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18.
9.
10.
14.
work
19.
20.
21.
22.
23.
24.
25.
dP
(c) dT
(a)
17.
dV
(d) dE
(b)
26.
27.
28.
H E
(b)
H E
(c)
H E
4.
(b) S
(c) G
E and H is
(a) H E P V
(c)
5.
E V H
(a)
12.
(b) U 0, w 0
(c) U 0, w 0
(d) U 0, w 0
Consider
the
reaction
N 2 3H 2 2NH 3
H E
(c) H E P V (d) E H P V
H 0
(c) H U
(a)
14.
15.
H U
(d) H U
(b)
(b) W U Q
(c) U W Q
(a) Reaction
(b) Formation
(c) Transition
16.
10.
1
O2(g) CO2(g)
2
(a) H E P V
9.
8.
(d)
(c) H E
7.
(d) E H P V
(b) H E
6.
(c)
(d)
(b) H E P V
CO(g)
11.
(b)
of
mechanical
and
chemical
E RT
(b)
E 2RT
(c)
E RT
(d)
E 2RT
17.
(b) Negative
(c) Zero
(d) None
18.
27.
mass
20. The enthalpies of the elements in their standard
states are assumed to be
(a) Zero at 298 K
(b) Unit at 298 K
(c) Zero at all temperatures
(d) Zero at 273 K
21.
22.
23.
24.
(b) H R H P
(c) E P E R
(b) E q W
(c) E q W
(d) E q W
H E W
(c) E W H
(a)
29.
30.
31.
32.
E H
(a) N 2O 4 (g) 2NO2 (g)
In which of the following
(c)
34.
(b)
W E
E 0
(d)
W0
and 1 atm.
(b) Endothermic
(c) One with negligible enthalpy change
(a) 874 kJ
35.
W E
25.
1
O2 (g) H 2O(l)
2
2.0103
W E H
E H W
(d) H 2 (g)
33.
1/T (K1)
(d)
6.0
1.5103
(b)
(H ) and work
2.0
160
(b) 871.53 kJ
(c) 876.47 kJ
(d) + 874 kJ
In a closed insulated container, a liquid is stirred
with a paddle to increase its temperature. In this
process, which of the following is true
(a) E W Q 0
(b) E 0, Q W 0
45.
H E is
at constant temperature,
38.
44.
(b) + RT
(d) + 3RT
46.
H E
(c) H E
48.
42.
H 0
(b)
S 0
E 0
(d)
W0
At
49.
and q are (R 2)
(a) 25 J
(c) 32 J
(b) 30 J
(d) 28 J
E o
of
combustion
(c)
50.
of
isobutylene
. The value of H
(a) E o
is
is
(b) E o
(d) E o
(CV 20 J / K )
(a) 100 K
(c) 195 K
51.
(b) 150 K
(d) 255 K
Enthalpy (H ) is equal to
X kJ mol
H E
1
O2 (g) H 2O(l)
(d) H 2 (g)
2
41.
(b)
E H
(a) N 2O4 (g) 2NO2 (g)
(c) H 2 (g) Cl 2 (g) 2HCl(g)
(a)
(c) 500 J
(d) 600 J
Work done during isothermal expansion of one
mole of an ideal gas from 10 atom. to 1 atm at
300K is
(a) 4938.8 J
(b) 4138.8 J
(c) 5744.1 J
(d) 6257.2 J
If gas, at constant temperature and pressure
expands then its
(a) Entropy increases and then decreases
(b) Internal energy increases
(c) Internal energy remains the same
(d) Internal energy decreases
(b)
47.
52.
N2O4 2NO2
(a)
H E
(b)
H E
(c)
H 0
(d)
H E
in
2C O2 2CO; H 220kJ
Which of the following statement is correct for this
reaction
4.
55.
56.
5.
6.
7.
(d)
pressure
of
1L atm 101.32 J )
(a) + 304 J
(c) 6 J
58.
For
the
3atm
is
T
(c) E
10.
E
T
q
(c)
T
(a)
2.
3.
(b)
S is
P V
T
(d) RT log K
rd
(a) + 540.3
(b) + 727.3
(c) 166.9
(d) + 19.8
Which of the following is the least random state of
water
(a) Ice
(b) Liquid water
(c) Steam
(d) All present same random state
Which one of the following process is nonspontaneous
(a) Dissolution of CuSO4 in water
8.
(b) 304 J
(d) 608 J
reaction,
H E
162
11.
12.
(b)
T
(2 / 3)
(c) T
14.
15.
(b) T +
2
3 0.0821
(d) T
2
3 0.0821
x
373
(b)
18x
100
(c)
18x
373
(d)
1 18x
2 373
16.
(d)
24.
1
J/mol K
88.3
S will be
25.
E 0
H E
(b)
(d)
the
reaction
at
H 0
H TS
steam,
water
at
37.3 J mol
26.
(b)
27.
(c)
28.
(a)
(b)
(c)
(d)
position
H
H TS
(b) H
(a)
is +ve ;
is ve ;
H TS
is also + ve but
S is also ve
but
H is ve ; S is + ve
(d) H is + ve ; S is ve
19.
(c)
1
(a) Ca(s) O2 (g) CaO(s)
2
18.
Predict
(a) Spontaneous
(b) Reversible
(c) Irreversible
(d) Non-spontaneous
The total entropy change for a system and its
surroundings increases, if the process is
(a) Reversible
(b) Irreversible
(c) Exothermic
(d) Endothermic
For chemical reactions, the calculation of change
in entropy is normally done
(a) At constant pressure
(b) At constant temperature
(c) At constant temperature and pressure both
(d) At constant volume
When the value of entropy is greater, then the
ability of work
(a) Is maximum
(b) Is minimum
(c) Is medium
(d) None of these
Which of the following is true for the reaction
H 2O(l) H 2O(g)
at
and
1
100o C
atmosphere
(a)
17.
22.
The
respectively.
298K is
23.
deg1
21.
20.
(a) 0.5 JK
mol1
(b) 1.0 JK
mol1
(c) 1.5 JK
mol1
(d) 2.0 JK
mol1
29.
The
The
The
The
S respectively are
(a) +,
(c) ,
30.
S indicates that
(b) +, +
(d) , +
(d) 22.05 kJ
40.
S negative
H and negative S
(c) Positive H and negative S
(d) Negative H and positive S
34.
35.
36.
37.
41.
39.
An
engine
operating
between
150o C
(a) 736 K
(b) 1050 K
(d) 1150o C
The volume of a gas decreases from 500cc to
300cc when a sample of gas is compressed by
an average pressure of 0.6 atm. During this
process 10 J of heat is liberated. The change in
internal energy is
(a) 2.16 J
(b) 12.156 J
(c) 2.16 J
(d) 101.3 J
(c) 1150K
42.
43.
O 2 (g)
205JK 1
are 213.5, 5.690 and
respectively. The standard entropy of formation of
CO 2 (g) is
(a) 1.86 JK
(b) 1.96 JK
(c) 2.81JK
(d) 2.86 JK
44.
45.
H TS
(c) H G
H TS
(d) H TS
(a)
46.
(b)
(Cv 20 JK
(a) 150 K
(b)
38.
(c) Zero
(d) Not definite
Which of the following conditions will always lead
to a non-spontaneous change
(a) Positive H and positive S
(b) Negative
164
(b) 100 K
o
47.
and
(c) 26.85 C
(d) 295 K
The entropy change, in the conversion of one mole
of liquid water at 373 K to vapour at the same
temperature is (Latent heat of vaporization of water,
H vap 2.257kJ / g)
(a) 105.9 Jk
(c) 108.9 Jk
48.
(b) 107.9 Jk
(d) 109.9 Jk
57.
49.
50.
51.
53.
54.
(a) 60.3 JK
(c) 70 JK
59.
60.
(d) J 1K 1mol1
The entropy changed involved in the conversion of
1 mole of liquid water at 373 K to vapour at the
same temperature will be
(b)
61.
56.
10.7
70
mol1
(b) 80.7 JK
mol1
(d) 10.7 JK
mol1
mol1
62.
63.
O2(g)
64.
55.
OH (aq) H 2O(l)
(b) Water
(d) Mercury
(b) JK mol1
(a)
0.119 kJ
0.109 kJ
(c) 0.129 kJ
(d) 0.120 kJ
When a liquid boils, there is
(a) An increase in entropy
(b) A decrease in entropy
(c) An increase in heat of vaporization
(d) An increase in free energy
H (aq)
S o (298K ) K 1mol1
(a) 8.74
(c) 24.06
(c) J mol1 K 1
52.
58.
Highest entropy is in
(a) Hydrogen
(c) Graphite
65.
(a) 2.76 JK
(b) 2.12 JK
(c) 1.12 JK
(d) 1.40 JK
(a) Steam
(c) Water at 4o C
(d) Ice
Considering entropy (S) as a thermodynamic
parameter, the criterion for the spontaneity of any
process is
66.
H E
(c) H 0
(a)
68.
H TS
(d) S 0
(b)
7.
8.
(b) 400K
(d) 600K
Heat of reaction
9.
1.
H2
1
O2 H 2O 68.3 kcal
2
2.
375o C
is
is
10.
1
O2 (g) CO(g);H 110.5kJ
2
1
CO(g) O2(g) CO2(g);H 283.2kJ
2
(b) 375K
(d) 102o C
The enthalpy of fusion of ice per mole
(a) 18 kJ
(b) 8 kJ
(c) 80 kJ
(d) 6 kJ
In which of the following neutralisation reactions,
the heat of neutralisation will be highest
4.
11.
HCl
12.
5.
1
O2 SO3;(H 98.2)
2
SO3 H 2O H 2SO4 ; (H 130.2)
13.
SO2
H2
1
O2 H 2O;(H 287.3)
2
(c) 320.5 kJ
(d) 813.9 kJ
From Kirchhoff's equation which factor affects the
heat of reaction
(a) Pressure
(b) Temperature
(c) Volume
(d) Molecularity
(a) 816.15 kJ
(b) 1632.3 kJ
(c) 6528.2 kJ
(d) 2448.45 kJ
Thermochemical reactions
C(graphite
)
(c) 273K
3.
1
O2 6CO 2(g) 3H 2O(l);H 3264.6kJ
2
(a)
and
C6 H 6 7
KOH
166
14.
15.
(a) 393.7 kJ
(b) + 393.7 kJ
(c) 172.7 kJ
(d) + 172.7 kJ
The following is (are) endothermic reaction
(a) Combustion of methane
(b) Decomposition of water
(c) Dehydrogenation of ethane to ethylene
(d) Conversion of graphite to diamond
Evaporation of water is
(a) An endothermic change
(b) An exothermic change
(c) A process where no heat change occurs
(d) A process accompanied by chemical reaction
An exothermic reaction is one which
(a) Takes place only on heating
(b) Is accompanied by a flame
(c) Is accompanied by a absorption of heat
(d) Is accompanied by evolution of heat
An endothermic reaction is one in which
(a) Heat is converted into electricity
(b) Heat is absorbed
(c) Heat is evolved
(d) Heat is converted into mechanical work
Which of the following statement is correct
(a) H is positive for exothermic reaction
(b) H is negative for endothermic reaction
(c) The heat of neutralization of strong acid and
strong base is always the same
(d) The enthalpy of fusion is negative
23.
Given that
C 2 H 2 (g) 2
(c) C
(diamond)
If
H o
f
for
H 2O2
and
(c) 800kJ
24.
(b) C
H 2O
are
19.
(a)
26.
C(diamond
) C 2 (g) CO 2(g); H ykJ
20.
Correct
relationship
between
heat
of
27.
fusion
example
of
29.
(b) C O2 CO 2 ; E 393.5 kJ
(c) N 2 O2 2NO; E 180.5kJ
(d) 2H 2 O2 2H 2O; E 571.8 kJ
30.
(c) 120.6kcal
is
(a) C 2 H 2 2H 2 C 2 H 6 ; E 314.0kJ
22.
NaOH
21.
C(graphite
) O2 (g) CO2 (g); H x kJ
(b) (x y)kJ mol1
HCl and NH 4 OH
(d) 228kJ
1
1
H 2 Cl 2 HCl , is called
2
2
1
O2 (g) 2CO 2(g) H 2O(l);H 1301k
2
H f
1
O2 (g) H 2O(l); H 286kJ
2
(b) Exothermic
(d) Spontaneous
31.
HCl is
(a) 13.7kcal
(b) 13.7kcal
Heat
of
combustion
of
32.
(a) CH 4
(b) C 2 H 6
(c) C 2 H 4
(d) C 2 H 2
Heat of formation of
40.
33.
34.
41.
42.
43.
44.
45.
46.
(b) 94kcal
(c) 47kcal
(d) 47kcal
47.
(a) 57.0 kJ
(b) 11.4 kJ
(c) 28.5kJ
(d) 34.9 kJ
In the reaction
39.
H is known as
(b) Fe S FeS
38.
1
O2 H 2O is called
2
H2
CH 4 (g) are
168
48.
49.
(a) T1 T2
(b) T1 2T2
(c) T1 4T2
(d) T2 9T1
50.
51.
59.
56.
(a)
(b)
(c)
(d)
57.
52.
(a)
58.
60.
54.
55.
and
(d) 80kcal
62.
63.
H2
20kcal, 40kcal
(b) N 2 O2 2NO
are
CH 4(g) ,C(graphite
)
(a) 2H 2 O2 2H 2O
61.
H 2(g)
(c) 80kcal
(b) CH 3COOH NH 4 OH
53.
HCl NaOH
(c) NH 4 OH HCl
Is always negative
Is always positive
May be negative or positive
Is zero
and
1
O2 H 2O;H 68.39kcal
2
K H 2O Water
KOH (aq)
1
H 2 ;H 48kcal
2
64.
(a)
(c)
68.39 48 14
at 25o C in kJ is
(a) 7.43
(c) 3.72
1
(c) CO(g) O2 (g) CO 2 (g)
2
C
O2(g) CO 2(g);H 393.5 kJ
The
enthalpy
kJ
1
O2 (g) 6CO 2 3H 2O(l)
2
of
46.0 kJ mol
formation of ammonia is
. The enthalpy change for the
73.
(b) 870kcal
(c) 872kcal
(d) 874kcal
Which of
represents
the
the
equations correctly
heat of formation
) 2H 2 (g) CH 4 (g)
(a) C(diamond
) 2H 2 (g) CH 4 (l)
(b) C(graphite
) 2H 2(g) CH 4 (g)
(c) C(graphite
) 4H CH 4 (g)
(d) C(graphite
75.
70.
(H o
f ) of methane
(a)
(b)
(c)
(d)
69.
(b) 1.5 kJ
(d) 3.0 kJ
(graphite)
(c) 3.0 kJ
68.
72.
67.
C (diamond)
(b) + 3.72
(d) + 7.43
(d) C 6 H 6 (l) 7
66.
(d) 68.39 + 48 + 14
65.
71.
170
(b)
H 2 (g)
(c)
H 310kcal
76.
77.
(b) 6.0
(d) 14.0
(a) 10.0
(c) 12.0
1
O2 (g) 2CO 2(g) H 2O(l)
2
1
O2 (g) H 2O(l);H 58kcal
2
H is
(b) Zero
(d) Undeterminate
kcal is
(a) 21.16kJ
(b) 21.10kJ
(c) 13.62kJ
(d) 13.6 kJ
1
O2(g) CO2 (g);H 282kJ
2
H 2 (g)
1
O2 (g) H 2O(g);H 242kJ
2
78.
79.
The value of X is
(a) 393kJ
(b) 655kJ
(c) 393kJ
(d) 655kJ
(a)
reactants
(b)
reactants
(c)
reactants
81.
82.
(b) Cl e Cl
(c) S 2e S 2
(d) O 2e O 2
combustion
of
2.0 gm
of
83.
84.
(b) 200kcal
(c) 300kcal
(d) 400kcal
1mol of
of
carbon
H 2 Cl 2 2HCl 44kcal is
87.
(a) 44 kcal
(b) 44000 kcal
(c) 22 kcal
(d) 11 kcal
When water is added to quick lime, the reaction is
(a) Exothermic
(b) Endothermic
(c) Explosive
(d) None of these
88.
In an exothermic reaction
(a) Positive
(c) Zero
negative
89. The heat change
H is
(b) Negative
(d) Both
positive
for
the
following
90.
or
reaction
H 2(g)
methane
1
O2(g) H 2O(l);H 285.9kJ
2
methane would be
(a) 100kcal
formation
H is always positive
In the
(d)
80.
(a) + 3172.8 kJ
(c) 3172.8 kJ
(b) 1549.2 kJ
(d) 3264.6 kJ
(a) CO 2 H 2O
(b) CO2 H 2
(a)
(c) COCl 2
(d) CO CO 2 H 2O
(b)
91.
(d)
93.
SO2
(a) E P E R
(b) E R E P
(a) 200kJ
(b) 356.2kJ
(c) H P H R
(d) H R H P
(c) 200kJ
(d) 396.2kJ
94.
2.2016gm
H is
(b) Positive
(d) Constant
of
acetaldehyde
produced
O2 .
97.
(b)
(d) 66 kJ
H E
(b) H E
(c) H E
(a)
C O2 CO2; H X
(b)
BaCl2.2H 2O(s)
1
8.8 kJ mol
are
BaCl2(s) and
20.6
(a) 29.4 kJ
(b) 11.8 kJ
(c) 20.6 kJ
(d) 29.4 kJ
105. The enthalpy change of a reaction does not
depend on
(a) The state of reactants and products
(b) Nature of reactants and products
(c) Different intermediate reaction
(d) Initial and final enthalpy change of a reaction
3
O2 SO3 2x kcal
2
1
O2 SO3 y kcal
2
SO2
XY
(c) X Y
CO is
(b) Y 2X
(d) 2X Y
SO2 and
and
106. S
1
O2 CO2 ; H Y
2
(a)
99.
CO
12.802kJ mol1
98.
12.802kJ mol
1
O2 CO2 ;H 24kJ
2
(c) + 16 kJ
1
O2 CO; H 42kJ
2
CO
1
O2 SO3
2
combustion of carbon
95.
172
(a) 2x y
(c)
x y
(b) 2x y
(d) 2x / y
and
890.4 kJ mol1
890.4 kJ mol
(b)
298.8 kJ mol1
1
(b) Equal to
(d) Less than
x
x
Heat of formation of CH 4 is
[DCE 1999]
(a) 70 kJ
(c) 244 kJ
(b) 71.8 kJ
(d) + 782 kJ
50cm3
3
50cm
3
5 C . If 250cm of each liquid are mixed, the
temperature rise would be
(a) 5o C
(b) 10o C
(c) 25o C
(d) 20o C
116. H 2(g)
1
O2(g) H 2O(l) ;
2
H at 298 K = 285.8 kJ
The molar enthalpy of vaporisation of water at 1
atm and 25o C is 44 kJ. The standard enthalpy of
formation of 1 mole of water vapour at 25o C is
(a) 241.8 kJ
(b) 241.8 kJ
(c) 329.8 kJ
(d) 329.8 kJ
117. When 4 g of iron is burnt to ferric oxide at constant
pressure, 29.28 kJ of heat is evolved. What is the
enthalpy of formation of ferric oxide (At. Wt. of Fe
= 56)
(a) 81.98 kJ
(b) 819.8 kJ
(c) 40.99 kJ
(d) + 819.8 kJ
118. When a strong acid, strong base or their salt are
dissolved in water, they are completely ionised. If
a strong acid is added to a strong base, H ions
from the former combine with OH ions of the
latter forming water. The formation of each water
molecule liberates a certain quantity of energy
and the reaction is exothermic. The heat liberated
when one mole of water is formed by combining
hydrochloric acid and sodium hydroxide is 13.7
kcal. The heat liberated when one mole of water is
formed by combining sulphuric acid and sodium
hydroxide is
(a) 25.5 kcal
(b) 8.5 kcal
(c) 13.7 kcal
(d) 34 kcal
119. 2.1 g of Fe combines with S evolving 3.77 kJ. The
heat of formation of FeS in kJ/mol is
(a) 1.79
(b) 100.5
(c) 3.77
(d) None of these
120. In
the
reaction:
H 2 Cl 2 2HCl, H 194kJ .
Heat
of
formation of
HCl is
(a) + 97 kJ
(b) + 194 kJ
(c) 194 kJ
(d) 97 kJ
121. Enthalpy of neutralisation of acetic acid by
NaOH is 50.6 kJ / mol. and the heat of
neutralisation of a strong acid with a strong base
for the
(b)
(c) HCl NH 4 OH
(d)
HCOOH KOH
CH 3COOH NaOH
123. The heat change for the following reaction at
298o K and at constant pressure is 7.3 kcal
C6H 6(l) 7
1
O2(g) 3H 2O(l) 6CO2(g)
2
1
Na(s)
1
Cl 2 (g) NaCl(s), H
2
KCl (H 17.64)
174
o
126. The H f for CO 2 (g),CO(g) and H 2 O(g)
are 393.5,
110.5 and 241.8kJmol1
respectively. The standard enthalpy change (in kJ)
CO2(g) H 2(g)
for
the
reaction
CO(g) H 2O(g) is
(a) 524.1
(b) 41.2
(c) 262.5
(d) 41.2
127. Which of the following compounds will absorb the
maximum quantity of heat when dissolved in the
same amount of water ? The heats of solution of
these compounds at 25o C in kJ/mole of each
solute is given in brackets
(d)
HCl (H 74.1)
128. In the reaction C 2S CS 2 H , H is the
(a) Heat of combustion (b) Heat of neutralisation
(c) Heat of solution
(d) None of these
129. The
heat
of
formation
of
methane
C(s) 2H 2 (g) CH 4 (g) at constant pressure
is 18500 cal at 25o C . The heat of reaction at
constant volume would be
(a) 17904 cal
(b) 18202 cal
(c) 18798 cal
(d) 19096 cal
130. The enthalpy of combustion of C 6 H 6(l) is
(b) 16.25 kJ
(d) 32.5 kJ
1
O 2 (g) CO 2 ; H 135.2kcal
2
Then heat of formation of CO(g) is
(a)
CO(g)
26.4 kcal
(c) 26.4 kcal
1
O 2 MO 351.4 kJ
2
1
O 2 XO 90.8 kJ
2
(a) 422.2 kJ
(b) 268.7 kJ
(c) 442.2 kJ
(d) 260.6 kJ
134. If the heat of combustion of carbon monoxide at
constant volume and at 17o C is 283.3 kJ, then
its heat of combustion
at constant pressure
-1
(R 8.314J degree
mol1 )
(a) 284.5 kJ
(c) 384.5 kJ
(b) 284.5 kJ
(d) 384.5 kJ
(b) 196 kJ
(d) 984 kJ
(b) C 2 H 4
H2
1
O2 H 2O 68.3kcal
2
(a) 4 g
(c) 12 g
(b) 8 g
(d) 16 g
CH 4 (g)
and
213kcal/ mol.
are
respectively.
and
value
of
(d) Zero
(a) 11 kcal
(c) 44 kcal
(c)
HCl ,
C S 2 CS 2 ; H 22.0 kcal
(b) 32 kcal
(d) 22 kcal
The
(b) E1 E 2 ve
94, 68
HCl
176
1
O 2 (g) CO 2 (g)
2
(c) X 2Y
(b) X
1
Y
2
o
156. Which of the reaction defines H f
1
1
H 2 (g) F2 (g) HF (g)
(b)
2
2
(c) N 2 (g) 3H 2 (g) 2NH 3 (g)
1
O 2 (g) CO 2 (g)
(d) CO(g)
2
157. One gram sample of NH 4 NO3 is decomposed in
a bomb calorimeter. The temperature of the
calorimeter increases by 6.12 K the heat capacity
of the system is 1.23 kJ/g/deg. What is the molar
heat of decomposition for NH 4 NO3
(a) 7.53 kJ/mol
(c) 16.1 kJ/mol
1
X
2
(d) H 2 H 2 H H
(a) Y
(d) CO(g)
(c)
C gr O2 CO 2 ; H 393.4 kJ / mole
C gr C dia; H
(a) 3.8
(b) 1.9
(c) + 3.8
(d) + 1.9
(b) 96.0 kg
(d) 2.8 kg
HCl
with
(b) 31.5 kJ
(c) 315kJ
(d) 31.5 kJ
164. Which of
represents
the
the
following
standard
equations correctly
heat of formation
(H o
f ) of methane
(a)
(b)
(c)
(d)
.9 kJ
(b) 1275
.0 kJ
(c) 1572
.5 kJ
(d) 1165
has
heat
of
(d)
H 2SO4 , NH 4OH
2.
(b) 676.5 kJ
(c) 110.5 kJ
(d) 110.5 kJ
3.
(b) 278kJ
(c) 890kJ
(d) 178kJ
4.
5.
in
air
Given
H o
f
for
Mg
6.
7.
H of the reaction
Mg Fe2O3 3MgO 2Fe
(a) 70
(c) 170
Given
(a) 1802 kJ
(c) 800 kJ
(b) +1802 kJ
(d) + 228 kJ
8.
that
C H will be
208 kJ/mole
41.6 kJ/mole
832 kJ/mole
None of these
The
about
(b) 65 kJ
(d) 50 kJ
9.
Bond energy
If the bond dissociation energies of XY , X 2 and
XY is
of X 2 will be
gaseous
(b) 100
(d) 270
(a)
(b)
(c)
(d)
of
(b) 44 kcal
(a) 68 kJ
(c) 57.3 kJ
energies
(c) 22 kcal
(d) 22 kcal
The first ionization energy for Li is 5.4 eV and
electron affinity of Cl is 3.61eV. The H (in
What is the
1.
dissociation
CC
NN
3
O2 Fe2O3, H 193.4 kJ ;
2
1
O2 MgO, H 140.2kJ
2
bond
(d)
gas would be
(a) 44 kcal
The
(b)
(a) 2
(b) 2
(c) 22
(d) 16
170. How much energy is released when 6 mole of
burnt
SO
(c) C N
is
(a)
octane
10.
HBr
are
433,
192
H H , Br Br and
and
for
H o
H 2(g) Br2(g) 2HBr(g) is
respectively,
(b) 800kJ mol1
(b) 40 calories
(d) 120 calories
the
364
the
kJ mol1
reaction,
(b) 103 kJ
(d) + 103 kJ
2.
3.
4.
5.
10.
11.
(d) H
6.
200J mol , S
The relation
12.
40 JK
13.
1
mol
(b) Faraday
(d) Thomson
Ag
ions with
14.
correct
(a)
15.
9.
vapour
occurs
(a) 540cal
(b) 9800cal
(c) 9800cal
(d) 0 cal
(a) 100
(b) 10
(c) 2
(d) 0.01
The standard enthalpy of the decomposition of
N 2O4 to NO2 is 58.04 kJ and standard entropy
of this reaction is 176.7 J/K. The standard free
energy change for this reaction at 25o C is
(a) 539 kJ
(b) 539 kJ
(c) 5.39 kJ
(d) 5.39 kJ
Spontaneity of a chemical reaction is decided by
the negative change in
(a) Internal energy
(b) Enthalpy
(c) Entropy
(d) Free energy
For a reaction at 25o C enthalpy change and
entropy changes are 11.7 103 J mol1 and
105J mol1K 1
(d) [G] [H ]
8.
V2
V1
G H TS was given by
(a) Boltzmann
(c) GibbsHelmholtz
7.
(d)
mol1
mol1
P1
P2
(d) Condensation
of
water
spontaneously at 373K
GT nRT log
(c)
H o 200kJ mol1 , S o 4 JK
(c)
(b)
H o 200 kJ mol1 , S o 4 JK
GT nRT ln
(b) G H T S
(d) H T G S
P2
V2
(b) GT nRT ln
P1
V1
(a)
GT nRT log
178
16.
17.
G H TS
(b)
G H TS
19.
20.
G TS H
(d)
GSH
(a) 13.81
(c) 138.18
24.
25.
T
S
(a)
G H TS
(b) G H
(c)
H G TS
(d) G H T.C p
mol1 ,
(a) G RT ln K c
(b) G RT ln K c
(c) Go RT ln K c
(d) Go RT ln K c
26.
(b) G ve, E 0
(c) G ve, E ve
(d) G ve, E ve
27.
The
free
energy
H 31400ca; .
1000o C is
reaction
having
at
1.
C2H 2(g)
for
S 32cal K 1 mol1
28.
for
(a) G 0, E 0
1 ,
22.
21.
(b) 1381.8
(d) 1391.6
5
O2(g)
2
H 2 (g)
1
O 2 (g) H 2O(l) G o 237kJ
2
23.
(a) 209 kJ
(b) 2259 kJ
(c) + 2259 kJ
(d) 209 kJ
The equilibrium concentration of the species in the
reaction A B C D are 3, 5, 10 and 15
moleL1 respectively at 300K the G for
the reaction is
2.
(a) 11.4 kJ
(b) 11.4 kJ
(c) 0 kJ
(d) 4.8 kJ
Heat of neutralization of strong acid against strong
base is constant and is equal to
(a) 13.7 kcal
(b) 57 kJ
(c) 5.7 104 J
4.
5.
6.
7.
8.
S 35.7 JK
14.
H must be negative
(d) S must be negative
(c)
15.
16.
(a)
TB
10.
Enthalpy of solution of
11.
12.
13.
(b) Positive
(d) Unknown
(b)
TA
S
TA
T
(a) 1 : 1
(b) 7 : 2
(c) 7 : 5
(d) 5 : 7
The enthalpy change for the reaction of 50.00 ml
of ethylene with 50.00 ml of H 2 at 1.5 atm
mol1
9.
180
(c)
(d)
S
17.
TB
TA
TA TB
In endothermic
reaction, the valueT of change in
T
enthalpy (H ) is
(a) Positive
(c) Zero
18.
19.
(b) Negative
(d) None of these
(b) SO2Cl2(g)
(c) SO2Cl2(l)
(d) SO2(g)
Cr2O3
are
respectively.
1596kJ
Al2O3
and
for
and
1134kJ
the
reaction
20.
(a) 2730kJ
(b) 462kJ
(c) 1365kJ
(d) 2730kJ
22.
G
(c) E
(a)
23.
H
(c) More than H
24.
25.
26.
27.
28.
29.
H
(d) PV
(b)
32.
(b) Zero
(d) Equal to
(c) 10 kJ
33.
ionisation of
34.
(b) 19 kJ
(d) 9 kJ
NaOH is
12.13kJ mol
(b) 45.10 kJ
(c) 451.9 kJ
(d) 45.19 kJ
35.
36.
(b) Joule
(c) Erg
(b) Cl 2
(c) Br2
(d) I 2
. The enthalpy of
(a) 4.519 kJ
H 94.05kcalmol1
H is
by
HCN will be
HCN
other
37.
30.
31.
H 94.50kcalmol1
therefore
(a) C (graphite) C (diamond);
o
1
H 298
K 450calmol
;
(b) C (diamond) C(graphite)
o
1
H 298
K 450calmol
39.
47.
40.
the
(a) Zero
(c) ve
41.
(b) + ve
(d) Unpredictable
The equilibrium constant of a reaction at 298K
is 5 103 and at 1000K is 2 105 . What
42.
43.
fusion
44.
C H bond is
(b) x1 kcalmol1
(c) x / 4 kcalmol1
(d) x1 / 4 kcalmol1
N N, H H
945, 436
and
and
45.
46.
(b) 102kJ
(c) 90kJ
(d) 105kJ
1
1
H 2 Cl 2 HCl
2
2
( H 298 22060kcal)
means
(a) The heat absorbed when one gram molecule of
HCl is formed from its elements at 25o C is
22.060 kcal
(b) The heat given out when one gram molecule
of HCl is formed from its elements at 298 K
is 22.060 kcal
(c) The heat absorbed when one atom of
hydrogen reacts with one atom of chlorine to
form one molecule of HCl at 25o C and
one atmospheric pressure is 22.060 kcal
(d) The heat absorbed when one gram equivalent
of HCl is formed from its elements at 298 K
is 22.060 kcal
(e) The intrinsic heat of one molecule of HCl is
22.060 kcal more than the intrinsic heats of
one atom of hydrogen and one atom of
chlorine
49. The H 2O(g) molecule dissociates as
50.
51.
52.
(a) ykcalmol1
48.
182
H 2 (g)
1
O2 (g) H 2O(l),H 285.8 kJ mol1
2
236.9 kJ mol
(a)
Assertion :
(b)
2NO(g) .
281.4 kJ mol1
1
Reason
10.
2.
3.
4.
Assertion :
Reason
Assertion
Reason
Assertion
Reason
Assertion
:
:
:
:
:
Reason
5.
Assertion :
Reason
6.
Assertion :
Reason
7.
Assertion :
8.
Reason
:
Assertion :
Reason
of
at
of
11.
12.
13.
Assertion :
Reason
1.
Assertion :
Reason
Assertion :
Reason
Assertion :
15.
16.
17.
18.
19.
HCl
with
Assertion :
Reason
Assertion :
Reason
Reason
14.
G is
Assertion :
Internal energy
property.
Reason
Assertion :
Reason
is
an
extensive
are
Assertion :
Reason
Assertion :
Assertion :
Reason
21.
22.
184
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
37
38
39
40
41
42
43
44
45
Assertion :
36
46
47
48
49
50
Reason
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
Assertion :
Reason
Basic concepts
1
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
bc
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
10