LATIHAN :

1. Tekanan uap eter (Mr = 74), 442 mmHg pada 293 K. Jika 3 g senyawa A dilarutkan ke dalam
50 g eter ini pada suhu ini, tekanan uap menjadi 426 mmHg. Hitung massa molekul relatif,
Mr senyawa A ??
Dik = Mr Eter = 74
Gr Eter = 50 gr
P0
= 442 mmHg
Gr A = 3 gr
P
= 426 mmHg
Dit = Mr A
Jawab =

P 0P
P0

XA =

442 mmHg426 mmHg

442 mmHg

16 mmHg
=0,036
442 mmHg

0,036 =

XA =

na
na+nb

na
50
na+
74

0,036 na + 0,024 = na
0,024 = ( 1- 0,036 ) na
0,024 = 0,964 na
na =

0,024
0,964

na = 0,025

na

Mr

gr
Mr

gr
3
=
na 0,025

Mr = 120

2. The vapor pressure of pure water at 20.0 C is 17.5 mmHg. What is the vapor pressure at 20.0
C above a solution that has 0.250 mol sucrose (C12H22O11) dissolved per kilogram of
water??
Dik = P0 = 17,5 mmHg
n C12H22O11 = 0,250 mol
gr Air
= 1000 gr
Dit = P ??
Jawab =
nB

XA

gr 1000
=
=55,556 mol
Mr
18

XA

na
0,250
=
na+nb 0,250+55,556

0,0045* 17,5 mmHg = 17,5 mmHg P

0,250
=0,0045
55,806

P 0P
P0

0,07875 mmHg = 17,5 mmHg P

P = 17,5 0,07875 mmHg
P = 17,421 mmHg

3. What is the freezing point of an aqueous sucrose solution that has 25.0 g C12H22O11 per
100.0 g H2O??
Dik = C12H22O11 = 25,0 gr
H2O
= 100,0 gr
Dit = Tf??
Jawab =
Tf = Kf * m
= Kf *

gr
1000
Mr
P

= 1,86 *

25
1000
342
100

465
342

Tf =

Tf = 1,359
Tf = 0 Tf
Tf = 0 Tf
Tf = - 1,359oC
4. An aqueous solution is prepared by dissolving 1.50 g of hemocyanin, a protein obtained from
crabs, in 0.250 L of water. The solution has an osmotic pressure of 0.00342 atm at 277 K.
(a) What is the molar mass of hemocyanin??
(b) What should the freezing point of the solution be??
Dik = Hemocyanin = 1,50 gr
V Water
= 0,250 L

= 0,00342 atm
T
= 277 K
Dit = a. Mr Hemocyanin ..??
b. Tf...??

Jawab =
a. = M R T

gr
1
mr
RT
v

Mr =

Mr =
=

grRT
V
1,500,082277
0,003420,250
34,071
0,000855

Mr = 39849,12
b. Tf = Kf * m

= Kf *

gr
1000
Mr
P

= 1,86 *

1,50
1000
39849,12
250

2790
9962280

= 0,00028
Tf = 0 Tf
Tf = 0 Tf
Tf = 0,00028oC