Professional Documents
Culture Documents
4, 2009 469
François Flory
Directeur de Centrale Marseille Recherche et Technologies,
and IM2NP UMR 6242,
Ecole Centrale Marseille,
Technopole de Chateau-Gombert,
38 rue Joliot Curie, 13451 Marseille Cedex 20, France
E-mail: francois.flory@ec-marseille.fr
Abstract: Organic Solar Cells (OSC) have received increasing attention over
the last few years for their potential technological applications as well as
fundamental science. To increase the part of the incident light which is
absorbed in the photoactive layer, optical properties of the cell are critical and
should be optimised. In this paper, we review how photonics has stimulated
researches and news experimental approaches to improve photovoltaic
conversion in OSC. Solutions used to confine the light in the device are
described and new architectures of organic solar cell are presented.
Reference to this paper should be made as follows: Simon, J-J., Escoubas, L.,
Monestier, F., Torchio, P. and Flory, F. (2009) ‘Optical properties engineering
for Organic Solar Cells’, Int. J. Materials and Product Technology, Vol. 34,
No. 4, pp.469–487.
Florent Monestier was graduated from the Engineer School of Dijon (France)
in 2004. After he did receive his PhD Degree (2008) from the University
Paul Cezanne of Marseille, he joined the Astron-Fiamm-safety company
as engineer.
François Flory received his PhD in 1978 and his ‘thèse d'Etat’ in 1985 in light
scattering and in the relation between optical properties and the microstructure
of thin films, respectively. He is now Professor in Optics at the Ecole Centrale
de Marseille. He is editor of the book Thin Films for Optical Systems and
of more than 150 papers and communications. He has been chairman or
member of the scientific committee of more than 15 international conferences.
His current research interest is now in the field of micro/nano photonics.
1 Introduction
The aim of this paper is to review how photonics has stimulated researches and news
experimental approaches to improve photovoltaic conversion in OSC. After a short
historic review of OSC, we will described, in the first part of this paper, the general
architecture of OSC and the physical mechanisms leading to the generation and collection
of charge carriers in such devices. Differences between OSC and conventional solar cells
(silicon based) will be underlined. In a second part, we will focus on the optical
optimisation of a standard organic solar cell (modulation of the electromagnetic field
inside the device – implementation of periodic structures – realisation of tandem
cells – use of plasmon properties). The third part will be devoted to news concepts and
architectures of OSC. We will present recent efforts and promising routes to increase the
interaction between light and OSC.
Figure 1 Schematic of an Organic Solar Cell (see online version for colours)
Figure 2 Energetic diagram and photovoltaic conversion process in OSC (see online version
for colours)
C60 based fullerenes. Because the separation is faster than any other competing process,
its efficiency is about 100%.
The basic idea developed in this paragraph is to increase the part of the incident light
which is absorbed in the photoactive layer.
An example of the spectral redistribution of the incoming light (on reflection
and layer absorption) for a standard bulk heterojunction solar cells (pentacene:
PTCDI-C13H27 blend) is shown in Figure 3. If most of the incoming light is absorbed in
the blend in the 400–700 nm range, average reflection is about 10%, ITO absorption is
about 15% while PEDOT absorbs mainly in the blue range (4%). Although a remarkably
high external quantum yield measured in this device (83%), the best power conversion
efficiency reported for this couple of materials does not exceed 2% (Pandey et al., 2006).
Figure 3 Electromagnetic field distribution in OSC (see online version for colours)
The first approach to improve the performance of the cell is to increase the thickness of
the absorbing layer. However, this thickness is generally restricted (<150 nm) by the
Optical properties engineering for Organic Solar Cells 475
limited charge carrier mobility in conjugated polymers (highly efficient devices with
thickness around 200–250 nm have been recently demonstrated (Irwin et al., 2008)).
Thus, to overcome this problem and from the optical point of view the following
solutions can be considered:
• optimisation of the electromagnetic field distribution inside an OSC
• fabrication of tandem cells
• implementation of periodic structures (such as gratings or photonic crystals) in the
thin layers stacking
• investigation of plasmons effects for increasing absorption in OSC.
where Q is the local energy dissipated in the material, ε0 is the permittivity of vacuum
and µ0 is the permeability of vacuum, α is the absorption coefficient, n0 is the real part of
the complex refractive index of the glass substrate, and Isolar light is the polychromatic
incoming light with standard AM1.5 distribution. Indeed, from equation 1 and by taking
into account values (ηA, ηD and ηCC), the generation rate of free carriers G(z) and
the short current density Jsc can be computed (Peumans et al., 2003) and used to predict
the organic solar cell efficiency. Thus, a large number of recent papers concerns the
comparison between experimental results and optical modelisation of OSC (Sievers et al.,
2006; Monestier et al., 2007b; Sylvester-Hvid et al., 2007). For example, it has been
shown that the dependency with the active layer thickness of the short circuit current
density of OSC based on blend heterojunction (Figure 5) follows a rather complicated
behaviour (Moulé and Meerholz, 2007; Hoppe and Sariciftci, 2007; Monestier et al.,
2007b). Furthermore, based on the electromagnetic field optimisation, Monestier et al.
(2007a) has developed an automatic software for optimising the design of OSC.
As regards organic tandem cells, this software is set to find simultaneously optimal
thickness of each layer and to balance the photocurrent in the two active regions.
In summary, optical modelling is essential to understand the behaviour of OSC devices
consisting of multilayer structures.
476 J-J. Simon et al.
Figure 5 Comparison of computed short circuit current density (solid line) with experimental
data (circles) as a function of blend thickness
tandem cells. For more details please refer to the review of organic tandem cells
which has been recently published by Hadipour et al. (2008). The first significant
power conversion efficiency of an organic tandem cell (2.5 %) has been described by
Yakimov and Forrest (2002). The two cells were connected by a silver layer. In the work
of Xue et al. (2004) related to tandem cells based on evaporated layers of small molecules
(CuPc and C60), a power conversion efficiency higher than 5% is achieved using Ag
nanoclusters with a typical thickness 0.5 nm instead of a very thin Ag interlayer as used
before for the separating layer. The role of the Ag nanoclusters is not yet clearly
understood, in addition to recombination centres, silver particles can also serve as
scattering centres for incident light and can also excite plasmons as it will be shown in
the part three of this paper. Then, various concepts of intermediate layer were
successively introduced in order to allow the fabrication of polymer tandem cells:
• by Kawano et al. (2006) with ITO deposited by sputtering
• by Hadipour et al. (2006) with a composite layer of Al, Au, Lif and PEDOT:PSS
• by Gilot et al. (2007a) with ZnO nanoparticles deposited by spin coating and covered
by a neutral PEDOT layer.
Finally, with a power conversion of 6.7% the recent work of Kim et al. (2007) is the best
power conversion efficiency reported until now and not only for organic tandem solar
cells but for all OSC. To reach this value, the authors have used a highly transparent
sol-gel processed titanium oxide (TiOx) as intermediate layer and a second TiOx layer
between the top cell and the Al electrode (Figure 6). As explained by the authors, this
second layer acts as an optical spacer that redistributes the light intensity to optimise the
efficiency of the back cell. This work confirms that inserting a transparent electron
transporting layer between the active layer and the Al top electrode allows us to confine
the electromagnetic field inside the active layer. The same effect has also been
demonstrated by Gilot et al. (2007b) with a ZnO layer as the optical spacer.
Figure 6 Tandem polymer solar cell as describe in by Kim et al. (2007) (see online version
for colours)
It is important to note that more than 200 individual tandem cells were necessary,
as reported by the authors, to optimise the fabrication procedure and device architecture
478 J-J. Simon et al.
(optimising and balancing the current in each subcell), proving that the optical
modelisations described previously are essential.
In summary, the organic tandem cell research has developed during the last five years
with a scientific interest triggered by a rapid increase in power conversion efficiencies.
This was achieved by the introduction of new materials, but mainly by the improvement
of technical processes (sol-gel technique) and the improvement of the understanding
of the optical properties of the multilayer structure. To go further, the knowledge coming
from optical interference coatings (generally inorganic) may allow the development
of new concepts.
Figure 7 Diffractive optical structures in OSC (diffraction gratings (a) and buried
nano-electrodes (b)) as describe by Yang et al. (2007) (see online version for colours)
Still to increase the interaction of the light with the photoactive layer, an original study of
nanometric periodic patterning for enhancement of OSC power efficiency has been
reported by Cocoyer et al. (2006). As illustrated in Figure 9, a nanostructured azopolymer
layer is used as a substrate in a classical CuPc/C60 bilayer organic solar cell
(ITO/PEDOT/CuPc/C60/BCP/Ag). Sinusoidal periodic structures are realised in one step
using optical interferences. A mass transport process occurs in azopolymer films when
illuminated. According to the grating formula, new absorption bands (which depends on
the grating period) appear in the external quantum efficiency spectra leading to an
enhancement of the short-circuit photocurrent (Jsc) of about 15%. Indeed 2D gratings
can increase the interaction of the light with the photoactive layers in OSC by coupling a
part of the solar spectrum into a quasi-guided mode. This is clearly one of the solution
to increase the overlapping between the absorption range of OSC and the solar spectrum.
Before closing this part, we would like to mention a preliminary study of Escarre
et al. (2005) devoted to the realisation of random roughness surfaces on plastic substrates
by means of hot embossing processes. Different random roughnesses (nanometer and
micrometer sizes) have been transferred on poly(methylmethacrylate) (PMMA) using
two kind of master (commonly available frosted glass and commercial transparent
conductive oxide). After stamping, the PMMA rough surfaces have been optically
characterised by measuring the transmitted and reflected scattered light (red-diode laser
source (λ = 633 nm)). With a roughness RMS value around 2.6 µm, the PPMA layer
embossed with a frosted glass exhibits the best optical behaviour (much closer to an ideal
diffuser). Beyond the results, this work demonstrates that a low cost technique
480 J-J. Simon et al.
(hot embossing) with available and cheap masters (frosted glass) can be used to produce
random textures on plastic surfaces. This can be of a great interest to enhance the
absorption an OSC, especially in the near infra-red domain.
D-A heterojonctions including a very thin metallic nanocluster layer separating each
subcell. It was shown an optical-field enhancement due to plasmon generation on the
ultra-thin cluster surfaces which involved higher efficiencies.
Figure 10 Schematic of the simple structure with the intermediate metallic clusters layer
At the same time, apart the development of new photovoltaic organic materials,
many studies concern new architectures of organic solar cell which are alternative to the
typical thin film structures described in the first part of this paper. This research area can
be illustrated by four examples of architectures in which new optical properties of OSC
are demonstrated:
• an organic solar cell manufactured on the model of an optical fibre (Liu et al., 2007)
• a folded reflective tandem organic solar cell (Tvingstedt et al., 2007)
• an OSC without ITO (Tvingstedt and Inganas, 2007)
• a luminescent concentrator coupled to an organic solar cell (Koeppe 2007).
Figure 11 Optical fibre based architecture for OSC as describe by Liu et al. (2007)
(see online version for colours)
Figure 12 Folded reflective tandem organic solar cell as describe by Tvingstedt et al. (2007)
(see online version for colours)
more complex stacks like a thin metallic layer embedded between two transparent layers.
Metallic grids are already used to realised the electrode at the front side of silicon solar
cells. The thickness of the silver grips for OSC is much smaller than in the case of silicon
solar cells (around 100 nm instead of more than 10 µm) but the working principle is the
same: dimensions of the grids are optimised to reach the conductivity needed (around
2 × 105 S.cm–1) and the period of the structure is calculated to minimise the shadow effect
of the metallic grids. The power conversion efficiency (1%) of this free ITO solar cell is
found to be better than the ITO based OSC (0.83%). This remarkable result is obtained
by using a new high conductive layer: a PEDOT:PSS with diethylene glycol (DEG) for
which conductivity is 4000 times higher than conventional PEDOT:PSS. However, if the
concept of such architecture without expensive ITO is demonstrated, the process to
realise the grids remains complex with a fluidic deposition method exploiting PDMS
stamps. For manufacturing, a cheaper grids deposition technique should be developed.
Figure 13 Architecture of an OSC without ITO as describe by Tvingstedt and Inganas (2007)
(see online version for colours)
6 Conclusion
Recently, OSC have broken the 6.5% power conversion efficiency barrier. In this paper
we have reviewed how photonics has stimulated researches and news experimental
approaches to improve photovoltaic conversion in OSC. If it seems to be sure that new
materials are needed to push the efficiencies into the 10% range, developing new optical
concepts (including photonic crystal for example) might be one promising way for OSC
development.
References
Berning, T.A. and Berning, P.H. (1963) ‘Theory and calculation of optical thin films’, Physics of
Thin Films, p.69.
Brabec, C.J., Zerza, G., Cerullo, G., De Silvestri, S., Luzzati, S., Hummelen, J.C. and
Sariciftci, N.S. (2001) ‘Tracing photoinduced electron transfer process in conjugated
polymer/fullerene bulk heterojunctions in real time’, Chem. Phys. Lett., Vol. 340, p.232.
Cocoyer, C., Rocha, L., Sicot, L., Geffroy, B., de Bettignies, R., Sentein, C.,
Fiorini-Debuisschert, C. and Raimond, P. (2006) ‘Implementation of submicrometric periodic
surface structures toward improvement of organic-solar-cell performances’, Appl. Phys. Lett.,
Vol. 88, p.133808/1-3.
Derkacs, D., Lim, S.H., Matheu, P., Mar, W. and Yu, E.T. (2006) ‘Improved performance of
amorphous silicon solar cells via scattering from surface plasmon polaritons in nearby metallic
nanoparticles’, Appl. Phys. Lett., Vol. 89, p.093103.
Escarre, J., Villar, F., Fonrodona, M., Soler, D., Asensi, J.M., Bertomeu, J. and Andreu, J. (2005)
‘Optical analysis of textured plastic substrates to be used in thin silicon solar cells’,
Solar Energy Materials and Solar Cells, Vol. 87, pp.333–341.
Gilot, J., Wienk, M.M. and Janssen, R.A.J. (2007a) ‘Double and triple junction polymer solar cells
processed from solution’, Appl. Phys. Lett., Vol. 90, p.143512.
Gilot, J., Barbu, I., Wienk, M.M. and Janssen, R.A.J. (2007b) ‘The use of ZnO as optical spacer in
polymer solar cells: theoretical and experimental study’, Appl. Phys. Lett., Vol. 91, p.113520.
Gregg, B.A. (2003) ‘Excitonic solar cells’, J. Phys. Chem. B, Vol. 107, No. 20, pp.4688–4698.
Hadipour, A., de Boer, B., Wildeman, J., Kooistra, F.B., Hummelen, J.C., Turbiez, M.G.R.,
Wienk, M.M., Janssen, R.A.J. and Blom, P.W.M. (2006) ‘Solution-processed organic tandem
solar cells’, Adv. Funct. Mater., Vol. 16, pp.1897–1903.
Hadipour, A., de Boer, B. and Blom, P.W.M. (2008) ‘Organic tandem and multi-junction solar
cells’, Adv. Funct. Mater., Vol. 18, p.169.
Optical properties engineering for Organic Solar Cells 485
Hava, S. and Auslender, M. (2000) ‘Design and analysis of low-refection grating microstructures
for a solar energy absorber’, Solar Energy Materials and Solar Cells, Vol. 61, pp.143–151.
Hoppe, H. and Sariciftci, N.S. (2007) ‘Polymer solar cells’, Adv. Polym. Sci., p.121.
Irwin, M.D., Buchholz, D.B., Hains, A.W., Chang, R.P.H. and Marks T.J. (2008) ‘p-Type
semiconducting nickel oxide as an efficiency-enhancing anode interfacial layer in polymer
bulk-heterojunction solar cells’, PNAS, Vol. 105, No. 8, pp.2783–2787.
Jurchescu, O.D., Baas, J. and Palstra, T.T.M. (2004) ‘Effect of impurities on the mobility of single
crystal pentacene’, Appl. Phys. Lett., Vol. 84, No. 16, p.3061.
Kallmann, H. and Pope, M. (1959) ‘Photovoltaic effect in organic crystals’, Journal of Chemical
Physics, Vol. 30, p.585.
Kawano, K., Ito, N., Nishimori, T. and Sakai, J. (2006) ‘Open circuit voltage of stacked bulk
heterojunction organic solar cells’, Appl. Phys. Lett., Vol. 88, p.073514.
Kim, J.Y., Lee, K., Coates, N.E., Moses, D., Nguyen, T., Dante, M. and Heeger, A.J. (2007)
‘Efficient tandem polymer solar cells fabricated by all-solution processing’, Science, Vol. 317,
p.222.
Kim, J., Kim, S., Lee, H., Lee, K., Ma, W., Gong, X. and Heeger, A.J. (2006) ‘New architecture for
high-efficiency polymer photovoltaic cells using solution-based titanium oxide as an optical
spacer’, Adv. Mater., Vol. 18, p.572.
Koeppe, R., Sariciftci, N.S. and Büchtemann, A. (2007) ‘Enhancing photon harvesting in organic
solar cells with luminescent concentrators’, Appl. Phys. Lett., Vol. 90, p.181126.
Liu, J., Namboothiry, M.A.G. and Carroll, D.L. (2007) ‘Optical geometries for fiber-based organic
photovoltaics’, Appl. Phys. Lett., Vol. 90, p.133515.
Monestier, F., Torchio, P., Simon, J.J., Escoubas, L. and Cathelinaud, M. (2007a) ‘Software for
automatic optimization of the electromagnetic field in organic solar cells’, Nonlinear Optics
and Quantum Optics, Vol. 37, pp.159–168.
Monestier, F., Simon, J.J., Torchio, P., Escoubas, L., Flory, F., Bailly, S., De Bettignies R.,
Guillerez, S. and Defranoux, C. (2007b) ‘Modeling the short-circuit current density of
polymer solar cells based on P3HT:PCBM blend’, Sol. Energ. Mater. Sol. Cells, Vol. 91,
pp.405–410.
Moulé, A.J. and Meerholz, K. (2007) ‘Minimizing optical losses in bulk heterojunction polymer
solar cells’, Appl. Phys. B, Vol. 86, pp.721–727.
Niggemann, M., Glatthaar, M., Gombert, A., Hinsch, A. and Wittwer, V. (2004) ‘Diffraction
gratings and buried nano-electrodes – architectures for organic solar cells’, Thin Solid Films,
Vol. 451–452, pp.619–623.
Pandey, A.K., Dabos-Seignon, S. and Nunzi, J-M. (2006) ‘Pentacene:PTCDI-C13H27 molecular
blends efficiently harvest light for solar cell applications’, Appl. Phys. Lett., Vol. 89, p.113506
Pettersson, L.A.A., Roman, L.S. and Inganas, O. (1999) ‘Modeling photocurrent action spectra of
photovoltaic devices based on organic thin films’, Journal of Applied Physics, Vol. 86, No. 1,
pp.487–496.
Peumans, P., Yakimov, A. and Forrest, S.R. (2003) ‘Small molecular weight organic thin-film
photodetectors and solar cells’, J. Appl. Phys., Vol. 93, p.3693.
Pillai, S., Catchpole, K.R., Trupke, T. and Green, M.A. (2007) ‘Surface plasmon enhanced silicon
solar cells’, J. Appl. Phys., Vol. 101, p.093105.
Rand, B.P., Genoe, J., Heremans, P. and Poortmans, J. (2007a) ‘Solar cells utilizing small
molecular weight organic semiconductors’, Prog. Photovolt: Res. Appl., Vol. 15, pp.659–676.
Rand, B.P., Peumans, P. and Forrest, S.R. (2007b) ‘Long-range absorption enhancement in organic
tandem thin-film solar cells containing silver nanoclusters’, J. Appl. Phys., Vol. 96, No. 12,
p.7519.
Schaadt, D.M., Feng, B. and Yu, E.T. (2005) ‘Enhances semiconductor optical absorption
via surface plasmon excitation in metal nanoparticles’, Appl. Phys. Lett., Vol. 86, p.063106.
486 J-J. Simon et al.
Shaheen, S., Radspinner, R., Peyghamberian, N. and Jabbour, G. (2001) ‘Fabrication of bulk
heterojunction plastic solar cells by screen printing’, Appl. Phys. Lett., Vol. 79, p.2996.
Sievers, D.W., Shrotriya, V. and Yang, Y. (2006) ‘Modeling optical effects and thckness dependent
current in polymer bulk-heterojunction solar cells’, J. Appl. Phys., Vol. 100, p.114509.
Stenzel, O., Stendhal, A., Voigtsberger, K. and von Borczyskowski, C. (1995) ‘Enhancement of the
photovoltaïc conversion efficiency of copper phthalocyanine thin film devices by
incorporation of metal clusters’, Solar Energy Materials and Solar Cells, Vol. 37, pp.337–348.
Sylvester-Hvid, K.O., Ziegler, T., Riede, M.K., Keegan, N., Niggemann, M. and Gombert, A.
(2007) ‘Analyzing P3HT/PCBM bulk-heterojunction solar cells by UV-visible spectroscopy
and optical simulations’, Journal of Applied Physics, Vol. 102, p.054502.
Tang, C.W. (1986) ‘2-layer organic photovoltaic cell’, Appl. Phys. Lett., Vol. 48, p.183.
Tvingstedt, K. and Inganas, O. (2007) ‘Electrode grids for ITO-free’, Adv. Mat., Vol. 19,
pp.2893–2897.
Tvingstedt, K., Andersson, V., Zhang, F. and Inganas, O. (2007) ‘Folded reflective tandem polymer
solar cell doubles efficiency’, Appl. Phys. Lett., Vol. 91, p.123514.
Unni, K.N.N., De Bettignies, R., Seignon, S.D. and Nunzi J-M. (2004) ‘A nonvolatile memory
element based on an organic field effect transistor’, Appl. Phys. Lett., Vol. 85, p.1823.
Westphalen, W., Kreibig, U., Rostalski, J., Lüth, H. and Meissner, D. (2000) ‘Metal cluster
enhanced organic solar cells’, Solar Energy Materials and Solar Cells, Vol. 61, pp.97–105.
Xue, J., Rand, B.P., Uchida, S. and Forrest S.R. (2005) ‘Mixed donor-acceptor molecular
heterojunctions for photovoltaic applications’, II. Device Performance, J. Appl. Phys., Vol. 98,
p.124903.
Xue, J., Uchida, S., Rand, B.P. and Forrest, S.R. (2004) ‘Asymmetric tandem organic photovoltaic
cells with hybrid planar-mixed molecular heterojunctions’, Appl. Phys. Lett., Vol. 85, p.5757.
Yakimov, A., and Forrest, S.R. (2002) ‘High photovoltage multiple-heterojunction organic
solar cells incorporating interfacial metallic nanoclusters’, Journal of Applied Physics,
Vol. 80, No. 9, p.1667.
Yang, L-G., Chen, L., Bai, R., Yang, F., Wang, M. and Chen, H-Z. (2007) ‘Modelling of organic
nanograting heterojunctions for photoelectric conversion’, Solar Energy Materials and Solar
Cells, Vol. 91, pp.1110–1119.
Yu, G. and Heeger, A.J. (1995) ‘Charge separation and photovoltaic conversion in polymer
composites with internal donor/acceptor heterojunctions’, J. Appl. Phys., Vol. 78, p.4510.
Zechner, C., Fath, P., Willeke, G. and Bucher, E. (1998) ‘Two- and three-dimensional optical
carrier generation determination in crystalline silicon solar cells’, Sol. Energy Mater. Solar
Cells, Vol. 51, p.255.
Bibliography
Blom, P.W.M., Mihailetchi, V.D., Koster, L.J.A. and Markov, D.E. (2007) ‘Device physics of
polymer:fullerene bulkheterojunction solar cells’, Adv. Mater., Vol. 19, pp.1551–1566.
Dennler, G., Sariciftci, N.S. and Brabec, C.J. (2007) ‘Conjugated polymer-based organic solar
cells’, Semiconducting Polymers: Chemistry, Physics and Engineering, Vol I, 2nd ed.,
WILEY-VCH Verlag.
Günes, S., Neugebauer, H. and Sariciftci, N.S. (2007) ‘Conjugated polymer-based organic solar’,
Cells Chem. Rev., Vol. 107, pp.1324–1338.
Hoppe, H., Arnold, N., Sariciftci, N.S. and Meissner D. (2003) ‘Modeling the optical absorption
within conjugated polymer/fullerene-based bulk-heterojunction organic solar cells’,
Sol. Energ. Mater. Sol. Cells, Vol. 80, pp.105–113.
Koch, N. (2007) ‘Organic electronic devices and their functional interfaces’, ChemPhysChem,
Vol. 8, No. 10, pp.1438–1455.
Optical properties engineering for Organic Solar Cells 487
Krebs, F.C. and Norrman, K. (2007) ‘Analysis of the failure mechanism for a stable organic
photovoltaic during 10,000 h of testing’, Prog. Photovolt: Res. Appl., Vol. 15, pp.697–712.
Macleod, H.A. (1986) Thin Film Optical Filters, Adam Hilger, London.
Moliton, A. and Nunzi, J-M. (2006) ‘How to model the behaviour of organic photovoltaic cells’,
Polym. Int., Vol. 55, No. 6, pp.583–600.
Pivrikas, A., Sariciftci, N.S., Juska, G. and Osterbacka, R. (2007) ‘A review of charge transport
and recombination in polymer/fullerene organic solar cells’, Prog. Photovolt: Res. Appl.,
Vol. 15, pp.677–696.