CODE
PAPER2
P2148
2207548
Note: Front and back cover pages are reproduced from actual paper back to back here.
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INSTRUCTIONS
A.
1.
2.
3.
4.
5.
6.
7.
8.
9.
B.
10.
11.
12.
13.
C.
14.
15.
16.
General
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Question Paper Format
The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists of two sections.
Section 1 contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONE is correct.
Section 2 contains 3 paragraphs each describing theory, experiment and data etc. Six questions relate to three
paragraphs with two questions on each paragraph. Each question pertaining to a particular passage should have only
one correct answer among the four given choices (A), (B), (C) and (D).
Section 3 contains 4 multiple choice questions. Each questions has two lists (Lits1: P, Q, R and S; List2, : 1,
2, 3, and 4). The options for the correct match are provided as (A), (B), (C) and (D) out of which ONLY one is
correct.
Please read the last page of this booklet for rest of the instructions.
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JEE(ADVANCED)2014Paper2PCM2
PAPER2 [Code 8]
JEE(ADVANCED) 2014
PARTI: PHYSICS
SECTION 1 : (Only One Option Correct Type)
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE option is correct.
1.
Charges Q, 2Q and 4Q are uniformly distributed in three dielectric solid spheres 1, 2 and 3 of radii R/2, R
and 2R respectively, as shown in figure. If magnitudes of the electric fields at point P at a distance R from
the centre of spheres 1, 2 and 3 are E1, E2 and E3 respectively, then
P
P
R
P
R
2Q
4Q
R/2
2R
Sphere 1
Sphere 2
Sphere 3
C
For point outside dielectric sphere E
Q
4 0 r 2
r
R
Exact Ratio E1 : E2 : E3 = 2 : 4 : 1
2.
A glass capillary tube is of the shape of truncated cone with an apex angle so that its two ends have cross
sections of different radii. When dipped in water vertically, water rises in it to a height h, where the radius
of its cross section is b. If the surface tension of water is S, its density is , and its contact angle with glass
is , the value of h will be (g is the acceleration due to gravity)
2S
(A)
cos( )
bg
(B)
2S
cos( )
bg
(C)
2S
cos( / 2)
bg
(D)
2S
cos( / 2)
bg
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JEE(ADVANCED)2014Paper2PCM3
Sol.
D
If R be the meniscus radius
R cos ( + /2) = b
2S
Excess pressure on concave side of meniscus =
R
2S 2S
hg
cos
R
b
2
2S
h
cos
bg
2
+ (/2)
/2
3.
If cu is the wavelength of K Xray line of copper (atomic number 29) and Mo is the wavelength of the K
Xray line of molybdenum (atomic number 42), then the ratio cu/Mo is close to
(A) 1.99
(B) 2.14
(C) 0.50
(D) 0.48
Sol.
B
Cu ZMo 1
Mo ZCu 1
4.
A planet of radius R =
1
(radius of Earth) has the same mass density as Earth. Scientists dig a well of
10
R
on it and lower a wire of the same length and of linear mass density 103 kgm1 into it. If the wire
5
is not touching anywhere, the force applied at the top of the wire by a person holding it in place is (take the
radius of Earth = 6 106 m and the acceleration due to gravity of Earth is 10 ms2)
(A) 96 N
(B) 108 N
(C) 120 N
(D) 150 N
depth
Sol.
B
Inside planet
r 4
g i g s Gr
R 3
Force to keep the wire at rest (F)
= weight of wire
R
4
4
9
dr Gr G R 2
3
3
50
4R /5
Me
Here, = density of earth =
4
R 2e
3
R
Also, R e ; putting all values, F = 108 N
10
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JEE(ADVANCED)2014Paper2PCM4
5.
A tennis ball is dropped on a horizontal smooth surface. It bounces back to its original position after hitting
the surface. The force on the ball during the collision is proportional to the length of compression of the
ball. Which one of the following sketches describes the variation of its kinetic energy K with time t most
appropriately? The figures are only illustrative and not to the scale.
(A)
(B)
K
(C)
(D)
K
Sol.
B
d KE
dt
mv
dv
dt
6.
A metal surface is illuminated by light of two different wavelengths 248 nm and 310 nm. The maximum
speeds of the photoelectrons corresponding to these wavelengths are u1 and u2, respectively. If the ratio
u1 : u2 = 2 : 1 and hc = 1240 eV nm, the work function of the metal is nearly
(A) 3.7 eV
(B) 3.2 eV
(C) 2.8 eV
(D) 2.5 eV
Sol.
A
hc
1
u2
12
hc
u2
2
= 3.7 eV
7.
A wire, which passes through the hole in a small bead, is bent in the form of quarter of a circle. The wire is
fixed vertically on ground as shown in the figure. The bead is released from near the top of the wire and it
slides along the wire without friction. As the bead moves from A to B, the force it applies on the wire is
A
(A) always radially outwards.
(B) always radially inwards.
(C) radially outwards initially and radially inwards later.
(D) radially inwards initially and radially outwards later.
90
Sol.
D
Initially bead is applying radially inward normal force.
During motion at an instant, N = 0, after that N will act radially outward.
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JEE(ADVANCED)2014Paper2PCM5
8.
During an experiment with a metre bridge, the galvanometer shows a null point when the jockey is pressed
at 40.0 cm using a standard resistance of 90 , as shown in the figure. The least count of the scale used in
the metre bridge is 1 mm. The unknown resistance is
90
(A) 60 0.15
Sol.
40.0cm
(B) 135 0.56
(C) 60 0.25
C
Alternatively
x
90
100 x
R 60
R
dR 0.1 0.1
R
40 60
dR = 0.25
dR
100
dx
R (x) (100 x)
dR
100
0.1 60
(40) (60)
= 0.25
9.
Parallel rays of light of intensity I = 912 Wm2 are incident on a spherical black body kept in surroundings
of temperature 300 K. Take StefanBoltzmann constant = 5.7108 Wm2 K4 and assume that the energy
exchange with the surroundings is only through radiation. The final steady state temperature of the black
body is close to
(A) 330 K
(B) 660 K
(C) 990 K
(D) 1550 K
Sol.
A
Rate of radiation energy lost by the sphere
= Rate of radiation energy incident on it
4r 2 T 4 (300) 4 912 r 2
T 11 102 330 K
10.
Sol.
Liquid
Block
S
(D) 1.42
C
r 5.77
3
h
10
C 30
Liquid
tan C
sin C
r
C
2.72
1
1.36
2
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JEE(ADVANCED)2014Paper2PCM6
S
d
Wire I
Wire 2
a
11.
When d a but wires are not touching the loop, it is found that the net magnetic field on the axis of the
loop is zero at a height h above the loop. In that case
(A) current in wire 1 and wire 2 is the direction PQ and RS, respectively and h a
(B) current in wire 1 and wire 2 is the direction PQ and SR, respectively and h a
(C) current in wire 1 and wire 2 is the direction PQ and SR, respectively and h 1.2a
(D) current in wire 1 and wire 2 is the direction PQ and RS, respectively and h 1.2a
Sol.
C
The net magnetic field at the given point will be zero if.
Bwires Bloop
2
0 I
0 Ia 2
2 (a 2 h 2 )3/ 2
2 a 2 h 2
a2 h2
h 1.2 a
The direction of magnetic field at the given point due to the loop is normally out of the plane. Therefore,
the net magnetic field due the both wires should be into the plane. For this current in wire I should be along
PQ and that in wire RS should be along SR.
12.
Consider d >> a, and the loop is rotated about its diameter parallel to the wires by 30 from the position
shown in the figure. If the currents in the wires are in the opposite directions, the torque on the loop at its
new position will be (assume that the net field due to the wires is constant over the loop)
I2a 2
I2a 2
3 0 I 2 a 2
3 0 I 2 a 2
(A) 0
(B) 0
(C)
(D)
d
2d
d
2d
Sol.
B
MBsin Ia 2 2
I2a 2
0 I
sin 30 0
2 d
2d
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JEE(ADVANCED)2014Paper2PCM7
Consider the partition to be rigidly fixed so that it does not move. When equilibrium is achieved, the final
temperature of the gases will be
(A) 550 K
(B) 525 K
(C) 513K
(D) 490 K
Sol.
D
3
Heat given by lower compartment = 2 R (700 T) ...(i)
2
7
Heat obtained by upper compartment = 2 R (T 400) ...(ii)
2
equating (i) and (ii)
3 (700 T) = 7 (T 400)
2100 3T = 7 T 2800
4900 = 10 T T = 490 K
at eq. TK
400 K
700 K
14.
Now consider the partition to be free to move without friction so that the pressure of gases in both
compartments is the same. Then total work done by the gases till the time they achieve equilibrium will be
(A) 250 R
(B) 200 R
(C) 100 R
(D) 100 R
Sol.
D
5
Heat given by lower compartment = 2 R (700 T)
2
7
Heat obtained by upper compartment = 2 R (T 400)
2
By equating (i) and (ii)
5(700 T) 7(T 400)
3000 5T = 7T 2800
6300 = 12 T
T = 525K
Work done by lower gas = nRT = 350 R
Work done by upper gas = nRT = +250 R
Net work done 100 R
...(i)
...(ii)
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JEE(ADVANCED)2014Paper2PCM8
If the piston is pushed at a speed of 5 mms1, the air comes out of the nozzle with a speed of
(A) 0.1 ms1
(B) 1 ms1
(C) 2 ms1
(D) 8 ms1
Sol.
C
By A1V1 = A2V2
(20) 2 5 (1)2 V2
V2 2 m/s 2
16.
If the density of air is a and that of the liquid , then for a given piston speed the rate (volume per unit
time) at which the liquid is sprayed will be proportional to
a
(A)
(B) a
(C)
(D)
Sol.
A
1
1
a Va2 V2
2
2
For given Va
a
V
This section contains four questions, each having two matching lists. Choices for the correct combination of
elements from ListI and ListII are given as option (A), (B), (C) and (D) out of which one is correct.
17.
A person in a lift is holding a water jar, which has a small hole at the lower end of its side. When the lift is
at rest, the water jet coming out of the hole hits the floor of the lift at a distance d of 1.2 m from the person.
In the following, state of the lifts motion is given in List I and the distance where the water jet hits the
floor of the lift is given in List II. Match the statements from List I with those in List II and select the
correct answer using the code given below the lists.
List I
List II
Lift is accelerating vertically up.
P.
1. d = 1.2 m
Lift is accelerating vertically down 2. d > 1.2 m
Q.
with an acceleration less than the
gravitational acceleration.
Lift is moving vertically up with
R.
3. d < 1.2 m
constant speed.
Lift is falling freely.
S.
4. No water leaks out of the jar
Code:
(A) P2, Q3, R2, S4
(B) P2, Q3, R1, S4
(C) P1, Q1, R1, S4
(D) P2, Q3, R1, S1
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JEE(ADVANCED)2014Paper2PCM9
Sol.
C
In P, Q, R no horizontal velocity is imparted to falling water, so d remains same.
In S, since its free fall, aeff = 0
Liquid wont fall with respect to lift.
18.
Four charges Q1, Q2, Q3 and Q4 of same magnitude are fixed along the x axis at x = 2a, a, +a and +2a,
respectively. A positive charge q is placed on the positive y axis at a distance b > 0. Four options of the
signs of these charges are given in List I. The direction of the forces on the charge q is given in List II.
Match List I with List II and select the correct answer using the code given below the lists.
(+0, b)
List I
List II
q
Q1, Q2, Q3 Q4 all positive
P.
1. +x
Q1, Q2 positive; Q3, Q4 negative
Q.
2. x
Q1, Q4 positive ; Q2, Q3 negative
R.
3. +y
Q1, Q3 positive; Q2, Q4 negative
S.
4. y
Q1
(2a, 0)
Code:
(A) P3, Q1, R4, S2
(C) P3, Q1, R2, S4
Sol.
Q3
(+a, 0)
Q4
(+2a, 0)
A
P: By Q1 and Q4, Q3 and Q2 F is in +y
Q: By Q1 and Q4, Q2 and Q3 F is in +ve x.
R: By Q1 and Q4, F is in +ve y
(+0, b)
By Q2 and Q3, F is in ve y
But later has more magnitude, since its closer to
(0, b). Therefore net force is in y
S: By Q1 and Q4, F is in +ve x and by Q2 and Q3, F is
in x, but later is more in magnitude, since its
closer to (0, b). Therefore net force is in ve x.
19.
Q2
(a, 0)
Q1
(2a, 0)
Q2
(a, 0)
Q3
(+a, 0)
Q4
(+2a, 0)
Four combinations of two thin lenses are given in List I. The radius of curvature of all curved surfaces is r
and the refractive index of all the lenses is 1.5. Match lens combinations in List I with their focal length in
List II and select the correct answer using the code given below the lists.
List I
List II
P.
1. 2r
Q.
2.
r/2
R.
3.
S.
4.
Code:
(A) P1, Q2, R3, S4
(C) P4, Q1, R2, S3
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JEE(ADVANCED)2014Paper2PCM10
Sol.
B
1
1
1
1
f
R1 R 2
f=R
Use
20.
f = 2R
f = 2R
1
1 1
f eq f1 f 2
(P)
1
1 1 2
R
; f eq
f eq R R R
2
(Q)
1
1
1
1
; f eq R
f eq 2R 2R R
(R)
1
1
1
1
; feq =  R
f eq
2R 2R
R
(S)
1
1
1
1
; feq = 2R
f eq R 2R 2R
A block of mass m1 = 1 kg another mass m2 = 2kg, are placed together (see figure) on an inclined plane
with angle of inclination . Various values of are given in List I. The coefficient of friction between the
block m1 and the plane is always zero. The coefficient of static and dynamic friction between the block m2
and the plane are equal to = 0.3. In List II expressions for the friction on the block m2 are given. Match
the correct expression of the friction in List II with the angles given in List I, and choose the correct option.
The acceleration due to gravity is denoted by g.
[Useful information: tan (5.5) 0.1; tan (11.5) 0.2; tan (16.5) 0.3]
m1
m2
List I
P.
= 5
Q.
= 10
R.
= 15
S.
= 20
Code:
(A) P1, Q1, R1, S3
(B) P2, Q2, R2, S3
(C) P2, Q2, R2, S4
(D) P2, Q2, R3, S3
1.
2.
3.
4.
List II
m2g sin
(m1+m2) g sin
m2g cos
(m1 + m2)g cos
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JEE(ADVANCED)2014Paper2PCM11
Sol.
D
Condition for not sliding,
fmax > (m1 + m2) g sin
N > (m1 + m2) g sin
0.3 m2 g cos 30 sin
6 30 tan
1/5 tan
0.2 tan
for P, Q
f = (m1 + m2) g sin
For R and S
F = fmax = m2g sin
m1g cos
m2g cos
m1
m2
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JEE(ADVANCED)2014Paper2PCM12
PAPER2 [Code 8]
JEE(ADVANCED) 2014
PARTII: CHEMISTRY
SECTION 1: (Only One option correct Type)
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
21.
Assuming 2s 2p mixing is NOT operative, the paramagnetic species among the following is
(A) Be2
(B) B2
(C) C2
(D) N2
Sol.
C
Assuming that no 2s2p mixing takes place
A Be2 1s 2 , *1s 2 , 2s 2 , *2s 2 diamagnetic
B B2
22.
(diamagnetic )
2p y
1
C C2
D N2
2p y
2p y
* 2p0x
, * 2p 0z
* 2p0y
* 2p0x
, * 2p 0z
* 2p0y
(paramagnetic)
(diamagnetic)
Sol.
B
H 2 O g is at equilibrium. For equilibrium Stotal 0
At 1000C and 1 atmosphere pressure H 2 O
and
Ssystem Ssurrounding 0
23.
For the elementary reaction M N, the rate of disappearance of M increases by a factor of 8 upon
doubling the concentration of M. The order of the reaction with respect to M is
(A) 4
(B) 3
(C) 2
(D) 1
Sol.
B
n
r1 1 M
n 3
r2 8 2M n
24.
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JEE(ADVANCED)2014Paper2PCM13
Sol.
D
N=NPh
OH
OH
Ph N N Cl
alkaline solution
25.
Isomers of hexane, based on their branching, can be divided into three distinct classes as shown in the
figure.
[Figure]
II
and
III
and
Sol.
B
III > II > I
More the branching in an alkane, lesser will be the surface area, lesser will be the boiling point.
26.
CH3
(A)
2. aqueous acid
(B)
O
H3C
H2C
CH3
(C)
CH3
CH3
(D)
O
Sol.
OH
CH3
CH2
CH3
D
OH
Cl
OMgX
CH 3MgBr, dry ether, 0 C
CH3
Cl
aqueous acid
CH3
CH3
CH3
CH3
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JEE(ADVANCED)2014Paper2PCM14
27.
Under ambient conditions, the total number of gases released as products in the final step of the reaction
scheme shown below is
Complete
Hydrolysis
XeF6
P other product
OH / H 2 O
Q
slow disproportionation in OH / H 2 O
products
(A) 0
(C) 2
Sol.
(B) 1
(D) 3
C
XeF6 3H 2 O
XeO3 3H 2 F2
OH
HXeO 4
OH / H 2 O (disproportionation)
XeO64 s Xe g H 2 O O2 g
28.
Sol.
A
P4s 8SOCl 2
4PCl3 4SO2 g 2S2 Cl 2g
29.
Hydrogen peroxide in its reaction with KIO4 and NH2OH respectively, is acting as a
(A) reducing agent, oxidising agent
(B) reducing agent, reducing agent
(C) oxidising agent, oxidising agent
(D) oxidising agent, reducing agent
Sol.
A
KIO4 H 2 O 2
KIO3 H 2O O 2
NH 2 OH 3H 2 O2
HNO3 4H 2 O
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JEE(ADVANCED)2014Paper2PCM15
30.
acid
OR
(A)
(B)
(C)
(D)
Sol.
OH ROH
C
When two phenyl groups are replaced by two para methoxy group, carbocation formed will be more stable
SECTION 2: Comprehension Type (Only One Option Correct)
This section contains 3 paragraphs, each describing theory, experiments, data etc. Six questions relate to the
three paragraphs with two questions on each paragraph. Each question has only one correct answer among
the four given options (A), (B), (C) and (D).
Paragraph For Questions 31 and 32
X and Y are two volatile liquids with molar weights of 10 g mol1 and 40 g mol1 respectively. Two cotton plugs,
one soaked in X and the other soaked in Y, are simultaneously placed at the ends of a tube of length L = 24 cm, as
shown in the figure. The tube is filled with an inert gas at 1 atmosphere pressure and a temperature of 300 K.
Vapours of X and Y react to form a product which is first observed at a distance d cm from the plug soaked in X.
Take X and Y to have equal molecular diameters and assume ideal behaviour for the inert gas and the two vapours.
L = 24 cm
Cotton wool
soaked in X
Initial formation of
the product
Cotton wool
soaked in Y
31.
Sol.
C
rX
d
40
2
rY 24 d
10
d = 48 2d
3d = 48
d 16cm
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32.
The experimental value of d is found to be smaller than the estimate obtained using Grahams law. This is
due to
(A) larger mean free path for X as compared to that of Y.
(B) larger mean free path for Y as compared to that of X.
(C) increased collision frequency of Y with the inert gas as compared to that of X with the inert gas.
(D) increased collision frequency of X with the inert gas as compared to that of Y with the inert gas.
Sol.
D
As the collision frequency increases then molecular speed decreases than the expected.
Paragraph For Questions 33 and 34
Schemes 1 and 2 describe sequential transformation of alkynes M and N. Consider only the major products formed
in each step for both schemes.
1. NaNH 2 excess
2. CH CH I 1 equivalent
3
2
H
X
3. CH 3 I 1 equivalent
Scheme 1
HO
1. NaNH 2 2 equivalent
2.
OH
Br
Y
3.H O , mild
Scheme 2
4. H 2 , Pd /C
5. CrO3
33.
The product X is
(A) H3 CO
(B)
H
(C)
H3 CO
(D)
CH3 CH2 O
CH3 CH2 O
Sol.
34.
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JEE(ADVANCED)2014Paper2PCM17
Sol.
C
Solution for the Q. No. 33 to 34.
H
HO
NaNH
CH CH I
3
2
M
H3 CO
H , Lindlar 's catalyst
CH I
H
X
OH
Br
NaNH
2
H
1 equivalent
NaNH 2 1eq
OH
H
H 2 , Pd/C
CrO3
mild
OH
X and Y are functional isomers of each other and Y gives iodoform test.
Paragraph For Questions 35 and 36
An aqueous solution of metal ion M1 reacts separately with reagents Q and R in excess to give tetrahedral and
square planar complexes, respectively. An aqueous solution of another metal ion M2 always forms tetrahedral
complexes with these reagents. Aqueous solution of M2 on reaction with reagent S gives white precipitate which
dissolves in excess of S. The reactions are summarized in the scheme given below.
SCHEME:
Q
R
Tetrahedral
M1
Square planar
excess
excess
Q
R
Tetrahedral
excess M 2
excess Tetrahedral
S,stoichiometricamount
S
White precipitate
excess precipitate dissolves
35.
Sol.
36.
Reagent S is
(A) K 4 Fe CN 6
(B) Na 2 HPO4
(C) K 2 CrO4
(D) KOH
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JEE(ADVANCED)2014Paper2PCM18
Sol.
D
Solution for the Q. No. 35 to 36.
HCl Q
KCN R
Ni 2
Ni CN 4
NiCl4 2
excess
excess
M
1
Tetrahedral
ZnCl4
Tetrahedral
square planar
HCl Q
excess
KCN R
excess
Zn 2
Zn CN 4
M2
Tetrahedral
KOH
S
KOH
Zn OH 2
Zn OH 4
excess
White ppt.
Soluble
Match each coordination compound in ListI with an appropriate pair of characteristics from ListII and
select the correct answer using the code given below the lists
{en = H2NCH2CH2NH2; atomic numbers: Ti = 22, Cr = 24; Co= 27; Pt = 78)
List I
List  II
P.
[Cr(NH3)4Cl2]Cl
1.
Q.
[Ti(H2O)5Cl](NO3)2
2.
R.
[Pt(en)(NH3)Cl]NO3
3.
S.
[Co(NH3)4(NO3)2]NO3
4.
Code:
(A)
(B)
(C)
(D)
Sol.
B
(P)
(Q)
(R)
(S)
P
4
3
2
1
Q
2
1
1
3
R
3
4
3
4
S
1
2
4
2
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JEE(ADVANCED)2014Paper2PCM19
38.
Match the orbital overlap figures shown in ListI with the description given in ListII and select the correct
answer using the code given below the lists.
List I
List  II
P.
1.
p d antibonding
Q.
2.
d d bonding
R.
3.
p d bonding
S.
4.
d d antibonding
Code:
(A)
(B)
(C)
(D)
Sol.
P
2
4
2
4
Q
1
3
3
1
R
3
1
1
3
S
4
2
4
2
P.
d d bonding
Q.
p d bonding
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JEE(ADVANCED)2014Paper2PCM20
R.
S.
39.
p d antibonding
d d antibonding
Different possible thermal decomposition pathways for peroxyesters are shown below. Match each
pathway from List I with an appropriate structure from List II and select the correct answer using the code
given below the lists.
P
CO 2
CO 2
O
R
R'
(Peroxyester)
S
R R 'O
R R 'O
R X carbonyl compound
RCO 2 R 'O
R X ' carbonyl compound
CO 2
RCO 2 R 'O
R R 'O
CO2
List I
P.
List II
Pathway P
1.
O
O
Q.
Pathway Q
2.
C6 H5 CH2
O
CH3
O
C6 H5
R.
Pathway R
O
O
3.
CH3
CH3
O
O
C6 H5 CH2
S.
Pathway S
4.
CH3
CH2 C6 H5
O
O
C6 H5
O
C6 H5
CH3
CH3
Code:
(A)
(B)
(C)
(D)
P
1
2
4
3
Q
3
4
1
2
R
4
3
2
1
S
2
1
3
4
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JEE(ADVANCED)2014Paper2PCM21
Sol.
A
(P) 1; (Q) 3; (R) 4; (S) 2
O
(P)
C6 H 5 C H 2 CO 2 CH 3O
O
H 5 C6 H2 C
CH3
(Q)
H5 C6 H 2 C
O
O
CH3
O
CH3
C6 H5 C H 2 CO 2 Ph CH 2 C CH 3

CH3
CH2C6H5
Ph C H 2 CH 3 CO CH 3
(R)
C6 H5
CH3
O
CH3
C6 H5 C O 2 CH3 C CH 3

CO2
Ph CH 3 CO Ph
CH3
C6 H5
C6 H5
(S)
C6 H 5 C O2 CH 3O
O
C6H5
40.
C6 H5 CO2
CH3
Match the four starting materials (P, Q, R, S) given in List I with the corresponding reaction schemes
(I, II, III, IV) provided in List II and select the correct answer using the code given below the lists.
List I
List  II
P.
1.
Scheme
I
H
H
i KMnO4 , HO
, heat ii H , H 2 O
iii SOCl iv NH
2
3
?
C7 H 6 N 2 O3
OH
2. Scheme II
i Sn / HCl ii CH3 COCl iii conc. H2 SO4
iv HNO v dil. H SO , heat vi HO
3
2
4
?
C6 H 6 N 2 O 2
Q.
OH
NO 2
3. Scheme III
i red hot iron, 873 K ii fu min g HNO 3 , H 2SO 4 , heat
2
3
2
2
4
?
C6 H 5 NO 3
iii H S.NH iv NaNO , H SO
R.
v hydrolysis
NO 2
4. Scheme IV
i conc. H 2SO4 , 60 C
ii conc. HNO3 , conc. H 2SO4 iii dil. H 2SO4 , heat
?
C6 H5 NO 4
S.
CH3
Code:
(A)
(B)
(C)
(D)
P
1
3
3
4
Q
4
1
4
1
R
2
4
2
3
S
3
2
1
2
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JEE(ADVANCED)2014Paper2PCM22
Sol.
C
(P)
NH2
NO2
red hot
3CH CH
iron873K
H S.NH
NaNO2
H SO
2
3
selective reduction
fuming HNO /H SO
3
2
4
NO2
NO2
+
N2 HSO4.
OH
Hydrolysis
NO2
(Q)
NO2
OH
OH
O2 N
O2 N
N O2
Conc.H 2SO 4
600 C
dil.H 2SO 4
OH
OH
SO3 H
NHCOCH3
NHCOCH3
NH2
NO2
OH
OH
SO3H
(R)
OH
OH
NHCOCH3
NO2
conc.H 2SO 4
Sn/ HCl
HNO3
CH3COCl
SO 3H
SO3 H
dil. H 2SO 4
NHCOCH3
NH2
NO2
NO2
OH
(S)
NO2
NO2
H O
KMnO 4
OH/
CH3
NO2
3
COO
NO2
NO2
SOCl2
COOH
NH
COCl
CONH2
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JEE(ADVANCED)2014Paper2PCM23
PAPER2 [Code 8]
JEE(ADVANCED) 2014
PARTIII: MATHEMATICS
SECTION 1 : (Only One Option Correct Type)
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE option is correct.
41.
Three boys and two girls stand in a queue. The probability, that the number of boys ahead of every girl is at
least one more than the number of girls ahead of her, is
1
1
(A)
(B)
2
3
3
2
(C)
(D)
3
4
Sol.
A
Either a girl will start the sequence or will be at second position and will not acquire the last position as
well.
3 C1 2 C1 = 1 .
Required probability =
5
2
C2
*42.
In a triangle the sum of two sides is x and the product of the same two sides is y. If x2 c2 = y, where c is
the third side of the triangle, then the ratio of the inradius to the circumradius of the triangle is
3y
3y
(A)
(B)
2x x c
2c x c
(C)
Sol.
3y
4x x c
(D)
3y
4c x c
B
x=a+b
y = ab
x2 c2 = y
a 2 b2 c 2
1
cos 120
2ab
2
2
C =
3
abc
R=
,r=
4
s
1
2
4 ab sin
2
2
r
4
3
xc
R s abc
yc
2
3y
r
.
R 2c x c
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JEE(ADVANCED)2014Paper2PCM24
*43.
Six cards and six envelopes are numbered 1, 2, 3, 4, 5, 6 and cards are to be placed in envelopes so that
each envelope contains exactly one card and no card is placed in the envelope bearing the same number and
moreover the card numbered 1 is always placed in envelope numbered 2. Then the number of ways it can
be done is
(A) 264
(B) 265
(C) 53
(D) 67
Sol.
The common tangents to the circle x2 + y2 = 2 and the parabola y2 = 8x touch the circle at the points P, Q
and the parabola at the points R, S. Then the area of the quadrilateral PQRS is
(A) 3
(B) 6
(C) 9
(D) 15
Sol.
D
(2, 4)
Area = 1 4 3 2 15
2
(1, 1)
(1, 1)
(2, 4)
*45.
The quadratic equation p(x) = 0 with real coefficients has purely imaginary roots. Then the equation
p(p(x)) = 0 has
(A) only purely imaginary roots
(B) all real roots
(C) two real and two purely imaginary roots
(D) neither real nor purely imaginary roots
Sol.
D
P (x) = ax2 + b with a, b of same sign.
P(P(x)) = a(ax2 + b)2 + b
If x R or ix R
x2 R
P (x) R
P(P(x)) 0
Hence real or purely imaginary number can not satisfy P(P(x)) = 0.
46.
/ 2
17
2cosec x
dx is equal to
/ 4
log 1 2
(A)
log 1 2
u
2 e e
16
du
(B)
log 1 2
(C)
e u
17
du
e
0
log 1 2
u
17
du
(D)
2 eu e u
16
du
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JEE(ADVANCED)2014Paper2PCM25
Sol.
2
17
2 cosec x
dx
u = ln 1 2 , x =
u=0
4
2
eu e u
cosec x + cot x = eu and cosec x cot x = eu cot x
2
(eu eu) dx = 2 cosec x cot x dx
Let eu + eu = 2 cosec x, x =
u 17
ln 1 2
ln 1 2
e u
2 cosec x cot x
= 2
16
e u
du
du
2 eu e u
16
du
47.
dy
xy
x4 2 x
2
in (1, 1) satisfying
dx x 1
1 x2
3
2
f (0) = 0. Then
f x dx is
Sol.
(A)
3 2
(B)
3 4
(C)
6 4
(D)
6 2
B
dy
x
x 4 2x
2
y
dx x 1
1 x2
This is a linear differential equation
x
ln x 2 1
2 dx
I.F. = e x 1 e 2
1 x2
solution is
x x3 2
2
y 1 x
1 x 2 dx
1 x2
or y 1 x 2 x 4 2x dx =
x5
x2 c
5
f (0) = 0 c = 0
f (x) 1 x 2
x5
x2
5
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JEE(ADVANCED)2014Paper2PCM26
3/2
3/2
f x dx
Now,
3/2
3/2
= 2
3 /2
/3
x2
1 x2
dx = 2
0
x2
1 x2
dx (Using property)
sin 2
cos d (Taking x = sin )
cos
/3
3
3
sin 2
= 2 sin 2 d 2
= 2 2
.
6
8
3
4
2
4
0
0
/3
48.
Let f : [0, 2] R be a function which is continuous on [0, 2] and is differentiable on (0, 2) with f(0) = 1.
x2
Let F x
f t dt
for x [0, 2]. If F(x) = f (x) for all x (0, 2), then F(2) equals
(A) e2 1
(C) e 1
Sol.
(B) e4 1
(D) e4
B
F(0) = 0
F(x) = 2x f(x) = f(x)
f(x) = e x
f(x) = e x ( f(0) = 1)
x2
F(x) =
e dx
0
F(x) = e x 1 ( F(0) = 0)
F(2) = e4 1
*49.
Sol.
C
2x1 + 3x2 + 4x3 = 11
Possibilities are (0, 1, 2); (1, 3, 0); (2, 1, 1); (4, 1, 0).
Required coefficients
= (4C0 7C1 12C2) + (4C1 7C3 12C0) + (4C2 7C1 12C1) + (4C4 7C1 1)
= (1 7 66) + (4 35 1) + (6 7 12) + (1 7)
= 462 + 140 + 504 + 7 = 1113.
*50.
Sol.
D
sin x + 2 sin 2x sin 3x = 3
sin x + 4 sin x cos x 3 sin x + 4 sin3 x = 3
sin x [2 + 4 cos x + 4(1 cos2 x)] = 3
sin x [2 (4 cos2 x 4 cos x + 1) + 1] = 3
sin x [3 (2 cos x 1)2] = 3
sin x = 1 and 2 cos x 1 = 0
x and x
2
3
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JEE(ADVANCED)2014Paper2PCM27
53
105
1
(D)
2
(B)
Sol.
B
Case I : One odd, 2 even
Total number of ways = 2 2 3 + 1 3 3 + 1 2 4 = 29.
Case II: All 3 odd
Number of ways = 2 3 4 = 24
Favourable ways = 53
53
53
Required probability =
.
3 5 7 105
52.
Sol.
C
Here 2x2 = x1 + x3
x1 + x3 = even
Hence number of favourable ways = 2C1 4C2 + 1C1 3C1 = 11.
Paragraph For Questions 53 and 54
Let a, r, s, t be nonzero real numbers. Let P(at2, 2at), Q, R(ar2, 2ar) and S(as2, 2as) be distinct points on the
parabola y2 = 4ax. Suppose that PQ is the focal chord and lines QR and PK are parallel, where K is the point (2a, 0).
*53.
The value of r is
(A)
(C)
1
t
1
t
(B)
t2 1
t
(D)
t2 1
t
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JEE(ADVANCED)2014Paper2PCM28
Sol.
D
Slope (QR) = Slope (PK)
2a
2ar
2at 0
t
a
at 2 2a
ar 2
2
t
1
r
t
t2 1
2
t
r
t
t 2
1 r2
2
*54.
If st = 1, then the tangent at P and the normal at S to the parabola meet at a point whose ordinate is
t
(A)
(B)
2t 3
a t2 1
(C)
Sol.
a t2 1
2
2t 3
a t2 2
(D)
t3
t3
B
Tangent at P: ty = x + at2 or y =
x
at
t
x 2a a
t
t t3
2a a
Solving, 2y = at +
t t3
Normal at S: y
a t2 1
y=
2t 3
1 t a 1 dt
Sol.
1
The value of g is
2
(A)
(C)
2
(B) 2
(D)
4
A
1
g lim
2 h0
1 h
t 1/ 2 1 t
1/ 2
dt
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JEE(ADVANCED)2014Paper2PCM29
dt
tt
dt
1 1
t
4 2
= sin1 1 sin1( 1) = .
0
t 2
1
= sin
1
2 0
1
The value of g is
2
(A)
2
(C)
2
56.
Sol.
(B)
(D) 0
D
We have g (a) = g (1 a) and g is differentiable
1
Hence g = 0.
2
SECTION 3 : Matching List Type (Only One Option Correct)
This section contains four questions, each having two matching list. Choices for the correct combination of
elements from ListI and ListII are given as options (A), (B), (C) and (D), out of which ONE is correct.
57.
(P)
List II
(1)
(2)
(3)
(4)
f x dx 1 , is
0
(Q)
3x2
1 e
(R)
dx equals
1/2
1 x
cos 2 x log
dx
1 x
1/2
equals
1/2
1 x
cos 2 x log
dx
1 x
0
(S)
Codes:
(A)
(B)
(C)
(D)
P
3
2
3
2
Q
2
3
2
3
R
4
4
1
1
S
1
1
4
4
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JEE(ADVANCED)2014Paper2PCM30
Sol.
D
1
f x dx 1
0
2a + 3b = 6
(a, b) (0, 2) and (3, 0).
x2 = 2n +
x=
9
,
as x 3,
4
4
(R)
2n
4
3x 2
3x 2
0 1 ex 1 e x
13 .
dx
3x 2 dx 8 .
1/ 2
(S)
58.
1 x
cos 2x ln
dx 0 as it is an odd function.
1 x
1/ 2
List II
3
. Then
2
(1)
a
=
a ak 1 , then the minimum
k
k
1
k 1
k 1 k
(2)
(3)
(4)
(P)
d 2 y x
dy x
1 2
x
x 1
equals
2
y x
dx
dx
(Q)
*(R)
value of n is
If the normal from the point P(h, 1) on the ellipse
2
x
y
1 1
1 2
tan 1
tan
tan 2 is
2x 1
4x 1
x
(S)
Codes:
(A)
(B)
(C)
(D)
P
4
2
4
2
Q
3
4
3
4
R
2
3
1
1
S
1
1
2
3
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JEE(ADVANCED)2014Paper2PCM31
Sol.
A
(P) y = cos (3 cos1 x)
3sin 3 cos 1 x
y =
1 x2
1 x 2 y 3sin 3 cos 1 x
x
1 x
y 1 x 2 y 3 cos 3 cos 1 x .
xy + (1 x2) y = 9y
3
1 x2
1
x 2 1 y xy 9 .
2
n
2
ak ak+1 = r 2 cos
n
n 1
n 1
a k a k 1 a k a k 1
k 1
k 1
2
2
r2 (n 1) sin
r 2 n 1 cos
n
n
2
8
tan
1 n =
n = 8.
n
4k 1
h 2 12
(R)
1, h = 2
6 3
2x y
Tangent at (2, 1) is
1 x + y = 3.
6 3
1
2
1
1
(S) tan 1
tan 1 2
tan
4x 1
x
2x 1
3x 1
1 2
tan 1 2
tan
4x
3x
x2
3x2 7x 6 = 0
2
x = , 3.
3
59.
List I
(P)
(Q)
(R)
(S)
f4 is
f3 is
f2 o f1 is
f2 is
(1)
(2)
(3)
(4)
x0
x0
List II
onto but not oneone
neither continuous nor oneone
differentiable but not oneone
continuous and oneone
Codes:
(A)
(B)
(C)
(D)
P
3
1
3
1
Q
1
3
1
3
R
4
4
2
2
S
2
2
4
4
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website: www.fiitjee.com.
JEE(ADVANCED)2014Paper2PCM32
Sol.
D
x 2 , x 0
f2 (f1) =
2x
, x 0
e
f4: R [0, )
f 2 f1 x
, x0
f4(x) =
f 2 f1 x 1 , x 0
x 2
, x0
=
2x
e 1 , x 0
y =f1(x)
y = f2(x)
y = f3(x)
y =f2(f1(x))
y = f4(x)
2k
2k
Let zk = cos
i sin
; k = 1, 2, . , 9.
10
10
*60.
List I
For each zk there exists a zj such zk . zj = 1
(P)
(Q)
1 z1 1 z2 .... 1 z9
(R)
10
1
(S)
9
k 1
List II
(1)
True
(2)
False
(3)
(4)
equals
2k
cos
equals
10
Codes:
(A)
(B)
(C)
(D)
P
1
2
1
2
Q
2
1
2
1
R
4
3
3
4
S
3
4
4
3
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website: www.fiitjee.com.
JEE(ADVANCED)2014Paper2PCM33
Sol.
C
(P) zk is 10th root of unity zk will also be 10th root of unity. Take zj as zk .
z
(Q) z1 0 take z = k , we can always find z.
z1
10
(R) z 1 = (z 1) (z z1) (z z9)
(z z1) (z z2) (z z9) = 1 + z + z2 + + z9 z complex number.
Put z = 1
(1 z1) (1 z2) (1 z9) = 10.
(S) 1 + z1 + z2 + + z9 = 0
Re (1) + Re (z1) + + Re (z9) = 0
Re (z1) + Re (z2) + + Re (z9) = 1.
9
2k
1 cos
2.
10
k 1
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website: www.fiitjee.com.
JEE(ADVANCED)2014Paper2PCM34
CODE 5
D.
17.
Marking Scheme
For each question in Section 1, 2 and 3 you will be awarded 3 marks if you darken only the bubble
corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases, minus one
(1) mark will be awarded.
Part darkening
Figure1 : Correct way of bubbling for a valid answer and a few examples of invalid answers.
Any other form of partial marking such as ticking or crossing the bubble will be invalid.
5
8
9
8
9
Figure2 : Correct Way of Bubbling your Roll Number on the ORS. (Example Roll Number : 5045231)
Name of the Candidate
Roll Number
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website: www.fiitjee.com.
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