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2.008 Polymer
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2.008 spring 2004 S. Kim 2
Materials Plastics
Solid materials
$400 billion shipments, Applications
Plastics 2002 US Name it
metals ceramics Music LPs, CDs
No-sticking TEFLON
thermoplastics thermosetts elastomers Stre-e-e-tching SPANDEX
www.plasticsdatasource.org
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Automotive Plastics and Plastics,
Composites Use Polymers, Macromolecules
Exterior Poly (many) + mer (structural unit)
doors -[C2H4]n- ,poly[ethylene] spaghetti
hoods
fenders H H H H
bumper covers (most cars have soft fascia) C C C C
Interior H H H H
instrument panels, door trim, seats, consoles Metal: single atoms, metallic bond
Engine Ceramic: metallic oxides, ionic bond or dipole
valve covers, intake manifolds, fluid containers, interactions, van der Waals bonds
etc.
(linear)
Crystallinity Cross-linking
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Specific Volume:
Amorphous vs. Crystalline Injection Molding Machine
Tg Tg+60C Tg Tm
(a) (b)
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Packing, holding, cooling Mold opening, part removal
Ejector pins
2.008-spring-2004 S.
Kim2.008 spring 2004 S. Tadmor & Gogos
2.008 spring 2004 S. Kim 15 Kim 16
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Injection Molding Parameters Viscosity
Temperature and Pressure: Function (x,y,z)
Melt Temperature Control
Shear thinning: paints
Through Cylinder(Barrel)
Frictional Heating
Shear Thickening
Rear zone
Viscosity
Newtonian
Front Zone (10F-20F hotter)
Nozzle
Shear Thinning
Shear Rate
20,000 psi
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Pressure Control Clamp force
Pressure Required
Total force = projected area times injection pressure (A X P)
Example,
Part is 10 in by 10 in by 1 in
100 in
2 x 15,000 psi= 1,500,000 lbs = 750 tons (note : 2000
lbs = 1 ton)
10 in
End of filling
Parting line ? 10 in
2.008 spring 2004 S. Kim 21 2.008 spring 2004 S. Kim 22
Warpage or stress in a part can be generated when mold shrinkage Hot mold for less residual stresses (orientation)
varies due to different thickness, leading internal residual stress Low thermal inertia
difference.
Uneven cooling
Even cooling
warpage, twisting, shrinkage defects
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Flow path ratio Injection molding process
window
-Flow path ratio is the ratio between L (the distance between the
gate and the farthest point in the molding dimension) and T (the
thickness of the part) . flash
-When molding large or thin parts, the flow path ratio is calculated Better weld
to determine if molten plastics can fill the mold cavity. Pmax
Poor Degradation
Rule of thumb Good
quality burn
Polyethylene (PE) L/T = 280-100
Polypropylene (PP) L/T = 280-150 Pmin
Polyvinyl chloride (PVC) L/T = 280-70 Low cost shortshot
Polystyrene (PS) L/T = 300-
220 Polycarbonate (PC) L/T = 160-90
Tmin Tmax
Acrylonitrile butadienstylene
(ABS) L/T = 280-120
Polyamide (PA) L/T = 320-200
2.008 spring 2004 S. Kim 25 2.008 spring 2004 S. Kim 26
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Reinforcement
Shrinkage
Thickness increase
chamfered
corners
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Mold Structure Mold Structure - Cavity and core
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Three plate mold Mold Structure: Undercut, Slide core
Gate
A gate is an entrance through
which molten plastics enters the cavity.
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Fan gate, Film gate, Direct gate
Gate Positioning
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Defects Weldline
Molding defects are caused by related and complicated This is a phenomenon where a thin line is created when different flows of
reasons as follows: molten plastics in a mold cavity meet and remain undissolved. It is a boundary
between flows caused by incomplete dissolution of molten plastics. It often
develops around the far edge of the gate.
* Malfunctions of molding machine
Cause
* Inappropriate molding conditions Low temperature of the mold causes incomplete dissolution of the molten
* Flaws in product and mold design plastics.
* Improper Selection of molding material
Solution
Increase injection speed and raise the mold temperature. Lower the molten
plastics temperature and increase the injection pressure. Change the gate
position and the flow of molten plastics. Change the gate position to prevent
development of weldline.
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Warpage Sink marks
This deformation appears when the part is removed from the mold and
pressure is released.
ts
Cause
Uneven shrinkage due to the mold temperature difference (surface ts < t
temperature difference at cavity and core), and the thickness difference in
the part. Injection pressure was too low and insufficient packing.
t
Solution
Take a longer cooling time and lower the ejection speed. Adjust the ejector -Equal cooling from the surface
pin position or enlarge the draft angle. Examine the part thickness or
dimension. Balance cooling lines. Increase packing pressure.
-Secondary flow
-Collapsed surface
Sink Mark
MOLDFLOW
C-Flow
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