2,303/t
k
log (a-x)
(mol/dm3
)

0,340444
11

Gb 1. Plotting [absorbance] vs t
500
400
300
Axis Title 200

f(x) = - 313.73x + 653.29

R = 0.94

100
0
0.8 1 1.21.41.61.8 2 2.22.4
Axis Title

time / min
Linear (time / min)

+
0,008773
924

Gb 2. Plotting Log (a-x) vs t

500
400
f(x) = - 1106.39x + 356.01
R = 0.98

300
Axis Title

Linear ()

200
100
0
-0.1

0.1

0.2

0.3

0.4

Axis Title

Gb 3. Plotting Log (a/a-x) vs t

500
400
300
Axis Title 200

f(x) = 1494.69x + 94
R = 0.11

100

Linear ()

0
0

0.02 0.04 0.06 0.08 0.1 0.12

Axis Title

Reaksi bukan reaksi orde satu karena grafik yang ditunjukkan tidak linear.

Nilai k adalah nilai rata-rata dari semua k:

k=

0,003400366+ 0,002077392+ 0,001499184+0,00095352+0,000388531+0,000175772

=0,001416
6