CONFIDENTIAL

4541/1
Chemistry
Paper 1
Ogos
2017
1 hours

SIJIL PENDIDIKAN
MAKTAB RENDAH SAINS MARA
2017

CHEMISTRY
KIMIA

Paper 1
Kertas 1

One hour and fifteen minutes

Satu jam dan lima belas minit

DO NOT OPEN THE QUESTION BOOKLET UNTIL BEING TOLD TO DO SO

JANGAN BUKA BUKU SOALAN SEHINGGA DIBERITAHU

1 This question booklet is bilingual.

Kertas soalan ini adalah dalam dwibahasa.

2 Candidates are required to read the information at the last page of this question
booklet.
Calon dikehendaki membaca maklumat di halaman belakang kertas soalan.

This question booklet contains 34 printed pages.

Buku soalan ini mengandungi 34 halaman bercetak.
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1 Which substance exists as an atom?

Bahan manakah wujud sebagai atom?

A Air
Udara
B Steam
Wap air
C Argon
Argon
D Ethane
Etana

2 Diagram 1 shows the set-up of apparatus for an experiment to determine the

empirical formula of magnesium oxide.
Rajah 1 menunjukkan susunan radas bagi satu eksperimen untuk menentukan formula
empirik magnesium oksida.

Lid
Penutup
Crucible
Magnesium Mangkuk pijar
Magnesium

Heat
Panaskan

Diagram 1
Rajah 1

Why the crucible lid is opened once in a while during the experiment?
Mengapakah penutup mangkuk pijar dibuka sekali sekala semasa eksperimen?

A To avoid explosion
Untuk mengelakkan letupan
B To cool the magnesium
Untuk menyejukkan magnesium
C To see what happen inside the crucible
Untuk melihat apa yang berlaku di dalam mangkuk pijar
D To allow oxygen gas to enter the crucible
Untuk membenarkan gas oksigen masuk ke dalam mangkuk pijar

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3 Which anion present in copper(II) sulphate solution?
Anion manakah yang hadir dalam larutan kuprum(II) sulfat?

A SO42-
B Cu2+ , H+
C OH- , SO42-
D Cu2+ , SO42- , H+ , OH-





4 Why are weather balloons filled with helium gas instead of hydrogen gas?
Mengapakah belon kaji cuaca diisi dengan gas helium berbanding gas hidrogen?

A Helium is unreactive
Helium tidak reaktif
B Helium is easily found in air
Helium mudah ditemui dalam udara
C Helium is lighter than hydrogen
Helium lebih ringan daripada hidrogen
D Helium is less dense than hydrogen
Helium kurang tumpat daripada hidrogen





5 Which compound is formed by sharing electrons?
Sebatian manakah yang terbentuk melalui perkongsian elektron?

A Methane, CH4
Metana, CH4
B Sodium oxide, Na2O
Natrium oksida, Na2O
C Lithium chloride, LiCl
Litium klorida, LiCl
D Calcium hydroxide, Ca(OH)2
Kalsium hidroksida, Ca(OH)2

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6 Diagram 2 shows the apparatus set-up of an electrolytic cell.
Rajah 2 menunjukkan susunan radas suatu sel elektrolisis.

Bulb lights up
Mentol menyala

Substance P
Bahan P

Diagram 2
Rajah 2

Which of the following is substance P?

Antara yang berikut, yang manakah bahan P?

A Ethyl ethanoate, CH3COOC2H5

Etil etanoat, CH3COOC2H5
B Glucose solution, C6H12O6
Larutan glukosa, C6H12O6
C Chloromethane, CH3Cl
Klorometana, CH3Cl
D Ethanoic acid, CH3COOH
Asid etanoik, CH3COOH





7 Why ammonia solution is a weak alkali?
Mengapakah larutan ammonia adalah alkali lemah?

A Has high pH value

Mempunyai nilai pH yang tinggi
B Ionises partially in water
Mengion separa dalam air
C Contains a lot of ammonium ions
Mengandungi banyak ion ammonium
D Produces high concentration of hydroxide ions in the water
Menghasilkan kepekatan ion hidroksida yang tinggi di dalam air

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8 Which of the following substances are monoprotic acid?

Antara bahan-bahan berikut,yang manakah merupakan asid monoprotik?
I Hydrochloric acid
Asid hidroklorik
II Sulphuric acid
Asid sulfurik
III Phosphoric acid
Asid fosforik
IV Nitric acid
Asid nitrik

A I and III
I dan III
B I and IV
I dan IV
C II and III
II dan III
D II and IV
II dan IV

9 Diagram 3 shows the apparatus set-up for the preparation of a salt.
Rajah 3 menunjukkan susunan radas bagi penyediaan suatu garam.

Solution A Salt
Larutan A Garam

White
precipitate
formed Solution B
Mendakan putih Larutan B
terhasil

Diagram 3
Rajah 3
Which salt is prepared through this method?
Garam manakah yang disediakan melalui kaedah ini?

A Zinc sulphate
Zink sulfat
B Silver nitrate
Argentum nitrat
C Barium chloride
Barium klorida
D Lead(II) sulphate
Plumbum(II) sulfat

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10 The following are the uses of substance Q in industries.
Maklumat berikut adalah kegunaan bahan Q dalam industri.

To remove the surface oxide layer on metals in

electroplating.
Untuk menanggalkan lapisan oksida pada logam
dalam penyaduran
To produce detergents.
Untuk menghasilkan detergen.
To make paints.
Untuk menghasilkan cat.

What is substance Q?
Apakah bahan Q?

A Nitric acid
Asid nitrik
B Ammonia
Ammonia
C Sulphuric acid
Asid sulfurik
D Ammonium sulphate
Ammonium sulfat

11 Diagram 4 shows a cookware which is coated with teflon or also known as
polytetrafluoroethene, PTFE.
What is the monomer of teflon?
Rajah 4 menunjukkan peralatan memasak yang disaluti dengan teflon atau dikenali juga
sebagai politetrafloroetena, PTFE.
Apakah monomer bagi teflon?

Diagram 4
Rajah 4
A Ethene
Etena
B Fluoroethene
Floroetena
C Tetrafluoroethane
Tetrafloroetana
D Tetrafluoroethene
Tetrafloroetena

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12 Which statement is true about both methanol and ethanol?

Antara pernyataan berikut yang manakah benar mengenai metanol dan etanol?

A Both have different functional groups

Kedua-duanya mempunyai kumpulan berfungsi berbeza
B Both show similar physical properties
Kedua-duanya menunjukkan sifat fizikal yang sama
C Both show different chemical properties
Kedua-duanya menunjukkan sifat kimia yang berbeza
D Both have same general formula
Kedua-duanya mempunyai formula am yang sama


13 Which of the following is not a correct unit for the rate of reaction?
Unit manakah yang tidak betul untuk kadar tindakbalas?

A g s-1
B g dm-3
C mol s-1
D cm3 min-1

14 Diagram 5 shows a fruit that contains compound R which gives its fruity smell.
Rajah 5 menunjukkan buah yang mengandungi sebatian R yang memberikannya bau
buah-buahan.

Diagram 5
Rajah 5

What is the homologous series of compound R?

Apakah siri homolog bagi sebatian R?

A Ester
Ester
B Alkene
Alkena
C Alcohol
Alkohol
D Carboxylic acid
Asid karboksilik

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15 Which of the following is a reduction process?
Antara berikut yang manakah proses penurunan?

A A copper(II) ion gains two electrons

Ion kuprum(II) menerima dua elektron
B Hydrogen sulphide loses its hydrogen
Hidrogen sulfida kehilangan hidrogen
C Iron(II) ion converted to iron(III) ion
Ion ferum(II) bertukar kepada ion ferum(III)
D A magnesium atom loses two electrons
Atom magnesium kehilangan dua elektron





16 Aluminium atom undergoes oxidation to form ion by donating three electrons.
What is the oxidation number of aluminium in the ion formed?
Atom aluminium mengalami pengoksidaan membentuk ion dengan menderma tiga
elektron.
Apakah nombor pengoksidaan aluminium bagi ion yang terbentuk?

A -3
B 0
C +2
D +3





17 Which of the following process or reaction absorbs heat?
Antara proses atau tindak balas berikut, yang manakah menyerap haba?

A Boiling of water
Pendidihan air
B Freezing of liquid sulphur
Pembekuan cecair sulfur
C Reaction between hydrogen and nitrogen
Tindabalas antara hidrogen dan nitrogen
D Reaction between zinc and hydrochloric acid
Tindak balas antara zink dan asid hidroklorik

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18 Diagram 6 shows the part of labelling on the food packaging.
Rajah 6 menunjukkan bahagian berlabel pada pembungkus makanan.

MFG: 060317
EXP : 060319

Diagram 6
Rajah 6

What is the type of food additive added to make sure that the food last longer until
the expiry date?
Apakah jenis bahan tambah makanan yang ditambah untuk memastikan makanan
tersebut dapat bertahan sehingga tarikh luput?

A Stabilizers
Penstabil
B Flavourings
Perisa
C Antioxidants
Antioksidan
D Preservatives
Pengawet

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19 Diagram 7 shows the apparatus set-up to determine the heat of precipitation for
magnesium carbonate, MgCO3.
Rajah 7 menunjukkan susunan radas bagi menentukan haba pemendakan bagi
magnesium karbonat, MgCO3.

Magnesium nitrate, Sodium carbonate, Magnesium carbonate,

Mg(NO3)2 solution Na2CO3 solution MgCO3 solid
Larutan magnesium Larutan natrium karbonat, Pepejal magnesium
nitrat, Mg(NO3)2 Na2CO3 karbonat, MgCO3

Diagram 7
Rajah 7

Which of the following is correct about the reaction?

Antara yang berikut, yang manakah betul bagi tindak balas tersebut?

A Heat is absorbed from the surroundings

Haba diserap dari persekitaran
B Heat is released and the container become hot
Haba dibebaskan dan bekas menjadi panas
C Total energy content of the reactant is higher than total energy content of
the product
Jumlah kandungan tenaga bahan tindak balas adalah lebih tinggi daripada
jumlah kandungan tenaga hasil tindak balas
D Heat absorbed during the broken of the bond is lower than heat released
during the formation of bond
Haba diserap semasa pemutusan ikatan adalah lebih rendah daripada haba
dibebaskan semasa pembentukan ikatan

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20 Which of the following is correct about properties of isotopes?

Antara berikut, yang manakah betul tentang ciri-ciri isotop?

A Have different chemical properties

Mempunyai sifat kimia yang berbeza
B Have different physical properties
Mempunyai sifat fizikal yang berbeza
C Have the same number of neutrons in an atom
Mempunyai bilangan neutron yang sama di dalam atom
D Have the same nucleon number
Mempunyai nombor nukleon yang sama

21 The melting point of substance W is -5 oC and its boiling point is 78 oC.

What is the physical state of substance W at -8 oC and 80 oC?
Takat lebur bahan W adalah -5 oC dan takat didih adalah 78 oC.
Apakah keadaan fizikal bahan W pada -8 oC dan 80 oC?

At -8 oC At 80 oC
Pada -8 oC Pada 80 oC
A Solid Gas
Pepejal Gas
B Solid Liquid
Pepejal Cecair
C Liquid Gas
Cecair Gas
D Liquid Liquid
Cecair Cecair

22 The following equation represents a chemical reaction involving gas J and L.

Persamaan berikut mewakili tindak balas kimia melibatkan gas J dan L.

J2 (g) + L2 (g) 2 JL (g)

What is the ratio of volume of product to volume of reactants at the same

temperature and pressure?
Apakah nisbah isipadu hasil tindak balas kepada isipadu bahan tindak balas pada suhu
dan tekanan yang sama?

A 1:2
B 1:1
C 2:1
D 4:2

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23 Table 1 shows the result when three oxides of elements in period 3 are added to
potassium hydroxide solution, KOH and hydrochloric acid, HCl.
Jadual 1 menunjukkan keputusan apabila tiga oksida bagi unsur-unsur dalam Kala 3
ditambahkan dengan larutan kalium hidroksida, KOH dan asid hidroklorik, HCl.

Oxide Added to KOH Added to HCl

Oksida Ditambah dengan KOH Ditambah dengan HCl
Oxide of P Reaction occurs Reaction occurs
Oksida P Tindak balas berlaku Tindak balas berlaku
Oxide of Q No reaction Reaction occurs
Oksida Q Tiada tindak balas Tindak balas berlaku
Oxide of R Reaction occurs No reaction
Oksida R Tindak balas berlaku Tiada tindak balas

Table 1
Jadual 1

Arrange the elements P, Q, R in ascending order of their electronegativity.

Susun unsur P, Q, R dalam tertib menaik keeletronegatifan.

A P, Q, R
B R, P, Q
C Q, P, R
D Q, R, P

24 Atom G has 6 electrons while atom L has 17 electrons.

What is the chemical formula of the compound formed between G and L?
Atom G mempunyai 6 elektron manakala atom L mempunyai 17 elektron.
Apakah formula kimia bagi sebatian yang terbentuk antara G dan L?

A GL2
B GL4
C G2 L
D G4 L

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25 Diagram 8 shows an incomplete apparatus set-up of an electrolytic cell.

Rajah 8 menunjukkan susunan radas yang tidak lengkap bagi suatu sel elektrolisis.

0.5 mol dm-3

hydrochloric acid
0.5 mol dm-3
asid hidroklorik

Diagram 8
Rajah 8

Which of the following shows the correct observation at T when the solution has
been electrolyzed for 10 minutes?
Antara berikut, yang manakah menunjukkan pemerhatian yang betul pada T apabila
larutan dielektrolisiskan selama 10 minit?

A B C D

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26 Diagram 9 shows the electron arrangement of magnesium ion with nucleon

number 24.
Rajah 9 menunjukkan susunan elektron ion magnesium dengan nombor nukleon 24.

2+

Diagram 9
Rajah 9

Which of the following shows the electron arrangement and the number of
neutrons in magnesium atom?
Antara yang berikut, yang manakah menunjukkan susunan elektron dan bilangan
neutron dalam atom magnesium?

Electron arrangement Number of neutrons

Susunan elektron Bilangan neutron
A 2.8.2 12
B 2.8.2 24
C 2.8 12
D 2.8 24

27 The pH value of 0.1 mol dm-3 of acid U is 1.

Which statement is true about acid U?
Nilai pH bagi asid U 0.1 mol dm-3 adalah 1.
Pernyataan manakah adalah benar tentang asid U?

A Slightly soluble in water

Larut sedikit dalam air
B Reacts only with a weak alkali
Hanya bertindak balas dengan alkali lemah
C The degree of ionization in water is high
Darjah pengionan dalam air adalah tinggi
D Has a low concentration of hydrogen ions
Mempunyai kepekatan ion hidrogen yang rendah

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28 Diagram 10 shows four processes involving chromium(II) oxide, CrO.

Rajah 10 menunjukkan empat proses yang melibatkan kromium(II) oksida, CrO.

Diagram 10
Rajah 10

Which of the following statements are correct about the processes undergoes by
chromium(II) oxide?
Antara penyataan berikut, yang manakah betul mengenai proses-proses yang dilalui oleh
kromium(II) oksida?

I Chromium(II) oxide undergoes reduction in process M

Kromium(II) oksida mengalami penurunan dalam proses M
II Chromium(II) oxide undergoes oxidation in process K
Kromium(II) oksida mengalami pengoksidaan dalam proses K
III Oxidation number of chromium increases from +2 to +6 in process N
Nombor pengoksidaan kromium meningkat dari +2 kepada +6 dalam
proses N
IV Oxidation number of chromium decreases from +2 to 0 in process L
Nombor pengoksidaan kromium menurun dari +2 kepada 0 dalam
proses L

A I and II
I dan II
B I and III
I dan III
C II and IV
II dan IV
D III and IV
III dan IV

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29 Table 2 shows the pH value when ammonia is dissolved in two different solvents.
Jadual 2 menunjukkan nilai pH apabila ammonia dilarutkan dalam dua pelarut berbeza.

Solvent pH value
Set Pelarut Nilai pH
Ammonia in solvent E
I Ammonia dalam pelarut E 7
Ammonia in solvent F
II Ammonia dalam pelarut F 11

Table 2
Jadual 2

Which statement explains the difference in pH value?

Pernyataan manakah menerangkan perbezaan nilai pH?

A Ammonia molecules ionised in Set II

Molekul-molekul ammonia mengion dalam Set II
B Ammonia molecules dissolved in solvent E
Moleku-molekul ammonia melarut dalam pelarut E
C Solvent E is water and solvent F is methylbenzene
Pelarut E ialah air dan pelarut F ialah metilbenzena
D Concentration of hydroxide ion in Set I is higher
Kepekatan ion hidroksida dalam Set I adalah lebih tinggi

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30 Diagram 11 shows a device V made up of stainless steel and ceramics.

Rajah 11 menunjukkan alat V yang diperbuat daripada keluli tahan karat dan seramik.

Diagram 11
Rajah 11

What are the important properties of the materials used in making device V?
Apakah ciri-ciri penting bahan-bahan yang digunakan dalam pembuatan alat V?

I High heat resistant

Tahan haba yang tinggi
II Has shiny surface
Mempunyai permukaan berkilat
III Resistant to rusting
Tahan karat
IV Strong and hard
Kuat dan keras

A I and III
I dan III
B I and IV
I dan IV
C II and III
II dan III
D II and IV
II dan IV

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31 Diagram 12 shows the uses of calcium sulphate hemihydrate salt which has known
as plaster of Paris in medicinal field.
Rajah 12 menunjukkan kegunaan garam kalsium sulfat hemihidrat dikenali sebagai
plaster Paris dalam bidang perubatan.

Diagram 12
Rajah 12

Which substances can be used to produce this salt?

Bahan manakah boleh digunakan untuk menghasilkan garam ini?

A Calcium + sulphuric acid

Kalsium + asid sulfurik
B Calcium oxide + sodium sulphate
Kalsium oksida + natrium sulfat
C Calcium nitrate + potassium sulphate
Kalsium nitrat + kalium sulfat
D Calcium carbonate + magnesium sulphate
Kalsium karbonat + magnesium sulfat

32 Substance U is produced in industrial process. It can react with barium hydroxide

solution to form a white pigment used in paint.
Which of the following is the equation involved in the manufacture of substance U?
Bahan U dihasilkan dalam proses industri. Ianya boleh bertindak balas dengan larutan barium
hidroksida untuk menghasilkan pigmen putih yang digunakan dalam cat.
Antara persamaan berikut, yang manakah terlibat dalam penghasilan bahan U?

A N2 + 3 H2 2 NH3
B 2 NH3 + H2SO4 (NH4)2SO4
C H2S2O7 + H2O 2 H2SO4
D Ba(OH)2 + H2SO4 BaSO4 + 2 H2O

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33 Diagram 13 shows the apparatus set-up used to determine the rate of reaction.
Rajah 13 menunjukkan susunan radas bagi menentukan kadar tindak balas.

Gas
Gas

Reaction mixture
Campuran tindak
balas

Diagram 13
Rajah 13

Which of the following chemical reaction is not suitable to determine the rate of
reaction by using the apparatus set-up?
Antara tindak balas berikut, yang manakah tidak sesuai bagi penentuan kadar tindak
balas menggunakan susunan radas tersebut?

A CaCO3 + 2 HCl CaCl2 + H2O + CO2

B NaHCO3 + HNO3 NaNO3 + H2O + CO2
C Mg + 2 CH3COOH Mg(CH3COO)2 + H2
D ZnO + H2SO4 ZnSO4 + H2O

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34 Diagram 14 shows two processes involving compound W.

Rajah 14 menunjukkan dua proses melibatkan sebatian W.

Compound U Compound V
Sebatian U Sebatian V
Decolourised Has carboxyl
brown colour of group
bromine water Mempunyai
Melunturkan kumpulan karboksil
warna perang air Process I Process II Turns blue litmus
bromin Proses I Proses II paper to red
Undergoes Compound W Menukarkan kertas
combustion to Sebatian W litmus biru kepada
produce carbon merah
dioxide and Vinegar smell
water Menghasilkan bau
Mengalami cuka
pembakaran bagi
menghasilkan
karbon dioksida
dan air

Diagram 14
Rajah 14

Which structural formula represents compound W?

Formula struktur yang manakah yang mewakili sebatian W?

A H H

H C = C H

B H H

H C C OH

H H

C H O

H C C OH

D H H H

H C C C OH

H H H

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35 Which of the following diagram shows an endothermic reaction?

Antara rajah berikut, yang manakah menunjukkan suatu tindak balas endotermik?

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36 Diagram 15 shows a structural formula of ethyl butanoate which found in

pineapple.
Rajah 15 menunjukkan formula struktur etil butanoat yang terdapat di dalam nenas.

H H H O H H

H C C C C O C C H

H H H H H

Diagram 15
Rajah 15

0.004 mol of ethyl butanoate has a mass of 0.464 g.

Which pair of information is correct about ethyl butanoate?
0.004 mol etil butanoat mempunyai jisim 0.464 g.
Antara pasangan maklumat berikut, yang manakah benar tentang etil butanoat?

Relative molecular mass Empirical formula

Jisim molekul relatif Formula empirik
A 86 C6H12O2
B 58 C3H6O
C 116 C3H6O
D 116 C6H12O2

37 The equation represents the reduction reaction of acidified potassium

manganate(VII) solution.
Persamaan mewakili tindak balas penurunan bagi larutan kalium manganat(VII) berasid.

MnO4- + x H+ + y e- Mn2+ + z H2O

What are the values of x, y and z?

Apakah nilai bagi x, y and z?

x y z
A 16 10 8
B 16 5 4
C 8 5 4
D 8 3 2

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38 Table 3 shows the nucleon number and the number of neutrons for atoms of
elements S, T, U and V.
Jadual 3 menunjukkan nombor nukleon dan bilangan neutron bagi atom unsur S, T, U dan
V.

Atom Nucleon number Number of neutrons

Atom Nombor nukleon Bilangan neutron

S 1 0
T 16 8
U 35 18
V 40 22

Table 3
Jadual 3

Which element will reacts with an alkali metal to produce a white solid that
dissolved in water to form a colourless solution with pH 7.
Unsur manakah yang bertindak balas dengan logam alkali untuk menghasilkan pepejal
putih yang larut dalam air membentuk larutan tidak berwarna dengan pH 7.

A V
B U
C T
D S

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39 Diagram 16 shows a flow chart for the formation of compound Q from the reaction
between element P and element R.
Rajah 16 menunjukkan carta alir pembentukan sebatian Q daripada tindak balas antara
unsur P dan unsur R..

Element P + Element R
Unsur P Unsur R

Compound Q
Sebatian Q

+ water
air

Can conduct electicity

Boleh mengalirkan elektrik
Change the red litmus paper to blue
Menukarkan kertas litmus merah kepada biru

Diagram 16
Rajah 16

Which of the following is correct about element P, element R and compound Q?

Antara yang berikut, yang manakah betul bagi unsur P, unsur R dan sebatian Q?

Electron arrangement
Susunan elektron Type of bond in compound Q
Jenis ikatan dalam sebatian Q
Element P Element R
Unsur P Unsur R
Covalent
A 1 2.8.7 Kovalen
Ionic
B 2.8.8.1 2.6 Ion
Ionic
C 2.8.1 2.8.7 Ion
Covalent
D 2.4 2.6 Kovalen

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40 Sulphuric acid is one of the important chemical used in tin mining. It is also a by-
product of the mine when mixed with water to form acidic waste. In a titration, the
chemist found that 25 cm3 of 0.2 mol dm-3 potassium hydroxide solution
neutralised 25 cm3 of acidic waste.
What is the concentration of the acidic waste?
Asid sulfurik adalah salah satu bahan kimia penting yang digunakan dalam perlombongan
timah. Ia juga adalah bahan sampingan perlombongan apabila bercampur dengan air
membentuk air kumbahan berasid. Dalam suatu pentitratan, seorang ahli kimia mendapati
25 cm3 larutan kalium hidroksida 0.2 mol dm-3 meneutralkan 25 cm3 air kumbahan
berasid.
Apakah kepekatan air kumbahan berasid tersebut?

A 0.1 mol dm-3

B 0.2 mol dm-3
C 1.0 mol dm-3
D 2.0 mol dm-3

41 Diagram 17 shows the apparatus set up to electroplate iron spoon with copper.
Rajah 17 menunjukkan susunan radas bagi penyaduran sudu besi dengan kuprum.

Copper
Kuprum
Iron spoon
Sudu besi
Copper (II) sulphate
solution
Larutan kuprum(II)
sulfat
Diagram 17
Rajah 17

After one hour, it is found that the iron spoon is not electroplated.
What should be done to ensure electroplating takes place?
Selepas satu jam, didapati sudu besi tidak disadurkan.
Apakah yang perlu dilakukan untuk memastikan penyaduran berlaku?

A Use a bigger iron spoon

Gunakan sudu besi yang besar
B Interchange the terminal in the cell
Saling tukar terminal pada sel
C Use copper(II) nitrate solution as electrolyte
Gunakan larutan kuprum(II) nitrat sebagai elektrolit
D Increase the concentration of copper(II) sulphate solution
Tambah kepekatan larutan kuprum(II) sulfat

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42 Diagram 18 shows how Ali prepares a syrup solution during the activity week at
his school.
Rajah 18 menunjukkan bagaimana Ali menyediakan larutan sirap semasa minggu aktiviti
di sekolahnya.

2 litre of water
2 liter air
2 kg of sugar
2 kg gula

Diagram 18
Rajah 18

By using the prepared syrup solution, Ali has to make a new syrup solution to be
given to six groups of students. Each group must receive 0.5 litre of solution.
What is the concentration of the syrup solution received by each group?
[1 litre = 1 dm3, relative molecular mass of sugar = 342]

Dengan menggunakan larutan sirap yang disediakan, Ali perlu menyediakan larutan
sirap yang baru untuk diedarkan kepada enam kumpulan pelajar. Setiap kumpulan mesti
menerima 0.5 liter larutan.
Apakah kepekatan larutan sirap yang diterima oleh setiap kumpulan?
[1 liter = 1 dm3, jisim molekul relatif gula = 342]

A 0.487 mol dm-3

B 1.949 mol dm-3
C 2.924 mol dm-3
D 11.696 mo ldm-3

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43 The following equation shows the displacement of metal Q from its salt solution.
Persamaan berikut menunjukkan penyesaran logam Q daripada larutan garamnya.

P + Q(NO3)2 P(NO3)2 + Q

What are metal P and metal Q?

Apakah logam P dan logam Q?

P Q
A Iron Zinc
Ferum Zink
B Iron Magnesium
Ferum Magnesium
C Zinc Magnesium
Zink Magnesium
D Zinc Iron
Zink Ferum

44 The following chemical equation shows the reaction between copper(II) oxide and
nitric acid.
Persamaan kimia berikut menunjukkan tindak balas antara kuprum(II) oksida dan asid
nitrik.

CuO + 2 HNO3 Cu(NO3)2 + 2 H2O

If 10 g of copper(II) oxide powder is added to 50 cm3 of 2 mol dm-3 nitric acid,

calculate the mass of unreacted copper(II) oxide.
[Relative formula mass of CuO = 80]
Sekiranya 10 g serbuk kuprum(II) oksida ditambahkan kepada 50 cm3 larutan asid nitrik
2 mol dm-3, hitung jisim kuprum(II) oksida yang tidak bertindak balas.
[Jisim formula relatif CuO = 80]

A 2g
B 4g
C 5g
D 6g

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45 Table 4 shows two sets of reaction between metals and salt solutions.
Jadual 4 menunjukkan dua set tindak balas antara logam dan larutan garam.

Set Substances Observation

Set Bahan-bahan Pemerhatian
Excess magnesium and
copper(II) sulphate solution Blue solution turns to colourless
1 Magnesium berlebihan dan Larutan biru bertukar kepada tidak
larutan kuprum(II) sulfat berwarna

Excess copper and silver

nitrate solution Colourless solution turns to blue
2 Kuprum berlebihan dan Larutan tidak berwarna bertukar
larutan argentum nitrat kepada biru

Table 4
Jadual 4

Which of the following statements are true about the confirmatory test of the ions
present in solution formed in both set?
Antara penyataan-penyataan berikut yang manakah benar tentang kehadiran ion-ion
dalam larutan yang terbentuk dalam kedua-dua set?

I White precipitate is formed and insoluble when ammonia solution is added in

excess to the solution formed in Set I
Mendakan putih terbentuk dan tidak larut apabila larutan ammonia berlebihan
ditambah kepada larutan dalam Set I
II Blue precipitate is formed and insoluble when excess ammonia solution is
added to the solution formed in Set II
Mendakan biru terbentuk dan tidak larut apabila larutan ammonia berlebihan
ditambah kepada larutan dalam Set II
III White precipitate is formed when lead(II) nitrate solution is added to the
solution formed in Set I
Mendakan putih terbentuk apabila larutan plumbum(II) nitrat ditambah kepada
larutan dalam Set I
IV White precipitate is formed when sodium chloride solution is added to the
solution formed in Set II
Mendakan putih terbentuk apabila larutan natrium klorida ditambah kepada larutan
dalam Set II
A I and III
I dan III
B I and IV
I dan IV
C II and III
II and III
D II and IV
II dan IV

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46 Diagram 19 shows the energy profile diagram for a reaction.

Rajah 19 menunjukkan gambar rajah profil tenaga bagi suatu tindak balas.

S + T V + W

Energy
Tenaga

S + T
150 kJ
95 kJ
V + W

Diagram 19
Rajah 19

What is the value of the activation energy for this reaction?

Apakah nilai tenaga pengaktifan untuk tindak balas ini?

A 150 kJ
B 95 kJ
C 55 kJ
D 15 kJ

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47 Table 5 shows the condition of reactants used in Experiment I, II and III.

Jadual 5 menunjukkan keadaan bahan tindak balas yang digunakan dalam
Eksperimen I, II dan III.
Experiment Condition of reactants
Eksperimen Keadaan bahan tindak balas

Excess Mg powder + 50 cm3 of 2.0 mol dm-3 HCl solution

I Serbuk Mg berlebihan + 50 cm3 larutan HCl 2.0 mol dm-3

Excess Mg powder + 50 cm3 of 2.0 mol dm-3 HCl solution and

copper(II) sulphate solution
II Serbuk Mg berlebihan + 50 cm3 larutan HCl 2.0 mol dm-3 dan
larutan kuprum(II) sulfat

Condition W
III Keadaan W

Table 5
Jadual 5

Graph 1 shows the result of the experiments.

Graf 1 menunjukkan keputusan eksperimen tersebut.

Graph 1
Graf 1
What is condition W used in Experiment III to obtain the curve III as shown in
Graph 1?
Apakah keadaan W yang digunakan dalam Eksperimen III bagi memperoleh lengkung
III seperti yang ditunjukkan dalam Graf 1?
A Excess Mg powder + 100 cm3 of 2.0 mol dm-3 HCl solution
Serbuk Mg berlebihan + 100 cm3 larutan HCl 2.0 mol dm-3
B Excess Mg powder + 25 cm3 of 4.0 mol dm-3 HCl solution
Serbuk Mg berlebihan + 25 cm3 larutan HCl 4.0 mol dm-3
C Excess Mg powder + 25 cm3 of 2.0 mol dm-3 H2SO4 solution
Serbuk Mg berlebihan + 25 cm3 larutan H2SO4 2.0 mol dm-3
D Excess Mg powder + 50 cm3 of 2.0 mol dm-3 H2SO4 solution
Serbuk Mg berlebihan + 50 cm3 larutan H2SO4 2.0 mol dm-3

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48 The following chemical equation shows a combustion reaction of propane, C3H8.

Persamaan kimia berikut menunjukkan tindak balas pembakaran propana, C3H8.

C3H8 + 5O2 3CO2 + 4H2O

What is the mass of propane needed to produce 550 cm3 of carbon dioxide gas at
room condition?
[ Relative atomic mass: C = 12, H = 1]
[Molar volume of gas at room condition = 24 dm3 mol-1]
Apakah jisim propana yang diperlukan bagi menghasilkan 550 cm3 gas karbon dioksida
pada keadaan bilik?
[Jisim relatif atom C = 12, H = 1]
[Isipadu molar gas pada keadaan bilik = 24 dm3 mol-1]

A 336.112 g
B 22.917 g
C 1.008 g
D 0.336 g

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49 Diagram 20 shows a type of chemical cell.

Rajah 20 menunjukkan sejenis sel kimia.

MnO2 cathode
Katod MnO2
Zn-KOH paste
Steel case (anode)
Bekas keluli Pasta ZnKOH
(anode)

Brass current
collector
Loyang pengumpul
arus

Diagram 20
Rajah 20

Electricity is generated when the following reaction occurs:

Elektrik dihasilkan apabila tindak balas berikut berlaku:

Zn + 2 MnO2 ZnO + Mn2O3

Which of the following is the correct change in the oxidation number of zinc and
manganese?
Antara yang berikut, yang manakah betul tentang perubahan nombor pengoksidaan zink
dan mangan?

Change in oxidation Change in oxidation

number of zinc number of manganese
Perubahan nombor Perubahan nombor
pengoksidaan zink pengoksidaan mangan
A +2 to 0 +2 to +6
B +2 to 0 +2 to +3
C 0 to +2 +4 to +3
D 0 to +2 +4 to +6

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50 Diagram 21 shows the apparatus set-up for the reaction between 50 cm3
of 1.0 mol dm-3 copper(II) sulphate solution with excess magnesium powder.
Rajah 21 menunjukkan susunan radas bagi tindak balas antara 50 cm3 larutan kuprum(II)
sulfat 1.0 mol dm-3 dengan serbuk magnesium berlebihan.

Magnesium powder
Serbuk magnesium

50 cm3 of 1.0 mol dm-3

copper(II) sulphate solution
50 cm3 larutan kuprum(II) sulfat
1.0 mol dm-3
Diagram 21
Rajah 21

105 kJ of heat is released when 1 mol of the metal is displaced.

What is the temperature change of the mixture?
[Specific heat capacity of a solution = 4.2 Jg-1oC-1, density of solution = 1g cm-3]
105 kJ haba dibebaskan apabila 1 mol logam disesarkan.
Berapakah perubahan suhu bagi campuran itu?
[Muatan haba tentu larutan = 4.2 Jg-1oC-1, ketumpatan larutan = 1g cm-3]

A 2.5 oC
B 5.0 oC
C 12.5 oC
D 25.0 oC

END OF QUESTION PAPER

KERTAS SOALAN TAMAT

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INFORMATION FOR CANDIDATES

MAKLUMAT UNTUK CALON

1. This question paper consists of 50 questions.

Kertas soalan ini mengandungi 50 soalan.

2. Answer all questions.

Jawab semua soalan.

3. Answer each question by blackening the correct space on the answer sheet.
Jawab setiap soalan dengan menghitamkan ruangan yang betul pada kertas
jawapan.

4. Blacken only one space for each question.

Hitamkan satu ruangan sahaja pada setiap soalan.

5. If you wish to change your answer, erase the blackened mark that you have made.
Then blacken the new answer.
Sekiranya anda hendak menukar jawapan, padamkan tanda yang telah dibuat.
Kemudian hitamkan jawapan yang baru.

6. The diagrams in the questions provided are not drawn to scale unless stated.
Rajah yang mengiringi soalan tidak dilukiskan mengikut skala kecuali dinyatakan.

7. You may use a scientific calculator.

Anda dibenarkan menggunakan kalkulator saintifik.

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