,t:t-/

L,

-! -t -a

5 li
|\

!i

\
F-'
{
:

,!-

l-t\q i\/)iLt//t

! r-.-?,
!\

W-/i J ,t/] -i

i;p.tz") YG,39
i

v 'iD
,t i ,'r'J i ti: : ,L; ,,) {/

J-),,

*:
rr/

-jlr,,

,tb
n

r,rD,,.-i, ?,
**t
/,!

t*i,J )ubTtt,-i crt

rr J ffi.r,;

f;..i.yr,!
Ll

l'/ - r-t

t:,

-:

,' 1-a.\11. i t; LJ'-) t't

l\

a-urtl

lrttt Jtur

r-

ox!,

c/
L

ff

R.eagent ,4 undergoes an essentially irreversible

isomerization reaction that obeys first-order

kinetics.

A--+ts
Both A and B are liquids at room temperature and both have extremely high boiling points. Deterrnine the reactor volumes necessary to produce 2 million pounds of B in 7000 hr of operation:

r, 3) Irnm / { Tn a , k ) t mark)

1. If the reactor operates isothermally at 163 "C. ( 2. If the reactor operates adiabatically. (
Use the data and assumptions listed below.

Data and Assumptlons

Reaction rate expression : r : kC e R.ate constant at 163 oC : 0.8 hrActivation energy : 28,960 callg mole Heat of reaction : - 83 callg Molecular weight : 250 The heat capacities of species ,4 and B may be assumed to be identical and equal to 0.5 callg:9. Their densities may be assumed to be equal to
0.9 g/cm3.

The times necessary to filI and drain the reactor may be assumed to be equal to 10 and 12 min, respectively. It may be assumed that negligible reaction occurs during the 14 min it takes to heat the feed from the temperature at which it enters the reactor to 163 "C. After 97/, of the ,4 has been isomerized, the hot product mixture is discharged to a cooling tank.

D,, !,t,rrr

Et
?,,,

[.

T"f ll.. teo"lu" oynaLcs isrlA". dlt

,t

lb] z

S,1r

r/c_

"f *1, A l)^,ot ^o*J ?A

*)

/ tke ,f

[01",
OO

- | ro[e o! ^olr\

) (A

o*L

- /*rk ol wl' )= /"o1, ol nrle (n a ccttn'J'lt^ ,) il,o YP'^'l

(A

G (-Yr) V

de
JT
ct)

Gr&)

z
I.C *

J c"' n /V)

2^b

JI

JI

,'t ,rJ*
ry"td

*TF =

ltde

C*. C*rg1-X+)

[cn I -lg
J+

J[ z
"ln

G Ucnocr-]a)) ? .
l.
Co,

lxo

cr-r1;

fuVcn*\
-

fst

= l^
t+&F

Prbh
CI

o,4)

=-LLvrct-Io)1o'1r lc ^) cr-Xp) I.
).v

'

2 a. gLr-)

o.

I^ ., I"6 , - g. t9 ? l.:l ghrr \

I

J.

?.

lo*1,
A") tW
Cto,
r-?

lc

lr,r1

,*, =

t"q

t Lw

1
ry1 c*o
fln
Cao=

2 24 nLl
z

lsoo t',3

Cr'tl

3.1 w4" lL

%_
llCI
?ro

.t1n

Cg

ce6)tn

2 G.6*")c6-q2) -g

3'tqz

w
L

P.r*

tate

, /t*fdh

ce'V

tw\
v2
%* rlc
F Lg

Ic

Ic

V = s",otPllol.sqy i z.qrk lv,t, I r' ,,,

r
o

nJ 0"Y31

''o

dBr,r^ \oe k^,)*

oy*/v*'s

,'lt''"ally 'i

ollt tbl

"c

r5

r3

&?3q Y

2.

It,', Nholb(

ryetdlus

^AtroL^lwally
o-49

"

q!-i',L
q\n t

lR = J I
a

Jro
L c,-xe)

= }ao e'r. C'Ya t AT)

o-Ql

{r?d }o=tIJr^/-ltnr) Soj

cty

-C

-o)

r-xe)

L l^, {10

ln

*t t sl? z

a.

t;r4 ,E = *l*uo *'ll\nde rqz l'txY ffi

ghll-lc

-l;

s.

ttrJ

? I.,

et{,:gtQl,o

/Cr.nugrtl[,J'ri)].lou)l

I,
'cY\in a_u +Fru,h[u
_Zr_

Ytlad
[,,

b Jl
?*

\i = \i, + ii=tr,*il[* - itn

{= lo"

u,

7^rtrcr.PYi)lt, 5F;cta,rurlf,,1 tngbol- : ilr, atrfta[tc s,-o , l# h,, l" ,onl

la

A-ul *

Yl

d?, =o
JINN

czs

n)o
p.$?

Et 2 Ut 'Y?^:,fr"
Ui a l{,t *PVl
2-o

q.to* )J- J(fntcFt -PYl )) tq

Jl Jt

i ( trnrHi , Y\f

'".U* ti
igr

Lcr,lil{il
)

e- o

) F- (-' J# + hiJN;)- #oiili*r :1, pilivl e v*/r,1.lon *v

=o

" 4i rr '+;
fY"* ,Er"r6rf + iurv&i H
Ni = CIY
oocansl.

)iAn,

6i .,Il;p1 Ja ',4 J+ i'-r

fr
JT

=o
t/; (-to)

110 fr; = h;o( $1 *1); Ae)

9:151

dq2
{!
xA) cr,'

lrr

fi
Y1

,r,, rrioc ei "'Yi

* Vg }J+v; c4s)
c+oi Milt
i-r

=6

t{Fo

11

( p,, orir +
-T+,

fr,xo

)*

-O

Jt
410
YU

No, Jr*

V J}
4r l0

---

,fr,Hi

vi

Jl4n

' ,x
\^/

2 P^,-df L ('1 o;4;

+fr, xo-^y( ,d, lxo\ -rHe

ry)

-o
ho

lrar4t+
rn
)-

At?\t,ft) )"f
Xn

c-Ar,B s

n, C aun2
0

^l

/ i"l

IP

lvre

I '

r:

)xo otce; a Acr Xa

a

T4tn
larn

To

6-Atrn)

J[" i' = il* (L,oti; + t,r-)l*r= aC, t /lo +1"( t

sf

'*tfrlol
?-,'t6t/

lrv,,

ric,

6ilpamsJan
n

l.L3 lyr [r+il)

" X *L r ]

rr,,cr+tt)
Q'70

eX

2 T
a

I
a(,p t p \n ^' ,Z Di Lri tzl

lr(

| + frrxo \

ilil/

r-t

Y,
\9 I O ?y$ l.

T--I;
Alte

XF

Mr

ry/

f" ot
Jo
C-dpnl Xr

c,i

94
cll

1=
aln

3,

r' q,
o-4

+u

t,
L,
v

r
I

Jro ery ( ^vt w1) ( l-xA)

A3b.
19

Cl)

,v.A

kl

qrn

&)
=

lo

Cttr,)Yt.l6)K,

$n'Cn

fr"r\
V=
2Saboenl

Crp(^Et*t) ct-xn)

1.fu, R'r t,otg| erl/\qAtt<

TcK)
,dJ u.

Xs
o 9-I

lc6

to

'
,tata

looy

c luis

3. JC b

lz,ot

l9z.vG

I,

oblnul!
r lo'l

U. C3
t3"G$

o-2
o-3
o-a

bq

'3b

3.8.1?

nsc"qg
Gb

r.ct6
3.rtL,

rto''
xtr'?

3.1

z,&o

fr. 6b2 rw'2

t T=LI

o-6 o.L
o"'1
@.9

Glq.?o o3G" y0
&B

t). eq
12.

9. 36

l"b 3Jrr,'? q.$o6xt,"

b,.b ?) x rox
b"

t.q3

DvL-

qa

o-1
sq?

lt"tz
rt.91

'

&G6 69). t7

ol

166 "toll
3

t.

2v

,w'2

l2.ls

,d

t,

Y,

+e

= Jr< C'duosrJ

T;l

cl";{w,)

J}r+8:r&:t.-,'*t, wj6 12'bn ,rt2''* ,o!1 ruttl tr'l'I * ld'"" l0 + lD o.t I lrti'3* tols''
+ o.o? c r olr'49 )

i]

3.A0
,
-9-

xto13'

o6rtrt3 ffiwtohr'l
{r,}p*}o
z

=o.

tlY)
t

I"'r

ryn

-[c

to. rr:)

g;5 )

I"'n"

e.

yl:.r

[rr

u._]}
Prro ?

CBu

3Jq9 -,lwlt

rla
tro

r^r ulc B

u l,
a')lr:
3-

?q* +" = **rotfi s3"c1

Cs wooV

En

*c0 w

I aool

o.

Iob

3
"n

6*rf. ,Ro,* vDJ Re"iq tDtt a\t*L4y a'l',{,

o.tob n

6ffnt)

ry 't (r

a?,^)

-f2-1"+

*l*B) Y *
ero

Iz terr C-rL lR-T )

X6
O

T c"cl
tl,3 t?1.v

Tcxl
,d

k chr{)
o.B
x"

lb.tG
2,)G

o. I q-2
o.3
a.a
o-O

TG

)J

9 b"2
912,9

/bq.3a
,4

9.50

lG.4G

J/" O?
ub"lu lb v"23

),olSr.u

0,@2.

ao

o"v o.y o-!

oA
o-q?

Jr1.I
21q.2

Gtl .rG orc.ye

662. 3G
Gtr3. 4C

3q",.12 q ct.e2

J16.

lqc2.2e

312.t
32A 02

Gl6-s6 65 7.rl

ic

zs "7b

E@a " la

D'sc

^s,

JL',,

*s^[l , Y cr s of
lrrE)

ce?

g)?VfiX*2 alllrrc"

R..^']w rlUU

isoll,ev

nc4 alF: Plla l'uh'6