CNG HA X HI CH NGHA VIT NAM c lp T do Hnh phc

THI TUYN SINH CAO HC NM 2009 TRNG I HC S PHM H NI Mn thi: C s l thuyt Ho hc (thi gian 180 pht khng k thi gian giao ) Cu I: 1. Hy pht biu ni dung nguyn l phn i xng v p dng nguyn l tm hm song m t trng thi c bn ca Li+ (c trnh by chi tit). 2. Cho nguyn t ho hc c Z = 26, hy trnh by: a) Chi tit v kt qu cu hnh electron ca nguyn t (c dung lng t). b) Tnh cht ho hc in hnh dng n cht ca nguyn t. c) Vi ht c s oxi ho no (ion no) bn nht ca nguyn t ? d) Tm s hng c bn ca nguyn t v ion va xt im c) 3 a) p dng h thc En = 13, 6
Z2 (theo eV), hy tnh cc tr nng lng E1, n2

E2, E3 theo kJ.mol -1 cho N +6. b) C qui lut no lin h cc tr s En vi n (n l s lng t chnh)? Qui lut phn nh quan h no v cu to nguyn t? Cu II. 1. Thc nghim cho bit: CO 2- c hnh tam gic u, 3 nh l 3 O; cc lien kt C O cng di; in tch h c gii tro u trn cc O. Hy vit cng thc cu to Lewis v p dng m hnh VSEPR gii thch kt qu thc nghim . 2. p dng ng thi thuyt lin kt ho tr (thuyt VB) v thuyt obitan phn t (thuyt MO) hy gii thch s hnh thnh lin kt Ho hc (c v y ) trong: a) N2; b) CH4 (hnh t din u, tm l C, 4 nh l 4H). 3. p dng m hnh ht chuyn ng t do trong hp th hnh ch nht mt chiu. hy tnh: a) Nng lng cc electron pi (e- )ca phn t hexatrien, C6H10, mch h theo kJ/mol; b) di sng (theo nano met, nm) ca vach ph hp th tng ng s chuyn di mt electron t HOMO ln LUMO trong phn t ny. Bit: me = 9,11.10 31 kg; c = 3.108 m.s -1; h = 6,626.10 34J.s; d = 0, 140nm.

Cu III S phn hu metan CH4 (kh) C(rn, graphit) + 2H2 (kh) c cc s liu sau y 0 ti 250C: Nhit ca phn ng, H pu = 74,85kJ / mol : Bin thin entropi ca 0 phn ng, S pu = 80, 67 J / K .mol . 1. Hy tnh hng s cn bng Kp 298K. 0 2. Tnh hng s cn bng 500C vi gi thit nhit ca phn ng, H pu khng ph thuc nhit . Hy nhn xt v chiu ca phn ng ti nhit ny. 3. Tnh phn ly ca CH4 2 p sut 0,01 bar v 1 bar ( cng 250C). 4. Hy gii thch s thay i ca phn ly theo p sut v theo c nhit . S thay i nyc ph hp vi nguynl chuyn dch cn bng Le Chatelier khng? Cu IV Phn ng izome ho xyclopropan thnh propen c thc hin 5000C. Trong mt th nghim, s chuyn ho ca xyclopropan c kho st cc p sut ban u khc nhau v kt qu c ghi trong bng sau: P0 (Torr) 200 200 400 400 600 600 Thi gian (giy 100 200 100 200 100 200 P(Torr) 186 173 373 347 559 P0 l p sut ban u v P l p sut ti thi im t ca xyclopropan ) 1. Hy xc nh bc v hng s tc phn ng. 2. Xc nh thid gian na phn ng (t1/2) 520

Cu V Cho 2 in cc Ni2+ (0,1M)/Ni v Ag+(0,1M)/Ag cng cc th kh tiu chun ln lt l -0,25V v 0,799V. 1. Hy thit lp s pin hnh thnh t hai in cc cho. Vit cc phn ng xy ra trn cng trn tng in cc v phn ng tng qut xy ra trong pin. 2. Tnh sc in ng E 250C ca pin theo iu kin cho. Khi h t ti trng thi cn bng, sc in ng ca E bng bao nhiu? 3. Tnh hng s cn bng ca phn ng tng qut. ---------------------------------------------------------------------Ghi ch: Ngi coi thi khng gii thch g thm.