CHEMISTRY

1. mNahlgh/h;k; Nrhjidf;F cl;gLk; Nrh;kk;

Compound which undergoes iodoform test is
a) 1-ngd;ldhy; pentanol
b) 2-ngd;lNdhd; 2-pentanone
c) 3-ngd;lNdhd; 3-pentanone
d) ngd;lNdy pentanal.
2. tpy;ypak;rd; njhFj;jy; Kiwapy; il-vj;jpy;-<jh; jahhpj;jy; !
The preparation of diethyl ether by Williamson's synthesis is a / an
a) f!f;fth; Nrh;f;if tpid nucleophilic addition reaction
b) vyf;l;"hd; fth;Nrh;f;if tpid electrophilic addition reaction
c) vyf;l;"hd; fth; gjpy#l;L tpid electrophilic substitution reaction
d) f!f;fth; gjpy#l;L tpid. nucieophilic substitution reaction.
3. fjhpy; c$;$ %f;&p'd; typikkpf;f mkpy(;f)ld; %f;Nrhdpak;
cg;igj;j!k; tpidapy; *pf+;t,
n the formation of o!oniurn salt when etherial o!ygen reacts with strong mineral acid is called
a) vyf;l;"hd; -w;wk; electronation
b) .N"hl;lhd; -w;wk; protonation
c) .N"hl;lhd; *#f;fk; deprotonation
d) *#h; *#f;fk; dehydration.
/. gpd;t!tdtw;0$; vr;Nrh;kk; %f;&p'Ndw;wj;jpd;Ngh, <j;ijy; k#j;ijy;
f#l;Nlhidj; j!k;1
Which of the following compounds is o!idised to gi"e ethyl methyl #etone $
a) 2-."g;gdhy; 2-propanol
b) 2-ngd;lNdhd; 2-pentanone
c) 1-gpa2l;ldhy; %-butanol
d) 2-gpa2l;ldhy;. 2-butanol
3. vj;jpypd; ilraidil mkpyj;ij gad;gLj;jp *#"hw;gFj;jhy; fpilg;g,
&thylene dicyanide on hydrolysis using acid gi"es
a) %f;rhypf; mkpyk; '!alic acid
b) rf;rpdpf; mkpyk; (uccinic acid
c) m4g;gpf; mkpyk; )dipic acid
d) .N"hg;gpahdpf; mkpyk; *ropionic acid.
5. /g;n"(;fy; FiwghL c$;$ g4f(;f$py; vjph;kpd; madpapd; c!t$6
The si+e of the anion in ,ren#el defect crystal is
a) N*h;kpd; madpia tpl nghpajhf 7!f;Fk; larger than the cation
b) N*h;kpd; madpia tpl rpwpajhf 7!f;Fk; smaller than the cation
c) N*h;kpd; madpapd; m$tpw;F rkkhf 7!f;Fk; e-ual in si+e
with cation
d) 7"8;Lk; nghpa m$thf 7!f;Fk;. both are larger in si+e.
9. ! *#h;kk; nfhjpf;Fk; Ngh,
When a li-uid boils. there is
a) vd;l;N"hgp ca!fpw, an increase in entropy
b) vd;l;N"hgp Fiwfpw, a decrease in entropy
c) %tpahjypd; ntg;gk; ca!fpw, an increase in heat of "apori+ation
d) fl;4yh %w;wy; mjpfhpf;fpd;w,. an increase in free eneregy
:. fpg;&; fl;4yh %w;wypy; -w;gLk; khw;wk;
Change in /ibbs free energy is gi"en by
a; /012T( b) /01-T(
c) /013T( d; /01/T(
9. N<gh; Kiwapy; mk;Nkhdpah c!thjy; 4444 *piyapy;
mjpfhpf;Fk;.
n the 1aber process the yield of ammonia is greater
a) mjpf m=j;jk; at high pressure
b) Fiw*;j m=j;jk; at low pressure
c) cah; ntg;g*piyapy; at high temperature
d) tpida2f;fp 7y;yhj Ngh,. in absence of catalyst.
1>. vyf;l;"hdpd; <hpay;.j; jd;ikia tp$f;fpath
5ual character of an electron was e!plained by
a) Nghh; 6ohr
b) n<a;rd;gh;f; 1eisenberg
c) 4. gp"hf;N$ de 6roglie
d) ghyp. *auli.
11. 2s %h;gpl;lhypy; c$;$ Nfh$ N*hLf$pd; ?(pherical nodes;
v8;8pf;if
7umber of spherical nodes in 2s orbital is
a)% b) 2 c) 3 d) 8
12. njhFjpapy; Nkyp!*;, f#+hfr; nry;@k; Ngh, madpapd; %"k;
'n mo"ing down the group. the radius of an ion.
a) Fiwfpw, decreases
b) mjpfhpf;fpd;w, increases
c) v*;jtpj khw;wKk; 7y;iy no change
d) 7it midj;,k;. all of these
13. gpd;t!tdtw;0$; v, vjph; %f;&p'Ndw;w *piyia kl;Lk;
ngw;wp!f;Fk;1
Which of the following shows negati"e o!idation state only$
a) 6r b) , c) Cl d).
1/. FN"hkpaj;jpd; nt$pf;Al;4d; vyf;l;"hd; mikg;.
The outer electronic configuration of chromium is
a) 3d
9
8s : b) 3d
;
8s
%
c) 3d
8
4s
2
d) 3d
3
4s
2
4p
1
.
15. i*l;N"h %f;Nfdp@$;$ <7'
2
-njhFjpia <71
2
njhFjpahf khw;0k;
f"8p
n nitroal#anes -7'
2
group is con"erted to -71
2
group by the reaction with
a) (n/1C b)=n dust>=n ,f$;)
c) =n / 71
8
Cl d) =n / 7a'1.
15. f#+;f8;ltw;wpy; v, Btpi8a i*l;N"h Nrh;kk;
The tertiary nitro compound is
a) 2-i*l;N"h ."g;Ngd; 2-nitropropane
b) 1-i*l;N"h ."g;Ngd; %-nitropropane
c) 1-i*l;N"h-2C 2-il nkj;jpy; ."g;Ngd; %-nitro-2. 2-dimethyl propane
d) 2-i*l;N"h-2-nkj;jpy; ."g;Ngd;. 2-nitro-2-methyl propane
19. f#+;f;f8;ltw;wpy; v, ngd;r#d; i*l;N"h -w;w tpidapy; tpid
7ilg;ngh!$hFk;
The intermediate formed in the nitration of ben+ene is
a) mh;h#dpak; madp )rrenium ion
b) fhh;Ngdpahd; Carbanion
c) %f;N&hdpak; madp '!onium ion
d) i*l;i"l; madp 7itrite ion.
1:. Df;N"hrpd; vjph;D+w;rp khw;wk; vd;g,
n"ersion of sucrose refers to
a) Df;N"hD -w;wkiljy; o!idation of sucrose
b) Df;N"hD Lf;fk; miljy; reduction of sucrose
;c) Df;N"hDC F)NfhDC kw;0k; /g;"f;Nlhrhf rpijjy hydrolysis of
sucrose to glucose and fructose
d) Df;N"hD gyg4ahjy; polymerisation of sucrose.
1E. ! ilngg;il4y; 7y;yhj,
) dipeptide does not ha"e
a) 7"8;L ngg;ilL myFf$; two peptide units
b) 7"8;L mkpNdh mkpy gFjpf$; portions of two amino acids
c) ! mkpNlh njhFjp an amido group
d) cg;. Nghd;wnjh! mikg;. salt li#e structure.
2>. tpidNtfr; rkd;ghl;4y; c$;$ nrwp6f$pd; mLf;Ff$pd; ALjy;
The sum of the powers of the concentration terms that occur in the rate e-uation is called
a) Byf;A0 v8; molecularity
b) tpidtif order
c) tpidNtfk; rate
d) tpidNtf rate constant.
21. 4d;lhy; tpi$tpw;F cl;glhj,
The phenomenon of Tyndall effect is not obser"ed in
a) ghy;kk; emulsion
b) A+;k fi"ry; colloidal solution
c) nka; fi"ry; true solution
d) njh(;fy suspension .
22. 4fhd; ?5eacon; Kiwapy; FN$hhpd; jahhpj;jypy;
tpidNtfkhw;wpahf nray;gLt,
Catalyst used in 5eacon's method of manufacture of chlorine is
a) 7' -b) CuC
2
c) ,e
2
?
3
d) 7i.
23. mh;'p"hy; vd;g,
)rgyrol is
a) rpy;th; A+;kk; colloidal sil"er
b) %d;4kdp A+;kk; colloidal antimony
c) Nfhy;L A+;kk; colloidal gold
d) nkf;d#rpah ghy;kk; mil# of magnesia.
2/. rpy;th; *h8aj;jpyp!*;, rpy;ti"g; ng0jypy; Kjypy; *h8aj;,ld;
Nrh;f;fg;gLk; f"8p
The reagent which is added first in the separation of sil"er from sil"er coin is
a) mlh; ry;/g;a2hpf; mkpyk; conc. sulphuric acid
b) mlh; i<l;N"hFN$hhpf; mkpyk; conc. hydrochloric acid
;c) mlh; i*l;hpf; mkpyk conc. nitric acid
;d) 7"h' jp"htk )-ua regia.
25. 4444 %f;N&h N*h; madpfi$ c!thf;Ffpw,.
------------------------- ,orms o!ocations
a) yh*;jidLf$; @anthamide
b) %f;4idLf$; )ctinides
c) cahpa thFf;f$; 7oble gases
d) fh" cNyhf(;f$;. )l#ali metals