Professional Documents
Culture Documents
(PHYS393)
0. Background
1. Basic statistics
Dr Kai Hock
University of Liverpool
0. Background
PHYS393/Hock 1 2009-2010
What this course is about.
PHYS393/Hock 2 2009-2010
Recommended texts
PHYS393/Hock 3 2009-2010
Required Background
Physics
1. Thermodynamics (PHYS253)
http://en.wikipedia.org/wiki/Mole_(unit)
PHYS393/Hock 4 2009-2010
Required Background
Maths
http://en.wikipedia.org/wiki/Antiderivative
2. Statistics
http://en.wikipedia.org/wiki/Expected_value
http://en.wikipedia.org/wiki/Variance
http://en.wikipedia.org/wiki/Binomial_distribution
3. Lagrange multipliers
http://en.wikipedia.org/wiki/Lagrange_multipliers
PHYS393/Hock 5 2009-2010
Table of Integrals
Z ∞
2 2 n!
x2n+1e−a x dx =
0 2a2n+2
(2n)!π 1/2
Z ∞
2n −a2 x2
x e dx =
−∞ n!(2a)2na
Z ∞ 1/2
x
x
dx = 2.32
0 e −1
Z ∞ 3/2
x
x
dx = 1.78
0 e −1
x3 π4
Z ∞
x
dx =
0 e −1 15
PHYS393/Hock 6 2009-2010
Physical constants
Electron rest mass me 9.109 × 10−31 kg
Proton rest mass mp 1.6726 × 10−27 kg
Atomic mass unit u 1.6605 × 10−27 kg
Electronic charge e 1.6022 × 10−19 C
Speed of light in free space c 2.9979 × 108 m s−1
Planck’s constant h 6.626 × 10−34 J s
h/2π = ~ 1.0546 × 10−34 J s
Boltzmann’s constant kB 1.3807 × 10−23 J K−1
Gas constant R 8.314 J mol−1 K−1
Avogadro constant NA 6.022 × 1023 mol−1
Standard molar volume 22.414 × 10−3 m3 mol−1
Bohr magneton µB 9.274 × 10−24 J T−1
Nuclear magneton µn 5.051 × 10−27 J T−1
Stefan’s constant σ 5.671 × 10−8 W m−2 K−4
Gravitational constant G 6.673 × 10−11 N m2 kg−2
Proton magnetic moment µp 2.7928µN
Neutron magnetic moment µp −1.9130µN
Acceleration due to gravity g 9.807 m s−2
Permeability of free space µ0 4π × 10−7 H m−1
Permittivity of free space 0 8.854 × 10−12 F m−1
PHYS393/Hock 7 2009-2010
CONTENTS
1. Basic statistics.
2. Distinguishable particles.
5. Electrons in metals.
PHYS393/Hock 8 2009-2010
Part 1: Statistical Mechanics
PHYS393/Hock 9 2009-2010
1. Basic statistics
PHYS393/Hock 10 2009-2010
Contents
PHYS393/Hock 11 2009-2010
Aim
Objectives
PHYS393/Hock 12 2009-2010
Contents
PHYS393/Hock 13 2009-2010
Why coin tossing?
We often use the familiar coin tossing to develop the
techniques. There is a rather broad analogy with the quantum
mechanics:
PHYS393/Hock 14 2009-2010
Defining some terms
H = head
T = tail
and so on.
PHYS393/Hock 15 2009-2010
Level of description
1. Macrostate.
2. Microstate.
PHYS393/Hock 16 2009-2010
The most probable macrostate.
x Macrostate Microstates
0 4T TTTT
1 1H3T TTTH, TTHT, THTT, HTTT
2 2H2T HHTT, HTHT, THHT, THTH, TTHH, HTTH
3 3H1T HHHT, HHTH, HTHH, THHH
4 4H HHHH
PHYS393/Hock 17 2009-2010
Some calculations
Let
N!
Ω= (1)
n!(N − n)!
PHYS393/Hock 18 2009-2010
Contents
PHYS393/Hock 19 2009-2010
Very large number of tosses
PHYS393/Hock 20 2009-2010
Basic ideas in probability and statistics
P (0) = 1/4
P (1) = 2/4
P (2) = 1/4
PHYS393/Hock 21 2009-2010
Mean and standard deviation
PHYS393/Hock 22 2009-2010
If we know the probaility distribution P (x), we can also
calculate the mean and standard deviation without actually
tossing the coin.
It is given by
r
(x − µ)2P (x).
X
σ=
PHYS393/Hock 23 2009-2010
When the standard deviation is small
PHYS393/Hock 25 2009-2010
Coin tossing and a cup of tea
PHYS393/Hock 26 2009-2010
The total number of H would then be the total energy, or
temperature. We would of course expect this total to be quite
different each time we toss.
PHYS393/Hock 27 2009-2010
The binomial distribution
http://en.wikipedia.org/wiki/Binomial_distribution
PHYS393/Hock 28 2009-2010
Mean and standard deviation
x=0
It looks like the number of heads changes more from one toss
to the next, as the number of coins is increased.
PHYS393/Hock 32 2009-2010
The dotted curve is the smallest N , the solid curve the largest
N . Notice that the peak gets narrower for large N .
PHYS393/Hock 34 2009-2010
What we have learnt so far.
PHYS393/Hock 35 2009-2010
Some exercises
Exercise 1
Answer
x P (x)
0 0.36
1 0.48
2 0.16
PHYS393/Hock 36 2009-2010
Some exercises
x x−µ (x − µ)2
0 -0.8 0.64
1 0.2 0.04
2 1.2 1.44
√
= 0.64 × 0.36 + 0.04 × 0.48 + 1.44 × 0.16 = 0.48.
PHYS393/Hock 37 2009-2010