S GD & T BC NINH

Trng THPT Hn Thuyn

thi c 4 trang
Ngy thi 27/10/2016

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THI TH THPT QUC GIA LN 1

NM HC 2016-2017
Bi thi: Khoa hc t nhin; MN: Ha Hc
Thi gian lm bi 50 pht; khng k thi gian pht
( gm 40 cu trc nghim)

M thi 061
H, tn th sinh:....................................................................SBD
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t:
H = 1; Li = 7; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5;
K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Ba = 137.
----------------------------------------------------------------------Cu 1: Dung dch cht X khng lm i mu qu tm; dung dch cht Y lm qu tm ha xanh.
Trn ln hai dung dch trn thu c kt ta. Hai cht X v Y tng ng l
A. KNO3 v Na2CO3.
B. Ba(NO3)2 v Na2CO3.
C. Ba(NO3)2 v K2SO4.
D. Na2SO4 v BaCl2.
Cu 2: Axit no sau y l axit bo?
A. Axit aipic
B. Axit glutamic
C. Axit stearic
D. Axit axetic
Cu 3: Fructoz khng phn ng c vi cht no sau y?
A. Cu(OH)2 nhit thng.
B. H2 (xc tc Ni, t0).
C. nc Br2.
D. dung dch AgNO3/NH3, t0.
Cu 4: Ha cht no sau y khng c dng khi sn xut saccaroz trong cng nghip t cy
ma ?
A. Vi sa.
B. Kh sunfur.
C. Kh cacbonic.
D. Phn chua.
Cu 5: Thy phn este Z trong mi trng axit thu c hai cht hu c X v Y (MX < MY).
Bng mt phn ng c th chuyn ho X thnh Y. Cht Z khng th l.
A. metyl propionat.
B. etyl axetat.
C. vinyl axetat.
D. metyl axetat.
Cu 6: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C2H4O2 ln lt
tc dng vi: Na, dung dch NaOH, dung dch NaHCO3, dung dch AgNO3/NH3, t0. S phn ng
xy ra l
A. 3.
B. 5.
C. 6.
D. 4.
Cu 7: Cht kh no sau y c to ra t bnh cha chy v dng sn xut thuc gim au
d dy?
A. CO2.
B. CO.
C. CH4.
D. N2.
Cu 8: Hai cht ng phn ca nhau l
A. amiloz v amilopectin.
B. xenluloz v tinh bt.
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C. saccaroz v glucoz.
D. fructoz v glucoz.
Cu 9: Trong phn t ca cc cacbohyrat lun c
A. nhm chc xetn.
B. nhm chc axit.
C. nhm chc anehit.
D. nhm chc ancol.
Cu 10: Cho 0,1 mol tristearin tc dng hon ton vi dung dch NaOH d, un nng, thu c
m gam glixerol. Gi tr ca m l
A. 9,2.
B. 14,4.
C. 4,6.
D. 27,6.
Cu 11: iu kin thng, cacbohirat no sau y khng ha tan c Cu(OH)2.
A. saccaroz
B. fructoz
C. glucoz
D. xenluloz
Cu 12: Cho glixerol phn ng vi hn hp axit bo gm C17H35COOH v C15H31COOH, s loi
trieste c to ra ti a l
A. 3.
B. 5.
C. 6.
D. 4.
Cu 13: Sn phm ca phn ng nhit phn hon ton AgNO3 l:
A. Ag2O, NO2, O2.
B. Ag, NO2, O2.
C. Ag2O, NO, O2. D. Ag, NO, O2.
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Cu 14: Nh t t tng git n ht 30 ml dung dch HCl 1M vo 100 ml dung dch cha
Na2CO3 0,2M v NaHCO3 0,2M, sau phn ng thu c s mol CO2 l
A. 0,015.
B. 0,020.
C. 0,010.
D. 0,030.
Cu 15: Cho Fe tc dng vi dung dch H2SO4 long to thnh kh X; nhit phn tinh th KNO3
to thnh kh Y; cho tinh th KMnO4 tc dng vi dung dch HCl c to thnh kh Z. Cc kh X,
Y v Z ln lt l
A. SO2, O2 v Cl2.
B. Cl2, O2 v H2S. C. H2, O2 v Cl2.
D. H2, NO2 v Cl2.
Cu 16: C th phn bit 3 dung dch: KOH, HCl, H2SO4 (long) bng mt thuc th l
A. giy qu tm.
B. BaCO3.
C. Al.
D. Zn.
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Cu 17: Lng glucoz cn dng to ra 1,82 gam sobitol vi hiu sut 80% l
A. 1,80gam.
B. 2,25gam.
C. 1,82gam.
D. 1,44gam.
Cu 18: C th dng NaOH ( th rn) lm kh cc cht kh
A. NH3, SO2, CO, Cl2.
B. N2, Cl2, O2 , CO2, H2.
C. N2, NO2, CO2, CH4, H2.
D. NH3, O2, N2, CH4, H2.
Cu 19: Isoamyl axetat l este c mi chui chn c khi lng phn t l.
A. 116
B. 144
C. 102
D. 130
Cu 20: C 4 dung dch mui ring bit: CuCl2, ZnCl2, FeCl3, AlCl3. Nu thm dung dch KOH
(d) vo 4 dung dch trn, ri thm tip dung dch NH3 c (d) vo th sau khi kt thc cc phn
ng s cht kt ta thu c l
A. 3.
B. 2.
C. 4.
D. 1.
Cu 21: Trong cc th nghim sau:
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(1) Cho SiO2 tc dng vi axit HF.
(2) Cho kh SO2 tc dng vi kh H2S.
(3) Cho kh NH3 tc dng vi CuO un nng.
(4) Cho CaOCl2 tc dng vi dung dch HCl c.
(5) Cho Si n cht tc dng vi dung dch NaOH.
(6) Cho kh O3 tc dng vi Ag.
(7) Cho dung dch NH4Cl tc dng vi dung dch NaNO2 un nng.
S th nghim to ra n cht l
A. 4.
B. 5.
C. 6.
D. 7.
Cu 22: Mt phn t saccaroz c
A. mt gc -glucoz v mt gc -fructoz. B. mt gc -glucoz v mt gc -fructoz.
C. mt gc -glucoz v mt gc -fructoz. D. hai gc -glucoz.
Cu 23: Tc nhn ch yu gy ma axit l
A. SO2 v NO2.
B. CH4 v NH3.
C. CO v CH4.
D. CO v CO2.
Cu 24: Tng h s (cc s nguyn, ti gin) ca tt c cc cht trong phng trnh phn ng
gia Cu vi dung dch HNO3 c, nng l
A. 8.
B. 10.
C. 11.
D. 9.
Cu 25: iu kin thch hp xy ra cc phn ng sau:
(a) 2C + Ca CaC2.
(b) C + 2H2 CH4.
(c) C + CO2 2CO.
(d) 3C + 4Al Al4C3.
Trong cc phn ng trn, tnh kh ca cacbon th hin phn ng
A. (a).
B. (b).
C. (c).
D. (d).
Cu 26: Cht no sau y va tc dng c vi dung dch NaOH, va tc dng c vi nc
Br2?
A. CH3CH2CH2OH.
B. CH3CH2COOH. C. CH2=CHCOOH. D. CH3COOCH3.
Cu 27: iu ch 53,46 kg xenluloz trinitrat (hiu sut 60%) cn dng t nht V lt axit nitric
94,5% (D = 1,5 g/ml) phn ng vi xenluloz d. Gi tr ca V l
A. 36.
B. 60.
C. 24.
D. 40.
Cu 28: Cacbohirat no sau y thuc loi isaccarit?
A. Xenluloz.
B. Glucoz.
C. Saccaroz.
D. Amiloz.
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Cu 29: t chy 24,48 gam hn hp X gm glucoz v saccacroz cn dng 0,84 mol O2. Mt
khc un nng 24,48 gam X trong mi trng axit, thu c hn hp Y gm cc hp cht hu
c. Cho ton b Y tc dng vi lng d dung dch AgNO 3/NH3 un nng, thu c m gam Ag.
Cc phn ng xy ra hon ton. Gi tr ca m l.
A. 43,20 gam
B. 25,92 gam
C. 34,56 gam
D. 30,24 gam
Cu 30: un nng 14,64 gam este X (C7H6O2) cn dng 120 gam dung dch NaOH 8%. C cn
dung dch thu c lng mui khan l.
A. 22,08 gam
B. 28,08 gam
C. 24,24 gam
D. 25,82 gam
Cu 31: Ha tan ht m gam kim loi M cn dng 136 gam dung dch HNO3 31,5%. Sau khi kt
thc phn ng thu c dung dch X v 0,12 mol kh NO duy nht. C cn dung dch X thu c
(2,5m + 8,49) gam mui khan. Kim loi M l.
A. Ca
B. Mg
C. Zn
D. Cu
Cu 32: Hn hp X gm OHC-CC-CHO; HOOC-CC-COOH, OHC-CC-COOH. Cho m gam
hn hp X tc dng vi dung dch AgNO3 trong nc amoniac d (un nng nh) thu c 43,2
gam Ag. Mt khc m gam hn hp X tc dng vi NaHCO3 d thu c 11,648 lt CO2 (ktc).
Thm m gam glucoz vo m gam hn hp X sau em t cn 60,032 lt O2 (ktc), sn phm
sinh ra c hp th vo dung dch Ba(OH)2 d thu c 614,64 gam kt ta. Gi tr ca (m +
m) l
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A. 94,28
B. 88,24
C. 96,14
D. 86,42
Cu 33: X, Y, Z, T l mt trong s cc dung dch sau: glucoz; fructoz; glixerol; phenol. Thc
hin cc th nghim nhn bit chng v c kt qu nh sau:
Cht
Y
Z
X
T
Dung dch AgNO3/NH3, un Xut hin kt
Xut hin kt
nh
ta bc trng
ta bc trng
Nc Br2
Nht mu
Xut hin kt
ta trng
Cc dung dch X, Y, Z, T ln lt l.
A. fructoz, glucoz, glixerol, phenol.
B. phenol, glucoz, glixerol, fructoz.
C. glucoz, fructoz, phenol, glixerol.
D. fructoz, glucoz, phenol, glixerol.
Cu 34: t chy hon ton 10,58 gam hn hp X cha ba este u n chc, mch h bng
lng oxi va , thu c 8,96 lt kh CO2 (ktc). Mt khc, hiro ha hon ton 10,58 gam X
cn dng 0,07 mol H2 (xc tc, t0) thu c hn hp Y. un nng ton b Y vi 250 ml dung
dch NaOH 1M, c cn dung dch sau phn ng, thu c mt ancol Z duy nht v m gam rn
khan. Gi tr ca m l.
A. 15,60
B. 15,46
C. 13,36
D. 15,45
Cu 35: Thy phn hon ton cht bo X trong mi trng axit, thu c axit oleic v axit
stearic c t l mol tng ng 1 : 2. Khi lng phn t ca X l:
A. 886
B. 890
C. 884
D. 888
Cu 36: t chy X cng nh Y vi lng oxi va , lun thu c CO2 c s mol bng s mol
O2 phn ng. Bit rng X, Y (MX < MY) l hai este u mch h, khng phn nhnh v khng
cha nhm chc khc. un nng 30,24 gam hn hp E cha X, Y (s mol ca X gp 1,5 ln s
mol Y) cn dng 400 ml dung dch KOH 1M, thu c hn hp F cha 2 ancol v hn hp cha
2 mui. Dn ton b F qua bnh ng Na d thy khi lng bnh tng 15,2 gam. t chy hon
ton hn hp mui cn dng 0,42 mol O2. Tng s nguyn t c trong Y l.
A. 21
B. 20
C. 22
D. 19
Cu 37: Pht biu no sau y l ng?
A. Hiro ha hon ton glucoz (xc tc Ni, un nng) to ra sobitol.
B. Xenluloz tan tt trong nc v etanol.
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C. Saccaroz c kh nng tham gia phn ng trng bc.
D. Thy phn hon ton tinh bt trong dung dch H2SO4, un nng, to ra fructoz.
Trang 3/5 - M thi 061

Cu 38: T m gam tinh bt iu ch ancol etylic bng phng php ln men vi hiu sut ca c
qu trnh l 75%. Lng CO2 sinh ra t qu trnh trn c hp th hon ton vo dung dch
Ca(OH)2, thu c 50 gam kt ta v dung dch X. Thm dung dch NaOH 1M vo X, lng
kt ta thu c l ln nht th cn ti thiu 100 ml dung dch NaOH 1M. Gi tr ca m l
A. 75,6 gam
B. 64,8 gam
C. 84,0 gam
D. 59,4 gam
Cu 39: Ho tan 8,4 gam Fe vo 500 ml dung dch X gm HCl 0,2M v H2SO4 0,1M. C cn
dung dch thu c sau phn ng th thu c bao nhiu gam mui khan ?
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A. 18,75 gam
B. 16,75 gam
C. 19,55 gam
D. 13,95 gam
Cu 40: C bn dung dch ring bit c nh s: (1) H2SO4 1M; (2) HCl 1M; (3) KNO3 1M v
(4) HNO3 1M. Ly ba trong bn dung dch trn c cng th tch trn vi nhau, ri thm bt Cu
d vo, un nh, thu c V lt kh NO (ktc). Hi trn vi t hp no sau y th th tch kh
NO l ln nht?
A. (1), (2) v (3)
B. (1), (2) v (4)
C. (1), (3) v (4)
D. (2), (3) v (4)
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