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5. Electrochemistry
1) Define Conductor?
Ans:
Conductor:
Substances which allow the flow of electric current through them are called conductor.
Eg: Metals, fused salts, aqueous solutions of Acids, Bases and Salts
2) Define Insulator?
Ans:
Insulator:
Substances which do not allow the flow of electric current through them are called insulator.
Eg: All Non-metals except carbon, wood, rubber, paper.
3) Write about types of conductors?
Ans:
Types of conductors:
There are two types of conductors.
They are
1) Metallic conductors (or) electronic conductors
2) Electrolytic conductors (or) Ionic conductors.
4) Define Metallic conductors:
Ans:
1) Metallic conductors:
a) Conductors which allow flow of electric current through them due to movement of electrons
are called metallic conductors (or) Electronic conductors.
Eg: metals (Al, Cu, Fe), alloys
b) In these conductors conductivity of current by the flow of electrons from cathode to anode.
c) In metallic conductors no chemical reactions occur due to flow of current.
d) They do not involve the transfer of matter.
e) The conductivity decreases with the increase.
Electrochemistry
Metallic Conductors
a) Conductors which allow flow of electric
current through them due to movement of
electrons are called metallic conductors (or)
Electronic conductors.
Eg: metals (Al, Cu, Fe), alloys
Electrolytic conductors
a) Conductors which allow flow of electric
current through them due to movement of ions
in the fused state (or) in solution are called
electrolytic conductors (or) Ionic conductors.
Eg: Acids, Bases and Salts.
Electrochemistry
Eg:
Ag + N O 3
+
Undissociated
ions
Molecule
5. When electricity is passed through the electrolyte, cations moves towards cathode and
anions move towards anode
6. The ions discharge at cathode and anode.
No . of Molecules dissociated into ions
7. Degree of Ionization () =
Total No. of molecules
8. The properties an electrolyte in solution are the properties of ions.
10) Write about Electrolysis with figure?
Ans:
Electrolysis:
Electro = EMF and lysis = decomposition
The process of decomposition of an electrolyte by the passage of electricity is called electrolysis.
In this process electrical energy converted into chemical energy.
The vessel in which electrolysis is carried out is known as electrolytic cell.
The electrolyte is taken in the cell in the form of solution or in molten state.
Two metal plates are placed in electrolyte, which act as electrodes.
The electrodes are connected with copper wire to the two terminals of a battery.
When electricity is passed through the electrolyte the ions towards oppositely charged electrodes.
Chemical reactions occur at the electrodes and products are formed.
Prepared by V Naga Surendra Reddy
Lecturer in chemistry
Electrochemistry
MA M+n + A-n
M+n + neM (Reduction at cathode)
-n
A
A + ne- (oxidation at anode)
Electrolysis of fused Sodium Chloride (NaCl):
Fused NaCl is taken as an electrolyte in an electrolytic cell.
Two platinum rods are dipped in it, act as electrodes.
They are connected to the two terminals of a battery.
The electrode connected to the +ve terminal is called anode and the electrode connected to the
ve terminal is called cathode.
When electricity is passed through the electrolyte, the Na+ ions move towards cathode, get
discharged forming Na atoms.
The Na atoms deposited on the cathode.
Similarly Cl- ions move towards anode, get discharged forming Cl atoms.
Two Cl atoms combine and liberates Cl2 gas
Reactions in the cell
NaCl
Na+ + ClNa+ + eCl-Cl + e
2Cl
Na (at cathode)
(at anode)
Cl2 (at anode)
Electrochemistry
m Ct But Q = Ct
m eCt
Where m = mass of substance deposited
Q = Quantity of electricity in coulombs = ampere/second
t = time in seconds
e = electro chemical equivalent
c = current in amperes.
E
ct
m = 96500
Where E = Chemical equivalent.
Electro chemical equivalent (e):
The mass of an element deposited at an electrode by passing one coloumb of electricity is called
electro chemical equivalent.
m
m = eQ (or) e = Q (or) e =
m
Ct
Electrochemistry
m1 m2
=
E 1 E2
Where m1 = mass of first element
m2 = mass of second element
E1 = chemical equivalent of first element
E2 = chemical equivalent of second element
Explanation:
If the same quantity of current passed through three electrolytes cells connected in series,
containing dilute H2SO4, CuSO4, and AgNO3 solutions then the masses of H2, Cu and Ag
deposited at the cathode will be in the ratio of their chemical equivalents.
M H : M Cu : M Ag=E H : E Cu : E Ag
2
= 1: 31.75: 108
Electrochemistry
The salt bridge is a U shaped tube containing agar agar gel saturated with an electrolyte KCl
or KNO3 or NH4NO3.
Working of the cell:
1. Whenever Zn and Cu electrodes are connected with a copper wire through a voltmeter, an
oxidation takes place at Zn half-cell and reduction takes place at Cu half-cell.
2. Zn undergoes oxidation, hence Zn electrode is anode. It is indicated ve sign.
Zn
Zn+2 + 2e- (oxidation at anode)
3. Cu electrode undergoes reduction, hence Cu electrode is cathode. It is indicated + ve
sign.
Cu+2 + 2eCu (Reduction at anode)
4. The voltmeter measures the emf of the cell.
5. Salt bridge prevents the accumulation of charges at the electrodes and proceed the
reactions spontaneously.
Cell is represented as Zn/Zn+2(1m)//Cu+2(1m)/Cu
Electrochemistry
17) Write the Differences between electrolytic cell and Galvanic Cell:
Electrolytic cell
1). Chemical reaction takes place by the
Galvanic Cell
1). Electricity is generated due to the chemical
to anode.
6). A salt bridge is not required.
cathode.
6). A salt bridge is required.
Electrochemistry
Zn
Cu
H2
Electrochemistry
= Eright ELeft
23) Define Electro Chemical series and write about the significance?
Ans:
Electro Chemical series:
The arrangement of electrodes in the increasing order of their standard reduction potentials is
called Electro Chemical series.
In this series the top most electrode is Li and the bottom electrode is fluorine.
Significance of Electro Chemical Series:
1) The metal which is higher in electro chemical series acts as reducing agent (or) anode and
undergoes corrosion first.
2) Metals above hydrogen are called active metals, which candisplace hydrogen from dilute
acids and water
Eg: Zn + 2HCl
ZnCl2 + H2
3) The metals below Hydrogen are less reactive.
They do not liberate H2 from dilute acids and water.
4) The metal with higher negative potential displaces a metal with lower negative potential
or positive potential from the salt solution of the metal.
Eg:Zn + CdSO
ZnSO + Cd
4
(aq)
(aq)
5) The reactivity (or) reducing character decreases from top to bottom
Li is strongest reducing agent.
F is strongest oxidizing agent.
Series:
Li+/Li
K+/K
Ca+2/Ca
Na+/Na
Zn+2/Zn
Fe+2/Fe
Cd+2/Cd
CO+2/CO
Ni+2/Ni
Sn+2/Sn
Pb+2/Pb
H+/H2
Cu+2/Cu
O2/OHI2/IAg2/AgBr2/BrCl2/Cl-
- Ve Values
0 (Zero)
+ Ve Values
10
Electrochemistry