S

GD&T
An

Ngh

K thi chn hc sinh gii tnh

Nm hc 2007-2008

chnh
Mn thi: Ho hc lp 12 THPT - bng a
Thi gian: 180 pht (khng k thi gian giao )

Cu 1 (5,0 im):
1. Nu hin tng, vit phng trnh phn ng xy ra trong cc trng
hp sau:
a) Trn dung dch Na2CO3 vi dung dch FeCl3.
b) Sc kh H2S n bo ho vo dung dch FeCl3 .
c) Cho ur vo dung dch Ba(OH)2 .
2. Vit cc qu trnh xy ra cc in cc v phng trnh in
phn cc dung dch sau:
a) BaCl2 (c mng ngn)
b) CuSO4
c) K2SO4
3. Gii thch hin tng st ty, tn b n mn trong khng kh m.
Cu 2 (7,0 im).
1. Cc cht hu c A, B, C, D c cng cng thc phn t C 4H6O4 u
phn ng vi dung dch NaOH theo t l mol 1:2. Trong :
- A, B u to ra mt mui, mt ru.
- C, D u to ra mt mui, mt ru v nc.
Bit rng khi t chy mui do A, C to ra th trong sn phm chy
khng c nc. Xc nh A, B, C, D v vit phng trnh phn ng vi
NaOH.
2. C th tn ti bao nhiu loi lin kt hyr trong ru etylic c ho
tan phenol. Vit cng thc biu din cc mi lin kt ny v cho bit
lin kt no bn nht, lin kt no km bn nht? Gii thch.
3. Cho 9,2g mt hp cht hu c n chc X tc dng va vi
dung dch cha 0,2mol Ag2O trong NH3 thu c 21,6g Ag. Xc nh
cng thc cu to ca X. Vit phng trnh phn ng ho hc xy ra.
Cu 3 (5,0 im). Cho 39,84g hn hp F gm Fe3O4 v kim loi M vo
dung dch HNO3 un nng, khuy u hn hp phn ng hon
ton thu c 4,48 lt kh NO2 l sn phm kh duy nht ( ktc),
dung dch G v 3,84g kim loi M. Cho 3,84g kim loi M vo 200ml
dung dch H2SO4 0,5M v KNO3 0,5M khuy u th thu c dung
dch H, kh NO duy nht. Cho dung dch NH3 d vo dung dch G thu
c kt ta K. Nung K trong khng kh n khi lng khng i thu
c 24g cht rn R.
a) Tm kim loi M (bit M c ho tr khng i trong cc phn
ng trn).
b) C cn cn thn dung dch H thu c bao nhiu gam mui
khan?
Cu 4 (3,0 im).
1. xi ho mt ru X bi xi c bt ng lm xc tc, c cht kh Y.
xi ho Y vi xc tc Pt thu c axt Z. Cho Z tc dng vi xt c mui
T. Cho T tc dng vi dung dch Ag2O/ NH3 c Ag kim loi. Tm cng
thc cu to ca X, Y, Z, T. Vit cc phng trnh phn ng.

2. Trn Y vi mt anht P c 5,9g ri un nng nh vi mt lng d

dung dch Ag2O trong NH3 thu c 2,24 lt CO2 ( ktc) v 64,8g Ag.
Xc nh cng thc cu to ca P.
( Cho Fe = 56; Al = 27; Cu = 64; N = 14; O = 16; H = 1; Ag = 108, Zn
= 65, Mg=24, C = 12, Pb = 207, K = 39)
Th sinh khng c s dng bt c ti liu g.
--------------Ht -------------H v tn th sinh:..............................................................................................
bo danh: .................................