No Volume (ml) T(O T(menit) Pengamatan

. C)
KI Amilu K2S2O8 Na2S2
m O3
1. 5 6tete 1 2.5 20 2 menit Ungu kecoklatan
s 35 s
2. 5 6tete 3 2.5 20 3 menit Ungu pekat
s 30 s
3. 5 6tete 5 2.5 20 2 menit Ungu cerah
s 36 s

1. 5 6tete 1 2.5 25 7 menit Ungu cerah

s 24 s
2. 5 6tete 3 2.5 25 3 menit Ungu cerah
s 10 s
3. 5 6tete 5 2.5 25 2 menit Ungu cerah
s 22 s

1. 5 6tete 1 2.5 30 6 menit Ungu cerah

s 18 s
2. 5 6tete 3 2.5 30 2 menit Ungu cerah
s 13 s
3. 5 6tete 5 2.5 30 2 menit 1 Ungu cerah
s s
Perhitungan

1.) Perhitungan
*KI
gr 1000
M = mr x v
gr 1000
0.4 = 166 x 250
gr
0.4 = 166 x4

4 gr
0.4 = 166
4gr = 66.4
Massa = 16.6 gr

*Na2S2O3
gr 1000
M= mr x v
gr 1000
1.1 = 158 x 250

gr
0.01 = 158 x4

4 gr
0.01 = 158

4gr = 1.58

Massa = 0.395gr

*K2S2O8

gr 1000
M= mr x v
 gr 1000
1.2 = 270 x 250

gr
0.02= 270 x4

4 gr
0.02= 270

4gr = 5.4

Massa = 1.35gr

*Amilum 2%

2
Gr = 100 x 50

Massa = 1gr
 2.) Penentuan nilai K
*Suhu 20oC
a.) V.K2S2O8 = 1ml = 1.10-3 L
n. K2S2O8 = M x V
= 0.02 x 1.10-3 = 2. 10-5 mol
n. KI =MxV
= 0.4 X 5.10-3 = 2.10-3 mol
Reaksi :
2KI + K2S2O8 2K2SO4 + I2

Mula : 2.10-3 2.10-5 - -

Reaksi : 4.10-5 2.10-5

Sisa : 0.00196 4.10 -5 2.10-5

b.) V.K2S2O8 = 3ml = 3.10-3 L

n. K2S2O8 = M x V
= 0.02 x 3.10-3 = 6. 10-5 mol
n. KI =MxV
= 0.4 X 5.10-3 = 2.10-3 mol
Reaksi :
2KI + K2S2O8 2K2SO4 + I2

Mula : 2.10-3 6. 10-5 - -

Reaksi : 12.10-5 6.10-5

Sisa : 0.00188 12.10-5 6.10-5

c.) V.K2S2O8 = 5ml = 5.10-3 L

n. K2S2O8 = M x V
= 0.02 x 5.10-3 = 1. 10-4 mol
n. KI =MxV
= 0.4 X 5.10-3 = 2.10-3 mol
Reaksi :
2KI + K2S2O8 2K2SO4 + I2

Mula : 2.10-3 1. 10-4 - -

Reaksi : 2.10-4 1. 10-4

Sisa : 0.0018 2.10 -4 1. 10-4

UNTUK T( 20OC)
T/OC V K2S2O8 (b-2x)mol Ln(b-2x) Waktu(s) k
O
20 C 1ml 0.00196 -6.23 2 menit 35 s 0.123
20 OC 3ml 0.00188 -6.28 3 menit 30 s 0.146
20 OC 5ml 0.0018 -6.34 2 menit 36 s 0.123
K ; 1ml

ln(b-2x) mol = -k

ln 0.00196 = -k (35) + ln -67

-6.23 = -k(35) - 1.9

-4.33 = -k(35)

k = 0.123

k ; 3 ml

ln(b-2x) mol = -k

ln 0.00188= -k (30)+ ln -67

-6.28 = -k(30) - 1.9

-4.38 = -k(30)

k = 0.146

k ; 5ml

ln(b-2x) mol = -k

ln 0.0018 = -k (36) + ln -67

-6.34 = -k(36) - 1.9

-4.44 = -k(36)

k = 0.123
 Ln (b-2x)mol
293031323334353637

-6.23

Ln (b-2x)mol
Axis Title -6.28
f(x) = - 0x - 6.16 Linear (Ln (b-2x)mol)
R = 0.04
-6.34

Axis Title

UNTUK T( 25OC)
T/OC V K2S2O8 (b-2x)mol Ln(b-2x) Waktu(s) k
O
25 C 1ml 0.00196 -6.23 7 menit 24 s 0.180
25OC 3ml 0.00188 -6.28 3 menit 10 s 0.438
25OC 5ml 0.018 -6.34 2 menit 22 s 0.201

K ; 1ml

ln(b-2x) mol = -k

ln 0.00196 = -k (24) + ln -67

-6.23 = -k(24) - 1.9

-4.33 = -k(24)

k = 0.180

k ; 3 ml

ln(b-2x) mol = -k

ln 0.00188= -k (10) + ln -67

-6.28 = -k(10) - 1.9

-4.38 = -k(10)

k = 0.438

k ; 5ml

ln(b-2x) mol = -k
ln 0.0018 = -k (22) + ln -67

-6.34 = -k(22) - 1.9

-4.44 = -k(22)

k = 0.201

Chart Title
5 10 15 20 25

-6.23 Ln (b-2x)mol
Linear (Ln (b-2x)mol)
Ln(b-2x) -6.28
f(x) = 0x - 6.29 Linear (Ln (b-2x)mol)
R = 0.01 Linear (Ln (b-2x)mol)
-6.34

T(C)

UNTUK T( 30OC)
T/OC V K2S2O8 (b-2x)mol Ln(b-2x) Waktu(s) k
25OC 1ml 0.00196 -6.23 6 menit 18 s 0.240
25OC 3ml 0.00188 -6.28 2 menit 13 s 0.337
25OC 5ml 0.018 -6.34 2 menit 1 s 4.44

K ; 1ml

ln(b-2x) mol = -k

ln 0.00196 = -k (18) + ln -67

-6.23 = -k(18) - 1.9

-4.33 = -k(18)

k = 0.240

k ; 3 ml

ln(b-2x) mol = -k

ln 0.00188= -k (13) + ln -67

-6.28 = -k(13) - 1.9

-4.39 = -k(13)

k = 0.337

k ; 5ml

ln(b-2x) mol = -k

ln 0.0018 = -k (1) + ln -67

-6.34 = -k(1) - 1.9

-4.44 = -k(1)

k = 4.44

Chart Title
0 5 10 15 20

-6.23
f(x) = 0.01x - 6.35 Ln (b-2x)mol
Ln(b-2x) R = 0.97 -6.28 Linear (Ln (b-2x)mol)
Linear (Ln (b-2x)mol)
-6.34 Linear (Ln (b-2x)mol)

T(C)

3.) Penentuan nilai Ea

V K2S2O8 = 1ml
T/ OK 1/T K Ln k
293 0.00341 0.123 -2.095
298 0.00335 0.146 -1.924
303 0.00330 0.123 -2.095
 f(x) =
R = 0 Chart Title
12
10
8
6
Axis Title Ln k
4
Linear (Ln k)
2
0
0 2 4 6 8 10 12

Axis Title

Y = mx + c

Ea = -(m x R)
Ea = -(-2038 x 8,314)
Ea = -16943.3 kj

V K2S2O8 = 3ml
T/ OK 1/T K Ln k
293 0.00341 0.180 -1.171
298 0.00335 0.438 -0.825
303 0.00330 0.201 -1.604

Chart Title
0 0
-2000.5 1 1.5 2 2.5 3 3.5
-400
-600 Ln k
-800 f(x) = - 216.5x - 492 Linear (Ln k)
Ln(b-2x)
-1,000 R = 0.07 Linear (Ln k)
-1,200 -1171
Linear (Ln k)
-1,400
-1,600 -1604
-1,800

T(C)
 Y = mx + c
Ea = -(m x R)
Ea =- (-216,51 x 8,314)
Ea = - 1800 kj

V K2S2O8 = 5ml

T/ OK 1/T K Ln k
293 0.00341 0.240 -1.427
298 0.00335 0.337 -1.087
303 0.00330 4.44 1.490

Chart Title
2,000
1,500 1,490
1,000
f(x) = 1458.5x - 3258.33
500 R = 0.84 Ln k
Ln(b-2x) 0 Linear (Ln k)
-5000.5 1 1.5 2 2.5 3 3.5 Linear (Ln k)
-1,000 -1,087 Linear (Ln k)
-1,500 -1,427
-2,000

T(C)
Y = mx + c
Ea = -(m x R)
Ea = -(1458,1 x 8,314)
Ea = 15448.2 kj