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com

Polychlorinated Biphenyls
PCB Analysis
Unique Selectivity Characteristics
Maximum Operating Temperature of 370C
Ideal for ECD & GC/MS systems

PRODUCT DATA

Carborane modified stationary phases have

been shown to demonstrate unique selectivity
characteristics towards complex mixtures of
isomers. SGE has utilized these unique
features and added 8% Phenyl to produce a
stationary phase (HT8) which is ideally suited

Phase:
Column:
Initial Temp:
Rate:
Final Temp:
Detector:
Injection Mode:
Carrier Gas:

GC/MS Analysis of PCB mixture

3
2

to the analysis of PCBs.

The low bleed nature of the HT8 column also
guarantees a low level of detection and
compatibility with a variety of detector
systems.

HT8, 0.25m
25m x 0.22mm ID
60C, 2min
12C/min
360C, 10min
Ion Trap MS
PTV
He, 15psi

10

Performance Specifications
HT8 8% Phenyl (Equiv)
Polycarborane-Siloxane
Minimum Operating Temp.: -20C
Maximum Cycling Temp.: 370C
(Polyimide)

9
11

7
1

8
12
5

13

16:40

18:20

20:00

21:40

1. PCB 18
2. PCB 31
3. PCB 28
4. PCB 52
5. PCB 44
6. PCB 70
7. PCB 101
8. PCB 110
9. PCB 149
10. PCB 153
11. PCB 138
12. PCB 180
13. PCB 170

23:00 MINUTES

Arocolor 1254
Phase:
Column:
Initial Temp:
Rate 1:
Temp 1:
Rate 2:
Temp 2:
Detector:
Carrier Gas:

30

35

40

45

50 min

HT8, 0.25m film

50m x 0.22mm ID
60C
40C/min
200C
3C/min
320C
ECD
He, 40psi

26

27

38

34

30

11

56

58

36
42
37

63

9
31
53

13

54

19
40

65

43
64

18
44
25

59

48
15

5
2 3

24
23

17
16

10

32
47

29

20

33 35

41

50

49 52

46

MINUTES

84

51

28

21
22

14

60
45

12

6 7

67

39

55

57

62 66
61

20

120

95

103

125

106

93

78
102

97

79

112
107

124

126

132

90
75
70
72

83

114
92

80
77

118

130

98
109

134
117

82
87

91

108

100

68

121

116

128

122

129

131

133

135

85
69 71 73 74 76 81

86 88 89 94

99

104 105

25

110 113 115 119

123

127

MINUTES

40

Odering Information for HT8 8% Phenyl (equiv.) Polycarborane-siloxane

Chromatogram courtesy of Environmental Institute, EC Joint Research Center, Ispra, Italy

111

PCB Congeners
1.
PCB1
2.
PCB2
3.
PCB3
4.
PCB10
5.
PCB4
6.
PCB9
7.
PCB7
8.
PCB6
9.
PCB8/5
10. PCB19
11. PCB18
12. PCB11
13. PCB17
14. PCB13
15. PCB24
16. PCB27
17. PCB15
18. PCB32
19. PCB16
20. PCB54
21. PCB23
22. PCB34
23. PCB29
24. PCB26
25. PCB25
26. PCB31
27. PCB28/53
28. PCB51
29. PCB21
30. PCB33/
45/20
31. PCB22
32. PCB46
33. PCB36
34. PCB52/69
35. PCB43
36. PCB49
37. PCB47/
48/75
38. PCB44
39. PCB59
40. PCB42
41. PCB35
42. PCB64
43. PCB71/103
44. PCB41
45. PCB37
46. PCB68
47. PCB100
48. PCB40
49. PCB57
50. PCB67
51. PCB63
52. PCB102
53. PCB95
54. PCB74
55. PCB121/
155/91
56. PCB70
57. PCB80
58. PCB66
59. PCB96/55
60. PCB84/92
61. PCB125
62. PCB90
63. PCB101
64. PCB60
65. PCB56
66. PCB152
67. PCB99
68. PCB119

69.
70.
71.
72.
73.
74.
75.
76.
77.
78.
79.
80.
81.
82.
83.
84.
85.
86.
87.
88.
89.
90.
91.
92.
93.
94.
95.
96.
97.
98.
99.
100.
101.
102.
103.
104.
105.
106.
107.
108.
109.
110.
111.
112.
113.
114.
115.
116.
117.
118.
119.
120.
121.
122.
123.
124.
125.
126.
127.
128.
129.
130.
131.
132.
133.
134.
135.

PCB83
PCB136
PCB86
PCB97
PCB89
PCB115
PCB87
PCB154
PCB85
PCB10/81
PCB151
PCB144
PCB147
PCB135
PCB77/82
PCB149
PCB124
PCB143
PCB134/
107/131
PCB123
PCB133
PCB118
PCB165
PCB146/114
PCB132/179
PCB122
PCB153
PCB176
PCB141
PCB105
PCB137
PCB130
PCB178
PCB163
PCB138
PCB160
PCB158/175
PCB187/182
PCB183/129
PCB126
PCB185
PCB159/202
PCB174/128
PCB177/201
PCB167
PCB171
PCB197
PCB173
PCB200
PCB156/172
PCB157
PCB180
PCB193
PCB191
PCB198
PCB199
PCB170
PCB190/
196/203
PCB169
PCB208
PCB207
PCB195
PCB189
PCB194
PCB205
PCB206
PCB209

Part No. 054676

ID
mm

FILM (df)
microns

12 METRE
Part No.

Description

25 METRE
Part No.

Description

50 METRE
Part No.

Description

0.22
0.32
0.53

0.25
0.25
0.50

054674
054679
054684

12QC2/HT8-0.25
12QC3/HT8-0.25
12QC5/HT8-0.5

054675
054680
054685

25QC2/HT8-0.25
25QC3/HT8-0.25
25QC5/HT8-0.5

054676
-

50QC2/HT8-0.25
-

Manufactured under licence from Hewlett-Packard Company (US Patent 4,293 and counterpart patents)

www.sge.com

SGE International Pty. Ltd.

Tel: +61 (0) 3 9837 4200
Fax: +61 (0) 3 9874 5672
email: support@sge.com

SGE Incorporated (USA)

Toll Free: 800 945 6154
Fax: +1 512 836 9159
email: usa@sge.com

SGE (France) Sarl

Tel: +33 (0) 1 6929 8090
Fax: +33 (0) 1 6929 0925
email: france@sge.com

SGE Deutschland GmbH

Tel: +49 (0) 6151 860486
Fax: +49 (0) 6151 860489
email: germany@sge.com

SGE Japan Inc.

Tel: +81 (45) 222 2885
Fax: +81 (45) 222 2887
email: sge@sgejpn.co.jp

SGE Australia Pty. Ltd.

Toll Free:1800 800 167
Fax: (03) 9874 5672
email: sales@sge.com

SGE Europe Ltd. (UK)

Tel: +44 (0) 1908 568 844
Fax: +44 (0) 1908 566 790
email: uk@sge.com

SGE (Italia) Srl.

Tel: +39 06 4429 0206
Fax: +39 06 4429 0724
email: sge.italia@tin.it

SGE China Service Centre

Tel: +86 (10) 6588 8666
Fax: +86 (10) 6588 6577
email: sge@bj.col.com.cn

SGE India
Tel: +91 (022) 471 5896
Fax: +91 (022) 471 6592
email: sgeindia@bom4.vsnl.net.in

Publication No. PD-0087-C

Rev:01 12/00

PCB ANALYSIS
Phase:
HT8, 0.25m film
Column:
50m x 0.22mm ID
Initial Temp:
90C, 1min
Rate 1:
20C/min
Temp 1:
170C, 7.5min
Rate 2:
3.5C/min
Temp 2:
285C
Rate 3:
20C/min
Temp 3:
320C
Carrier Gas:
H2, 43cm/sec
Detector:
ECD