ANDHERI / BORIVALI / DADAR / THANE / POWAI / CHEMBUR / NERUL / KHARGHAR

IIT JEE: 2017 CRASH COURSE (C - 2) DATE:18/11/16

TIME: 2HRS MAIN MARKS: 120
TOPIC: CHEMICAL EQUILIBRIUM, IONIC EQUILIBRIUM, CHEMICAL KINETICS

ANSWER KEY

1. (D) 2. (A) 3. (B) 4. (D) 5. (B)

6. (B) 7. (C) 8. (B) 9. (B) 10. (C)

11. (C) 12. (C) 13. (D) 14. (C) 15. (C)

16. (D) 17. (C) 18. (C) 19. (D) 20. (D)

21. (A) 22. (D) 23. (C) 24. (B) 25. (B)

26. (D) 27. (D) 28. (C) 29. (C) 30. (C)
 ANDHERI / BORIVALI / DADAR / THANE / POWAI / CHEMBUR / NERUL / KHARGHAR
IIT JEE: 2017 CRASH COURSE (C - 2) DATE:18/11/16
TIME: 2HRS MAIN MARKS: 120
TOPIC: CHEMICAL EQUILIBRIUM, IONIC EQUILIBRIUM, CHEMICAL KINETICS

SOLUTION
1. (D)
Since given K1 K 2
1011 e3000/T 1010 e2000/T
10 e1000/T
1000
n10
T
1000
T K
2.303

2. (A)

pH 14 pOH 14 pKb log
salt

base
80
So, 7.40 14 log pKb log pK b 6.0
20
K b 1.0 106

3. (B)
KOH is a strong electrolyte, so it ionizes completely. Hence OH 0.01M , which remains
constant, even at 500 C (assuming the volume of solution to be constant.)
Hence pOH log 0.01 2 , remains same.
At 500 C , pKw 14,
Since dissociation of water is endothermic
So, pH at 500 C pK w 2 12

4. (D)
A 3B 2C D
t 0 2a a 0 0
t eq 2a x a 3x 2x x
Given a-3x = 2x, xa 5
3x
Hence % of B reacted 100 60%
a

5. (B)
 In
pH pK In log pK In 1 (given)
HIn
In In
log 1 0.1
HIn HIn
0.1100 10
% ionized 9.1%
0.1 1 1.1

6. (B)
NH2COONH4 (S) 2NH3 g CO2 g
2P P
K P PNH PCO2 2P P 3.2 105 atm3
2 2
3

P 2 102 atm
PNH3 2P 2 2 102 4 102 atm

7. (C)
For equal Ea, forward and Ea backward, the reactant and product molecules have equal energies.
Hence, H 0; G H TS
Or G TS
For spontaneity G must be negative and hence S 0

8. (B)
H
nKp = Constant t
RT
Since H is ve for exothermic reaction, hence the plot (straight line) not passing through the origin
H
and will have a positive slope i.e. .
R
9. (B)
For a 10K rise in temperature, collision frequency increases merely by 1 to 2 % but the no. of
effective collisions increases by 100% to 200%.

10. (C)
2.0 103
K1 at 27 C
0
4.0
5 104
8 102
K 2 at 1270 C 20
4.0 103
K H T2 T1
log 2
K1 2.303R T1T2
T1 300K, T2 400K
2.303 8.314 300 400 20.0
H log J
100 4.0

11. (C)
Ice water, P = 1 atm, T = 273.15 K
 For P 1 and T 273.15K, the equilibrium shifts completely in forward direction leading to
reduction in volume of the system, i.e. ice melts completely.

12. (C)
H 1
nK constant
R T
Since Ea (forward) > Ea (backward), the reaction is endothermic, and so H 0
H
Slope
R

13. (D)
AgCl s Ag aq Cl aq
H2O

S S

Ksp Ag Cl
(A) In pure water solubility K sp
(B) In 0.1 M NaCl (strong electrolyte), Cl is the common ion, and Sc due to common ion effect
ionization of AgCl will be suppressed, so solubility is decreased.
Ksp Ag 1 Cl S1 S1 0.1 where S1 0.1M
Ksp S1 0.1
Ksp
S1
0.1
(C) Here Cl S2 0.2M 0.2M
Ksp S2 0.2
Ksp
S2 M
0.2
(D) Ag ion forms complex ion with NH3 as:

Ag aq 2 NH3 aq Ag NH3 2
Here solubility is increased (more than pure H 2 O , ) due to complehexation

14. (C)
PCl5 g PCl3 g Cl2 g
t eq 1
1
Mole reaction
1 1 1
P total pressure, degree of dissociation
12 P1 22 P2
KP
1 12 1 22
Since 1 0.5, 2 0.8, P1 4atm
P2 0.75atm .

15. (C)
 Data shows that t1/2 is inversely proportional to the initial pressure of the reactant. Hence, second
order reaction.

16. (D)
PC 5 PCl3 Cl2
t 0 1 0 0
T = eq. 1
Total moles at equilibrium 1 1
1
Molecular wt
moles

Molecular weight initially

n
Molecular weight at equilibrium 1
208.32
1 1.68
124
0.68

17. (C)
50 0.2
(I) HCl in the mixture 0.1M
100
H from HA (weak acid) is negligible due to common ion effect

H H 0.1M pH 1
HCl

(II) NaA HCl NaCl HA

50 0.2
HA 0.1M
100
Here no HCl is left
So H K a C 1.0 105 0.1 103
pH 3

18. (C)
The reaction is exothermic and takes place with a decrease in number of molecules of gaseous
species. Obviously high P and low T are the favorable conditions for of shifting the equilibrium to
product side. However, in ordinary flow process optimum elevated temperature is required to have
more NH3 due to high activation energy of the reaction. ( N 2 is quite stable at low T)

19. (D)
NH4OH aq H aq NH4 aq H2O
NH 4
K1 1.8 109
NH 4OH H


NH4 OH aq NH4 aq OH aq
NH 4 OH
K2
NH 4OH
K2
H OH K w 1.0 1014
K1
 1.0 1014 1.8 109 1.0 1014
K2
K1
1.8 105

20. (D)
Rate k A B
x y

Rate 0.024 0.070

2 x y
8 103
8
Rate 0.024 0.035 1103
3 x y

Or 2 y 8 y 3
Rate 2 8 103 0.024 0.070
x y

Also 2x
Rate 1 8 103 0.012 x 0.070 y
2x 1
Or x 0
d A
Rate K B A
3 0

dt

21. (A)
NaCN aq HCl aq HCN aq NaCl aq
t 0 50ml 0.1M 50ml 0.2M
5mmol 10m mol
HCl excess 10 5 5 m mol
5mmol
H 0.05M
100 ml
pH log 0.05 log 5 102
2 log5 2 0.6990
1.3
HCN practically remains unionized due to common ion effect of remaining HC

22. (D)
Each molecule of AB gets activated after absorption of one quantum of light. Hence, rate of
formation of AB* is proportional to the rate of quantum absorbed, i.e., the intensity of light I.

23. (C)
0.1
a H 0.05M ; pH log 0.05 1.301.
2
(b) Complete neutralization of strong acid and strong base, pH 7
(c) Hydrolysis of the salt CH3COOK, pH 7
(salt of weak acid and strong base)
(d) Hydrolysis of the salt NH4 NO3 , pH 7
(salt of strong acid and weak base)
24. (B)
Ea , uncata Ea , uncat T2 Ea , cat 75
0.75
T1 T2 T1 Ea ,uncat 100
300 300
0.75 T1 400 K 127o C
T1 0.75

25. (B)
Ksp Ca OH 2 4.0 106 Ca 2 OH
2

2
0.01 OH
OH 2 102 M
pOH log 2 102 2 log 2
pH 14 2 log 2 12 log 2

26. (D)
Rate of SN2 5.0 105 OH R X
Rate of SN 2
% of SN 2 100
Total rate SN1 SN 2
5 105 OH R X
100
5 105 OH R X 0.2 105 R X

5 10 5
102
100 20%
5 10 5
102 0.2 105

27. (D)
K Ae Ea / RT , K 2.3 103 min 1
e Ea / RT fraction of molecules crossing over the energy barrier
0.001
105
100
Hence 2.3 103 min 1 A 1.0 105
A 230 min 1
Kmax A when T
Hence Kmax 230 min 1

28. (C)
CO2 H2O HCO3 H
HCO3 H
K1 4.5 107
CO2
HCO3 4.5 107 4.5 107
Or 11.25
CO2 H 4 108
29. (C)
Ag 2 NH3 Ag NH3
2

The formation constant of the complex 108

This value is so high that we can practically assume that most of the Ag present in the reaction will
undergo complex formation

i.e. Ag NH3 2 Ag added 0.02 M
NH3 free 0.14 2 0.02 0.1M
Ag NH3 Ag 0.10
2 2

K d 10
8

Ag NH3 2

0.02
Ag 2 108 M

30. (C)

log
K2

Ea

4.606 103
2
K1 2.303RT 2.303 2 500
K
2 102 100
K1