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a force.
Non-Newtonian fluids do not undergo strain rates proportional to
the applied shear stress.
Newtonian fluids undergo strain rates proportional to the applied shear stress.
In a mechanical view, a fluid is a substance that does not support shear stress;
that is why a fluid at rest has the shape of its containing vessel. A fluid at
rest has no shear stress.
Assumptions[edit]
Balance for some integrated fluid quantity in a control volume enclosed by a con
trol surface.
Like any mathematical model of the real world, fluid mechanics makes some basic
assumptions about the materials being studied. These assumptions are turned into
equations that must be satisfied if the assumptions are to be held true.
For example, consider a fluid in three dimensions. The assumption that mass is c
onserved means that for any fixed control volume (for example a sphere)
enclosed
by a control surface the rate of change of the mass contained is equal to the r
ate at which mass is passing from outside to inside through the surface, minus t
he rate at which mass is passing the other way, from inside to outside. (A speci
al case would be when the mass inside and the mass outside remain constant). Thi
s can be turned into an equation in integral form over the control volume.[1]
Fluid mechanics assumes that every fluid obeys the following:
Conservation of mass
Conservation of energy
Conservation of momentum
The continuum hypothesis, detailed below.
Further, it is useful at low subsonic speeds to assume that a gas is incompressi
ble that is, the density of the gas does not change even though the speed and st
atic pressure change.
Similarly, it can sometimes be assumed that the viscosity of the fluid is zero (
the fluid is inviscid). If a fluid is viscous, and its flow contained in some wa
y (e.g. in a pipe), then the flow at the boundary must have zero velocity. For a
viscous fluid, if the boundary is not porous, the shear forces between the flui
d and the boundary results also in a zero velocity for the fluid at the boundary
. This is called the no-slip condition. For a porous media otherwise, in the fro
ntier of the containing vessel, the slip condition is not zero velocity, and the
fluid has a discontinuous velocity field between the free fluid and the fluid i
n the porous media (this is related to the Beavers and Joseph condition).
Continuum hypothesis[edit]
Main article: Continuum mechanics
Fluids are composed of molecules that collide with one another and solid objects
. The continuum assumption, however, considers fluids to be continuous. That is,
properties such as density, pressure, temperature, and velocity are taken to be
well-defined at "infinitely" small points, defining a REV (Reference Element of
Volume), at the geometric order of the distance between two adjacent molecules
of fluid. Properties are assumed to vary continuously from one point to another,
and are averaged values in the REV. The fact that the fluid is made up of discr
ete molecules is ignored.
The continuum hypothesis is basically an approximation, in the same way planets
are approximated by point particles when dealing with celestial mechanics, and t
herefore results in approximate solutions. Consequently, assumption of the conti
nuum hypothesis can lead to results which are not of desired accuracy. However,
under the right circumstances, the continuum hypothesis produces extremely accur
ate results.
Those problems for which the continuum hypothesis does not allow solutions of de
sired accuracy are solved using statistical mechanics. To determine whether or n
ot to use conventional fluid dynamics or statistical mechanics, the Knudsen numb
er is evaluated for the problem. The Knudsen number is defined as the ratio of t
he molecular mean free path length to a certain representative physical length s
cale. This length scale could be, for example, the radius of a body in a fluid.
(More simply, the Knudsen number is how many times its own diameter a particle w
ill travel on average before hitting another particle). Problems with Knudsen nu
mbers at or above one are best evaluated using statistical mechanics for reliabl
e solutions.
Navier Stokes equations[edit]
Main article: Navier Stokes equations
The Navier Stokes equations (named after Claude-Louis Navier and George Gabriel St
okes) are the set of equations that describe the motion of fluid substances such
as liquids and gases. These equations state that changes in momentum (force) of
fluid particles depend only on the external pressure and internal viscous force
s (similar to friction) acting on the fluid. Thus, the Navier Stokes equations des
cribe the balance of forces acting at any given region of the fluid.
The Navier Stokes equations are differential equations which describe the motion o
f a fluid. Such equations establish relations among the rates of change of the v
ariables of interest. For example, the Navier Stokes equations for an ideal fluid
with zero viscosity states that acceleration (the rate of change of velocity) is
proportional to the derivative of internal pressure.
This means that solutions of the Navier Stokes equations for a given physical prob
lem must be sought with the help of calculus. In practical terms only the simple
st cases can be solved exactly in this way. These cases generally involve non-tu
rbulent, steady flow (flow does not change with time) in which the Reynolds numb
er is small.
For more complex situations, involving turbulence, such as global weather system
s, aerodynamics, hydrodynamics and many more, solutions of the Navier Stokes equat
ions can currently only be found with the help of computers. This branch of scie
nce is called computational fluid dynamics.
General form of the equation[edit]
The general form of the Cauchy momentum equation is:
\rho {\frac {D\mathbf {u} }{Dt}}=\nabla \cdot {\boldsymbol {\sigma }}+\rho \math
bf {f}
where
\rho \ is the fluid density,
{\frac {D}{Dt}} is the substantive derivative (also called the material derivati
ve),
\mathbf {u} is the flow velocity vector,
\mathbf {f} is the specific body force vector, and
{\boldsymbol {\sigma }} is the stress tensor.
Unless the fluid is made up of spinning degrees of freedom like vortices, {\bold
symbol {\sigma }} is a symmetric tensor. In Navier Stokes equations the stress t
ensor can be decomposed as
{\boldsymbol {\sigma }}_{ij}=-p\delta _{ij}+\tau _{ij}
where -p\delta _{ij} is a static isotropic stress state (that would exist if the
fluid were at rest), and \tau _{ij} is the deviatoric stress tensor, correspond
ing to the part of the stress due to the fluid motion. Generally, the scalar p c
an be taken as the thermodynamic pressure, whereas \tau _{ij} is called the visc
ous stress tensor. Furthermore, the diagonal components of tensor \mathbf {\tau
} are called normal stresses and the off-diagonal components are called shear s
tresses.
The vectorial Cauchy equation above can be written then as
\rho {\frac {D\mathbf {u} }{Dt}}=-\nabla p+\nabla \cdot \mathbf {\tau } +\rho \m
athbf {f}
This is actually a set of three equations, one per dimension. By themselves, the
se equations are not sufficient to produce a solution. However, adding other con
servation laws and appropriate boundary conditions to the system of equations pr
oduces a solvable set of equations. The conservation of mass provides another eq
uation relating the density and the flow velocity:
{\frac {\partial \rho }{\partial t}}+\nabla \cdot (\rho \mathbf {u} )=0
On the other hand, the identification of p with the thermodynamic pressure is us
ually possible (unless the fluid is not in thermodynamic equilibrium; such situa
tion is however rare [e.g. shock waves]). Therefore, a thermodynamic equation of
state must be used to connect the pressure with the density and another state p
roperty, such as temperature or enthalpy. This in turn brings another unknown to
the problem so that an equation for conservation of thermal energy must also be
solved along with momentum and mass conservations.
In the case of an incompressible fluid there is no relationship between the pres
sure and the density. The Navier Stokes equations and mass conservation are then s
ufficient to determine the solution to a fluid mechanics problem. Actually, the
absolute pressure in an incompressible fluid is indeterminate, and only its grad
ient is relevant for the equations of motion. Taking the divergence of the Navie
r Stokes equation and using the mass conservation equation to simplify the result
gives a Poisson equation for the pressure.
Additionally, in order to close the system of equations a constitutive equation
relating the viscous stress tensor to the velocity field must be introduced. Thi
s constitutive model, which depends on the nature of the fluid, is the basis for
the distinction between Newtonian and non-Newtonian fluids.
Newtonian versus non-Newtonian fluids[edit]
A Newtonian fluid (named after Isaac Newton) is defined to be a fluid whose shea
r stress is linearly proportional to the velocity gradient in the direction perp
endicular to the plane of shear. This definition means regardless of the forces
acting on a fluid, it continues to flow. For example, water is a Newtonian fluid
, because it continues to display fluid properties no matter how much it is stir
red or mixed. A slightly less rigorous definition is that the drag of a small ob
ject being moved slowly through the fluid is proportional to the force applied t
o the object. (Compare friction). Important fluids, like water as well as most g
ases, behave
to good approximation
as a Newtonian fluid under normal conditions
on Earth.[2]
By contrast, stirring a non-Newtonian fluid can leave a "hole" behind. This will
gradually fill up over time this behaviour is seen in materials such as pudding
, oobleck, or sand (although sand isn't strictly a fluid). Alternatively, stirri
ng a non-Newtonian fluid can cause the viscosity to decrease, so the fluid appea
rs "thinner" (this is seen in non-drip paints). There are many types of non-Newt
onian fluids, as they are defined to be something that fails to obey a particula
r property for example, most fluids with long molecular chains can react in a no
n-Newtonian manner.[2]