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FIITJEE Students From All Programs have bagged 34 in Top 100, 66 in Top 200 and 174 in Top 500 All India Ranks. FIITJEE Performance in JEE (Advanced), 2014:
2521 FIITJEE Students from Classroom / Integrated School Programs & 3579 FIITJEE Students from All Programs have qualified in JEE (Advanced), 2014.
CONCEPT RECAPITULATION TEST - I
t h e t es t .
INSTRUCTIONS
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part has only one section: Section-A.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
Section-A (03 to 08) contains 6 multiple choice questions which have only one correct answer.
Each question carries +8 marks for correct answer and 2 marks for wrong answer.
Enrolment No.
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Useful Data
PHYSICS
Acceleration due to gravity g = 10 m/s2
3 3
Density of water water = 10 kg/m
CHEMISTRY
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Physics PART I
SECTION A
Single Correct Choice Type
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
3. A particle of charge q and mass m is projected from a large distance towards another
identical charged particle at rest with velocity v0. The distance of closest approach will be
(Assume negligible gravitational attraction)
q2 q2
(A) (B)
20mv 02 0mv 02
2q2 q2
(C) (D)
0mv 02 40mv 02
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5. In an npn transistor amplifier circuit when working in common emitter configuration when
the input signal changes by 0.02 V, the base current changes by 10 A and the collector
1 A. If the load in the collector circuit is 10 K for this the power given.
4 4
(A) 10 (B) 2 10
4
(C) 5 10 (D) 5 103
6. Two nicols A and B are placed in the path of a beam of unpolarised light. In between
these two a third nicol C is placed such that its principal section is at an angle of 30 with
that of A. The percentage of intensity of incident unpolarized light that emerges from C to
B.
(A) 2.8% (B) 9.4%
(C) 15.3% (D) 10.2%
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9. In problem 8, the current flowing in the upper arc PQ of the loop is given by (resistance
per unit length is )
3Bv 0a
(A) 0 (B)
2
3 3 3
(C) Bv 0 a (D) Bv 0a
2
0
10. A parallel beam of light of all wavelengths greater than 3000 A falls on a double slit in a
Young's double slit experiment. It is observed that the wavelengths 3600 A0 and 6000 A0
are absent at a distance of 31.5 mm from the position of the central maximum, and the
orders of the interference at this point for the two wavelengths differ by 7. If the distance
between the slits and the screen is 1m, the separation between the two slits is
(A) 0.08 mm (B) 0.13 mm
(C) 0.2mm (D) 0.1mm
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-3 -1 -3 -1
12. A thin walled cylindrical metal vessel ( = 10 K ) contains a liquid (r = 10 K ). If the
vessel and its contents are now heated by 10 K the pressure due to the liquid at the
bottom
(A) increases by 2 % (B) decreases by 1 %
(C) remains unchanged (D) decreases by 2%
15. 1 mole of H2 and 1 mole of He at a pressure of P0 & 2P0 respectively and a temperature
T0 are kept in two different containers. The ratio of their rms velocities is CH2 : CHe =
(A) 10 : 3 (B) 1 : 1
(C) 5 : 3 (D) 2 : 2
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0
16. The wavelength of the K line for an element is measured to be = 1.55 A . The
element has Z (atomic number) equal to
(A) 28 (B) 27
(C) 29 (D) 30
17. An equimolar mixture of a monoatomic and a diatomic ideal gas is suddenly compressed
1 th
to of its original volume. The ratio of final temperature to the initial temperature.
8
(A) 80.53 (B) 80.5
1.53
(C) 8 (D) 82/3
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22. A charged particle of mass m and charge e moves in a circular path of radius r under the
action of a constant magnetic field B acting perpendicular to the plane of its orbit. If
Bohr's postulate is valid for this system, then the radius of the path, r is given by
(A) r n2 (B) r 1/n
-n
(C) r e (D) r n
where n is the quantum number of the orbit.
23. The molar heat capacity of a diatomic ideal gas undergoing the process :
1/4
PV = constant is
17 2
(A) R (B) R
6 5
23
(C) R (D) 0
6
24. A wheel of radius r rolls without slipping on a flat surface, with its centre of mass
undergoing a linear deceleration a. Then,
(A) a non -zero toque is acting on the wheel about its CM.
(B) the net torque acting on the wheel may be zero or non-zero
(C) the net torque acting on the wheel is zero
(D) the net torque acting on the wheel cannot be calculated as the data is insufficient.
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25. A capacitor C and a resistance R are connected in a circuit in series with each other, so
that the capacitor discharges through R. If the temperature coefficient of the resistance is
positive, as the temperature increases the time constant of the circuit
(A) increases
(B) decreases
(C) remains uncharged
(D) may increase or decrease depending on other factors
26. A particle A having charge q is placed at a distance d from another particle B having an
equal charge q an dielectric slab of thickness t is placed midway between the two.
Electrostatic force on A due to B
(A) decreases
(B) increases
(C) remains constant
(D) may increase or decrease depending upon the magnitudes of the charges
27. A radioactive element A decays into another element B with a decay constant 4, which
then decays into a third element C (decay constant = 9). If all the atoms in the
beginning consisted of atoms of type A only, then the ratio of the number of atoms of A to
that of type B (i.e. NA/NB) when the number of atoms of B is at a maximum (NB is
maximum ) is
3 9
(A) (B)
2 4
1 ln3
(C) (D)
1 ln2
28. If planck's constant (h) were to be doubled while other fundamental quantities like and
charge mass electron. remaining constant the force acting on the electron in the nth orbit
of a hydrogen atom will
(A) increases 4 times (B) decrease 1/8 of its value
(C) remains unchanged (D) decreases 1/16 of its original value
29. A positron -electron pair form a hydrogen like system. Applying Bohr's theory to this
system and ignoring any relativistic effects, the distance (a) between the positron and
electron in the ground state is given by
(A) a > 0.53 A0 (B) a < 0.53 A0
0
(C) a = 0.53 A (D) a = 1.06 A0
30. Two identical spherical stars each having a mass equal to that of the sun move in a
common circular orbit of radius equal to the earth's orbital radius, under their mutual
gravitational interaction. Their time period of rotation equals
(A) 2yr (B) 1 yr
(C) 22 yr (D) 2 yr
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Chemistry PART II
SECTION A
Single Correct Choice Type
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
1. A gas in an open container is heated from 27C to 127C. The fraction of the original
amount of remaining in the container will be:
3 1
(A) (B)
4 4
1 1
(C) (D)
2 8
2+
3. The number of electrons gained in the following reaction Fe2(SO4)3 Fe + SO2 is
(A) 2 (B) 1
(C) 6 (D) 8
4. The values of observed and calculated molecular weights of silver nitrate are 92.64 and
170 respectively. The degree of dissociation of silver nitrate is
(A) 60% (B) 83.5%
(C) 46.7% (D) 60.23%
5. The pH of pure water at 25C and 35C are 7 and 6 respectively. The heat of formation of
water from H+ and OH are
1 1
(A) 84.55 kcal mol (B) 84.55 kcal mole
1
(C) 74.55 kcal mol (D) 74.55 kcal mole1
6. In a face centred cubic arrangement of A and B atoms whose A atoms are at the corner
of the unit cell and B atoms are at the face centres. One of the A atom is missing from
one corner in unit cell. The simplest formula of the compound is:
(A) A7B3 (B) AB3
(C) A7B24 (D) A7/8B3
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7. In which one of the following reactions, we will get only one crossed Aldol product,
(A) C6H5CHO, (CH3)2CO (B) C6H5CHO, CH3CHO
(C) C6H5CHO, (C2H5)2CO (D) CH3CHO, CH3CH2CHO
10. CH3
CH OH / OH
CH3 C CH2 A. A is
3
O
CH3
CH3
(A) CH3 C CH2 (B)
CH3OH + CH3 C = CH2
OCH3OH
CH3
CH3
(C) CH3 C CH2 (D)
HCHO + CH3 C = CH2
OH OCH3
+
11. HO CH2 CH2 X + HC C Na A + B
A & B can be
(A) HO CH2 CH2 C CH, NaX (B) Acetylene + NaO CH2 CH2 X
+ +
(C) Ethanol + XC CNa (D) Ethylhalide + HOC CNa
12. Which of the following will be most reactive towards the nucleophilic substitution.
Br OTs
(A) (B)
OH OSO2CF3
(C) (D)
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13. The correct order of hybridisation in the following species SO2, ClO3, XeF4 is
3 2 3 2 2 3 2
(A) sp , sp , sp d (B) sp , sp , sp d
2 3 3 2 3 3 2
(C) sp , sp , sp d (D) sp, sp , sp d
16. 17g of hydrogen peroxide is present in 1120 ml of solution. This solution is called
(A) 5 volume solution (B) 10 volume solution
(C) 15 volume solution (D) 16 volume solution
17. The density of a gas at 27C and 1 atm is d. Pressure remaining constant, at which of the
following temperature will its density become 0.75d.
(A) 20C (B) 30C
(C) 36C (D) 127C
18. Radioactivity of radioactive element remains 1/10 of the original radioactivity after 2.303
seconds. The half life period (in seconds) is
(A) 2.303 (B) 0.693
(C) 0.2303 (D) 0.0693
19. Assuming complete dissociation predict which of the following will have pH = 12.
(A) 500 ml 0.005 M NaOH (B) 1000 ml 0.005 M Ca(OH)2
(C) 100 ml 0.05 M Ca(OH)2 (D) 50 ml 0.05 M NaOH
20. The percentage of metal in its oxide is 60. The percentage of bromine in metal bromide
(oxidation state of metal remains the same) will be
(A) ~ 87 (B) ~ 97
(C) ~ 77 (D) ~ 80
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21. 50g of CaCO3 when treated with 60 ml of 20 N HCl at 300 K and 4 atm produces
(A) 22 g CO2 (B) 44g CO2
(C) 11g CO2 (D) 88 g CO2
5
22. A certain weak acid has a dissociation constant of 10 . The equilibrium constant for its
reaction with a strong base is
(A) 109 (B) 10+14
9
(C) 10 (D) 105
st
23. The set representing the correct order of 1 ionisation potential is
(A) Cu Ag Au (B) Au Ag Cu
(C) Ag Cu Au (D) Au Cu Ag
25. The number of monochloro derivaties of 2-methoxy propane are possible are
(A) 2 (B) 1
(C) 3 (D) 4
27. 0.10g of a sample containing CuCO3 and some inert impurity was dissolved in dilute
sulphuric acid and volume made up to 50 ml. This solution was added into 50 ml of 0.04
M KI solution where copper precipitates as CuI and I is oxidised into I3 . A 10 ml portion
of this solution is taken for analysis filtered and made up free I3 and then treated with
excess of acidic permanganate solution. Liberated iodine required 20 ml of 2.5 mM
sodium thiosulphate solution to reach the end point. Determine the wt. percentage of
CuCo3 in the original sample.
(A) 7.41 (B) 74.1
(C) 61.75 (D) None of these
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A
B H 2400 cal mol1
0.2
Fraction of moleculess
Frequency factor for both forward and backward reaction
is equal. The [Keq]400 K is 4e 0.5n.
A
The value of n is (Assume H independent of
temperature)
B
(Ea)b (Ea)f
Speed
(A) 1 (B) 2
(C) 4 (D) 6
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SECTION A
Single Correct Choice Type
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
1. Let y = f(x) be a curve passing through (e, ee), which satisfy the differential equation
e
(2ny + xy ln x) dx x ln x dy = 0, x > 0, y > 0. It g(x) = lim f x then
n g x dx equals to
1/e
(A) e (B) 1
(C) 0 (D) none of these
2. The smaller area enclosed by y = f(x), when f(x) is a polynomial of least degree satisfying
1/ x
f x 2 2
lim 1 3 e and the circle x + y = 2 above the x-axis is
x 0
x
3
(A) (B)
2 5
3 3
(C) (D)
2 5 2 5
1 cos 2 t
3. For x R and a continuous function f, let I1 x f x 2 x dx ,
sin2 t
1 cos2 t
I1
I2 f x 2 x dx . Then is
sin2 t
I2
(A) 0 (B) 1
(C) 2 (D) 3
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2 2x 2 12xf x f x
4. If xf(x) = 3(f(x)) + 2, then 2
dx equals to
6f x x x2 f x
1 1
(A) 2
c (B) 2
c
x f x x f x
1 1
(C) c (D) c
x f x x f x
y y
5. If f 2x , 2x xy , then f(m, n) + f(n, m) = 0
8 8
(A) only when m = n (B) only when m n
(C) only when m = n (D) for all m and n
1 1
7. A function g(x) is defined as g x
4
f 2x 2 1 f 1 x 2 and f(x) is an increasing
2
function then g(x) is increasing in the interval
2 2 2 2
(A) , (B) , 0 ,
3 3 3 3
(C) (1, 1) (D) none of these
8. If sin and cos are the roots of the equation ax2 bx c = 0, where a, b, c are the
sides of a triangle ABC, then cos B is equal to
c c
(A) 1 (B) 1
2a a
c c
(C) 1 (D) 1
2a 3a
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x
a a
t
2
9. The equation 8t 13 dt x sin has a solution if sin is equal to
0 x 6
1
(A) 1 (B)
2
1
(C) (D) 0
2
10. If x and y are two non-collinear vectors and a triangle ABC with side lengths a, b, c
satisfying
20a 15b x 15b 12c y 12c 20a x y 0 . Then triangle ABC is
(A) an acute angle triangle (B) an obtuse angle triangle
(C) a right angle triangle (D) an isosceles triangle
11. The Cartesian equation of the plane r 1 i 2 j 3 2 2 k is
(A) 2x + y = 5 (B) 2x y = 5
(C) 2x + z = 5 (D) 2x z = 5
x2 y2 2
12. If the ellipse y 2 1 meets the ellipse x 2 1 in four distinct points and a = b
4 a
5b + 7, then b does not lie in the interval
(A) [4, 5] (B) (, 2) (3, )
(C) (, 0) (D) [2, 3]
x2 y2
13. Portion of asymptote of hyperbola 1 (between centre and the tangent at vertex)
a2 b 2
in the first quadrant is cut by the line y + (x a) = 0 ( is a parameter) then
(A) R (B) (0, )
(C) (, 0) (D) R {0}
14. A focal chord of parabola y2 = 4x is inclined at an angle of with positive x-direction,
4
then the slope of normal drawn at the ends of chord will satisfy the equation
2 2
(A) m 2m 1 = 0 (B) m + 2m 1 = 0
2 2
(C) m 1 = 0 (D) m + 2m 2 = 0
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15. The range of values of a such that the angle between the pair of tangents drawn from
2 2
(a, 0) to the circle x + y = 1 lies in the interval , is
3
(A) (2, 1) (1, 2)
(B) 2, 0 0, 2
(C) 3, 2 (D) 3, 2 2, 3
16. The equation of the parabola to which the line m2(y 10) mx 1 = 0 is a tangent for
any real value of m is
2 2
(A) x = 4y (B) x = 4(y 10)
2 2
(C) y = 4(x 4) (D) x = y 10
17. Consider a curve ax 2 + 2hxy + by2 1 = 0 and a point P not on the curve. A line drawn
from the point P intersects the curve at the points Q and R. If the product PQPR is
independent of the slope of the line, then the curve is
(A) a pair of straight lines (B) a circle
(C) a parabola (D) an ellipse or a hyperbola
18. In a ABC if A = (1, 2) and internal angle bisectors through B and C are y = x and y =
2x. The in radius r of ABC is
1 1
(A) (B)
3 2
2
(C) (D) none of these
3
19. If 0 [x] < 2; 1 [y] < 1 and 1 [z] < 3 (where [.] denotes the greatest integer function)
x 1 y z
then the maximum value of determinant x y 1 z is
x y z 1
(A) 2 (B) 6
(C) 4 (D) none of these
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m
1 xi 1
21. If m and x are two real numbers, then the real value of e2mi cot x
xi 1 is equal to
m
(A) cos x + i sin x (B)
2
m
(C) 1 (D) 1
2
200
5
22. If {x} represents the fractional part of x, then is
8
1 1
(A) (B)
4 8
3 5
(C) (D)
8 8
a 2a3 a 2 a3 a a3
23. If 3 2 , then a1, a2, a3, a4 are in
a1a 4 a1 a4 a1 a 4
(A) A.P. (B) G.P.
(C) H.P. (D) none of these
24. n-similar balls each of weight w when weighed in pairs the sum of the weights of all the
possible pairs is 120 when they are weighed in triplets the sum of the weights comes out
to be 480 for all possible triplets, then n is
(A) 20 (B) 10
(C) 16 (D) 28
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25. If a, b, c are unit vectors such that a 2b 3c 3 2 2 . Angle between a and b is
2
, between a and c is and angle between b and c varies in , , then the
2 3
greatest value of 4 cos + 6 cos is
(A) 2 2 5 (B) 2 2 5
(C) 2 2 5 (D) 2 2
26. If two events A and B are such that P(Ac) = 0.3, P(B) = 0.4 and P(A Bc) = 0.5 then
B
P C
is equal to
A B
(A) 0.9 (B) 0.5
(C) 0.6 (D) 0.25
27. ABC is a triangular park with AB = AC = 100m. A block tower is situated at the midpoint
of BC. The angles of elevation of the top of the tower at A and B are cot1(3.2) and cosec
1
(2.6) respectively. The height of the tower is
(A) 16 m (B) 25 m
(C) 50 m (D) none of these
29. If the normal to the curve y = f(x) at x = 0, be given by the equation 3x y + 3 = 0, then
1
x 0
the value of lim x 2 f x 2 5f 4x 2 4f 7x 2 is equal to
1 1
(A) (B)
3 3
1 1
(C) (D)
5 4
30. Let P (n) be the statement 2n < n ! where n is a natural number, then P (n) is true for
(A) all n (B) all n > 2
(C) all n > 3 (D) none of these
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