2 CLEANSING ACTIVITY

CHEMICAL FOR CONSUMER

The cleansing action of soap and detergent
The cleansing action for soaps and detergent results from their
ability;
i. to lower the surface tension of water,
ii. to emulsify oil or grease / dirt, and
iii. to hold them in suspension in water.
This ability is due to the structure of soaps and detergent
Structure of soaps
Soap consists of sodium/potassium cations and soap anions.
When a sodium/potassium soap is dissolve in water, it will form
soap anions and sodium ion, Na+ or potassium ion, K+
Sodium soap soap anions + sodium cations [Na+]
Potassium soap soap anions + potassium cations [K+]
What is soap anions?
CH3
CH2

CH2

CH2
CH2

CH2

CH2
CH2

CH2

CH2

CH2
CH2

Hydrophobic
[hydrocarbon chains]

CH2

CH2

CH2

C
O

Hydrophilic
[carboxilate group]

COO
Soap anions
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From the diagram above shows that the structure of soap anions
consists of,
i. hydrocarbon chains known as hydrophobic part
ii. carboxylate/ionic group known as hydrophilic part
Structure of detergent
Detergent of sodium cations and detergent anions.
When a detergent is dissolve in water, it will form detergent anions
and sodium ion, Na+.
What is detergent anions?
i) Sodium alkyl sulphate detergent
CH3
CH2

CH2

CH2
CH2

CH2

CH2
CH2

CH2

CH2

CH2
CH2

CH2

Hydrophobic
[hydrocarbon/alkyl chains]

CH2

CH2

OSO
Na+

Hydrophilic
[sulphate ions]
OSO3

Alkyl sulphate ion

From the diagram above shows that the structure of alkyl sulphate
anions consists of,
i. hydrocarbon/alkyl chains known as hydrophobic part
ii. sulphate/ionic group known as hydrophilic part

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i) Sodium alkyl benzene sulphonate detergent

CH3
CH2

CH2

CH2
CH2

CH2

CH2
CH2

CH2

CH2

CH2
CH2

CH2

CH2

SO
Na+

Hydrophobic
Hydrophilic
[hydrocarbon/alkyl benzene chains] [sulphonate ions]
SO3
Alkylbenzene sulphonate anios

From the diagram above shows that the structure of alkyl benzene
sulphonate anions consists of,
i. hydrocarbon/alkyl benzene chains known as hydrophobic
part
ii. sulphonate/ionic group known as hydrophilic part
Remember this;
In water, soap and detergent dissolves to form soap anions and
detergent anions. The anions will carry out the cleansing action,
because these anions consists of hydrophobic and hydrophilic part.
Why?
Hydrophobic is water-hating part, is soluble in oil/grease/dirt,
but insoluble in water.
Hydrophilic is water-loving part, is soluble in water but
insoluble in oil/grease/dirt.
Both of the properties of anions, makes soap and detergent act
as an effective cleansing agent.
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How soap and detergent carry out the cleansing action?

Sodium ion

Soap/detergent ion

+
+

Grease/dirt

Dirt cloth

- The cloth is dipped in a soap or detergent solutions.

- Soap and detergent reduces the surface tension of water.
- This increase the wetting ability of water, therefore the surface of
the cloth is wetted thoroughly.

+
+

Hydrophilic part

Hydrophobic
part

- Hydrophilic part dissolves in water.

- Hydrophobic part dissolves in dirt/grease.
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- Mechanical agitation during scrubbing helps pull the dirt/grease

free, and break the grease into small part.
+
+

- The droplets do not coagulate and redeposit on the surface of the

cloth because the repulsion between the negative charges on their
surface.
- The droplets is suspended in the water forming an emulsion.
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- Rinsing washes away these droplets and leaves the surface clean.
The effectiveness action of soap and detergent
Advantages of soap
1. Soap are effective cleaning agent in soft water.
- Soft water did not contains Mg2+ ions and Ca2+ ions.
- Example: rain water, tap water
2. Soap does not polluted the environment.
- Soap is biodegradable (can be decomposed by bacteria)
because it was made from substance that found in animal
and plant.
3. Soap will not harmed the aquatic life.
- Soap will not change pH value of river and pool because
soap is salt and weak alkali.
Disadvantage of soap
1. Soap is not suitable for use in hard water.
- Hard water contains Mg2+ ions and Ca2+ ions.
- Example: Sea water, river water
Why not suitable?
- Mg2+ and Ca2+ ions react with the soap ions to form an
insoluble precipitate known as soap scum.
- Soap scum reduces the amount of soap available for
cleaning, thus wasting soap.
- Soap scum does not rinse away easily.
- Soap scum can form deposits on clothes causing them to
be grey or yellow in colour.
2. Soap did not effective in acidic water.
- Soap ion react with ion H+ to produce carboxylic acid
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molecule.
Advantage of detergent
1. Detergent is effective in hard and soft water.
- Detergent do not form scum with hard water.
- Detergent form soluble substances with calcium or
magnesium ions.
2. Detergent effective in acidic water
- Detergent ion did not combine with H+ .
3.

Detergent is synthetic cleansing agent.

- Structure of the hydrocarbon chain can be modified to
produce detergents with specific properties.

Disadvantage of detergent
1. Detergent can cause pollution to environment
- Detergents not biodegradable, so that it cannot be
decomposed by bacteria
2. Detergent harmed to aquatic life
- Detergent contains phosphate fertilizer will increases the
growth of seaweed and algae in pond or river. Lots of
soluble oxygen in water will be use up by bacteria to
decompose seaweed and algae when the plant died.
The content of oxygen in water decreases, thus can kill
aquatic life.
3. Detergent produce a lot of foam.
- Foam can cover the water surface and prevent the
oxygen dissolves into water, thus will kill aquatic life.

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Additives in detergent
The main substance in detergent is sodium alkyl benzene
sulphonate and sodium alkyl sulphate. Example of detergent is
shampoo, clothes washing powder and dishes washing liquid.
Various type of additive is also added to detergent to enhance the
cleaning efficiency and to meet the needs of consumers.
additives
Whitening agent
(sodium perborate)
Biological enzymes
(amilase, lipase,
protease, selulase)
Fluorescent agent
(Blancophor)
Buildup agent
(sodium
tripoliphosphate)
Drying agent
(sodium sulphate,
Sodium silicate)
Stabilizers
Perfumes
Antiseptic substance

Function
React as bleach agent to vanished the colour
stain but did not fade the colour of the
clothes.
React to substance that in organic properties
like blood, food and water. Enzymes
dissolve and change it to substance that can
dissolve in water.
Make the clothes more white, shiny and
bright.
Soften hard water, expel ion Mg2+ dan Ca2+ .
increase the pH value
Ensured that the detergent is always in a dry
condition.
To prevent the formation of foam
To make clothes smell fresh and clean.
To kill all microorganism that cause disease
and smell.
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End