SOLUTIONS & ANSWERS FOR AIEEE-2011

VERSION – S

PART A − CHEMISTRY Sol: A1B5 = A2 B5

2
1. Ans: Acetaldehyde
10. Ans: AlCl3
Sol: Acetaldehyde reduces tollen’s reagent to
metallic silver on warming. Sol: Fajan’s rules.
3+
Al is the smallest cation and it has high
2. Ans: 0 .086 charge.

Sol: Mole fraction of methanol 11. Ans: Al2O3 < MgO < Na2O < K2O
moles of methanol 5 .2
= = Sol: K2O is more basic than Na2O. Al2O3 is
total moles 1000
5 .2 + amphoteric.
18
= 0.086
12. Ans: pentagonal bipyramid
3. Ans: 2, 2, 2–Trichloroethanol
Sol: IF7 is pentagonal bipyramidal.
Sol: 2Cl3C – CHO + NaOH
13. Ans: 2–Pentanone
→ Cl3C – CH2OH + Cl3C – COONa
O
4. Ans: 32 times
Sol:
CH3 C CH2 CH 2 CH3
Sol: 2 times increase for 10°C
5
2 = 32 times increase for 50°C ketoform
OH
5. Ans: a for Cl2 > a for C2H6 but b for Cl2 < b for
C2H6 CH3 C CH CH2 CH 3

Sol: ‘a’ is a measure of attraction between the enol form

molecules and ‘b’ the size of the
molecules. 14. Ans: 2, 4, 6–Tribromophenol
–1 –1
6. Ans: 38.3 J mol K Sol: Phenol forms 2, 4, 6–tribromophenol when
treated with a mixture of KBr, KBrO3 and
V2 HCl.
Sol: ∆S = 2.303 nR log
V1
15. Ans: 804.32 g
= 2.303 × 2 × 8.314 × log 10
–1
= 38.3 J K W2 1
Sol: ∆Tf = Kf × ×
M2 W1
7. Ans: 1.8 atm
W2 1
6 = 1.86 × ×
Sol: CO2 + C → 2CO 62 4
a–x 2x W 2 = 800 g
Wt. of glycol required is more than 800 g
a = 0.5 atm
a + x = 0.8 atm i −1
x =0.3 atm 16. Ans: α=
( x + y − 1)
2
pCO (0.6)2
Kp = = = 1.8 atm
pCO2 0 .2 Sol: i = 1 – α + nα; n = x + y
i −1
α=
8. Ans: 743 nm x + y −1

BF63−
1 1 1
Sol: = − 17. Ans:
355 680 λ
λ = 743 nm
Sol: Boron cannot form BF63− since boron has
9. Ans: A2 B5 no available d–orbitals.
18. Ans: CH3CH2CH(Cl)CO2H Sol: Sulphur exhibits oxidation state lower than
+4 in its compounds.
Sol: Presence of Cl having –I effect on the
α–carbon makes 2–chlorobutanoic acid 30. Ans: The stability of hydrides increases from
the strongest acid among the given NH3 to BiH3 in group 15 of the periodic
compounds. table.

19. Ans: Ethyl ethanoate Sol: Stability of hydrides decreases from NH3
to BiH3.
Sol: CH3COCl + C2H5ONa
→ CH3COOC2H5 + NaCl Part – B – Mathematics

20. Ans: 2
nd
31. Ans: −5

Sol: RNA contains β–D–ribose while DNA Sol: |a| = |b| = 1 a. b = 0

contains β–D–2–deoxyribose. (2a − b). ((a × b) × (a + 2b))
= (2a − b) ×
21. Ans:
7
4f 5d 6s
1 2 [(a. a) b − (a. b) a + (2b. a) b − (2b. b)]
(2a − b). (b − 2a) = − 5
Sol: The outer electronic configuration of
7 1 2
64Gd is 4f 5d 6s
32. Ans: − 144
22. Ans: 2.82 BM
(1 − x − x + x ) = (1 − x) (1 − x )
2 3 6 6 2 6
Sol:
= (1 − 6x + ..− 20x … − 6x ) x
3 5
Sol: There are two unpaired electrons is
2–
(1 − 6x + 75x − 20x ….)
2 4 6
[NiCl4] hence the paramagnetic moment
is 2.82 BM. = 120 − 300 + 36
2 3 = 156 − 300 = − 144
23. Ans: sp , sp, sp
33. Ans: β ∈ (1, ∞)
NO3− – sp , NO2+ – sp and NH+4 – sp
2 3
Sol:
Sol: If 1 + ai is root (a, real)
Then (1 + i a) + α (1 + I a) + β = 0
2
24. Ans: a vinyl group
2a + aα = 0 ⇒ α = − 2 a ≠ 0
1−a +α+β=0
2
Sol: Formation of HCHO in ozonolysis shows
1−a +β=0
2
the presence of CH2 = CH – group.
β = a + 1 > 1 ∴ β ∈ (1, ∞)
2

25. Ans: The complex is an outer orbital complex

34. Ans: ~ (Q ↔ (P ∧~R))
Sol: [Cr(NH3)6]Cl3 is not an outer orbital
complex. Sol: The given statement is
(P ∧~R) ↔ Q ≡ Q ↔(P ∧~R)
+
26. Ans: p(H2) = 2 atm and [H ] = 1.0 M ∴ The required negative is
~ [Q ↔ (P ∧~R)]
2H + 2e → H2
+ –
Sol:
0.0591 [H+ ]2  d2 y   dy  −3
ECl = log 35. Ans: − 2  
2 [H2 ]  dx   dx 
 
+ 2
[H2] > [H ]
d2 x d  dx 
27. Ans: Availability of 4f electrons results in the Sol: 2
=  
formation of compounds in +4 state for all dy dy  dy 
the members of the series  
d  1 
=
Sol: All the lanthanoids does not exhibit +4 dy  dy 
oxidation state.  dx 
−1 d  dy 
28. Ans: Neutral FeCl3 = 2
.  
 dy  dy  dx 
 
Sol: Neutral FeCl3 solution gives violet colour  dx 
with phenol.
−1 d2 y  dx 
= 2
. 
29. Ans: The oxidation state of sulphur is never  dy  dx 2  dy 
less than +4 in its compounds  
 dx 
  d2 y   dy  −3 ∴ f(x) has maximum at x = π
= − 2   And minimum at x = 2π
 dx   dx 
 
a⋅c
36. Ans: Statement-1 is true, Statement-2 is true; 41. Ans: c − b
a.b
Statement -2 is not a correct explanation
for Statement-1.
Sol: b × c = b×d
Sol: A (1, 0, 7) B,(1, 6, 3) a⋅d = 0
x y −1 2 − 2
= = (
b× c −d = 0 )
1 2 5
P (λ, 2λ + 1, 3λ + 2) (
b and c − d are collinear)
drs (λ - 1, 2λ + 1, 3λ - 5) (
b = k c −d )
∴ λ - 1 + 2 (2λ + 1) + 3(3λ - 5) = 0
14λ - 14 = 0 ⇒ λ = 1
(
a ⋅ b =k c − c − a ⋅ d ) ]
P (1, 3, 5) is mid point of A and B k [c − c ]
Statement-1 is true
a⋅b
Statement-2 is also true but k=
statement-1does not follow from 2 a⋅c
ac
b c−d= b
37. Ans: P(C|D) ≥ P(C) a ⋅b
a⋅c
P(CD) d=c− b
Sol: P(C | D) =
P(D )
a.b

P(C ) 42. Ans: Statement-1 is true, Statement-2 is true;

=
P(D ) Statement -2 is not a correct explanation
≥ P(C) for Statement-1.

Sol: A = (x, y) y – x ∈ z
 1
38. Ans: 0, 2  B = (x , y) x = αy for rational α
  A : x – x = 0 ∈ z ⇒ (x, x) ∈ A reflexive
Sol: 1 -P ≥
5 31 y–x∈z⇒x–y∈z
32 ⇒ (y, x) ∈ A symmetric
31 y – x ∈ z and z – y ∈ z ⇒ z – x ∈ z
P ≤1-
5
32 ∴ (x, z) ∈ A transitive
A is equivalence relation
1
≤ Statement – 1 is true
32 B: x = 1, x ⇒ (x, x) ∈ B reflexive
1  1 1
P≤ = 0,  x = αy ⇒ y = x ∴ (y, x) ∈ B
2  2 α
Choice (3) symmetric
x = αy and y = αz ⇒ x = α z
2

39. Ans: π log 2 ∴ (x, z) ∈ B transitive

B is equivalence relation
1 Statement – 2 is true but I does not
log (1 + x )
Sol: I= 8 ∫ 1+ x2
follow from 2.
0
π
43. Ans: Statement-1 is true, Statement-2 is true;
4 Statement -2 is not a correct explanation
∫
= 8 Log(1 + tan θ) dθ for Statement-1.
0
= π log 2 Sol: if AB = BA
T T T
(AB) = A B
40. Ans: local maximum at π and local minimum at ⇒ AB is symmetric
2π Statement-2 is true
T T T T
(ABA) = A B A
Take A = I and B = some non – symmetric
Sol: f’(x) = x sin x ∴ABA always
2x cos x + sin x ∴A(BA) and (AB)A are symmetric
f’’(x) =
2 x Statement-1 is true nut does not depend
f’(x) = 0 ⇒ x = nπ, n ∈ Z on Statement-2
ie., x = π, 2π in 0 5π (
2
)
f’’(π) < 0 and f’’(2π) > 0
44. Ans: a =c Point on the parabola corresponding to t = 1 is
 1 1
⇒  , 
Sol: Two circle should touch each other 4 2
a  1 1
Centres are  ,0  and (0,0) − +1
2  3 2
∴ shortest distance = 4 2 =
∴ also second circle passes through (0, 0) 2 8
∴c=a⇒ a =c
51. Ans: 21 months
45. Ans: Does not exist Sol: Total savings = 11040
Savings in the first 2 months = 400
sin( x − 2) Hence, savings in the next n months
Sol: lim 2
x →2 ( x − 2) = 10640
We have
Limit does not exist
n
[ 400 + (n − 1)40] = 10640
3 2
46. Ans: ≤A≤1 [200 + (n−1) 20] n = 10640
4
200n + 20 n − 20 n = 10640
2

20n + 180 n − 10640 = 0

2
2 4
Sol: A = sin x + cos x
4 2
= cos x – cos x + 1 n2 + 9n − 532 = 0
2
 1 3 9 ± 81 + 2128
=  cos2 x −  + n=
 2 4 2
3 − 9 ± 2209 −9 ± 47
∴ ≤ A≤ 1 = =
4 2 2
= 19
47. Ans: Statement-1 is true, Statement-2 is false. Therefore, answer is 21 months

Sol: P is (-2, -2) and Q (-1, 2) since R bisect 52. Ans: 4

∠POQ, PR ¨RQ = OP : OQ
= 4 + 4 : 1+ 4 = 8 : 5 25a + 26b
Sol: Median =
∴ Statement 1 is true 2
But statement 2 is false. 51a
=
2
48. Ans: (-∞, 0) Numerical value of the sum of the derivation
1 3 5 49 
Sol: |x| − x > 0 = 2a + + + .... + 
⇒|x| > x 2 2 2 2 
⇒ x ∈ (-∞, 0) 2a × 252
= = 252 a
2
2
49. Ans:
3 25 2 a
Mean derivation about median =
50
3
Sol: The angle is sin−
1

14 25 2 a
= 50
1 + 4 + 3λ 3 50
∴ =
(1 + 4 + λ )(1+ 4 + 9)
2 14
|a| =
50 × 50
=4
14 (3λ + 5) = 9 × 14 (5 + λ )
2 2 25 × 25
2 2
9λ + 30λ + 25 = 9λ + 45
2 53. Ans: (1, 1)
⇒ 30λ = 20 ⇒ λ =
3 Sol: (1 + ω) = A + Bω
7

(− ω ) = A + B ω
2 7

− ω = A + Bω
14
3 2
50. Ans:
− ω = A + Bω
2
8
Sol: Slope of the line perpendicular to 1 + ω = = A + Bω
y – x = 1is (-1) ∴A=1 B=1
Hence t = 1 ∴ (1, 1)
 3 3 1
54. Ans: square units ∴p= − ,q=
2 2 2

57. Ans: Statement-1 is true, Statement-2 is true;

Statement -2 is a correct explanation for
Statement-1.
1
Sol: x1 + x2 + x3 +x4 = 6
y= x
xI ≥ 0
9
no. of ways = C3
A x=c S2 is true
S1 is true
S1 follows from S2

3x + 5y − 32 = 0
2 2
Sol: y=x 58. Ans:
1 2
y= ⇒x =1
x x2 y2
Sol: + =1
⇒ x = 1 (x > 0) a2 b2
1
y= ,x=e⇒x=e 9 1
x + =1
a2 b2
e
 1 1 9
∴area A = ∫  x − x  dx b 2
= 1−
a
1

e −1
2 1 a2 − 9
=
2
− log e
(
a 1− 2
1
5
) =
a2
e2 − 3 3
a −9=
2
=
2 5
1 2 e2 − 3 3 3 32
=
2
Required area = .e − = a =9+
2 2 2 5 3
3 32 3 32
b =a × = × =
2 2
55. Ans: 2 5 3 5 5
Equation of the ellipse is
4 k 2 x y2
+ =1
Sol: k 4 1 =0 32 32
2 2 1 3 5
3x + 5y − 32 = 0
2 2
4(4 – 2) – k (k -2) + 2 (2k – 8) = 0
2
= 8 – k + 2k + 4k – 16 = 0
2
⇒ - k + 6k – 8 = 0 kT 2
2 59. Ans: I−
k – 6k + 8 = 0 2
⇒ (k – 4) (k – 2) = 0
⇒ k = 2, 4 dv ( t )
∴k=2 Sol: = − k (T − t)
dt

56. Ans: p= −
3
,q=
1 V(t) = ∫ − k (T − t ) dt
2 2
k (T − t )2
+C
sin(p + 1) x + sin x 2
Sol: f(x) = ,x<0 t = 0, V(t) = I
x
= q, x = 0 kT 2
⇒I= +C
2
x + x2 − x
,x>0
3 kT 2
x2 C=I−
is continuous. 2
Therefore,
x
⇒ p + 1 + 1 = q = lim k (T − t )2 kT 2
x →0 3   +I−
x 2  x + x2 + x  V(t) =
2 2
 
1 kT 2
= ⇒ V(T) = 0 + I −
2 2
 = 5 × 10− × 2 × 1.50
5
kT 2
=I−
2 = 0.15 mV

60. Ans: 7 64. Ans: Wave moving in −x direction with speed

dy b
Sol: = y+3
dx a
dy
= dx
y(x, t) = e− ( a x + b t )
y+3 2
Sol:
log (y + 3) = x + c
This is of the form y(x, t) = f(x + vt), where
∴y+3=ce
x

x=0 y=2 ⇒ c=5 b

v= travels in negative x direction.
∴y=5e −3
x
a
∴ y (log 2) = 5 e −3
log 2

=5×2−3=7
πv 4
65. Ans:
g2
PART – B – PHYSICS
v2
1 1 Sol: Rmax =
× 15 = m s−
1
61. Ans: g
152 15
Area = π(Rmax)
2

1 1 1 πv 4
Sol: + = =
v − 2 .8 0 . 2 g2
1 15
⇒ =
v 2 .8 π
66. Ans:
2 .8 2
v=
15
v 1 Sol: Particle 1 is at equilibrium position (φ = 0).
=
u 15  π
Particle 2 is at maximum position.  φ = 
v2 1  2 
2
=
u 15 2
67. Ans: Statement – 1 is false, Statement-2 is
1 1 1
+ = true.
v u f
dv Sol: If υ ⇒ 2υ,
v2
⇒ dt = − 2 V0’ > 2V0, well known result
du u ⇒ Statement 1 is wrong.
dt Statement 2 is true.
dv v 2 du
= 2.
dt u dt 68. Ans: 45°
1 1
× 15 = m s−
[ ] [ ]
1
=
15 2 15 Sol: µ1 N̂ × K1 = µ2 N̂ × K 2 . But plane of
separation need to be XY.
62. Ans: 20 min
69. Ans: 372 K and 310 K
N0
Sol: N=
2t / T1 / 2 T2 1
Sol: 1− =
N0 N log 3 T1 6
= t /020 ⇒ t 2 = 20
3 2 2 log 2 T2 − 62 1
1− =
2 N 20(log 3 − log 2) T1 3
N0 = t /020 ⇒ t1 =
3 21 log 2 T2 5
=
20 T1 6
t2 − t1 = (log 3 − log 3 + log 2)
log 2
= 20 min T2 − 62 2
=
T1 3
63. Ans: 0.15 mV

Sol: E = Bλv
 T2 5 q0
= i.e. q’ =
T2 − 62 4 2
q0
4T2 = 5T2 − 310 = q0 cosωt
2
π
T2 = 310 K ⇒ ωt =
4
⇒ T1 = 372 K π
t= LC
4

70. Ans: 108.8 eV 75. Ans: Statement-1 is true, Statement-2 is true

and Statement -2 is not the correct
13.6 Z2  1
Sol: = 13.6 × 9 1 −  explanation of statement - 1
n2  9
8 Sol: Statement-1 is true, Statement-2 is true
= 13.6 × 9 ×
9 and Statement -2 is not the correct
= 108.8 eV explanation of statement - 1

2.7 × 10 Ω
6
71. Ans: 76. Ans: 0.052 cm

V = V0(1 − e− )
t/RC
Sol: 1
Sol: LC = = 0.01 mm
120 = 200(1 − e− )
t/RC
100
2 Reading = PSR × pitch + CSR × LC
e−
t/RC
=
5 = 0 + 52 × 0.01
t/RC
e = 2.5 = 0.52 mm
t = 0.052 cm
= 0.4 × 2.5 × 2.303
RC
⇒ R = 2.7 × 10 Ω
6 n1T1 + n2T2 + n3T3
77. Ans:
n1 + n2 + n3
1 Mv 2 (γ − 1)
72. Ans: Sol: P1V = n1KT1
2 R
P2V = n2KT2
P3V = n3KT3
Sol: Volume is constant 1 3 3 3
R mv 2 = KT1 × n1 + KT2n2 + K − T3n3
Cv = 2 2 2 2
(γ − 1) 3
1 = K(n1 + n2 + n3)T
KE = Mv 2 2
2 n1T1 + n2T2 + n3T3
∆Q = nCv ∆θ = 1 × Cv ∆θ T=
n1 + n2 + n3
KE 1 Mv 2 (γ − 1)
∴ ∆θ = =
Cv 2 R 78. Ans: −6 ε0a

2
73. Ans: 0.4π mJ Sol: V = ar + b
dV
E= − = −2ar
E = T.8π(r2 − r1 )
2 2
Sol: dr
 25 9  2 Q
= 8πT  4 − 4  4πr .E =
 10 10  ε0
= 8 × 16 × π × 0.03 × 10− Q = −4πr .2ar.ε0
4 2

= 0.4π mJ − 8πar 3ε0

ρ=
4 3
π πr
74. Ans: LC 3
4 = −6 ε0a
Sol: q’ = q0 cosωt
79. Ans: Statement 1 is true. Statement 2 is true.
q 2 and statement 2 is the correct explanation
E= 0
2C for statement – 1.
E 1 q0 2
=
2 2 2C
 Sol: Statement 1 is true. Statement 2 is true. ⇒ −2.5t = 2 v [ ] 0
6.25
and statement 2 is the correct explanation
2 6.25
for statement – 1. t=
2 .5
2 2 × 2 .5
80. Ans: g = =2
3 2 .5

3.6 × 10− m
3
Sol: mg − T = ma 86. Ans:
mR 2 a
TR = . 1
2 R Sol: P0 + ρv12 + ρgh
2
3
⇒ mg = ma 1
2 = P0 + ρv 22
2
2
⇒a= g ⇒2gh = (v2 − v1 )
2 2
3 2 2
⇒ 2gh + v1 = v2 ;
v1 = 0.4 m s− , h2 = 0.2 m
1
µ0Ι
81. Ans: ⇒ v2 = 2.0396 m s−
1
π2R
2 d12 v1
A1v1 = A2v2 ⇒ d2 =
Ι µ v2
Sol: B= Rdθ 0 sin θ
πR 2πR v1
⇒ d2 = d1.
v2
dθ •
• R
• 0 .4
= 8 × 10− ×
3
•
• • 2.0396
• •
≅ 3.6 × 10− m
3

µ0 Ι π/2

2π R ∫0
= sin θdθ
2 87. Ans: v∝x
µ0Ι
= Sol: T cosθ = mg
π2R T sinθ = F
F
82. Ans: Increases by 0.2% tanθ =
mg
R∝λ
2 x F
Sol: =
R’ ∝ λ’
2
2λ mg
∝ (1.001) λ
2 2
F∝x
∆R
R
= 0.002 ∫ vdv ∝ ∫ xdx
v ∝x
2 2
∴ 0.002 × 100
= 0.2% v∝x

1/ 2
83. Ans: First increases and then decreases. M+m
88. Ans:  
 M 
Sol: Angular momentum is conserved.
Ι decreases ω increases then Ι increases Sol: Mv1 = (M + m) v2
ω decreases. v1 M + m
=
v2 M
84. Ans: 8.4 kJ
1
(M + m)v 22 = 1 KA 22
Sol: ∆U = mC∆T 2 2
= 4184 × 20 × 0.1 1 1
= 8.4 kJ Mv1 = KA12
2
2 2
1 1
85. Ans: 2s Mv12 = KA12
2 2
2
dv
= −2.5 v A12 M M+m 
Sol: ⇒ =  
dt A 22 M+m  M 
dv
= −2.5 dt M+m
v =
M
 1/ 2 90. Ans: more than 3 but less than 6.
A1  M + m 
∴ = 
A2  M  Sol: τ = Fr = 40t − 10t
2

τ
α = = 4t − t
2
−9 Gm Ι
89. Ans:
r
dω t3
= 4 t − t 2 ⇒ ω = 2t 2 −
Gm G4 m dt 3
Sol: = (Θ At t = 0, ω = 0)
x 2
(r − x )2 At t = 6 s. ω again become zero
(r − x )2 =4 dθ t3 2t 3 t 4
2 ω= = 2t 3 − ⇒ θ− −
x dt 3 3 12
r − x = 2x ∴ θ in 6 s = (144 − 108) = 36 rad
r θ 36
x= ⇒N= = = 5.72rotation.
3 2π 2π
−Gm G4 m
V= −
r 2r
3 3
= −
Gm
(3 + 6 )
r
−9 Gm
=
r