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Refrigerants: Desirable Properties of A Refrigerant
Refrigerants: Desirable Properties of A Refrigerant
2. Low condensing pressure (to avoid heavy machine plant scantling and
reduce the leakage risk)
4. Low specific volume in vapour state (reduces size and increases efficiency)
9. No action with oil ( the fact that most refrigerants are miscible may be
advantageous e.e. the removal of oil films, lowering pour points etc,
provided separators are fitted
The production of R12 and R11 has now stopped under the Montreal Protocol
and EU regulation on ozone depleting gasses. A short term solution has been conversion
to HCFC's such as R22 (HCFC's have an Ozone Depletion Rate {ODP} 2-15% of CFC's)
but this refrigerant also has a harmful effect on the environment, although far less
damaging than R12. HCFC's are also targeted for eventual production phase out as
controlled substances, with usage totally banned by the EU in new equipment rated at
150kW and over from the 1st Jan 2000. In some countries such as Germany and
Sweden tighter restrictions are in force.
New refrigerants such as R134a and R404A, which are HFC's may offer a
longer term solution against harmful emissions. They contain no chlorine atoms and thus
do not attack the ozone layer but they are greenhouse gasses and may be subject to
future legislation.
An uncertainty over the long term future of HFC's has led to growing interest
in old natural refrigerants such as ammonia and carbon dioxide or hydrocarbons such as
propane and iso-butane. Using the refrigerants, however, dictates more stringent safety
measures which are being drafted by the appropriate classification societies.
The naming of freon (or Arcton) refrigerants comes from the constituents.
For R12, formed by reacting methane with flourine and chlorine. This forms a molecule
containing 1 carbon atom, 2 flourine atoms and 2 chlorine atoms
Number of Carbon atoms number of hydrogen atoms
number of flourine atoms
minus 1 plus one
0 (1-1) 1 (0+1) 2
For R22, again formed by reacting methane with flourine and chlorine. This forms a molecule
containing 1 carbon atom, 1 hydrogen atom and 2 chlorine atom
0 2 2
Refrigerant 12
R12 is halogenated hydrocarbon derived from methane (CH4) with the hydrogen being
displaced by chlorine and fluorine. The resulting compound is Dichlorodifluoromethane
(CCl2F2) also known as Freon 12
R12 escaping under pressure can cause skin damage on contact. It is non-
irritant and not considered flammable.
Working pressures and temperatures are moderate and the high critical
temperature (112oC) is well above the working range.
Methyl Chloride
Refrigerant 11
Refrigerant 13
CClF3
Refrigerant 22
Is suitable for a lower temperature range than R12 because the pressure on the
evaporator side of the system is higher than atmospheric at low temperatures thus
reducing the risk of drawing air into the system. Its performance is better than R12
approaching that of ammonia.
The chemical and other properties are similar to R12 except that it is not
miscible with oil over the whole temperature range. The compound is
Chlorodifloromethane (CHClF2)
Refrigernat 113
CCl2F/CClF2
Refrigerant 502
Composed of 48.8% R22 and 51.2% R115 (C2ClF5). It is particularly suited for use with
hermetic compressors.
Carbonic anhydride
a suggested replacement for R22, has been used in shore based air-con and refrigeration
installations for the past few years and could replace R22 in the reefer market without
technical problems.
) It is very comparable in blend to R502 which has been in use for several decades.
another blend but has a very high glide of 6-7oC ( the difference between the boiling
points of the blended components). Its efficiency has some attraction for the reefer
market, particularly with regard to its performance in cooling down bananas when
chillers are expected to operate at their maximum capacity. The problem today is that
R407c has only been used in tests and offers little, if any, industrial experience.
One component of the blend is R32,it is expensive and will continue to be for
some time and also introduces problems with regard to lubrication. Maintenance could
present another difficulty, calling for skilled personnel in handling the blends.
Refrigerant 407d
A chlorine free replacement for R12 in reefer container systems, is claimed to be 20%
more efficient than R134a and able to operate at box temperatures as low as -25oC
Refrigerant 410a
Does not have a high degree of glide, the blend facilitating a reduction in swept volume
of compressor units. The main disadvantage is that it requires a 50% higher working
pressure than R22, although compressor and plant size is reduced.. The availability of
compressors for this refrigerant is thus limited, increased safety precautions are
necessary due to this increased pressure.
The blend contains R32 giving the same cost drawback as for R407c.
Does not have a high degree of glide, the blend facilitating a reduction in swept volume
of compressor units. The main disadvantage is that it requires a 50% higher working
pressure than R22, although compressor and plant size is reduced.. The availability of
compressors for this refrigerant is thus limited, increased safety precautions are
necessary due to this increased pressure.
The blend contains R32 giving the same cost drawback as for R407c.
SUVA 9100
Is a near azeotropic mix of HFC 32 and HFC 125. DuPont has recently changed its mix
from 45/55 R32/R125 to 50/50 simplifying the HCFC replacement process.
Bar -0.5 0 1 2 4 6 8 10 12 14 16 18 20
R12 -46 -30 -12 -1 17 28 39 48 56 63 68 73 78
R22 -51 -41 -24 -14 0 11 20 28 35 41 46 51 55
R502 -57 -46 -28 -19 -4 7 17 24 31 38 43 47 51