CBSE TEST PAPER-05

CLASS - XI CHEMISTRY [ANSWERS]

Topic: - Quantum Mechanical Model of the Atom

Ans1:

It states that
It is impossible to determine simultaneously the exact position and exact
momentum (or velocity) of an electron.

Ans2:

Mathematically, it can be given as

x px h

or , x ( mvx ) h
or , x U x h

4 m

Where x is the uncertainty in position and px ( vx ) is the uncertainty in

momentum (or velocity) of the particle.

Ans3:

If the position of the electron is known with high degree of accuracy ( x is small),
then the velocity of the electron will be uncertain ( (Vx ) is large.) .

Ans4:

According to de Broglies relation, = h

mv

i.e.

1
the mass of the car is very
m

large and its wavelength ( ) or wave character is negligible. Therefore, we do not

see a car moving like a wave.

Ans5:

According to de Broglie, every particle in motion is associated with a wavelength

and other wave characteristics. He deduced the relation that wavelength ( ) of a
particle in motion is equal to the Plancks constant (h) divided by the momentum (p)
of the particle.
i.e. =

h
1
=
p mv

Where m is the mass, v is the velocity after particles

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Ans6:

Because there is an uncertainty in the velocity of moving electron around the

nucleus (Heisenbergs Uncertainty Principle).

Ans7:

According to uncertainty Principle

h
4
h
or, p =
4x
x.p =

or , p =

6.626 1034 kgm2 s 1

4 3.143 10 10 m)

= 5.27 1026 kgms 1

Ans8:

Uncertainty in velocity ( v ) is given by

h
4 mx
6.6 10 34 kgm2 s 1
=
22
4 4 103 kg (10m)
7
= 1.3 10 39 ms 1
v

The uncertainty in the velocity of the wagon is = 1.3 1039 ms 1

Ans9:

2 represent probability of finding an electron.

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