FORMULARIO

G H TS

1 P

L dP
fi L T, P fi Sat T exp
V

i
RT PiSat T

T, P RT ln x
iID G
i
i

A U TS

S ID x iS i (T, P) R x i ln x i

V
dP S dT
dG
i
i
i

GI (T, P) RT ln y
iGI G
i
i

yi P x i PiSat

x M
M1 M
2
x 2

ID x V

V
i i T, P
i 1

(G iEx RT)
HiEx
ln i

RT 2
T

P,n T P,n

Raoult
12
P1Sat P2Sat

H Ex x 1 1
i T2 , P, x i T1 , P, x exp i

R T2 T1

x M
M2 M
1
x1 T,P

T,P

d U EK EP N
dV
W

E E Q
q j H
K
P
Mec WS P
j
dt
dt
j1
LV TV
LV
H

dm N
q j q 1 q 2 q N
dt j1

LV T 1.092 ln Pc 1.013
H
n
n

R
0.930 Tr,n

dPSat
dT

LV 1 Tr,2
H
2

LV 1 T
H
1
r,1

Ex n
nG
i
G iEx
T,P,n ji
ln i

RT
RT

x H
H1 H
2
x 2
Lim
P0

x H
H2 H
2
x1
M
Mi

n i T,P,n ji

H
H
xH

Q
1 1 x 2H2

i 1

2B ji B j Bi

ii kk 0

lim i 1
x i 1

i 1, 2

G iEx RT ln i
T2

ln i T2 , P, x ln i T1 , P, x

HiEx T, P, x
RT 2

Ex M
M
ID
M

fi T, P, x
fi T, P
o

M iEx M i M iID

o RT
K exp i G
i

ln i

xiV
i
x jV j

ln 1

12
12 x1
1 x

21 2

ln 2

ln 1 Ax 22

ln 2 Ax12
i 1

i 4 1 B
i

ln 2 2 x12 2 x13
2

21x 2
1 x

12 1

Ex x V

2
G
1 1 x 2 V2
1 2
1
2

Ex
G
Ax1x 2
RT

i A 3 1 B

ln 1 1x 22 1x 32

21

B12 B1B2

o
d ln K H
R ,T

dT
RT 2

K (ai ) i

Margules:

G iEx
(G Ex RT)i
RT

x ln 2
12 1 2
ln 1
x1 ln 1

x ln 1
21 1 1
ln 2
x 2 ln 2

2 RT ln V
2
RT ln 1 V
1 2
1
2
2
2 1
1
2
2

z1

x11V
x1
1

x V

x11V
x

12 x 2
1
12 2
1

Ex
G
x1 ln x1 12 x 2 x 2 ln x 2 21x1
RT

12

21
ln 1 ln x1 12 x 2 x 2

x
x

x
12 2
2
21 1
1

12

V
11
2
exp 12

V
RT

12
21

ln 2 ln x 2 21x1 x1

x1 12 x 2 x 2 21x1

21

V
22
1
exp 21

V2
RT

BPc
0
1
f f
RTc

dB R 0.675
0.722

5.2
dT Pc Tr2.6
Tr

dT

1 P2Sat

1
2 P1Sat

i 1 j1

Ex
G
x1x 2

RT x1 21 x 2 12

van Ness-Abbott

fi LR fi ID x i fi

N
Ex
G
1 N
=
x i G iEx x i ln i

RT RT i 1
i 1

Ex RT x x A B x x C x x 2
G
1 2
1
2
1
2

Wilson

fi L
f L L
iID i
x i fi fi
i

N 2 N 2

fi ID T, P, x x i H i T, P

Soluciones
Regulares

i T, P, x

BMix T, y yi y jBij T y12 B1 T 2y1 y2 B12 T y22 B2 T

ViEx T, P, x
ln i T, P, x

RT
P

T,x

van
Laar

i 1

f i V,ID T, P, y f i LR T, P, y y i f i T, P

BMix T, y P
RT

Redlich
-Kister

N
x M
Mi M

i
x T,P,x ki

T1

fi V iV yi P

ai T, P, x

i 1

x i dM i 0

ZV 1

i 1

f i L T, P, x iH T, P, x x i H i T, P

1
ln dx1 0
0

x M
M
i
i

fi L T, P, x fi V T, P, y

PL PV

T,P

f i L T, P, x i T, P, x x i f i T, P

RT ln i G iR

TL TV

ji

27

dS N 2
Q
S Gen
qS
j
dt j1
T

P
1 N 2 N 2

Bi T y j y k 2 ji jk
RT
2 j1 k 1

ln iV

d i dG i RTd ln fi

Sat V
Z1 T Tc
V
L
c c

T, P, x x M T, P, x x M
T, P
M
i
i
i
i

T,P

fi
1
Pi

0.38

f 0.083 0.422 Tr1.6

0

f 0.139 0.172 Tr4.2

1