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Rotary Kiln Process of Making Sponge Iron: Hapter
Rotary Kiln Process of Making Sponge Iron: Hapter
Dry ESP/
bag filter
ID fan
Ash
Stack
Waste gas
Iron ore
coal
flux
After
Fine Shell-mounted
burning &
coal air fans cooling
n chamber
tion kil
Reduc Inlet hood
blower
Cooler
Product
Dust
Magnetic separator
Fig. 2.2 A concise schematic representation of a rotary kiln sponge iron plant
Rotary Kiln Process of Making Sponge Iron // 11
1 1 1 1 1 Waste gas
5
Air
8 9 11
2 6 6 6 10
][ ][ ][
12
Water 4
3
13 7 7 7 7 7
1. Raw material bins 4. Surge bin 7. Product storage bins 10. Induced draught fan 13. Cooler
2. Belt conveyor 5. Vibratory screen 8. After burning chamber 11. Waste gas stack
3. Bucket elevator 6. Magnetic separator 9. Radial flow scrubber 12. Rotary kiln
Fig. 2.3 A schematic of the sponge iron Pilot Plant of RDCIS, SAIL
This Plant of capacity 5 to 9 tonnes per making. When operated with a good quality
day of sponge iron was commissioned in coal, metallisation level was consistently
March 1982 within the premises of M/s HEC above 90%. On the other hand three of the
at Ranchi, with the objective of adapting and coals tested in Pilot Plant were either not
assimilating coal based sponge iron suitable or were only marginally acceptable.
technology in India. The Pilot Plant was in In such cases obviously metallisation levels
regular operation since its commissioning till were reduced – in extreme cases upto 70%.
1992-93, with 4 to 5 Campaigns each year. Other major results include:
48 campaigns were carried out in the • Development of ore-coal composite
Pilot Plant with various ore and coal pellets technology, which improves
combinations from different deposits in the kiln productivity and reduces energy
country. The two longest campaigns lasted consumption (patented)
62 days each. A total of 26 ore-coal • Pre-heating system of ore (patented)
combinations were processed in the Pilot • Simultaneous injection of under-bed
Plant. Most of the iron ores tested in Pilot hydrocarbon fuel and over-bed air in a
Plant were found suitable for sponge iron rotary reactor
Air
Waste gas
Iron ore
Fig. 2.4 Essential features of a reduction kiln in a rotary kiln sponge iron plant
12 // Advances in Rotary Kiln Sponge Iron Plant
2.4 FEATURES OF A ROTARY KILN gas and conversion cost at similar capacities
SPONGE IRON PLANT are higher. But even then, gas-based
Figure 2.4 indicates the essential features processes have generally found favour due
which are needed in the reduction kiln of a to better and more consistent quality,
sponge iron rotary kiln plant. However, the lower energy consumption and higher
air tubes indicated in this diagram can be module size. It was realised early that
substituted by a ported kiln design, which is rotary kiln processes can be up-scaled only
discussed later in this book. to a limited extent and bigger module size
A typical material balance for the sponge does not mean a higher economy of scale.
iron making process is presented in Fig. 2.5. Modules bigger than 500 tpd were
Here coal is assumed to contain about 20% continuously plagued by problems of
ash, something which is hardly available now accretion formation and were maintenance
a days. Product is shown to be screened into prone. All such modules have now been
three fractions. But due to difficulty in phased out.
screening the -1 mm fraction, it is usual now India has been the largest producer of
a days not to separate out this fraction. Use sponge iron since last few years. Its
of 6 to 20 mm iron ore is indicated. Presently contribution to world DRI production is in
it is more common to use 5 to 18 mm fraction. excess of 25% at present. India has been
A typical energy balance in the form of increasing the gap with the next country
Sankey diagram is presented in Fig. 2.6. Venezuela. Trends indicate that this gap
Rotary kiln processes have had to would continue to increase in the foreseeable
compete with gas-based processes. Gas future. Iran is third on the line and Mexico,
based processes use relatively costlier who was once the world leader, is presently
input such as pellets and reformed natural placed fourth. One thing may be noted though
Rotary Kiln Process of Making Sponge Iron // 13
Input energy
6.0, coal
2.25,
1.7
Waste
Sponge
gases
1.15, Char iron
(Chemical
(Chemical (Chemical
energy +
energy)* energy)
Sensible heat)
0.3, Cooling
losses
(Sensible heat in
solid product)
that the entire production by number 2, 3 and Figure 2.8 presents the scene with respect to
4 countries is through gas based route while coal and gas based processes.
in India, more than half the production is by 60 30%
the coal based route.
World DRI
50
2.5 THE INDIAN SCENE production
DRI production million tonnes
in India vis-à-vis world, over the years. Fig. 2.7 A comparison of sponge iron
production of India and World over the years
14 // Advances in Rotary Kiln Sponge Iron Plant
59.80
Sponge iron production in the year 2006,
million tonnes
60.00 –
49.10
50.00 –
40.00 –
India
30.00 – World
Fig. 2.8 Another comparison of sponge iron production of India and World indicating
the dominant position of coal based route in India
The Krupp-Renn process, about which in the latter, in spite of the fact that a 2 mtpa
we mentioned in chapter 1, was probably gas based module has been commissioned
the last of the rotary kiln processes, which recently in western India.
attempted to produce iron in fused or As mentioned earlier, nearly 35% of
semi-fused mass. All of the current
India’s sponge iron production is accounted
processes attempt to prevent any type of
for by the three gas based plants located near
fusion during production.
the western coast. M/s Essar Steel Limited
The processes, which are currently in
located in Hazira in the state of Gujarat has
vogue, are Jindal Process (50, 350 and 500 tpd),
five operating modules with a total capacity
SIIL Process (100 tpd), OSIL Process (300 and
of 5.5 mtpy and claim to be the largest sponge
500 tpd), SL/RN (Lurgi) Process (100 and 500
iron plant in the world. Ispat Industries
tpd), Krupp-Codir Process (400 and 500 tpd),
DRC Process (250 to 350 tpd) and TDR Process Limited and Vikram Ispat Limited both
(400 tpd). OSIL Process has evolved from the located in the state of Maharashtra have one
ported kiln concept of ACCAR Process, while module each of capacities 1.4 and 0.9 mtpy.
SIIL Process has been based on the Lurgi or On the coal based front, the plant of M/s
SL/RN Process. Presently, of the total sponge Jindal Steel and Power Limited (JSPL) in
iron produced in the world, coal based rotary Raigarh in the central Indian state of
kiln processes contribute only about 15%, but Chhattisgarh is the largest in India and
considering India alone this percentage is probably in the world. It has ten modules
about 65%. Trends point to substantial increase totalling 1.2 mtpy capacity.
Rotary Kiln Process of Making Sponge Iron // 15
Table 2.1 DRI Production: India and World* Thus we see that the largest coal based
Million Tonnes plant in the world barely stands up to the
smallest gas based module in India. But then
Year India World
the coal based plants make it up in numbers.
1970 0 0.79 As mentioned earlier, over 300 modules of
1975 0 2.81 coal based plants are operating in India. And
1978 0 5.00 situation is changing so fast, almost on daily
1979 0 6.64 basis, that not much point is served by
describing these plants here.
1980 0.01 7.14
Apart from JSPL, some of the plants
1981 0.02 7.92
which operate large size modules (300 to 500
1982 0.03 7.28
tpd) are Bihar Sponge Iron in Jharkhand,
1983 0.04 7.90 Prakash Industries, Nova Iron and Steel,
1984 0.08 9.34 Monnet Ispat, Godavari Ispat and Power all
1985 0.09 11.17 in Chhattisgarh, Sunflag Iron and Steel
1986 0.17 12.53 Company, Lloyds Metals and Engineers, in
Maharashtra, Orissa Sponge Iron, Tata
1987 0.19 13.52
Sponge Iron, in Orissa, GSAL India in Andhra
1988 0.19 14.09
Pradesh, etc. We must make special mention
1989 0.26 15.63 of Sponge Iron India Limited in Paloncha in
1990 0.61 17.68 Andhra Pradesh, which was the first of the
1991 1.15 19.32 commercial plants (originally called a
1992 1.44 20.51 demonstration plant) commissioned in 1980,
1993 2.21 23.65
and which started the race for the installation
of the 100 tpd modules, the total number now
1994 3.12 27.37
being well over one hundred. 50 tpd modules
1995 4.28 30.67
could also have exceeded 100 in number. But
1996 4.84 33.30 another special mention must be made of the
1997 5.26 36.19 25 tpd modules. One is operating in Ramgarh
1998 5.26 36.96 in Jharkhand (Palash Sponge Iron), while at
1999 5.22 38.59
least two modules are operating in Raipur in
Chhattisgarh.
2000 5.44 43.78
2001 5.59 40.51 2.6 WHY SHOULD WE SELECT A
2002 6.59 45.10 ROTARY KILN?
2003 7.67 49.45 The rotary kiln direct reduction (RKDR)
2004 9.37 54.60 processes have been looked upon with
2005 11.10 55.96 apprehension, mainly because there have been
rapid births and deaths of processes in this
2006 15.00 59.80
group. But the fact that it has re-emerged,
*Data taken mainly direct from Midrex
16 // Advances in Rotary Kiln Sponge Iron Plant
FeO + CO Fe + CO2
↑
CO + ½O = CO2 CO2 +C = CO + CO2
[Partial]
points to certain strengths of this process. Let (ii) As a large freeboard volume is
us examine some of them. available above the solid charge (about
85%), the rotary kiln can tolerate
2.6.1 Process Strengths heavily dust-laden gas. When the kiln
Rotary kiln process has to compete mainly is suitably designed, it would be best
with the shaft process of making sponge iron suited for utilising the Indian high ash
and in some cases with iron making blast non-cooking coals. In shaft reactors,
furnace. As compared to them, the rotary kiln generation of such dust leads to
has some advantages, as also some limitations, choking and channelling which leads
both with respect to the process and the finally to disruption of the process.
product it makes. The major process (iii) Rotary kiln can serve the dual purpose
strengths of rotary kiln are: of a coal gasifier as well as an ore
(i) A rotary kiln can mix the solid charge reducer. Preparation of reducing gas
as it heats and reduces it. Simultaneous from coal is an expensive step, which
mixing helps in the dilution of CO2 is coming in the way of commer-
concentration formed around the iron cialisation of coal gasification based
ore/sponge iron particles – which is DR process. Therefore, rotary kiln DR
necessary for the reduction reaction process has proved commercially
to proceed. viable, even with low productivity per
Rotary Kiln Process of Making Sponge Iron // 17
(i) For charging in electric furnaces in rotary kiln sponge iron is much less
substantial quantities, a system of susceptible to re-oxidation as
continuous charging needs to be compared to sponge iron from shaft
installed. This would mean an units using reformed gases.
additional investment for the existing Those who have ventured into sponge
units, which are not having this iron have to endeavour to exploit the
facility. strengths of RKDR to the fullest extent and
(ii) The sponge iron from rotary kiln has would have to try to mitigate the effects of
much lower carbon content (usually its weaknesses suitably. Those who
0.2%) than either the sponge iron from contemplate venturing into sponge iron have
shaft furnace (0.7 to 2%) or the hot to make a thorough analysis as to whether
metal from blast furnace. Carbon in the strengths outweigh the disadvantages or
sponge iron not only helps in adding to not in the scenario they are finding themselves
the opening carbon in molten bath, it in. It becomes the duty of the process
also carries in chemical energy, which developers to put in innovations, which make
helps in reducing the consumption of greater use of the strengths and minimise to
electric power. Too low a carbon content the extent possible the weaknesses of RKDR.
comes in the way of a healthy carbon There are many basic aspects, which need
boil and, therefore, bath carburisers to be considered for making sponge iron in
need to be added. Clean carburisers are rotary kiln, the important ones being:
costly while coke, char or pig iron carries
with it undesirable elements like sulphur (i) Thermodynamics of reduction and
and phosphorous. gasification reactions
(ii) Characteristics of raw materials and
(iii) Sponge iron from rotary kiln carries
their role in the process
with it more gangue and phosphorous
than those from shaft furnace, mainly (iii) Reaction kinetics, roles of reducibility
because shaft furnace uses cleaner of iron ore and reactivity of coal char
inputs. Gangue and phosphorous and thereby the basis of selection of
contents are much higher than they iron ore and coal
are in iron and steel scrap, which means (iv) Movement of solids in the rotary kiln
extra inputs of phosphorous and slag and its residence time
in electric furnaces. (v) Gas evolution and flow rate
(iv) When we compare with scrap and pig (vi) Heat transfer, temperature profile and
iron, all sponge irons are prone to re- process model
oxidation and the product from rotary These would be dealt in the subsequent
kiln is no exception. However, this chapters.