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Abstract- Banana and orange peels can provide an efficient and cost-effective biosorbents for
dyes, metals and organic pollutants removal from industrial water/wastewaters. Energy
dispersive Atomic X-ray (EDAX), Spectrometry Scanning electron microscopy (SEM),
Fourier transformation infrared (FTIR) and thermogravimetric (TGA) analysis were used to
characterize the surface of biosorbent. A better understanding of the chemistry behind these
interactions can help in the preparation of commercial biosorbents using waste banana and
orange peels. EDAX showed the presence of carbon, oxygen, sodium, aluminium, calcium,
Magnesium, potassium, sodium, silica and other minor elements on the surface of peels. FTIR
spectrometric results confirm that aliphatic group, carboxylic acid group etc on the surface of
peels. The TG traces showed the loss of moisture and the evolution of some light weight
molecules including water.
Key words Biosorbents, peels, EDAX and SEM analysis, FTIR spectrometry, TGA analysis
1. Introduction
Orange (Citrus sp.) is one of the citrus that
are abundant in India and orange residue is a
by-product of fruit industries that is mainly
used as animal feed. Banana (Musa sp.) peel
is an abundant and low cost agricultural
waste residue and is easily available in large
quantities. Achak et al. [2009] investigated
the efficiency of banana peel as a biosorbent
for removal of phenolic compounds from
Olive mill wastewaters. Orange residue, like
other citrus fruit residue, is composed of peel
and pulp (the fraction screened from the
juice). Orange peel is largely composed of
cellulose, pectin (galacturonic acid),
hemicellulose, lignin, chlorophyll pigments
and other low molecular weight compounds,
including limonene. Dominant components
of these fractions are respectively pectin,
cellulose, hemicellulose, lipid, some nitrogen
compound and almost 3% ash content
[Kefford and Chandler, 1970]. Pectic
substances are the predominant type of
polysaccharide identified for the cell walls of
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ISSN: 2229-6646
organic and organic pollutants from water
and wastewater. Fruits and their products can
serve as a major role for wastewater
treatment. The use of peel not only would
provide a less costly adsorbent in contrast to
activated carbon or synthetic ion exchangers
but is also easily available and will save the
environment from the abovementioned
pollution. Many sorbents based on low cost
agricultural by-products had been used for
dye sorption from wastewater, which
included banana pith [Namasivayam and
Kanchana,
1992],
orange
peel
[Namasivayam et al., 1996], tea waste
[Kamsonlian et al., 2011]wheat straw
[Robinson et al., 2002], sawdust [Garg et al.,
2004], powdered waste sludge [Serpil and
Fikret, 2006], wheat shells [Bulut et al.,
2007], wheat bran [Sulak et al., 2006] and
hen feathers [Mittal et al., 2007].
Polymerized onion skin with formaldehyde
[Kumar and Dara, 1981], waste wool
[Friedman and Nasri, 1973; Friedman and
Waiss, 1972], peanut skin [Randall et al.,
1975; Randall et al., 1978], modified barks
[Randall et al., 1976; Kumar and Dara,
1980], barks [Gharaibeh et al., 1998], barley
straw [Ajmal et al., 1998] have been studied.
Removal of nickel by adsorption using solid
residue form olive mill products [Guangju et
al., 1986], Mangifera indica seed shell
[Donali et al., 1992] have been reported.
Biosorption, the sorption of pollutants using
biological material, has emerged as a costeffective alternative to this problem, as it
utilizes cheap or even waste materials to
remove heavy metal ions. Citrus fruit waste
material has proved its potential as an
efficient lead biosorbent [Volesky, 1990;
Annadurai et al., 2003]. Some of biosorption
studied in literatures were shown here below.
Thirumavalavan et al. [2010] and Li et al.
[2007] was demonstrated to convert solid
fruit peel residue into an effective adsorbent
for the adsorption of metal ions and
compared the activity with activated carbon.
Lemon peel, orange peel, and banana peel as
adsorbents for the removal of various metal
ions such as Cu(II), Ni(II), Zn(II), Pb(II), and
Cd(II). All these adsorbents were
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ISSN: 2229-6646
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ISSN: 2229-6646
surface area has obtained in the modified
orange
peel
and
banana
peel
[Thirumavalavan et al., 2010].
3.1. Scanning electron microscopy
(SEM)
Characterization of the banana peel and
orange peel was studied using SEM
micrograph in the Fig. 1(a) and Fig. 1(b). It
showed the morphology behavior of banana
peel and orange peel. This figures showed
that the peels have an irregular and porous
surface.
Similar
structure
and
morphological were observed on the orange
peel [Thirumavalavan et al., 2010].
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ISSN: 2229-6646
251Cel
0.246 mg/min
197Cel
0.204 mg/min
64Cel
0.258 mg/min
30.00
0.600
298Cel
0.428 mg/min
200.0
0.400
372Cel
0.149 mg/min
180.0
0.200
303Cel
15.46 uV
20.00
0.000
160.0
-0.200
-42.9 uJ/mg
10.00
50
147 uJ/mg
48
-0.400
140.0
46
-20.00
38
1383.45
1734.98
40
1637.24
28
22
174Cel
86.6%
-1.200
250Cel
72.2%
80.0
310Cel
54.1%
-1.400
-1.600
60.0
400Cel
41.2%
-60.00
-1.800
600Cel
33.0%
499Cel
34.8%
-2.000
40.0
300 0
250 0
200 0
150 0
100 0
100
150
200
250
300
350
Temp Cel
400
450
500
550
600
16
350 0
-2.200
50
18
400 0
100.0
-70.00
20
-0.800
-1.000
99Cel
91.1%
-50.00
3421.57
24
3821.14
3853.67
26
120.0
71Cel
-7.20 uV
-40.00
2923.06
30
24Cel
99.9%
-30.00
1054.40
34
3751.32
%T
36
32
-10.00
TG %
534.42
42
DTA uV
-0.600
44
500
W av enu mber s ( c m- 1)
2339.73
619.25
1236.34
0.000
10.00
134 uJ/mg
2924.75
3841.10
3854.83
20
120.0
-10.00
25Cel
100.0%
74Cel
-2.82 uV
175Cel
89.8%
-1.500
300Cel
59.1%
225Cel
77.0%
60.0
-30.00
350 0
300 0
250 0
200 0
150 0
100 0
425Cel
33.8%
500
W av enu mber s ( c m- 1)
-2.000
350Cel
43.1%
10
400 0
-1.000
80.0
3422.43
12
-0.500
100.0
100Cel
93.3%
-20.00
14
140.0
0.00
DTA uV
22
180.0
160.0
1071.46
1438.70
2849.32
24
%T
200.0
20.00
1637.65
3752.25
26
1742.33
28
16
330Cel
0.428 mg/min
67Cel
0.180 mg/min
30
18
210Cel
0.346 mg/min
30.00
-40.00
599Cel 40.0
26.3%
500Cel
28.4%
-2.500
50
100
150
200
250
300
350
Temp Cel
400
450
500
550
600
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DTG mg/min
32
TG %
34
DTG mg/min
0.00
ISSN: 2229-6646
final adsorbent prepared from waste fruit
peel is ~10 times less than the cost of
activated carbons, it is reasonable to
conclude that waste peel can be fruitfully
used as low-cost adsorbents for the
treatment of wastewater. Thirumavalavan
et al. [2010] suggested that a cost-effective
and viable technology for effective
elimination of heavy metal ions from
industrial wastewater could be developed
using easily available, familiar, and ecofriendly fruit peels.
Acknowledgement
Authors are deeply acknowledges the
financial support provided by MHRD,
India.
References
[1] Achaka M.; Hafidib A.; Ouazzania N.;
Sayadic S.; Mandia L., Low cost
biosorbent banana peel for the removal of
phenolic compounds from olive mill
wastewater: Kinetic and equilibrium
studies. J. Hazardous Mater. Vol. 166,
2009, p 117125.
[2] Ajmal M.; Mohammad A.; Yousuf R.;
Ahmad A., Adsorption behaviour of Cd,
Zn, Ni and Pb from aquous solutions by
Mangifera indica seed shell. Indian J.
Environ. Health, Vol. 40, 1998, p 1526.
[3] Ajmal, M.; Rao, R. A. K.; Ahmad, R.;
Ahmad, J. Adsorption studies on citrus
reticulate (fruit peel of orange): removal and
recovery of Ni from electroplating
wastewater. J. Hazard. Mater. Vol. 79,
2000, p 117131.
[4] Annadurai, G.; Juang, R. S.; Lee, D.J.,
Adsorption of heavy metals from water
using banana and orange peels. Water Sci.
Technol. Vol.7, 2003, p 185190.
[5] Bhatnagar A.; Minochaa K.; Sillanpa M.,
Adsorptive removal of cobalt from aqueous
solution A. by utilizing lemon peel as
biosorbent. Biochemical Eng. J. Vol. 48,
2010, p 181186.
[6] Biswas B.K.; Inoue J-I.; Kawakita H.; Ohto
K.; Inoue K., Effective removal and
recovery of antimony using metal-loaded
saponified orange waste. J. Hazardous
Mater. Vol.172, 2009, p 721728.
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