ALDEHYDES AND KETONES KEY

1 10 D A D B C D C A ,B,C,DB , D A,C
11 20A,B,D B C D A C 6 4 9 9
21 23 1 2 3
SOLUTIONS

1)

2) Wittig reaction
3) conceptual
NaBH 4 H NaBD4 D
4) supplies while supplies

5) 2 isomers 6 isomers 2 with ortho,meta and para

each of syn and anti

has 2 isomers
6) Four possible products are

* *
C H(OH) C H(OH)CHO
Aldol condensation
Tetrose
HO CH2 CHO HO CH2
It can be D, L-erythrose and D, L-threose
7) Electron with drawing group increases reactivity in Benzoin condensation

8) Alkyne gives 1,2dicarbonyl on the other hand alkene gives carbonyl

compounds by breaking double bond in Reductive ozonolysis.

9) Conceptual

10)

O O
ph C H
OH ph C H
OH

R .D .S O
ph C H

ph CH 2 O

PARAGRAPH -1 (12-13)

12. Hydride transfer step is slow step in cannizaro reaction

13. More reactive aldehyde is converted to acid

PARAGRAPH -2 (14- 16 )

A is B is F is G is

18) a ,c d f show positive test for Fehlings test

19. Pinacol-Pinacolone rearrangement
O H
20. CCCHO C =C C HO C = C C C=COC
O H O
O
C=CCOH O C C C
21.

22. FCH2CHO, O2N CH2CHO

C H 2 R
+
O M gX
X
+ RH + M g
C H 3O Cl
C
+
M gX O R
23. CH 3