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Docslide - Us Reviewer 1 Chemical Engineering Day 1
Docslide - Us Reviewer 1 Chemical Engineering Day 1
_______6. Aldehydes
_______7. Ketones
_______8. Organic acids
_______9. Amine
______10. Amide
_______6. Naphthalene
_______7. Anthracene
_______8. Phenanthrene
_______9. O-cresol
_______10. Nitrobenzene
+
+
Cu
CO2
CO2
H2
H2O
H2O
C.
How many ml of a 12 N HCl solution is needed to neutralize 100 ml of a 1.2M Ba (OH)2 solution?
_____19.
_____20.
a. RCOOR
b. solutions of metallic oxides
c. ROR
d. methanol
e. alkyl-aryl sulfonate
f. substances that keep pH constant
g. same atomic mass different atomic number
h. molecular modifications
i. chemically different but the same atomic mass
j. Extraction of solids from solution by diffusion through membrane
k. RCHO
l. RCOOH
a. wine
b. soap
c. paper making
d. paint
e. coconut oil
f. baking
g. mining / metallurgy
h. alcohol
i. Powder detergent
j. caustic/ chloride
k. glass making
l. flour milling
m. pulp making
n. fertilizer
________6. Chloroform
________7. Acetyl-Salicylic acid
________8. Stearic acid
________9. O-phthalic acid
________5. Methane
_______10. Trinitrotoluene
Copper smelter is using copper sulfide concentrate containing 30% copper and 40% sulfur. The plant employs Autokumpu process with pure
oxygen to produce at its rate capacity of 130,000 MT per year of 99.9% copper. The following equation may be assumed during the smelting:
Copper sulfide
+
oxygen
=
copper +
sulfur dioxide
Compute
a. Feed rate per hour of the concentrate for 330 days/year operation.
b. Oxygen requirements in tons per hour.
27. Board Problem, May 1985
Ethyl alcohol and carbon dioxide are obtained from hydrolysis of sucrose. At T= 80 oF and 1atm, how many kilos of alcohol and liters of gas
can be obtained from a 1 metric ton of sucrose?
28. Board Problem, October 1978
It is desired to produce phenol by reacting chlorobenzene and sodium hydroxide. 1000kg of phenol are produced from reacting 1,320kg of
chlorobenzene and 1,200kg of sodium hydroxide, what is the:
a. % excess
b. % yield
Solutions/ Colligative Properties
29. Board Problem, April 1979/ May 1983
For a 25g sucrose dissolved in 1kg of water at 70 oC, calculate:
a. Vapor pressure of the solution
c. Freezing point
b. Boiling point
d. Osmotic pressure
30. Board Problem, May 1980
For a 1% sugar solution with a density of 1.03 g/ml, calculate:
a. Vapor pressure of the solution
c. Freezing point
b. Boiling point
d. Osmotic pressure
31. Board Problem, October 1980
A solution containing 4.5g of an unknown compound in 100g of benzene gave a freezing point of 4.02 oC (kf= 5.12oC, Tfo= 5.5oC). Give the
molecular weight of the unknown substance.
32. Board Problem, May 1982
At 60oC, the vapor pressure of Ethyl alcohol is 352.7 mmHg and that of methyl alcohol is 625 mmHg. If the two alcohols are mixed 50/50 by
weight at that temperature, assuming ideal solution, what will be the composition of the vapor above the solution?
33. Board Problem, November 1982
Find the molecular weight of the liquid from the following data obtained from measuring the vapor pressure of the liquid by the gas saturation
method.
Volume of oxygen at 740mmHg and 30oC
=
5.6 ml
Barometric pressure
=
740 mmHg
Temperature
=
30oC
Loss in weight of the solid
=
1.195g
Vapor pressure of the liquid at 30oC
=
78.2 mmHg
34. Board Problem, November 1982
By dissolving 22.5g sodium carbonate decahydrate in water and adding water until the total volume is 200 cc, a solution is made having a
density of 1.04 g/ml. Calculate:
a. Molarity
b. Normality
c. Mole fraction of the solute
35. Board Problem, May 1985
0.5g of N with MW of 160g/mol is dissolved in 10g of solvent S. The boiling point of the solution is 124.8 oC. If 0.4g of M is dissolved in 12g
of the same solvent S, the boiling point of the solution is 125.2oC. Boiling point of the solvent is 122oC. Calculate the MW of M.
Chemical Equilibrium
36. Board Problem, October 1980
One tenth of a mole of phosphorus pentachloride is heated to 250oC in a 2li vessel. At this temperature, the dissociation proceeds according to
the reaction with Kc= 0.0414. Calculate the concentration of Cl 2 in moles/li. PCl5 (g)
=
PCl3 (g)
+
Cl2 (g)
37. Board Problem, May 1981
Calculate the total pressure which must be applied to a mixture of 3 parts hydrogen and 1 part nitrogen to give a mixture containing 10%
ammonia at 400oC, Kp= 1.64 x 10-4.
38. Board Problem, November 1982
Calculate the mole percentage of ammonia present at equilibrium at 450oC when the total pressure is 100 atm, and the molar ratio of hydrogen
to nitrogen is 3 to 1. Refer to PhyChem by Maron and Lando (Table 10-1, p. 364), for the average value of K.
A sample weighing 0.6234g that might contain a mixture of NaOH + Na2CO3 or Na2CO3 + NaHCO3 is titrated with 0.1062M HCl by the two
indicator method. With phenolphthalein end point, 40.38ml of acid was used. The titration is continued after adding methyl orange, and an additional
12.38ml of acid was used.
a. Identify the mixture of bases in the sample
b. Calculate the % of each base in the sample
51. Board Problem, May 1984
A sample of impure magnetite (Fe3O4) weighing 0.5g was converted by chemical reaction to Fe2O3. The iron oxide, Fe2O3, was found to
weigh 0.41g. Determine the % Fe3O4 n the magnetite.
52. Board Problem, May 1984
A sample containing only ferric oxide (Fe2O3) and aluminum oxide (Al2O3) weighs 10g. This sample is heated with sufficient amount of
hydrogen gas to reduce all the iron oxide to elemental iron. The aluminum oxide remained unaffected in the process and the dry sample was found to
weigh 8.58g. Calculate the % Al in the original sample.
Sn
SO2
(g)
V (m3)
The total heat added to the system is 500J, the change in enthalpy of the system is
a. -100J
b. 300J
c. 500J
d. 1100J
Answer:
3.
a. 54%, b. 3, c. 20ml
4.
Na2B4O7
16.
KNO2
17.
Limestone= 144.68 tons, soda ash= 135.2 tons
18.
NaCl= 110.38 tons/day, CaCO3= 94.3 tons/day
19.
51.93 li
20.
V= 27,623 li
21.
Limestone= 31.25 MT, soda ash= 38.75 MT, lime= 32.41 MT
22.
Ammonium sulfate= 893.3MT, Phosphoric acid= 435.9MT, Muriate of potash= 800.9MT, gypsum=869.9MT.
23.
97.0%
24.
a. 7.826kg, b. 434.78 mole, c. 171.9 ft 3, d. 4,347.8 li
25.
a. 53.45kg, b. 26.93kg, c. 13.71 li
26.
a. 54.66, b. 4.13
27.
Alcohol= 538 kg, gas= 2.88 x 105 li
28.
a. 155.75%, b. 90.69%
29.
a. 23.77 mmHg, b. 100.038oC, c. -0.136oC, d. 1.79 atm
30.
a. 23.75 mmHg, b. 100.015oC, c. -0.055oC, d. 0.736 atm
31.
155.68 g/mol
32.
28% ethyl alcohol
33.
46,116 g/mol
34.
a. 0.393M, b. 0.786N, c. 7.04 x 10 -3
35.
93.33 g/mol
36.
0.0293M
37.
29.69 atm
38.
15.6%
39.
a. 0.103, b. 81.32%, 9.34%, 9.34%
40.
3.7
41.
a. 0.00478M, b. 4.78%, c. 2.32
42.
670 li
43.
a. 17.5 ml, b. 0.001855
44.
b. acidic, c. 36.5g HCl
45.
42.49%
46.
a. 2V1/ (V1+V2), b. 91.85%
47.
a. M=N=0.5, b. 12.25g
48.
a. 10.97% wt, b. 98.98%
49.
2.90%
50.
a. NaOH and Na2CO3, b. 18.77%NaOH and 23.16% Na2CO3
51.
79.26%
52.
27.90%
53.
a. basic, b. 17.1 ml
54.
a. Eo cell= 0.403V, b. Eo O2= 0.403V
55.
a. 0.0508li, b. 8.04hr
56.
b.Fo= 85,291 cal, c. no
57.
tK+= 0.487; tCl-= 0.513
58.
1.7 x 10-10
59.
23.33 mmHg, 0.018
60.
a. 39.36g/mol, b. 48,617 cm/s, c. 16,899g
61.
a. 146m3, b. 1.51 x 103g/ml
62.
1,257.44 cal
63.
1.397 li
64.
25.99 g/mol; ethyne
65.
29.94%
66.
64.14 g/mol
67.
90.46 g/mol
68.
a. CH3, b. 29.97, c. C2H6, d. ethene; paraffin
69.
a. 6.78 x 1012, b. 677,614, c. 161,954, d. 6,688, and e. 11.37oF
70.
478.13oK
71.
1,216 fps
72.
-11,800 cal
73.
1,126cal/g
74.
-1,192 cal
75.
a. 360,400cal, b. 11,472g
76.
205.28 eu
77.
78.
79.
80.
81.
82.
83.
84.
85.
86.
87.
88.
89.
90.
91.
92.
93.
94.
95.
96.
97.
98.
100.
101.
102.
24,546 cal
a. 9,494.72cal/mol, b. 118.34oC
6.33 x 10-3
COP= 4.27; Q= 3.33 x 106 cal/hr
a. 89.75, b. 0.1938 lb/min
14.1/g ammonia
338.54kg
1,782.53 Handbook/ 1,853.6 Steam table
a. 39.69 lb, b. 136.11
a. 75,000, b. 87,623, c. 63.76%CaO, 20.81%SiO2, 6.29%Fe2O3, 7.26%Al2O3, SO3
Ammonium sulfate= 45,913, diammonium phosphate= 15,652, KCl= 20,000
a. 800 ft3/hr; 22.67 m3/hr, b. 1.09mm
964.20
a. 29%, b. 18% xs
a. 57.24%, b. 50.2%
O2 sg= 1.45 mol, H2O= 8.5 mol
a. 20.72%, b. 87.68%, c. 216.57, d. 227.3, e. 2.95 inHg
CO2= 5.87 lbmol; H2O= 2.4 lbmol
5.92%
a. 6.67%, b. 3,214 lb
c. 7.22 MT
a. 23.3%, b. 4.54%
a. 27,000, b. 10,864.41, c. 21,559.32
11.01
CO2= 2 mol; O2 sg= 0.6 mol